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At least 775 records · Page 43

Importance of Cross-redistribution in Scattering Polarization of Spectral Lines: The Cases of {sup 3}P−{sup 3}S Triplets of Mg i and Ca i

Scattering on a multi-level atomic system has dominant contributions from resonance and Raman scattering. While initial and final levels are the same for resonance scattering, they are different for Raman scattering. The frequency redistribution for resonance scattering is described by the usual partial frequency redistribution functions of Hummer, while that for Raman scattering is described by cross-redistribution (XRD) function. In the present paper, we investigate the importance of XRD on linear polarization profiles of {sup 3}P−{sup 3}S triplets of Mg i and Ca i formed in an isothermal one-dimensional atmosphere. We show that XRD produces significant effects on the linear polarization profiles when the wavelength separations between the line components of the multiplet are small, like in the cases of Mg i b and Ca i triplets.

79 ASTRONOMY AND ASTROPHYSICS↗

Nonlinear absorption of short intense laser pulse in multispecies plasma

In the present paper, the detailed investigation concerning the effect of inclusion of heavy negative ions into the finite background plasma on the laser absorption has been carried out by employing particle-in-cell simulation method. For this purpose, in this configuration, the laser energy absorption relying on the nonlinear phenomena such as phase-mixing, wave-breaking, and scattering has been studied in the Raman-Brillouin regime. It is shown that the inclusion of heavy negative ions suppresses the scattering while increases the phase-mixing time. Moreover, it is illustrated that this inclusion can increase the laser absorption in finite plasma environment, after saturation. The obtained results are expected to be relevant to the experiments on the mass spectrometry with laser desorption techniques as well as on the laser-plasma interaction with application to particles acceleration.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Raman and AFM study of gamma irradiated plastic bottle sheets

In this investigation, the effects of gamma irradiation on the structural properties of plastic bottle sheet are studied. The Plastic sheets were exposed with 1.25MeV {sup 60}Co gamma rays source at various dose levels within the range from 0-670 kGy. The induced modifications were followed by micro-Raman and atomic force microscopy (AFM). The Raman spectrum shows the decrease in Raman intensity and formation of unsaturated bonds with an increase in the gamma dose. AFM image displays rough surface morphology after irradiation. The detailed Raman analysis of plastic bottle sheets is presented here, and the results are correlated with the AFM observations.

36 MATERIALS SCIENCE↗

Structural and optical investigation of Te-based chalcogenide thin films

We report the structural and optical properties of thermally evaporated Bi{sub 2}Te{sub 3}, In{sub 2}Te{sub 3} and InBiTe{sub 3} films by using X-ray diffraction, optical and Raman Spectroscopy techniques. The as-prepared thin films were found to be Semi-crystalline by X-ray diffraction. Particle Size and Strain has been calculated from XRD data. The optical constants, film thickness, refractive index and optical band gap (E{sub g}) has been reported for In{sub 2}Te{sub 3}, InBiTe{sub 3} films. Raman Spectroscopy was performed to investigate the effect of Bi, In, on lattice vibration and chemical bonding in Te based chalcogenide glassy alloys.

36 MATERIALS SCIENCE↗

Synthesis of high-performance graphene nanosheets by thermal reduction of graphene oxide

Graphical abstract: High-performance graphene nanosheets were synthesized by thermal reduction of graphene oxide under ethanol atmosphere. X-ray photoelectron spectroscopy, Raman spectroscopy and electrical transport measurements indicate that the resulting graphene nanosheets can effectively restore its graphic structure in GO and present high mobility. Highlights: {yields} Graphene nanosheets were synthesized by reduction of GO under ethanol atmosphere. {yields} Raman and XPS results indicate the reduced graphene sheets have high-performance. {yields} Graphene sheets field-effect transistors present high mobility. -- Abstract: High-performance graphene nanosheets have been synthesized by thermal reduction of graphene oxide (GO) under ethanol atmosphere. The reduced GO nanosheets were characterized by X-ray photoelectron spectroscopy, Raman spectroscopy and electrical transport measurements, respectively. The results indicated that the thermal reduction of GO under ethanol atmosphere can effectively remove the oxygen-containing functional groups and restore its graphic structure compared to the ones obtained using hydrazine or hydrogen. The electrical measurements indicated that the electrical mobility of single-layer graphene sheet reduced under ethanol atmosphere at 900 {sup o}C can reach 29.08 cm{sup 2} V{sup -1} S{sup -1}.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

