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At least 775 records · Page 43

Lost Foam Thin Wall: Feasibility of Producing Lost Foam Castings in Aluminum and Magnesium Based Alloys

With the increased emphasis on vehicle weight reduction, production of near-net shape components by lost foam casting will make significant inroad into the next-generation of engineering component designs. The lost foam casting process is a cost effective method for producing complex castings using an expandable polystyrene pattern and un-bonded sand. The use of un-bonded molding media in the lost foam process will impose less constraint on the solidifying casting, making hot tearing less prevalent. This is especially true in Al-Mg and Al-Cu alloy systems that are prone to hot tearing when poured in rigid molds partially due to their long freezing range. Some of the unique advantages of using the lost foam casting process are closer dimensional tolerance, higher casting yield, and the elimination of sand cores and binders. Most of the aluminum alloys poured using the lost foam process are based on the Al-Si system. Very limited research work has been performed with Al-Mg and Al-Cu type alloys. With the increased emphasis on vehicle weight reduction, and given the high-strength-to-weight-ratio of magnesium, significant weight savings can be achieved by casting thin-wall (≤ 3 mm) engineering components from both aluminum- and magnesium-base alloys.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Advanced Manufacture of Reflectors

The main project objective has been to develop an advanced gravity sag method for molding large glass solar reflectors with either line or point focus, and with long or short focal length. The method involves taking standard sized squares of glass, 1.65 m x 1.65 m, and shaping them by gravity sag into precision steel molds. The method is designed for high volume manufacture when incorporated into a production line with separate pre-heating and cooling. The performance objectives for the self-supporting glass mirrors made by this project include mirror optical accuracy of 2 mrad root mean square (RMS), requiring surface slope errors less than 1 mrad rms, a target not met by current production of solar reflectors. Our objective also included development of new methods for rapidly shaping glass mirrors and coating them for higher reflectivity and soil resistance. Reflectivity of 95% for a glass mirror with anti-soil coating was targeted, compared to the present ~94% with no anti-soil coating. Our mirror cost objective is ~$20/m 2 in 2020, a significant reduction compared to the present ~$35/m 2 for solar trough mirrors produced for trough solar plants.

14 SOLAR ENERGY↗

Glovebox Advanced Casting System Casting Optimization

Casting optimization in the GACS included three broad areas; casting of U-10Zr pins, incorporation of an integral FCCI barrier, and development of a permanent crucible coating. U-10Zr casting was improved over last year’s results by modifying the crucible design to minimize contact with the colder mold. Through these modifications casting of a three pin batch was successful. Incorporation of an integral FCCI barrier also was optimized through furnace chamber pressure changes during the casting cycle to reduce gas pressures in the mold cavities which led to three full length pins being cast which incorporated FCCI barriers of three different thicknesses. Permanent crucible coatings were tested against a base case; 1500°C for 10 minutes in a U-20Pu-10Zr molten alloy. None of the candidate coating materials showed evidence of failure upon initial visual examination. In all areas of work a large amount of characterization will be needed to fully determine the effects of the optimization activities. The characterization activities and future work will occur next year.

36 MATERIALS SCIENCE↗

Modeling Manufacturing Impacts on Aging and Reliability of Polyurethane Foams

Polyurethane is a complex multiphase material that evolves from a viscous liquid to a system of percolating bubbles, which are created via a CO2 generating reaction. The continuous phase polymerizes to a solid during the foaming process generating heat. Foams introduced into a mold increase their volume up to tenfold, and the dynamics of the expansion process may lead to voids and will produce gradients in density and degree of polymerization. These inhomogeneities can lead to structural stability issues upon aging. For instance, structural components in weapon systems have been shown to change shape as they age depending on their molding history, which can threaten critical tolerances. The purpose of this project is to develop a Cradle-to-Grave multiphysics model, which allows us to predict the material properties of foam from its birth through aging in the stockpile, where its dimensional stability is important.

