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At least 775 records · Page 43
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Secondary Electron Emission Yields

The secondary electron emission (SEE) characteristics for a variety of spacecraft materials were determined under UHV conditions using a commercial double pass CMA which permits sequential Auger electron electron spectroscopic analysis of the surface. The transparent conductive coating indium tin oxide (ITO) was examined on Kapton and borosilicate glass and indium oxide on FED Teflon. The total SEE coefficient ranges from 2.5 to 2.6 on as-received surfaces and from 1.5 to 1.6 on Ar(+) sputtered surfaces with 5 nm removed. A cylindrical sample carousel provides normal incidence of the primary beam as well as a multiple Faraday cup measurement of the approximately nA beam currents. Total and true secondary yields are obtained from target current measurements with biasing of the carousel. A primary beam pulsed mode to reduce electron beam dosage and minimize charging of insulating coatings was applied to Mg/F2 coated solar cell covers. Electron beam effects on ITO were found quite important at the current densities necessary to do Auger studies.

Krainsky, I.↗
NASA NTRS1981

Charging characteristics of silica fabrics

The charge dissipation mechanism of silica fabrics and silica fabric/Aluminum composites was studied by means of various sample configurations tested under monoenergetic electron beams at energies between 5 and 20 keV. Grounding of the aluminum rear face of the composite is necessary in order to ensure a good electrostatic performance. The surface potentials are dependent on the flux rate in the range 10 pA -cm(2-) to 3 nA cm(-2); they are the highest at the lowest flux rate. Strong discharges have been evidenced at 20 keV but do not occur under 15 keV electrons. A substantial decrease in the surface potential of the sample is observed every time that an irradiation by low energy electrons ( 2 to 4 keV) is performed simultaneously with the irradiation by medium-energy electrons (10 to 20 keV). Silica fabrics and composites are very sensitive of contamination or contamination-plus-irradiation effects.

Levy, L.↗
NASA NTRS1981

Review of NASA progress in thermal barrier coatings for stationary gas turbines

Ceramic thermal barrier coatings for industrial/utility gas turbines were investigated. In burner rig tests of a zirconia yttria/nickel chromium aluminum yttrium ZrO2-12w/0Y2O3/NiCrAlY coating system on air cooled superalloy specimens, ceramic coating life (spallation) was sensitive to Na and V concentration in the fuel. The locations of coating spallation correspond to areas where combustion products were predicted to condense. Three new thermal barrier coating systems were identified. These are based on calcium silicate, ZrO2-8w/0Y2O3, and a MgO-NiCrAlY cermet. The spall resistance can be increased by reducing the ceramic layer thickness from 0.038 to 0.013 cm and by the use of more oxidation/corrosion resistant bond coats.

Hodge, P. E.↗
NASA NTRS1982

Effect of fuel to air ratio on Mach 0.3 burner rig hot corrosion of ZrO2-Y2O3 thermal barrier coatings

A Mach 0.3 burner rig test program was conducted to determine how the fuel to air mass ratio affects the durability of ZrO2-Y2O3/Ni-16Cr-6Al-0.31Y thermal barrier coating systems in combustion products containing 5 ppm Na and 2 ppm V. As the fuel to air mass ratio was increased from 0.039 to 0.049, the durability of ZrO2-6Y2O3, ZrO2-8Y2O3 and ZrO2-12Y2O3 coatings decreased. ZrO2-8Y2O3 coatings were approximately 2X and 1.3X more durable than ZrO2-12Y2O3 and ZrO2-6Y2O3 coatings respectively at the fuel to air mass ratio of 0.039. The number of one hour cycles endured by ZrO2-8Y2O3 coatings varied from averages of 53 to 200 for the fuel to air mass ratios of 0.049 and 0.039, respectively. At the fuel to air mass ratio of 0.049, all ZrO2-Y2O3 coated specimens failed in 40 to 60 one hour cycles