X-ray radiation effects in multilayer epitaxial graphene

We characterize multilayer graphene grown on C-face SiC before and after exposure to a total ionizing dose of 12 Mrad(SiO{sub 2}) using a 10 keV x-ray source. While we observe the partial peeling of the top graphene layers and the appearance of a modest Raman D-peak, we find that the electrical characteristics (mobility, sheet resistivity, free carrier concentration) of the material are mostly unaffected by radiation exposure. Combined with x-ray photoelectron spectroscopy data showing numerous carbon-oxygen bonds after irradiation, we conclude that the primary damage mechanism is through surface etching from reactive oxygen species created by the x-rays.

36 MATERIALS SCIENCE↗

Viability of Cladosporium herbarum spores under 157 nm laser and vacuum ultraviolet irradiation, low temperature (10 K) and vacuum

Ultraviolet photons can damage microorganisms, which rarely survive prolonged irradiation. In addition to the need for intact DNA, cell viability is directly linked to the functionality of the cell wall and membrane. In this work, Cladosporium herbarum spore monolayers exhibit high viability (7%) when exposed to 157 nm laser irradiation (412 kJm⁻²) or vacuum-ultraviolet irradiation (110–180 nm) under standard pressure and temperature in a nitrogen atmosphere. Spore viability can be determined by atomic-force microscopy, nano-indentation, mass, μ-Raman and attenuated reflectance Fourier-transform far-infrared spectroscopies and DNA electrophoresis. Vacuum ultraviolet photons cause molecular damage to the cell wall, but radiation resistance in spores arises from the activation of a photon-triggered signaling reaction, expressed via the exudation of intracellular substances, which, in combination with the low penetration depth of vacuum-ultraviolet photons, shields DNA from radiation. Resistance to phototoxicity under standard conditions was assessed, as was resistance to additional environmental stresses, including exposure in a vacuum, under different rates of change of pressure during pumping time and low (10 K) temperatures. Vacuum conditions were far more destructive to spores than vacuum-ultraviolet irradiation, and UV-B photons were two orders of magnitude more damaging than vacuum-ultraviolet photons. The viability of irradiated spores was also enhanced at 10 K. This work, in addition to contributing to the photonic control of the viability of microorganisms exposed under extreme conditions, including decontamination of biological warfare agents, outlines the basis for identifying bio-signaling in vivo using physical methodologies.

36 MATERIALS SCIENCE↗

Effect of thickness on the stress and magnetoelectric coupling in bilayered Pb(Zr{sub 0.52}Ti{sub 0.48})O{sub 3}-CoFe{sub 2}O{sub 4} films

Magnetoelectric bilayered Pb(Zr{sub 0.52}Ti{sub 0.48})O{sub 3}-CoFe{sub 2}O{sub 4}(PZT-CFO) films with different PZT thicknesses were grown on (111)Pt/Ti/SiO{sub 2}/Si substrates using chemical solution spin-coating. Structural characterization by X-ray diffraction and electron microscopy shows pure phases and well-defined interfaces between the PZT and CFO films. The CFO-PZT-substrate structure effectively alleviates the substrate clamping effect for the CFO layer, showing appreciable magnetoelectric responses in the composite films. Both the direct magnetoelectric effect and the magnetic field-induced Raman shifts in the A{sub 1}(TO{sub 1}) soft mode of PZT demonstrate the magnetic-mechanical-electric coupling in the films. The results also indicate that with a constant CFO layer thickness, the thickness of the PZT layer plays an important role in the stress relaxation and strong magnetoelectric coupling. The coupling could be further enhanced by increasing the CFO thickness, optimizing the volume (thickness) fraction of the PZT thickness, and releasing the clamping effect from the substrate.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Ion irradiation of electronic-type-separated single wall carbon nanotubes: A model for radiation effects in nanostructured carbon