36 MATERIALS SCIENCE↗

Development of High-Performance Cast Crankshafts. Final Technical Report

The objective of this project was to develop technologies that would enable the production of cast crankshafts that can replace high performance forged steel crankshafts. To achieve this, the Ultimate Tensile Strength (UTS) of the new material needs to be 850 MPa with a desired minimum Yield Strength (YS; 0.2% offset) of 615 MPa and at least 10% elongation. Perhaps more challenging, the cast material needs to be able to achieve sufficient local fatigue properties to satisfy the durability requirements in today’s high performance gasoline and diesel engine applications. The project team focused on the development of cast steel alloys for application in crankshafts to take advantage of the higher stiffness over other potential material choices. The material and process developed should be able to produce high-performance crankshafts at no more than 110% of the cost of current production cast units, perhaps the most difficult objective to achieve. To minimize costs, the primary alloy design strategy was to design compositions that can achieve the required properties with minimal alloying and post-casting heat treatments. An Integrated Computational Materials Engineering (ICME) based approach was utilized, rather than relying only on traditional trial-and-error methods, which has been proven to accelerate alloy development time. Prototype melt chemistries designed using ICME were cast as test specimens and characterized iteratively to develop an alloy design within a stage-gate process. Standard characterization and material testing was done to validate the alloy performance against design targets and provide feedback to material design and manufacturing process models. Finally, the project called for Caterpillar and General Motors (GM) to develop optimized crankshaft designs using the final material and manufacturing processing path developed. A multi-disciplinary effort was to integrate finite element analyses by engine designers and geometry-specific casting simulations with existing materials models to optimize crankshaft cost and performance. Prototype crankshafts of the final design were to be produced and validated using laboratory bench testing and on-engine durability testing. ICME process simulation tools were used to investigate a broad range of processing concepts. These concepts included casting orientation, various mold and core materials, and various filling and feeding strategies. Each crankshaft was first simulated without gating and risers, which is termed natural solidification. The natural solidification results were used as a baseline for strategy development of each concept. Casting process simulations and ICME tools were proven to be reasonable predictors of real world results. Potential alloys were developed that could meet the project material property goals with appropriate normalization and temper treatments. For the alloys considered, post-normalization temper treatments proved to be necessary to achieve the desired yield strengths and elongations and appropriate heat treatments were designed using ICME tools. The experimental data of all the alloys were analyzed in combination with ICME tools to establish chemistry-process-structure relations. Several GM small gas engine (SGE) crankshafts were successfully cast in sand molds using two different sprue, runner, gate, riser, chill designs. These crankshafts were cast in two different steel alloys developed during the project, but casting finishing (e.g. riser removal) remains a cost challenge. A long list of future work was left unfinished when this project was unexpectedly terminated.

36 MATERIALS SCIENCE↗

HFIR Fuel Casting Support

Process exploration for fuel production for the High Flux Isotope Reactor (HFIR) using cast LEU-10wt.%Mo as an initial processing step has just begun. This project represents the first trials concerned with casting design and quality. The studies carried out over the course of this year and information contained in this report address the initial mold development to be used as a starting point for future operations. In broad terms, the final billet design is that of a solid rolling blank with an irregular octagonal cross section. The work covered here is a comprehensive view of the initial attempts to produce a sound casting. This report covers the efforts to simulate, predict, cast, inspect, and revise the initial mold design.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Develop and Manufacture an Ergonomically Sound Glovebox Glove Report

