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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

Effect of KOH Concentration and Anions on the Performance of a Ni-H2 Battery Positive Plate

The capacity and voltage behavior of electrochemically impregnated sintered nickel positive plates was examined by galvanostatic charging and discharging in a flooded electrolyte cell. Three different concentrations of potassium hydroxide (KOH) (40, 31, and 26 percent) and 31 percent KOH containing dissolved nitrate, sulfate, or silicate were investigated. The end-of-charge voltage at C/10 charge and at 10 degrees C showed the following order: 40 percent KOH greater than 31 percent KOH alone and in the presence of the anions greater than 26 percent KOH. The mid discharge voltage at C/2 discharge was higher in 26 percent KOH, almost the same for 31 percent KOH with and without added contaminants, and much lower for 40 percent KOH. The plate capacity was marginally affected by cycling in all cases except for 40 percent KOH, where the capacity declined after 1,000 cycles at 80 percent depth of discharge (DOD). At the end of cycling, all the plates tested experienced a weight loss, except in the case of 31 percent KOH, as a result of active material extrusion. Cyclic voltammetry of miniature electrodes in 31 percent KOH showed that the cathodic peak potentials are less polarized in the presence and absence of silicate at -5 degrees C compared to 25 degrees C indicating a slightly higher voltage during discharge in a Ni-H2 battery. Futhermore, the features of the current-potential profile were practically unchanged in the presence of silicate.

Vaidyanathan, Hari↗
NASA NTRS2010

Spatially-Resolved Beam Current and Charge-State Distributions for the NEXT Ion Engine

Plume characterization tests with the 36-cm NEXT ion engine are being performed at The Aerospace Corporation using engineering-model and prototype-model thrusters. We have examined the beam current density and xenon charge-state distribution as functions of position on the accel grid. To measure the current density ratio j++/j+, a collimated Eprobe was rotated through the plume with the probe oriented normal to the accel electrode surface at a distance of 82 cm. The beam current density jb versus radial position was measured with a miniature planar probe at 3 cm from the accel. Combining the j++/j+ and jb data yielded the ratio of total Xe+2 current to total Xe+1 current (J++/J+) at forty operating points in the standard throttle table. The production of Xe+2 and Xe+3 was measured as a function of propellant utilization to support performance and lifetime predictions for an extended throttle table. The angular dependence of jb was measured at intermediate and far-field distances to assist with plume modeling and to evaluate the thrust loss due to beam divergence. Thrust correction factors were derived from the total doubles-to-singles current ratio and from the far-field divergence data

Pollard, James E.↗
NASA NTRS2012

Recovering Swift-XRT Energy Resolution through CCD Charge Trap Mapping

The X-ray telescope on board the Swift satellite for gamma-ray burst astronomy has been exposed to the radiation of the space environment since launch in November 2004. Radiation causes damage to the detector, with the generation of dark current and charge trapping sites that result in the degradation of the spectral resolution and an increase of the instrumental background. The Swift team has a dedicated calibration program with the goal of recovering a significant proportion of the lost spectroscopic performance. Calibration observations of supernova remnants with strong emission lines are analysed to map the detector charge traps and to derive position-dependent corrections to the measured photon energies. We have achieved a substantial recovery in the XRT resolution by implementing these corrections in an updated version of the Swift XRT gain file and in corresponding improvements to the Swift XRT HEAsoft software. We provide illustrations of the impact of the enhanced energy resolution, and show that we have recovered most of the spectral resolution lost since launch

Pagani, C.↗
NASA NTRS2017

Predicting Electron Population Characteristics in 2-D Using Multispectral Ground-Based Imaging

