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At least 775 records · Page 43
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Electric field distribution in a non-self-sustained RF discharge with ionization generated by Ns discharge pulses

Abstract Electric field in a capacitively coupled, non-self-sustained RF discharge nitrogen plasma with external ionization generated by high-voltage ns pulses has been measured by ps Electric field induced second harmonic generation (EFISH). The measurements are made both in the bulk of the plasma and in the sheaths, using the absolute calibration by the Laplacian field between two plane electrodes. The results are compared with the kinetic modeling calculations. The RF electric field in the sheaths is significantly higher compared to that in the plasma, due to the displacement of the electrons by the drift oscillations and the resultant plasma self-shielding. However, the kinetic modeling predictions indicate that the electron impact ionization in the sheaths is largely ineffective, due to the low electron density. The reduction of the electric field in the plasma by the self-shielding in the sheaths is moderate, such that the energy is coupled to the plasma by the below-breakdown RF field. The peak RF field in the plasma is in the range of 15–25 Td, indicating the efficient vibrational excitation of N 2 by electron impact. The modeling predictions suggest that the targeted vibrational excitation of molecular species in a non-self-sustained RF discharge with external ionization is scalable to high pressures, electron densities, and discharge powers. The present approach can be extended to the vibrational excitation of other molecular species where the vibrational relaxation is relatively slow, such as CO, CO 2 , and H 2 .

Physics↗
NASA NTRS1976

Absorption of CO2-laser radiation in a hypocycloidal-pinch plasma

Absorption of a 50-J pulsed CO2 laser beam in the plasma produced in a hypocycloidal-pinch apparatus was studied. The apparatus consists of three disk electrodes with a 5-cm hole on the axis. The current sheets are snow-plowed toward the center of the hole to produce a plasma with a density greater than 10 to the 18th/cu cm and a temperature near 1 keV which emits soft X rays for 5 microsec. IR detectors measured the laser radiation incident onto, transmitted through, and scattered from the plasma as functions of time. For a period up to 70 microsec from the onset of X-ray emission, neither transmitted nor scattered laser radiation was observed above the detector threshold of 0.3% of the incident flux. This indicates effective absorption of the laser beam (greater than 99%) and that the particle confinement time extends far beyond the energy confinement time of 5 microsec. Thus, the plasma in this apparatus appears much more amenable to laser heating than that in a theta pinch.

Lee, J. H.↗
NASA NTRS1999

Pulsed high energy synthesis of fine metal powders

Repetitively pulsed plasma jets generated by a capillary arc discharge at high stagnation pressure (>15,000 psi) and high temperature (>10,000 K) are utilized to produce 0.1-10 .mu.m sized metal powders and decrease cost of production. The plasma jets impact and atomize melt materials to form the fine powders. The melt can originate from a conventional melt stream or from a pulsed arc between two electrodes. Gas streams used in conventional gas atomization are replaced with much higher momentum flux plasma jets. Delivering strong incident shocks aids in primary disintegration of the molten material. A series of short duration, high pressure plasma pulses fragment the molten material. The pulses introduce sharp velocity gradients in the molten material which disintegrates into fine particles. The plasma pulses have peak pressures of approximately one kilobar. The high pressures improve the efficiency of disintegration. High gas flow velocities and pressures are achieved without reduction in gas density. Repetitively pulsed plasma jets will produce powders with lower mean size and narrower size distribution than conventional atomization techniques.