Ergonomic injury and radiation exposure are two safety concerns for the Plutonium Facility at Los Alamos National Laboratory (LANL). This facility employs the largest number of gloveboxes (GB) at LANL with approximately 6000 gloves installed. The current GB glove design dates back to the 1960’s and is not based on true hand anatomy, revealing several issues: short fingers, inappropriate length from the wrist to finger webbing, nonexistent joint angles and incorrect thumb placement. These design flaws are directly related to elbow (lateral epicondylitis) and thumb (DeQuervain’s tenosynovitis) injuries. The current design also contributes to increased wear on the glove, causing unplanned glove openings (failures) which places workers at risk of exposure. An improved glovebox glove design has three significant benefits: 1) it will reduce the risk of injury, 2) it will improve comfort and productivity, and 3) it will reduce the risk of a glovebox failures. The combination of these three benefits has estimated savings of several million dollars. The new glove design incorporated the varied physical attributes of workers ranging from the 5 th percentile female to the 95th percentile male. Anthropometric hand dimensions along with current GB worker dimensions were used to develop the most comprehensive design specifications for the new glove. Collaboration with orthopedic hand surgeons also provided major contributtions to the design. The new glovebox glove was developed and manufactured incorporating over forty dimensions producing the most comprehensive ergonomically sound design. The new design received a LANL patent (patent attorney docket No: LANS 36USD1 “Protective Glove”, one of 20 highest patents awarded by the Richard P. Feynman Center for Innovation. The glove dimensions were inputed into a solid works model which was used to produce molds. The molds were then shipped to a glove manufacturer for production of the new glovebox gloves. The new glovebox gloves were tested against the presently used glovebox gloves for design validity. The testing included a subjective survey and four dexterity tests. The prototype was statistically significant in 3 dexterity tests and favorable on 8 out of 10 survey questions. The more ergonomically sound glovebox glove will improve worker comfort, mitigate glovebox worker injuries, and reduce glove breaches.

42 ENGINEERING↗

Additively Manufactured, Net Shape Powder Metallurgy Cans for Valves Used in Energy Production

Additive manufacturing (AM) has the potential to enable a paradigm shift in fabricating complex net shape components with yields over 90%, significantly increasing productivity, decreasing energy consumption during manufacturing and improving downstream energy efficiency. ORNL has developed a technology for producing large-scale additively manufactured polymer matrix composite components at deposition rates on the order of 100 lbs. per hour. This project utilized tools, dies and molds made from this technology to enable the net shape forming of cans for the powder metallurgy (PM) manufacturing of valves used in energy production plants. This approach has the potential to develop affordable valves with superior performance to castings. It will also lead to increased strength values, decreased wall thickness size, and the potential for higher yields (less machining). This project is critical for evaluating new methodologies for the fabrication of additively manufactured tooling, molds and dies that could be used across multiple industries. In the first phase of this project, a new methodology of creating a Powder Metallurgy and Hot Isostatic Pressing (PM-HIP) container by hydroforming sheet metal over additively manufactured (AM) dies was evaluated. The goal in this stage of development was to evaluate some of the new polymer matrix composite materials designed for deposition on large scale additive manufacturing systems as candidates for hydroforming steel and aluminum sheet to make thin gauge net shape components. In order to meet this objective, most research was performed on subscale tools in order to evaluate the processing pressures, material options, and gauge thicknesses most relevant to this approach. In addition, full scale AM tools (30% over final component geometry) were produced to demonstrate scalability, but were not used in testing. The first phase of this project has proven this concept has merit, but future studies are required to address minor tool failures that occurred in phase one due to geometry, cost of the process over other techniques, and demonstration of a full-scale tool that could then be used in (HIP). Lastly, this project provides the PM community a new approach in using hydroforming for the manufacturing of cans, a process that was not highly utilized for this purpose previously.

42 ENGINEERING↗

Low-Cost Titanium Casting Technology

This is the final report of "Low-Cost Titanium Casting Technology" project. Titanium alloys have attracted increasing attentions as structural materials for high performance and weight-sensitive applications in aerospace and biomedical fields. However, in mass-production of civil applications like automotive components, titanium alloys are scarcely used due to the unaffordable costs in manufacturing compared with other metallic materials, such as aluminum, magnesium and steel. Therefore, there is a need to reduce the manufacturing cost of titanium alloys so that titanium alloys can be more competitive in terms of property and cost considerations. In this 4-year project, we started from exploring new low-cost titanium alloy systems with the guidance of Integrated Computational Materials Engineering – Calculation of Phase Diagram (ICME-CALPHAD) framework, and determined several promising alloy systems, alloying elements including Ti-Al-Fe-Mn-B-C, that can allow further development (lab-scale and industry-scale) in the future. During the new alloy system exploration, considerable amount of scientific work was completed regarding CALPHAD modeling, microstructure morphology, mechanical properties, and processing of the new alloy systems. The relevant ternary titanium alloy systems, Ti-Al-Mn and Ti-Al-Fe, were examined and reassessed both computationally and experimentally, leading to more comprehensive understanding of these alloy systems. Based on this above study, a new low-cost casting titanium alloy was developed, Ti-6Al-5Fe-0.05B-0.05C (designated as T65-0.05BC), which has competitive as-cast strength level with current commercial titanium alloys but relatively low ductility. However, in this project, since the target application, automotive engine connecting rod, is a fatigue-limited component and does not require high ductility, this alloy shall suffice as the deliverable alloy in this project. After designing and confirming the potent of the new alloy, we designed and built a lab-scale manufacturing equipment aided by computational tools at OSU labs to conceptually prove that this alloy can be manufactured with permanent mold casting, which is low-cost and potentially a mass production process. We produced a lab-scale prototype connecting rod demonstrating the capability of permanent mold casting of this new alloy.