Hodge, P. E.↗
NASA NTRS1982

Distribution of gas in the halo of the galaxy

Results are presented from a high-resolution, ultraviolet study of interstellar gas situated away from the plane of the Milky Way Galaxy, using the nuclei of Seyfert galaxies Mkn 509 and F9 as background probes. In these directions, low-velocity, galactic gas were detected as well as two extragalactic clouds, one probably associated with the Magellanic Stream and the other with Mkn 509. These data were combined with results from other lines of sight to show that the ultraviolet species extend about 10 kpc from the plane, assuming the high-latitude gas corotates with the galactic disk. Complimentary observations of the optical Ca II and Na I species suggests that these do not extend as far - perhaps 2 to 3 kpc from the plane. Further, the exceedingly complex velocity structure found only in Magellanic Cloud directions suggests that these sight-lines are not typical of high-latitude gas in general.

Blades, J. C.↗
NASA NTRS1981

Effect of laser frequency on a collision-induced radiative process

A review is presented of the principles of collision induced radiative processes, followed by an examination of the effects of laser frequencies on these processes. A one-dimensional problem involving two electron states is considered, and it is found that the Hamiltonian of the radiation field is dominated by electric-dipole interaction which couples states of different parity. Transitions are noted to be dependent on collisions, and the complexities of three-dimensional systems are expressed as considerations of the angular momentum of the photon, the necessity of treating different states simultaneously, and the fact that a radiation field destroys rotational invariance. Changing the radiation frequency alters the crossing point and offers opportunities to study the interplay of potential surfaces with molecular dynamics. Experiments on Na+A systems are outlined for several collision energies and various laser frequencies. Multiple crossings were obtained, although the total cross-section, at all energies, decreased at 18,350/cm.

Devries, P. L.↗
NASA NTRS1981

Ion sputtering from satellite surfaces

The manifestations of the induced surface currents as observed by the magnetic ion mass spectrometer (MIMS) and retarding potential analyzer (RPA) instruments on AE-C and AE-D are described. Data from these instruments are used to infer the source of some of the different secondary ions observed, as well as their time history and emission energy. It is noted that the emitted particles have a characteristic energy of approximately 1 eV in the spacecraft frame of reference and lack the normal ram energy possessed by the ambient ions. Alkali ions Na(+) and K(+), in addition to nonionospheric NO(+) and O2(+), are observed at low altitudes. With the exception of NO(+), all these are thought to be released by impacts of neutral N2 or O2 with the surfaces. These ion currents decrease with a time constant of about six weeks for the alkali and four weeks for the O2 ions.

Hanson, W. B.↗
NASA NTRS1981

Primitive ultrafine matrix in ordinary chondrites

Ultrafine matrix material has been concentrated by sieving and filtering disaggregated samples of six ordinary chondrites of different classes. This component(s), 'Holy Smoke' (HS), is enriched in both volatile, e.g. Na, K, Zn, Sb, and Pb, as well as refractory elements, e.g. W and REE; however, the element ratios vary greatly among the different chondrites. SEM studies show that HS contains fragile crystals, differing in composition, and apparently in gross disequilibrium not only among themselves but also with the major mineral phases and consequently thermodynamic equilibration did not occur. Thus HS must have originated from impacting bodies and/or was inherent in the 'primitive' regolith. Subsequent impact brecciation and reheating appears to have altered, to varying degrees, the original composition of this ultrafine matrix material. Recent 'cosmic dust' studies may indicate that HS still exists in the solar system. Survival of such delicate material must be considered in all theories for the origin of chondrites.

Rambaldi, E. R.↗
NASA NTRS1982

A new interstellar component in the spectrum of HD 72127A

New high dispersion observations are reported of the very strong, broad interstellar K line of Ca II in the spectrum of HD 72127A, a star located near a filament of the Vela supernova remnant. When compared with similar observations made in 1977, the new data reveal temporal variability of the interstellar absorption, as shown both by the presence of a new, sixth line component and by a 25% increase in the total equivalent width of the K line. All five Ca II components which were seen in both years show very large column-density ratios N(Ca II) /N(Na I) at least equal to 9, probably arising from anomalously large interstellar gas-phase abundances of Ca caused by disruption of interstellar grains. Marked differences in the structure of the K line between the two early-type components of this binary star, which are separated by only 3000 AU, are confirmed.