Witherspoon, F. Douglas↗
DOE OSTI2021

Plasma Guns for Magnetized Fuel Targets for PJMIF

In plasma jet driven magneto-inertial fusion (PJMIF) an array of discrete supersonic plasma jets is used to form a spherically imploding plasma liner, which then compresses a magnetized plasma target to fusion conditions. With funding from ARPA-E’s ALPHA program and from Strong Atomics LLC, HyperJet Fusion Corp and HyperV Technologies Corp. previously developed the plasma guns required for an experimental demonstration of the plasma liner formation part of the concept. A 36-gun demonstration of an imploding spherical plasma liner is currently underway on the PLX facility at Los Alamos National Laboratory. This present project addresses the next step required for a complete PJMIF concept, i.e. developing the magnetized plasma target. We proposed to form the target by stagnating a number of magnetized plasma jets in the center of the target chamber. This is accomplished by adding a bias field coil to the plasma liner gun to form a magnetized plasma jet. This experimental development took place at HyperJet in a geometry replicating the bias field environment that will be seen on a PLX port so the results are directly transferrable to the PLX experiment. The objective of this effort was the technical development and characterization of a new magnetized plasma jet using a high-performance, high momentum flux, contoured-gap coaxial plasma gun appropriate for use on the next stage of the PLX experiment. Electromagnetic modeling of the coil indicated the coil was best placed around the aluminum tubes of the gun transmission line, rather than around the chamber port as originally proposed. This maximized field strength in the breech and yielded much better flux linkage between gun electrodes. A 30-turn coil was ultimately implemented, allowing long pulses that could diffuse through the metal walls on the timescale of interest. \machtwo modeling predicted that less capacitance in the main PFN could potentially improve plasma jet velocities due to better matching of the current to the smaller plasma mass and the existing electrode contour designed to suppress blowby. This proved true, as testing showed markedly improved performance when the original 600uF bank was reduced to 400uF. A number of diagnostics were built and/or upgraded in order to characterize the plasma jets, inluding laser interferomtery for density, photodiodes for velocity, Bdot probes for magnetic field measurements, a Triple probe for temperature measurements, and spectroscopy for impurity content. A plasma gun with the 30-turn magnet coil installed, a 70% reduction in gas valve plenum volume, and a 33% reduction in main PFN capacitance produced a dense, high velocity, well magnetized plasma jet. We met or exceeded virtually all of the plasma jet parameter goals. Peak velocity of 135 km/s exceeded the 100 km/s goal by 35%, while the peak density of over 1.0x10 15 cm -3 was 3.3 times the goal of >3.0x10 14 cm -3 . Shot-to-shot repeatability is excellent, with a jitter of less than 300ns observed on the arrival fronts of the photodiode signals from one shot to the next. Average plasma jet lengths of 33cm (at 120km/s) were slightly longer than the 20cm goal, but jets as short as 11.8cm were observed at 135km/s. Mass is much higher than the targeted goal, averaging 106ug per shot compared to 20ug. The magnetic field is still a bit lower than desired, with a maximum to date of ~811G, compared to the goal of 1000G. Average values, though, were typically in the 300-450G range, when measured further downstream after some expected in flight decay. Temperature measurements are still a work in progress. Increasing the B field and completing temperature measurements will be continued on into the ongoing BETHE project.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2014

Particle-in-cell modeling for MJ scale dense plasma focus with varied anode shape

Megajoule scale dense plasma focus (DPF) Z-pinches with deuterium gas fill are compact devices capable of producing 10{sup 12} neutrons per shot but past predictive models of large-scale DPF have not included kinetic effects such as ion beam formation or anomalous resistivity. We report on progress of developing a predictive DPF model by extending our 2D axisymmetric collisional kinetic particle-in-cell (PIC) simulations from the 4 kJ, 200 kA LLNL DPF to 1 MJ, 2 MA Gemini DPF using the PIC code LSP. These new simulations incorporate electrodes, an external pulsed-power driver circuit, and model the plasma from insulator lift-off through the pinch phase. To accommodate the vast range of relevant spatial and temporal scales involved in the Gemini DPF within the available computational resources, the simulations were performed using a new hybrid fluid-to-kinetic model. This new approach allows single simulations to begin in an electron/ion fluid mode from insulator lift-off through the 5-6 μs run-down of the 50+ cm anode, then transition to a fully kinetic PIC description during the run-in phase, when the current sheath is 2-3 mm from the central axis of the anode. Simulations are advanced through the final pinch phase using an adaptive variable time-step to capture the fs and sub-mm scales of the kinetic instabilities involved in the ion beam formation and neutron production. Validation assessments are being performed using a variety of different anode shapes, comparing against experimental measurements of neutron yield, neutron anisotropy and ion beam production.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Multi-slit triode ion optical system with ballistic beam focusing

Multi-slit triode ion-optical systems with spherical electrodes are of interest for formation of intense focused neutral beams for plasma heating. At present, two versions of focusing multi-slit triode ion optical system are developed. The first ion optical system forms the proton beam with 15 keV energy, 140 A current, and 30 ms duration. The second ion optical system is intended for heating neutral beam injector of Tokamak Configuration Variable (TCV). The injector produces focused deuterium neutral beam with 35 keV energy, 1 MW power, and 2 s duration. In the later case, the angular beam divergence of the neutral beam is 20-22 mrad in the direction across the slits of the ion optical system and 12 mrad in the direction along the slits.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2022

Investigations into Plasma-Mediated Decomposition of Organoiodide Species as a Pretreatment for Mitigation of Radioiodine Emissions