36 MATERIALS SCIENCE↗

Manufacturing Induced Residual Stress Development and Deformation in PMDI-10 Structural Foam

In this report, we investigate how manufacturing conditions result in the warpage of moderate density PMDI polyurethane foam (12-50 lb/ft 3 ) when they are released from a mold. We have developed a multiphysics modeling framework to simulate the manufacturing process including resin injection, foaming and mold filling, gelation of the matrix, elevated cure, vitrification, cool down, and demolding. We have implemented this framework within the Sierra Mechanics Finite Element Code Suite. We couple Aria for flow, energy conservation, and foaming/curing kinetics with Adagio for the nonlinear viscoelastic solid response in a multi-staged simulation process flow. We calibrate a model for the PMDI-10S (10 lb/ft 3 free rise foam) through a suite of characterization data presented here to calibrate the solid cure behavior of the foam. The model is then used and compared to a benchmark experiment, the manufacturing and warpage over 1 year of a 10 cm by 10 cm by 2.5 cm foam "staple". This component features both slender and thick regions that warp considerably differently over time. Qualitative agreement between the model and the experiment is achieved but quantitative accuracy is not.

36 MATERIALS SCIENCE↗

Hygrothermal analyses of the moisture control and energy efficiency potential of an adaptive water-resistive barrier for building envelopes

A water-resistive barrier (WRB) is a material installed on the exterior side of the sheathing to prevent water intrusion so that building components are not damaged by moisture. A membrane that can change its water vapor permeability between two states to control water vapor transport into and out of residential and commercial building wall systems is being developed. This simulation study assesses if this membrane used as a WRB reduces moisture levels and mold growth risk in exterior walls and building energy consumption. The developed membrane may require modifications to fully function as a WRB in contact with liquid water. Hygrothermal component simulations were conducted for different climate zones, different wall assemblies, different switching points and permeabilities to identify the most beneficial application cases and their required perm range and switching control. The study details the required simulation settings and suggests that the switchable membrane can reduce the water content in the sheathing and reduce the mold growth risk in the cavity in all climate zones. The effect on energy consumption of the switchable membrane is not significant. The study also includes recommendations on how to model the material characteristics of a switchable membrane and recommendations on practical applications for the switchable membrane.

42 ENGINEERING↗

Metal Fuel Casting Simulation (Annual Report)

Continuing work to develop the capability to simulate metallic fuel fabrication at Idaho National Laboratory (INL) is presented in this report. Simulations using the Truchas code developed at LANL and the commercial software package FLOW3D were used to evaluate the capabilities necessary for modeling mold filling and solidification of the bench scale caster (BSC). The results suggest that surface tension and the pressure effects of the argon in the mold must both be included in the simulation to obtain results that are qualitatively similar to the experimentally observed rod size and morphology. Effects of viscosity of the liquid metal seem to be relatively unimportant. The possibility of flow of partially solidified material is examined, and may be important for the flow conditions in the BSC. A more general discussion of software requirements is included for casting processes that are suitable for metallic fuel rods. A comparison of current capabilities of Truchas and FLOW3D is presented. Neither of the two codes has all the capabilities needed, and future work will probably use both software packages. A performance and scaling evaluation of FLOW3D indicates that adequate performance can be obtained for this project using multiprocessor hardware.