The structural and electrical properties of electronic-type-separated (metallic and semiconducting) single wall carbon nanotube (SWCNT) thin-films have been investigated after irradiation with 150 keV {sup 11}B{sup +} and 150 keV {sup 31}P{sup +} with fluences ranging from 10{sup 12} to 10{sup 15} ions/cm{sup 2}. Raman spectroscopy results indicate that the ratio of the Raman D to G Prime band peak intensities (D/G Prime ) is a more sensitive indicator of SWCNT structural modification induced by ion irradiation by one order of magnitude compared to the ratio of the Raman D to G band peak intensities (D/G). The increase in sheet resistance (R{sub s}) of the thin-films follows a similar trend as the D/G Prime ratio, suggesting that the radiation induced variation in bulk electrical transport for both electronic-types is equal and related to localized defect generation. The characterization results for the various samples are compared based on the displacement damage dose (DDD) imparted to the sample, which is material and damage source independent. Therefore, it is possible to extend the analysis to include data from irradiation of transferred CVD-graphene films on SiO{sub 2}/Si substrates using 35 keV C{sup +} ions, and compare the observed changes at equivalent levels of ion irradiation-induced damage to that observed in the SWCNT thin-film samples. Ultimately, a model is developed for the prediction of the radiation response of nanostructured carbon materials based on the DDD for any incident ion with low-energy recoil spectra. The model is also related to the defect concentration, and subsequently the effective defect-to-defect length, and yields a maximum defect concentration (minimum defect-to-defect length) above which the bulk electrical transport properties in SWCNT thin-films and large graphene-based electronic devices rapidly degrade when exposed to harsh environments.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Evaluation of a frequency-dependent phase shift in chirped Raman lasers for atom gravimeters

Light-pulse atom gravimetry has emerged as a powerful technique for precisely measuring absolute gravitational acceleration. Raman lasers are commonly used in this technique to coherently manipulate the atomic wave packet, of which the effective frequency is chirped continuously to compensate for the Doppler shift. In this study we investigate an additional phase shift in the Raman lasers that arises due to the frequency chirp. Here, we directly measure this phase shift by recording the beat signal of the Raman lasers with a high-speed oscilloscope, providing an independent evaluation of the resultant error in atom gravimeters caused by this phase shift. Concurrently, we detect the influence of the additional phase shift on gravity measurements using our atom gravimeter, and the results are in good agreement with the independent evaluation. Notably, there may still be a residual error at the microgal level when performing differential measurements by reversing the direction of the effective wave vector of the Raman lasers. We propose that this residual error can in principle be eliminated by selecting the same chirp frequency range for both directions in the differential measurement.

Xu, Yaoyao [Huazhong Univ. of Science and Technolo↗

Effects of high-dose neutron irradiation at light-water reactor relevant temperature on the mechanical properties of SiC/SiC composites

For this study, the neutron dose-dependent evolutions and the underlying mechanisms of properties of SiC fiber-reinforced SiC matrix (SiC/SiC) composites at a temperature relevant to light-water reactors (∼600 K) were investigated and analyzed. Chemical vapor infiltrated (CVI) SiC/SiC composites reinforced with Hi-Nicalon Type S or Tyranno SA3 fiber were neutron-irradiated to doses up to 30 dpa. The irradiated composites retained their flexural strengths. The thermal diffusivity and dimensional changes were mostly retained from 2.0 to 30.2 dpa. Discrepancies in irradiation responses among CVI SiC/SiC composites from different sources were found. Additional microstructural analysis using Raman spectroscopy and numerical analysis on irradiation effect on residual stress were used to explain how the microstructural variables, especially of carbon interphases, affect the mechanical properties in the 30–40 dpa dose range.