A plasma-mediated pretreatment step is proposed to decompose methyl iodide (CH 3 I) for facilitating the capture of the iodine radioisotopes present in off-gas streams from used nuclear fuel reprocessing operations. Simulated CH 3 I gas streams were exposed to dielectric barrier discharge (DBD) plasma in a quartz glass continuous-flow reactor using copper electrodes. The kinetics of decomposition of CH 3 I in nitrogen was investigated by varying the applied voltage, inlet concentration, and residence time. The rate of decomposition was proportional to CH 3 I concentration and increased as the applied potential was increased. This effect was incorporated in the kinetics through the dependence of the rate constant on the applied electric field. Decomposition of CH 3 I was not affected by moisture, and the DBD pretreatment is likely to be similarly effective in an air environment as well; however, the results were confounded by a plasma-mediated reaction between nitrogen and oxygen.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2021

Investigations of the stability of etched or platinized p-InP(100) photocathodes for solar-driven hydrogen evolution in acidic or alkaline aqueous electrolytes

Here, the stability of p-InP photocathodes performing the hydrogen-evolution reaction (HER) has been evaluated in contact with either 1.0 M H 2 SO 4 (aq) or 1.0 M KOH(aq), with a focus on identifying corrosion mechanisms. Stability for the solar-driven HER was evaluated using p-InP electrodes that were either etched or coated with an electrodeposited Pt catalyst (p-InP/Pt). Variables such as trace O 2 were systematically controlled during the measurements. Changes in surface characteristics after exposure to electrochemical conditions as well as electrode dissolution processes were monitored using X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma mass spectrometry (ICP-MS). In either H 2 SO 4 or KOH, etched p-InP photoelectrodes corroded cathodically under illumination, forming metallic In 0 at the electrode surface. In contrast, electrodeposition of Pt kinetically stabilized illuminated p-InP photocathodes in both H 2 SO 4 and KOH by inhibiting the cathodic corrosion pathway. Notably, when held at 0 V vs. the reversible hydrogen electrode (RHE) in 1.0 M H 2 SO 4 (aq), p-InP/Pt exhibited a stable current density (J) of ~–18 mA cm –2 for >285 h under simulated 1 Sun illumination. The long-term current density vs. potential (J–E) behavior at pH 0 and pH 14 of p-InP/Pt photocathodes correlated with changes in the surface chemistry as well as the dissolution of p-InP. In acidic media, the J–E behavior of p-InP/Pt photocathodes remained nearly constant with time, but the surface of a p-InP/Pt electrodes gradually turned P-rich via a slow and continuous leaching of In ions. In alkaline electrolyte, the surface of p-InP/Pt electrodes was passivated by formation of an InO x layer that exhibited negligible dissolution but led to a substantial degradation in the J–E characteristics. Consequently, changes in the catalytic kinetics and surface stoichiometry are both important considerations for determining the corrosion chemistry and the long-term operational stability of InP photoelectrodes.

14 SOLAR ENERGY↗
DOE OSTI2012

Pulsed submicrosecond multichannel sliding discharges of opposite polarities: Filling of the discharge gap with spark channels

Results are presented from measurements of the discharge current and the factor of the discharge gap filling with spark channels during pulsed sliding discharges of opposite polarities in Ne, Ar, and Xe on an aluminum oxide ceramic surface. The measurements were performed in the regime of single pulses of submi-crosecond duration at discharge voltages of 0-12 kV with two discharge chambers with different thicknesses of the ceramic plate (0.4 and 0.17 cm) and different electrode gap lengths (4 and 10.3 cm) at gas pressures of 30 and 100 kPa. The results obtained for discharges of opposite polarities are compared with one another, and common features of discharges in three gases are revealed. It is shown that the filling of the discharge gap with spark channels in the gases under study is more efficient in the case of the positive polarity of the discharge voltage, except Xe at a pressure of 100 kPa in the electrode gap of length 10.3 cm. The quasi-homogeneous regime of discharge in each of the three gases is attained easier at lower gas pressures. Comparison of the data on the filling factors of the discharge gap and the peak currents of opposite-polarity discharges for each gas at a given pressure indicates that the higher the discharge current, the more densely the discharge gap is filled with spark channels.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS2005