Ground-based imaging and in situ sounding rocket data are compared to electron transport modeling for an active inverted-V type auroral event. The Ground-to-Rocket Electrodynamics-Electrons Correlative Experiment (GREECE) mission successfully launched from Poker Flat, Alaska, on 3 March 2014 at 11:09:50 UT and reached an apogee of approximately 335 km over the aurora. Multiple ground-based electron-multiplying charge-coupled device (EMCCD) imagers were positioned at Venetie, Alaska, and aimed toward magnetic zenith. The imagers observed the intensity of different auroral emission lines (427.8, 557.7, and 844.6 nm) at the magnetic foot point of the rocket payload. Emission line intensity data are correlated with electron characteristics measured by the GREECE onboard electron spectrometer. A modified version of the GLobal airglOW (GLOW) model is used to estimate precipitating electron characteristics based on optical emissions. GLOW predicted the electron population characteristics with 20% error given the observed spectral intensities within 10 deg of magnetic zenith. Predictions are within 30% of the actual values within 20 deg of magnetic zenith for inverted-V-type aurora. Therefore, it is argued that this technique can be used, at least in certain types of aurora, such as the inverted-V type presented here, to derive 2-D maps of electron characteristics. These can then be used to further derive 2-D maps of ionospheric parameters as a function of time, based solely on multispectral optical imaging data.

multispectral ground-based imaging↗
DOE OSTI2024

Defect Equilibria from First Principles: From Widegap Oxides to Topological Semimetals

Materials functionality and performance is rarely determined by the ideal crystal alone but is usually affected by formation of imperfections and the solution of impurities. In some applications, such as solar thermochemical hydrogen generation, defect formation is the fundamentally enabling mechanism of the desired functionality. In other cases, such as Cd3As2 topological semimetals, unintentional self-doping presents an obstacle to the access to the unique electronic properties. In either case, a quantitative understanding of the relevant defect mechanism is essential for developing design strategies. This presentation will touch upon numerous aspects in the computational simulation of defect equilibria, including non-equilibrium design strategies, the coupling of solid state and gas-phase reactions, dopant-defect and defect-defect interactions, both attractive and repulsive, the accuracy of total energy functionals and electronic structure methods, and the role of the shape of the density of states for the charge balance condition and Fermi level position, as well as machine-learning prediction of defect energies (1). Specific materials systems include Ga2O3 (2), Cd3As2 (3), and (Sr,Ce)MnO3 (4). (1) M.D. Witman, A. Goyal, T. Ogitsu, A.H. McDaniel, S. Lany, Nat. Comput. Sci. 3, 675 (2023). (2) A. Goyal, A. Zakutayev, V. Stevanovic, S. Lany, J. Appl. Phys. 129, 245704 (2021). (3) C. Brooks, M. van Schilfgaarde, D. Pashov, J.N. Nelson, K. Alberi, D.S. Dessau, S. Lany, Phys. Rev. B 107, 224110 (2023). (4) A. Goyal, M.D. Sanders, R.P. O'Hayre, S. Lany, PRX Energy 3, 013008 (2024).

CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS,M↗
NASA NTRS1975

Charge-exchange plasma generated by an ion thruster

The use of high voltage solar arrays greatly reduces or eliminates power processing requirements in space electric propulsion systems. This use also requires substantial areas of solar array to be at high positive potential relative to space and most of the spacecraft. The charge exchange plasma conducts electrons from the ion beam to such positive surfaces, and thereby electrically load the high voltage solar array. To evaluate this problem, the charge-exchange plasma generated by an ion beam was investigated experimentally. Based upon the experimental data, a simple model was derived for the charge-exchange plasma. This model is conservative in the sense that both the electron/ion density and the electron current density should be equal to, or less than, the preducted value for all directions in the hemisphere upstream of the ion beam direction. Increasing the distance between a positive potential surface (such as a high voltage solar array) and the thruster is the simplest way to control interactions. Both densities and currents vary as the inverse square of this distance.