Hobbs, L. M.↗
NASA NTRS1981

Comparison of electrochemical and thermal storage for hybrid parabolic dish solar power plants

The economic and operating performance of a parabolic point focus array of solar electricity generators combined with either battery or thermal energy storage are examined. Noting that low-cost, mass-producible power generating units are under development for the point focus of distributed dishes, that Zn-Cl battery tests will begin in 1981 and a 100 kWh Na-S battery in 1983, the state of thermal storage requires acceleration to reach the prototype status of the batteries. Under the assumptions of 10,000 units/yr with an expected 30 yr lifetime, cost comparisons are developed for 10 types of advanced batteries. A 5 MWe plant with full thermal or 80% battery storage discharge when demand occurs in conditions of no insolation is considered, specifically for Fe-Cr redox batteries. A necessity for the doubling of fuel prices from 1980 levels by 1990 is found in order to make the systems with batteries economically competitive.

Steele, H. L.↗
NASA NTRS1981

Accretionary dark rims in unequilibrated chondrites

Textural and qualitative EDX investigations of dark-rimmed particles in six low petrologic type chondrites indicate that the rims accreted on host particles over a wide range of temperatures prior to initial accumulation and lithification of the meteorites in which the rimmed particles are now contained. Many dark rims are enriched in moderately volatile trace elements such as Na, Cl, P, and K, relative to the host particles and matrix. The range of physical/chemical environments associated with hypervelocity impacts may have offered the setting for the formation of dark-rimmed particles early in solar system history.

King, T. V. V.↗
NASA NTRS1981

Flame structure in a swirl stabilized combustor inferred by radiant emission measurements

Results of measurements of time-averaged chemiluminescent emissions from CH, OH, and CO2 and of Na tracer emissions along lateral lines-of-sight through a cylindrical premixed, swirl-stabilized combustor are reported. Assuming axial symmetry and small optical depth, raw data are inverted to obtain local emission levels from these species as a function of radius. The chemiluminescent emissions are interpreted as signatures of chemical reaction and used in determining the regions of reactions and heat release in the combustor. The data are compared with composition and velocity data obtained in the combustor for identical operating conditions. The results demonstrate that reaction occurs in a relatively narrow, turbulent flame-like combustion zone which begins upstream of the time-averaged location of the swirl-induced recirculation zone and propagates around and laterally away from the recirculation zone into the unburned gas.

Beyler, C. L.↗
NASA NTRS1982

The source abundances of galactic cosmic rays

The galactic cosmic ray source abundances have been determined from two complete datasets, one at low and the other at high energy. For both exponential and truncated exponential pathlength distributions (PLD), the two sets of source abundances show significant differences for the primary elements, i.e., the Fe/O ratio. An energy dependent PLD reduces but does not eliminate the discrepancy, and this may indicate an energy dependence in the source composition. New source abundances for Na, P, Cl, Ca, and Mn are derived.

Dwyer, R. D.↗
NASA NTRS1982

The gaseous galactic halo as inferred from the line spectra of the galaxies Markarian 509 and Fairall 9

Narrow interstellar absorption lines of S II 1259.52, Si II 1260.42, and Fe II 1608.46 due to gas in the disk and the halo of the Galaxy have been detected in the spectrum of the Seyfert galaxy Mrk 509 with the International Ultraviolet Explorer. This gas is also seen at higher resolution in the Ca II and Na I absorption lines in two components at LSR velocities of +6 and +62 km/s. In addition, narrow Ly-alpha and C IV absorption near the Seyfert redshift seem to be present in the spectrum. Si II 1260.42 absorption from the galactic disk and from the Magellanic Stream or the halo of the SMC have been detected with the IUE in the spectrum of Fairall 9. The observations of these two objects when combined with existing results are shown to be consistent with a corotating galactic halo having a height of less than 10 kpc at the sun.