Radio-Frequency Plasma Cleaning of a Penning Malmberg Trap

Radio-frequency-generated plasma has been demonstrated to be a promising means of cleaning the interior surfaces of a Penning-Malmberg trap that is used in experiments on the confinement of antimatter. {Such a trap was reported in Modified Penning-Malmberg Trap for Storing Antiprotons (MFS-31780), NASA Tech Briefs, Vol. 29, No. 3 (March 2005), page 66.} Cleaning of the interior surfaces is necessary to minimize numbers of contaminant atoms and molecules, which reduce confinement times by engaging in matter/antimatter-annihilation reactions with confined antimatter particles. A modified Penning-Malmberg trap like the one described in the cited prior article includes several collinear ring electrodes (some of which are segmented) inside a tubular vacuum chamber, as illustrated in Figure 1. During operation of the trap, a small cloud of charged antiparticles (e.g., antiprotons or positrons) is confined to a spheroidal central region by means of a magnetic field in combination with DC and radiofrequency (RF) electric fields applied via the electrodes. In the present developmental method of cleaning by use of RF-generated plasma, one evacuates the vacuum chamber, backfills the chamber with hydrogen at a suitable low pressure, and uses an RF-signal generator and baluns to apply RF voltages to the ring electrodes. Each ring is excited in the polarity opposite that of the adjacent ring. The electric field generated by the RF signal creates a discharge in the low-pressure gas. The RF power and gas pressure are adjusted so that the plasma generated in the discharge (see Figure 2) physically and chemically attacks any solid, liquid, and gaseous contaminant layers on the electrode surfaces. The products of the physical and chemical cleaning reactions are gaseous and are removed by the vacuum pumps.

Sims, William Herbert, III↗
DOE OSTI2012

A theoretical approach to electric breakdown behaviour and effective secondary emission coefficient in gas discharge process between two parallel-plane disk electrodes

The gas discharge characteristics are seriously influenced by the effective secondary electron-emission coefficient ({gamma}{sub eff}) originally defined by Townsend. A theoretical approach has been proposed for the determination of variation of this coefficient as a function of the geometrical parameter d/R (the ratio of inter-electrode distance to electrode radius) in the most practical range of 0.08{<=}d/R{<=}1.90. Two geometrical factors g{sub i} and g{sub p}, which are attributed to ion-induced and photon-induced terms, respectively, were introduced to the effective gamma in parallel-plane arrangement. The factors were theoretically derived and hence the effective gamma and the breakdown voltage for a specified geometrical parameter, such as d/R=0.16, were obtained. Then, the effective gamma and the Paschen curves for various geometrical parameters such as d/R=0.32, 0.63, 1.27, and 1.90 were theoretically reproduced. The obtained results showed quite a good agreement with those reported by other researchers and verified that the proposed g{sub i} and g{sub p} have properly been introduced and derived.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

Electrode property of single-walled carbon nanotubes in all-solid-state lithium ion battery using polymer electrolyte

Electrode properties of single-walled carbon nanotubes (SWCNTs) in an all-solid-state lithium ion battery were investigated using poly-ethylene oxide (PEO) solid electrolyte. Charge-discharge curves of SWCNTs in the solid electrolyte cell were successfully observed. It was found that PEO electrolyte decomposes on the surface of SWCNTs.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2016

Digital holographic interferometry employing Fresnel transform reconstruction for the study of flow shear stabilized Z-pinch plasmas

The ZaP-HD Flow Z-Pinch project provides a platform to explore how shear flow stabilized Z-pinches could scale to high-energy-density plasma (HEDP) and fusion reactor conditions. ZaP-HD generates shear stabilized, axisymmetric Z-pinches with stable lifetimes approaching $60$$\mu$s. The goal of the project is to increase the plasma density and temperature compared to the previous ZaP project by compressing the plasma to smaller radii ($\approx 1$ mm). Radial and axial plasma electron density structure is measured using digital holographic interferometry (DHI), which provides the necessary fine spatial resolution. ZaP-HD's DHI system uses a 2 ns Nd:YAG laser pulse with a second harmonic generator ($\lambda = 532$ nm) to produce holograms recorded by a Nikon D3200 digital camera. The holograms are numerically reconstructed with the Fresnel transform reconstruction method to obtain the phase shift caused by the interaction of the laser beam with the plasma. This provides a two-dimensional map of line-integrated electron density, which can be Abel inverted to determine the local number density. The DHI resolves line-integrated densities down to $3\times 10^{20}$ m$^{-2}$ with spatial resolution near $10 \mu$m. This work presents the first application of Fresnel transform reconstruction as an analysis technique for a plasma diagnostic, and it analyzes the method's accuracy through study of synthetic data. It then presents an Abel inversion procedure that utilizes data on both sides of a Z-pinch local number density profile to maximize profile symmetry. Error estimation and Abel inversion are applied to measured data.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRSDate not supplied