Kaufman, H. R.↗
NASA NTRS1998

Composite x-ray image assembly for large-field digital mammography with one- and two-dimensional positioning of a focal plane array

To demonstrate the feasibility of a novel large-field digital mammography technique, a 1024 x 1024 pixel Loral charge-coupled device (CCD) focal plane array (FPA) was positioned in a mammographic field with one- and two-dimensional scan sequences to obtain 950 x 1800 pixel and 3600 x 3600 pixel composite images, respectively. These experiments verify that precise positioning of FPAs produced seamless composites and that the CCD mosaic concept has potential for high-resolution, large-field imaging. The proposed CCD mosaic concept resembles a checkerboard pattern with spacing left between the CCDs for the driver and readout electronics. To obtain a complete x-ray image, the mosaic must be repositioned four times, with an x-ray exposure at each position. To reduce the patient dose, a lead shield with appropriately patterned holes is placed between the x-ray source and the patient. The high-precision motorized translation stages and the fiber-coupled-scintillating-screen-CCD sensor assembly were placed in the position usually occupied by the film cassette. Because of the high mechanical precision, seamless composites were constructed from the subimages. This paper discusses the positioning, image alignment procedure, and composite image results. The paper only addresses the formation of a seamless composite image from subimages and will not consider the effects of the lead shield, multiple CCDs, or the speed of motion.

Mammography/methods/statistics & numerical data↗
NASA NTRS1984

Ion mass spectrometer

An ion mass spectrometer is described which detects and indicates the characteristics of ions received over a wide angle, and which indicates the mass to charge ratio, the energy, and the direction of each detected ion. The spectrometer includes a magnetic analyzer having a sector magnet that passes ions received over a wide angle, and an electrostatic analyzer positioned to receive ions passing through the magnetic analyzer. The electrostatic analyzer includes a two dimensional ion sensor at one wall of the analyzer chamber, that senses not only the lengthwise position of the detected ion to indicate its mass to charge ratio, but also detects the ion position along the width of the chamber to indicate the direction in which the ion was traveling.

Neugebauer, M.↗
NASA NTRS1996

A proof of concept investigation: A unique mobility spectrometer for In Situ diagnostics of positive and negative ion distributions in the mesosphere and lower ionosphere

We have carried out a proof-of-concept development and test effort that not only promises the reduction of parasitic effects of surface contamination (therefore increasing the integrity of 'in situ' measurements in the 60-130 km regime), but promises a uniquely expanded measurement set that includes electron densities, plasma conductivities, charged-particle mobilities, and mass discrimination of positive and negative ion distributions throughout the continuum to free-molecular-flow regimes. Three different sensor configurations were designed, built and tested, along with specialized driving voltage, electrometer and channeltron control electronics. The individual systems were tested in a variety of simulated space environments ranging from pressures near the continuum limit of 100 mTorr to the collisionless regime at 10(exp -6) Torr. Swept modes were initially employed to better understand ion optics and ion 'beam' losses to end walls and to control electrodes. This swept mode also helped better understand and mitigate the influences of secondary electrons on the overall performance of the PIMS design concept. Final results demonstrated the utility of the concept in dominant single-ion plasma environments. Accumulated information, including theoretical concepts and laboratory data, suggest that multi-ion diagnostics are fully within the instrument capabilities and that cold plasma tests with minimized pre-aperture sheath acceleration are the key ingredients to multi-ion success.

Szuszczewicz, Edward P.↗
DOE OSTI2020

Study of space charge in the ICARUS T600 detector

The accumulation of positive ions, produced by ionizing particles crossing Liquid Argon Time Projection Chambers (LAr-TPCs), may generate distortions of the electric drift field affecting the track reconstruction of the ionizing events. These effects could become relevant for large LAr-TPCs operating at surface or at shallow depth, where the detectors are exposed to a copious flux of cosmic rays. We report a detailed study of such possible field distortions in the ICARUS T600 LAr-TPC has been performed analyzing a sample of cosmic muon tracks recorded with one T600 module operated at surface in 2001. The maximum track distortion turns out to be of few mm in good agreement with the prediction by a numerical calculation. As a cross-check, the same analysis has been performed on a cosmic muon sample recorded during the ICARUS T600 run at the LNGS underground laboratory, where the cosmic ray flux was suppressed by a factor $\sim 10^6$ by 3400 m water equivalent shielding. No appreciable distortion has been observed, confirming that the effects measured on surface are actually due to ion space charge.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1984