1.02.02.02↗

Thermoplastic Composites Parts Manufacturing Enabling High Volumes, Low Cost, Reduced Weight with Design Flexibility – Phase 2

The deliverable of this IACMI PHASE II project is an innovative thermoplastic composite parts manufacturing process that addressed some of the most challenging aspects for commercial adoption in high volume market applications with requisite design flexibility while lowering cost and weight. The collaborative 15-month joint effort built upon the collective collateral value that was validated in PHASE I, as well as the synergies of a cross- functional team members comprised & lead by DuPont, Fibrtec & Purdue. Specifically, Fibrtec’s uniquely flexible coated tow (FibrFlex®) with DuPont's Rapid Fabric Formation (RFF) technology and a proprietary DuPont polyamide resin, were used to create near net shapes, while Purdue developed new simulation tools to predict the behavior of material system preforms in molding processes. These were ultimately deployed for the manufacturing with “informed” performance of industrially-interesting CFRP parts. Experiments, modeling, and simulations have shown that this process/materials combination offers advantages for producing lower cost continuous fiber reinforced polymer (CFRP) materials that drape well during molding while maintaining outstanding physical properties. This newly deployed process is ideally suitable for adoption in the automotive and other higher volume industries because of the associated cost savings due to reduction of waste and embodied energy. Furthermore, it overcomes the drawbacks of the prevalent two other typically deployed processes; the slow speed and expensive part formation associated with the usage of the stiff and brittle UD tapes, or the release of short conductive carbon fiber strands into the environment associated by the alternate layering of fiber woven fabric with resin film.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Manufacturing of Advanced Alnico Magnets for Energy Efficient Traction Drive Motors CRADA Final Report

The primary theme of this Technology Commercialization Fund (TCF) project was refining the pre-alloyed powder processing approach (with alnico 8, modified for higher coercivity) of that came out of the previous Development of Radically Enhanced alnico Magnets (DREaM) project to permit full size net-shape alnico magnets to be produced in a reproducible manner that could allow testing in an advanced Permanent Magnet (PM) drive motor. Previously, a lack of sufficient coercivity in alnico magnets limits their energy product and their application in automotive traction drive motors, despite their high temperature stability. Use of enhanced sintered alnico magnets, instead of rare earth (RE) magnets or larger cast alnico magnets, could lower costs and decrease cooling needs of these motors. Conventional production of the best (aligned) alnico magnets (alnico 9) involves costly directional solidification (DS) and achieves good alignment, but modest energy product (10 MGOe), because of low coercivity. Other limitations of cast alnico 9 magnets are poor mechanical properties and difficulty in scaling special casting molds to mass production. In spite of these problems with alnico 9, a commercial electric motor company, UQM, developed a fully capable traction drive motor that met many 2022 DOE-VTO performance targets, except full speed operation, due to brittle mechanical behavior. While UQM demonstrated an advanced drive motor that used alnico 9, they also encouraged the development of improved alnico, especially for greater coercivity (seeking 2X) and improved mechanical properties. While commercial sintered alnico magnets are less brittle and have improved coercivity, they have an inferior energy product due to their non-aligned, fine-grained microstructure. Thus, full development and up-scaling of well-aligned alnico magnets with a further increase in coercivity and good mechanical properties by a low cost powder processing route became the theme of this TCF project. The processing route for this project involved high-pressure gas atomization, at Ames and Carpenter, of modified alnico 8 compositions, compression molding of the resulting pre-alloyed powders into bulk samples, de-binding and sintering the samples to full density, and a final magneto-thermal treatment of the resulting bulk magnets, at Ames and Arnold Magnetic Technologies, to produce aligned magnets, which were intended for motor testing at UQM and Ford.