Broad Compatibility Study of Polymeric Materials with Ionic Silver Biocide, Part I

NASA is considering ionic silver as a residual biocide for use in potable water systems being planned for future exploration spacecraft. Compatibility of the biocide with the system’s wetted-materials of construction remains a challenge. Due to the relatively inert nature of plastics, their use in varied water system applications may offer unique opportunities to address many biocide compatibility issues. A 2020 ICES paper described a “Stage 1” assessment of several polymeric materials, in which coupons having a 2 cm 1 surface to volume ratio were exposed to solutions of 400 parts per billion (ppb) aqueous silver fluoride (AgF) for one week. In this current paper, additional Stage 1 test results are presented for select epoxies and lubricants applied on silver-inert substrates. The coupon exposure studies were also expanded to a duration of 5 weeks for the “well-behaved” Stage 1 plastics previously reported: those exhibiting silver losses above 10% and less than 50%. For this type of Stage 2 testing, silver biocide solution samples are taken from three separate (and not previously-sampled) coupon containers after 3 days, and 2, 3, 4, and 5 weeks of exposure. "Very well-behaved" Stage 1 plastics will be tested in the same manner over one year, with longer sample intervals; early-period results are included here. In addition, for select materials, the coupons were “aged” by refilling test containers with fresh AgF and observing the respective silver uptake over similar Stage 2 test durations. For all test series, Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and ion-selective electrode (ISE) analyses were used to determine total and ionic silver (Ag+) concentrations, respectively. Additional sample analyses for Stage 2 tests includes total organic carbon (TOC), pH, conductivity, and oxidation-reduction potential (ORP). Ultimately, these early compatibility studies will be used to guide future material selections for developing silver biocide-compatible spacecraft water systems.

Silver Biocide↗
DOE OSTI2024

Plasma Bubble Column Reactor: A High Throughput Reactor Design for Water Treatment

Plasma-based water treatment (PWT) is a promising technology that can degrade various emerging contaminants. However, PWT application on an industrially viable scale is hindered by the lack of an efficient reactor design that combines enhanced plasma-liquid contact with high liquid throughput. This work investigates the applicability of a bubble column gas-liquid contactor to PWT. A pulsed plasma bubble column reactor (PBCR) with a concentric rod-cylinder electrode configuration was used to correlate contaminant removal performance with the gas-liquid contact parameters of the bubble column. A surfactant, rhodamine B dye, and a nonsurfactant, caffeine, were used as model contaminants at µM concentration levels. The bubble column characteristics, i.e., gas holdup, bubble size distribution, and gas-liquid area, were measured as a function of superficial gas velocity using image-based methods. Degradation rates of both contaminants increased with gas flowrate. For caffeine, the increase was attributed to intensified bulk liquid mixing, while dye degradation increased due to the increased gas-liquid area. Ultimately, we show that bubble column contactors significantly improve the utilization of plasma-generated reactive species toward contaminant degradation by distributing them over a large contact area. As a result, a better match between the plasma species interfacial flux and the interfacial contaminant concentration leads to improved treatment energy efficiency. Furthermore, typical degradation energy efficiencies were ~10 g/kWh for caffeine and ~60 g/kWh for rhodamine B.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Moderate pressure plasma source of nonthermal electrons

Plasma sources of electrons offer control of gas and surface chemistry without the need for complex vacuum systems. The plasma electron source presented here is based on a cold cathode glow discharge (GD) operating in a dc steady state mode in a moderate pressure range of 2–10 torr. Ion-induced secondary electron emission is the source of electrons accelerated to high energies in the cathode sheath potential. The source geometry is a key to the availability and the extraction of the nonthermal portion of the electron population. The source consists of a flat and a cylindrical electrode, 1 mm apart. Our estimates show that the length of the cathode sheath in the plasma source is commensurate (~0.5–1 mm) with the inter-electrode distance so the GD operates in an obstructed regime without a positive column. Estimations of the electron energy relaxation confirm the non-local nature of this GD, hence the nonthermal portion of the electron population is available for extraction outside of the source. The use of a cylindrical anode presents a simple and promising method of extracting the high energy portion of the electron population. Langmuir probe measurements and optical emission spectroscopy confirm the presence of electrons with energies ~15 eV outside of the source. These electrons become available for surface modification and radical production outside of the source. In conclusion, the extraction of the electrons of specific energies by varying the anode geometry opens exciting opportunities for future exploration.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