Continuous fiber-reinforced ceramic matrix composi↗

Magnetooptical study of CdSe/ZnMnSe semimagnetic quantum-dot ensembles with n-type modulation doping

Magnetic and polarization investigations of the photoluminescence and resonant electron spin-flip Raman scattering in ensembles of self-organized CdSe/ZnMnSe semimagnetic quantum dots with n-type modulation doping are carried out. It is demonstrated that exciton transitions contribute to the photoluminescence band intensity, along with the transitions of trions in the singlet state. In the Hanle-effect measurements, negative circular polarization in zero magnetic field is observed, which is related to the optical orientation of a trion heavy hole. The lifetime and spin-relaxation time of a heavy hole are estimated as ≤3 and ≤1 ps, respectively. Such short times are assumed to be due to Auger recombination with the excitation of an intrinsic transition in a Mn{sup 2+} ion. Investigations of the photoluminescence-maximum intensity and shift in a longitudinal magnetic field at the σ{sup −}σ{sup +} and σ{sup −}σ{sup −} polarizations reveal the pronounced spin polarization of electrons. Under resonant excitation conditions, a sharp increase in the photoluminescence-band maximum intensity at σ{sup −} excitation polarization over the σ{sup +} one is observed. The Raman scattering peak at the electron spin-flip transition is observed upon resonant excitation in a transverse magnetic field in crossed linear polarizations. This peak is shown to be a Brillouin function of a magnetic field.

36 MATERIALS SCIENCE↗

Effect of potassium-doping on the microstructure development in polyfurfuryl alcohol - derived activated carbon

Potassium-doped activated carbon was prepared by mixing potassium salt with polyfurfuryl alcohol precursor followed by carbonization and activation. Several experimental techniques, such as thermogravimetric analysis, gas adsorption, X-ray diffraction and Raman scattering spectroscopy were employed to understand the effects of potassium on the texture and pore structures of the activated carbon, which ultimately affects the hydrogen adsorption properties. Furthermore, after doping with potassium, the activated carbon exhibits higher surface area, higher micropore volume, and enhanced hydrogen adsorption capacity. In understanding how alkali metals affect surface area and micropore development in activated carbon we may be able to clarify the hydrogen adsorption mechanism and improve the design of suitable carbon-based hydrogen storage materials.

36 MATERIALS SCIENCE↗

Density fluctuations due to Raman forward scattering in quantum plasma

Density fluctuations due Raman forward scattering (RFS) is analysed in the interaction of a high intensity laser pulse with high density quantum plasma. The interaction model is developed using the quantum hydrodynamic (QHD) model which consist of a set of equations describing the transport of charge, density, momentum and energy of a charged particle system interacting through a self-consistent electrostatic potential. The nonlinear source current has been obtained incorporating the effects of quantum Bohm potential, Fermi pressure and electron spin. The laser spectrum is strongly modulated by the interaction, showing sidebands at the plasma frequency. Furthermore, as the quiver velocity of the electrons in the high electric field of the laser beam is quit large, various quantum effects are observed which can be attributed to the variation of electron mass with laser intensity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Convective Raman amplification of light pulses causing kinetic inflation in inertial fusion plasmas

We perform 1D particle-in-cell (PIC) simulations using OSIRIS, which model a short-duration ({approx}500{omega}{sub 0}{sup -1} FWHM) scattered light seed pulse in the presence of a constant counter-propagating pump laser with an intensity far below the absolute instability threshold. The seed undergoes linear convective Raman amplification and dominates over fluctuations due to particle discreteness. Our simulation results are in good agreement with results from a coupled-mode solver when we take into account special relativity and the use of finite size PIC simulation particles. We present linear gain spectra including both effects. Extending the PIC simulations past when the seed exits the simulation domain reveals bursts of large-amplitude scattering in many cases, which does not occur in simulations without the seed pulse. These bursts can have amplitudes several times greater than the amplified seed pulse, and we demonstrate that this large-amplitude scattering is the result of kinetic inflation by examining trapped particle orbits. This large-amplitude scattering is caused by the seed modifying the distribution function earlier in the simulation. We perform some simulations with longer duration seeds, which lead to parts of the seeds undergoing kinetic inflation and reaching amplitudes several times more than the steady-state linear theory results. Simulations with continuous seeds demonstrate that the onset of inflation depends on seed wavelength and incident intensity, and we observe oscillations in the reflectivity at a frequency equal to the difference between the seed frequency and the frequency at which the inflationary stimulated Raman scattering grows.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Synthesis and characterization of FeSe{sub 1−x}Te{sub x} (x=0, 0.5, 1) superconductors