York, D. G.↗
NASA NTRS1982

Aspects of the history of 66095 based on trace elements in clasts and whole rock

Halogens, P, U and Na are reported in anorthositic and basaltic clasts and matrix from rusty rock 66095. Large fractions of Cl and Br associated with the separated phases from 66095 are soluble in H2O. Up to two orders of magnitude variation in concentrations of these elements in the breccia components and varying H2O-soluble Cl/Br ratios indicate different sources of volatiles. An approximately constant ratio of the H2O- to 0.1 M HNO3-soluble Br in the various components suggests no appreciable alteration in the original distributions of this element in the breccia forming processes. Up to 50% or more of the phosphorus and of the non-H2O-soluble Cl was dissolved from most of the breccia components by 0.1 M HNO3. Clast and matrix residues from the leaching steps contain, in most cases, the Cl/P2O5 ratio found in 66095 whole rock and in a number of other Apollo 16 samples. Evidence that phosphates are the major P-phases in the breccia is based on the 0.1 M acid solubility of Cl and P in the matrix sample and on elemental concentrations which are consistent with those of KREEP.

Jovanovic, S.↗
NASA NTRS1982

The interstellar spectrum of the supernova 1980k in NGC 6946

Bright supernovae in external galaxies offer a rare opportunity to probe the intervening interstellar media over very extended path-lengths, including the disk and halo of the Galaxy and the parent galaxy of the supernova. SN 1980k was discovered in NGC 6946 on 1980 October 29. In the first month after discovery, high resolution optical and ultraviolet observations were obtained to exploit the supernova as a probe of the intervening interstellar media. The obtained data are discussed. In the spectra, absorption lines were observed of Mg I, Mg II, Fe II, Mn II, Ca II and Na I. The absorption lines are attributed to the intervening interstellar media distributed over the very extended line of sight sampled, of order 7 Mpc. These lines are wider and stronger than any previously measured in the quiescent interstellar gas in the halo and disk of the Milky Way and of external galaxies

Pettini, M.↗
NASA NTRS1982

Interaction between ATP, metal ions, glycine, and several minerals

Interactions between ATP, glycine and montmorillonite and kaolinite clay minerals in the presence of various metal cations are investigated. The adsorption of adenine nucleotides on clays and Al(OH)3 was measured as a function of pH, and glycine condensation was followed in the presence of ATP, ZnCl2, MgCl2 and either kaolinite or montmorillonite. The amounts of ATP and ADP adsorbed are found to decrease with increasing Ph, and to be considerably enhanced in experiments with Mg(2+)- and Zn(2+)-montmorillonite with respect to Na(+)-montmorillonite. The effects of divalent cations are less marked in kaolinite. Results for Al(OH)3 show the importance of adsorption at clay platelet edges at high pH. The decomposition of ATP during drying at high temperature is observed to be inhibited by small amounts of clay, vacuum, or Mg(2+) or Zn(2+) ions, and to be accompanied by peptide formation in the presence of glycine. Results suggest the importance of Zn(2+) and Mg(2+) in chemical evolution.

Rishpon, J.↗
NASA NTRS1982

Theory of metal atom-water interactions and alkali halide dimers

Theoretical studies of the interactions of metal atoms with water and some of its isoelectronic analogs, and of the properties of alkali halides and their aggregates are discussed. Results are presented of ab initio calculations of the heats of reaction of the metal-water adducts and hydroxyhydrides of Li, Be, B, Na, Mg, and Al, and of the bond lengths and angles an; the heats of reaction for the insertion of Al into HF, H2O, NH3, H2S and CH3OH, and Be and Mg into H2O. Calculations of the electron affinities and dipole moments and polarizabilities of selected gas phase alkali halide monomers and dimers are discussed, with particular attention given to results of calculations of the polarizability of LiF taking into account electron correlation effects, and the polarizability of the dimer (LiF)2.

Jordan, K. D.↗