Electron capture by U(91+) and U(92+) and ionization of U(90+) and U(91+)

U(92+)/U(91+) and U(91+)/U(90+) electron-capture and ionization cross sections and equilibrium charge-state distributions are measured experimentally in mylar, Cu and Ta of varying thickness. Relativistic U(68+) ions at 437 or 962 MeV/nucleon are produced by a heavy-ion linear accelerator and synchrotron in tandem and passed through the target material into a magnetic specrometer and position-sensitive proportional counter for evaluation of charge states. The results are presented graphically and discussed. At 962 MeV/nucleon, beams containing 85 percent bare U(92+) nuclei are obtained using 150-mg/sq cm Cu or 85-mg/sq cm Ta; at 437 MeV/nucleon, 50 percent bare U(92+) nuclei are obtained with 90-mg/sq cm Cu. The techniques decribed can be applied to produce beams of bare U nuclei for acceleration to ultrarelativistic speeds or beams of few-electron U for atomic-physics experiments on quantum electrodynamics.

Gould, H.↗
NASA NTRS2007

Solar Modulation of Low-Energy Antiproton and Proton Spectra Measured by BESS

The spectra of low-energy cosmic-ray protons and antiprotons have been measured by BESS in nine high-latitude balloon flights between 1993 and 2004. These measurements span a range of solar activity from the previous solar minimum through solar ma>:im%am and the onset of the present solar minimum, as well as a solar magnetic field reversal from positive to negative in 2000. Because protons and antiprotons differ only in charge sign, these simultaneous measurements provide a sensitive probe of charge dependent solar modulation. The antiproton to proton ratio measured by BESS is consistent with simple spherically symmetric models of solar modulation during the Sun's positive polarity phase, but favor charge-sign-dependent drift models during the negative phase. The BESS measurements will be presented and compared to various models of solar modulation.

Mitchell, John W.↗
DOE OSTI2021

Improving the Operational Lifetime of the CEBAF Photo-Gun by Anode Biasing

The operating lifetime of GaAs-based photocathodes in DC high voltage electron photo-guns is dominated by the ionization rate of residual beamline gas molecules. In this work, experiments were performed to quantify the improvement in photocathode charge lifetime by biasing the photo-gun anode with a positive voltage, which repels ions generated downstream of the anode. The photo-cathode charge lifetime improved by almost a factor of two when the anode was biased compared to the usual grounded configuration. Simulations were performed using the particle tracking code General Particle Tracer (GPT) with a new custom element. The simulation results showed that both the number and energy of ions play a role in the pattern of QE degradation. The experiment results and conclusions supported by GPT simulations will be presented.

Yoskowitz, J. T.↗
NASA NTRS1993

Point charge representation of multicenter multipole moments in calculation of electrostatic properties

Distributed Point Charge Models (PCM) for CO, (H2O)2, and HS-SH molecules have been computed from analytical expressions using multi-center multipole moments. The point charges (set of charges including both atomic and non-atomic positions) exactly reproduce both molecular and segmental multipole moments, thus constituting an accurate representation of the local anisotropy of electrostatic properties. In contrast to other known point charge models, PCM can be used to calculate not only intermolecular, but also intramolecular interactions. Comparison of these results with more accurate calculations demonstrated that PCM can correctly represent both weak and strong (intramolecular) interactions, thus indicating the merit of extending PCM to obtain improved potentials for molecular mechanics and molecular dynamics computational methods.