42 ENGINEERING↗

Validation of Wichner Predictive Model for Chronic Oxidation by Moisture of Nuclear Graphite

This document reports the results of multi-year extensive research on chronic oxidation of nuclear graphite by traces of moisture that might be present in the helium coolant of high-temperature gas-cooled reactors (HTGRs). The research focuses on four grades of nuclear graphite that are considered potential candidates for component fabrication in advanced nuclear reactors. The four grades are (1) PCEA (medium-fine grain, extruded, manufactured by GrafTech Inc., USA); (2) NBG-17 (medium-fine grain, vibrationally molded, manufactured by SGL Carbon, Germany/France); (3) IG-110 (microfine grain, isostatically molded, manufactured by Toyo Tanso, Japan); and (4) 2114 (microfine grain, isostatically pressed, manufactured by Mersen, USA). The experimental part of this research comprised three objectives that were consistently pursued for each graphite material: (1) accelerated oxidation tests in well-controlled conditions (temperature, gas composition) and analysis of chemical kinetic models and of their parameters for each graphite grade; (2) measurements of water vapor transport rates from H 2 O/He mixtures through thin graphite slabs for estimation of the water effective diffusivity specific to each material; (3) controlled oxidation of graphite specimens in H 2 O/He mixtures and characterization of the effects of oxidation temperatures on the density profiles of oxidized layers. These three groups of experimental results were interpreted using the model developed by Wichner et al. for predicting the penetration depth of oxidants (moisture or oxygen) as a function of oxidation conditions. Basically, starting from the kinetic and transport properties of each graphite grade, the ultimate goal was predicting the stable density profile in the oxidized layer and its dependence on the oxidation temperature. The profiles obtained this way were then compared against direct observations of oxidized layers in specimens obtained in well-controlled oxidation conditions. The general agreement between predictions and observations validated the general applicability of the Wichner model. The results obtained in this project were presented at annual Department of Energy–Advanced Reactor Technologies program reviews and at specialist meetings and conferences and were published in Oak Ridge National Laboratory (ORNL) reports and in professional journals. The results published in 2018 had an immediate impact in 2019, when a group from three US universities used ORNL kinetic data as input information in a complex simulation of chronic oxidation by moisture using the same graphite grades during long-time operation in a modular high-temperature gas-cooled reactor. Their conclusion, in line with the conclusions obtained at the end of this project, was that chronic graphite oxidation by moisture during normal operation conditions of an HTGR will be limited to a thin surface layer of graphite blocks at the reactor bottom, where the highest temperatures are. That will not affect the integrity of graphite components and reactor safety, provided the impurity concentration in the helium coolant is rigorously controlled and maintained at the design specifications.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Process Development of a Direct Cast U-6Nb 250 mm Cylinder

Direct Casting is the process of casting a near-net shape part of U-6wt%Nb in a multi-zone VIM furnace for subsequent heat treatment and machining in to a final component. This interim report describes ongoing work to further develop a sound technical basis and best practices for mold design and process parameters for the Direct Casting of U-6Nb components with a cylindrical geometry. Specifically, process parameters and mold design are examined in detail for producing a hollow cylinder 250 mm diameter by 450 mm long which is 10 to 12 mm thick. The goal is to efficiently produce a sound casting with a minimum of microporosity and uniform niobium composition.

36 MATERIALS SCIENCE↗

Swab Tensile Testing Results and Procedures

This tensile test is to mimic the worst-case scenario of the swab being caught on an obstruction when being pulled out of the nasopharyngeal space. It is to determine how much tensile force the swab can withstand without breaking. A variety of different swabs (different materials and different geometries) were tested using the protocol outlined in Section 2 (Tensile Testing Procedure). Not all of the swabs were pre-treated using the Autoclave. For those swabs that were pre-treated using the Autoclave, the tensile tests were performed within 6 hours of completion of the Autoclave pre-treatment, with the exception of the Injection Molded samples. For the Injection Molded samples, the tensile tests were performed within 24 hours of the completion of the Autoclave pre-treatment. The FormLabs-USF and FormLabs-Northwell were printed at LLNL using FormLabs Surgical Grade V1 Resin on a Form 3B Printer. All other samples were provided by HP.

36 MATERIALS SCIENCE↗

Comparison of Polymer AM Technologies for Automotive Tooling for Composite Engines

Oak Ridge National Laboratory’s (ORNL) Manufacturing Demonstration Facility (MDF) worked with Polimotor to complete a set of molds for fabricating the oil pan for a composite engine. This project used multiple different AM processes to fabricate the mold set. The assembled parts were measured for tolerance and then sent to Polimotor to be used in the manufacture of engine components.

42 ENGINEERING↗