In this study, FeTe{sub 1-x}Se{sub x} (x=0,0.5,1) samples were prepared by conventional solid state reaction method and investigated by powder XRD, SEM, Raman and resistivity measurement techniques to reveal the effect of tellurium (Te) substitution in FeSe matrix. Rietveld analysis was performed on room temperature recorded, X-ray diffraction (XRD) patterns of pure FeSe, FeTe and FeSe{sub 0.5}Te{sub 0.5} which shows that all the compounds are crystallized in a tetragonal structure. SEM images show the dense surface morphology. Raman spectra recorded in the range from 100 to 700 cm{sup −1} at ambient temperature has been interpreted by P4/nmm space group of the lattice. The variation in intensity and shift in peak positions of some phonon modes has been discussed on the basis of variation in crystalline field effect by substituting Te in FeSe lattice. The resistivity versus temperature curves reveals that FeSe becomes superconductor at 7 K and FeSe{sub 0.5}Te{sub 0.5} shows superconductivity below 14 K while FeTe is non-superconducting compound.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Vulnerability of OFDR-based distributed sensors to radiations

Silica-based optical fibers have recently attracted much interest for their use in harsh environments such as the ones encountered in space, military or high energy physics applications. Small size, fast response, light weight and immunity to electromagnetic fields are favorable advantages that often become decisive for fiber sensing to be chosen over other conventional sensing technologies. As an important and representative example, Fukushima's accident highlighted weaknesses in the safety of nuclear power plants. Since, one of the strategic research axis of the nuclear industry is devoted to the development of novel technologies and sensors to enhance and reinforce the safety in nuclear power plants, especially in the case of accidental conditions associated with a strong increase of the constraints applied to the fiber-based system. The objective of this research field is to develop classes of distributed fiber-based sensors using scattering-based techniques, powerful solutions for various measurands measurement. Optical fiber properties, indeed, depend on several external parameters such as temperature, strain and therefore the fiber itself can be used as the sensitive element. Different classes of fiber-based sensing techniques have been recently investigated such as Fiber Bragg Gratings (FBGs) for discrete measurements and Brillouin, Raman and Rayleigh [8,9] scattering based techniques for distributed measurements of various environmental parameters. Whereas Brillouin and Raman sensor resolutions remain in the range of one meter, the advantage of Rayleigh scattering based technique is that it offers very high spatial resolution from 1 cm down to few μm over several hundred meters of fiber length down to few meters respectively. For nuclear industry, integrating fibers-based sensors has to improve the performances (resolution, operating range,...) of security systems in current nuclear power plants (NPPs) and offers new alternative technologies that may overcome the issues identified for next generation of NPPs. Such integration will only be possible if the OFDR based systems are able to resist to the constraints associated with industrial environments, one of the most constraining being the presence of high level of radiations. In this work, we carry out a systematic study to highlight the OFDR interest and sensitivity to probe the optical samples at high irradiation dose levels. The responses of five optical fibers types, from radiation hardened to radiation sensitive ones, are investigated to explore the influence of both the material compositions and the γ-irradiation on the ODFR sensors. Using these samples, we should highlight the influence of the core dopant concentration on the observed radiation-induced changes as well as the difference observed when the cladding is either radiation resistant or radiation sensitive. Our samples were irradiated using a {sup 60}Co source facility reaching total doses varying from 1 MGy up to a maximum of 10 MGy. All the measurements are performed after diverse months from irradiation to study permanents effects induced from these high γ-rays doses. We'll present at the conference all the experimental results acquired and use them to estimate the potential of OFDR-based systems for operation in radiation environments. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Raman measurements of substrate temperature in a molecular beam epitaxy growth chamber

A method is described for directly measuring the temperature of a substrate in a molecular-beam epitaxy (MBE) growth system. The approach relies on the establishment of the temperature dependence of Raman-active phonons of the substrate material using independently known calibration points across the range of interest. An unknown temperature in this range is then determined based on the Raman peak position with the substrate in situ the MBE chamber. The apparatus relies on conventional optics and Raman components. Shifting and broadening of the Raman spectrum are described based on the effects of thermal expansion and anharmonic decay. The choice of reference temperature is discussed. The method is qualified by examining the substrate temperature dependence, relative to that of a standard thermocouple, during a commonly used ramp procedure. Both temperature difference and time lag are obtained.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