Non-NASA Center↗
DOE OSTI2022

Charge Separation in Monolayer WSe 2 by Strain Engineering: Implications for Strain-Induced Diode Action

Strain-engineering band structure in transition-metal dichalcogenides (TMDC) is a promising avenue toward capabilities in optoelectronics. For example, controlling the flow of optically generated quasiparticles can be achieved by a localized strain field which reduces the bandgap and generates an energy-band gradient that funnels neutral excitons to the strain apex. It would be even more advantageous to mimic a diode’s internal field, where both conduction and valence bands bend in the same direction, to separate electrons and holes. This can be achieved if the strain in the TMDC layer lowers both the conduction band minimum as well as the valence band maximum during strain-induced band narrowing. Here, we have used density functional theory (DFT) calculations of monolayer WSe 2 electronic structure under biaxial strain to show that WSe 2 has this property. In this work, to test the band bending experimentally, we combined localized strain with electrostatic doping to follow photoluminescence from excitons and positive or negative trions. In unstrained WSe 2 , both positive and negative trion emissions dominate over excitons away from charge neutrality. In contrast, for strained areas, negative trions accumulate, while positive trion emission is near zero away from charge neutrality, indicating a lack of holes. Hence, strain bends both conduction and valence bands down, similarly to the band bending in a PN-diode depletion region, providing an opportunity to separate electrons and holes via localized strain.

2D materials↗
DOE OSTI2021

Temperature and solvent-dependent photoluminescence quenching in [Ru(bpy) 2 (bpy-cc-AQ)] 2+

I have herein investigated the solvent-dependent photoluminescence quenching mechanism of [Ru(bpy) 2 (bpy-cc-AQ)] 2+ using variable temperature emission spectroscopies. In this wok, the photophysics of this complex are dominated by an excited-state thermal equilibrium between a photoluminescent 3 MLCT state and a charge-separated state that lies higher in energy relative to the 3 MLCT state in low polarity solvents and approximately isoenergetic in high polarity solvents. Furthermore, an unusual photoluminescence temperature-dependence in high polarity solvents is shown to arise from competition between enthalpic factors favouring the charge-separated state and entropic factors favouring the photoluminescent 3 MLCT state, analogous to the molecular light-switch effect of [Ru(bpy) 2 (dppz)] 2+ . The solvent-dependent photoluminescence quenching of [Ru(bpy)2(bpy-cc-AQ)] 2+ is attributed to two key solvent-dependent factors: (1) the excited-state equilibrium position and (2) the rate of charge-recombination from the charge-separated state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2009

Secondary Electrons and Charging in the Lunar Environment

Charging of the lunar surface is of interest both from a scientific standpoint as well as a practical one because of plans for human return to the Moon. Recent work published in the scientific literature suggest that the lunar surface may charge to significant negative potentials at times when spacecraft above the surface only charge to moderate negative potentials or even positive values. This is possible only if secondary electron yields due to photoemission and electron impact are significantly less than unity for lunar regolith over a wide range of energies, inconsistent with values obtained by laboratory measurements. We review the available laboratory measurements of lunar secondary electron yields and photoemission yields and discuss their impact to lunar charging analyses.

Minow, Joseph I.↗
DOE OSTI2020

Two-Dimensional Molecular Charge Density Waves in Single-Layer-Thick Islands of a Dirac Fermion System

Charge density waves have been intensely studied in inorganic materials such as transition metal dichalcogenides however its counterpart in organic materials has yet to be explored in detail. Here we report the finding of a robust two dimensional charge density waves in molecular layers formed by α-(BEDT-TTF) 2 -I 3 on a Ag(111) surface. Low temperature scanning tunnelling microscopy images of a multi-layer thick α-(BEDT-TTF) 2 -I 3 on Ag(111) substrate reveal coexistence of 5a0 x 5a0 and √31 a0 x √31 a0 R9° charge density wave patterns commensurate with the underlying molecular lattice at 80 K. Both charge density wave patterns remain in nano-size molecular islands with just a single constituent molecular-layer thickness at 80 K and 5 K. Local tunneling spectroscopy measurements reveal the variation of the gap from 244 meV to 288 meV between the maximum and minimum charge density wave locations. Density functional theory calculations further confirm a vertical positioning of BEDT-TTF molecules in the molecular layer. While the observed charge density wave patterns are stable for the defect sites, they can be reversely switched for one molecular lattice site by means of inelastic tunnelling electron energy transfer with the electron energies exceeding 400 meV using a scanning tunneling microscope manipulation scheme.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