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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Strong magnetocaloric effect induced by spin reorientation transitions in epitaxial Ho thin films

In this work, magnetocaloric effect (MCE) in an antiferromagnetic holmium (Ho) film is studied near the spin reorientation temperatures. A series of magnetization isotherms from 60 to 150 K around the Néel temperature, $T_N$ ≈ 130 K were recorded for both in-plane and out-of-plane magnetic field orientations. A change in entropy, Δ$S_M$ of –5 J/kgK was found near $T_N$ for an in-plane field orientation. A large change in Δ$S_M$ of –11.8 J/kg K due to a fan-helix spin transition at $\textit{T}$ = 90 K is observed for an in-plane field orientation. Spin transition at both $T_N$ and at the fan-helix transition exhibit larger MCE in the in-plane field orientations in comparison with the perpendicular orientation. The value of the refrigerant capacity extracted from the temperature dependence of Δ$S_M(T)$ is found to be larger for the “in- plane” orientation by a factor of two.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

The Driving Force Controls Charge Separation Distance in Solid-State Organic Donor/Acceptors

In this work, charge pairs of varying separation distance are interpreted from photoinduced absorption detected magnetic resonance (PADMR) spectroscopy of organic, small molecule dilute donor/acceptor thin films. We report that a donor/acceptor film that generates few free charges at room temperature yet has a relatively large, calculated driving force for electron transfer generates a large concentration of tightly bound CT states when measured with PADMR. These states are markedly absent in films with smaller driving forces yet higher free charge yields which instead only show charge-separated state signals with weaker spin coupling. We interpret this result to be in support of a hypothesis where a larger reorganization energy associated with charge transfer to tightly bound CT states means that they are primarily generated in systems far from the Marcus optimum for free charge yield. And the highest free charge yielding systems instead predominantly undergo long-range charge separation into the acceptor host.

charge separation↗
DOE OSTI2022

Design of a Scavenging Pyrrole Additive for High Voltage Lithium-Ion Batteries

We report 1-(dimethylamino) pyrrole (PyDMA) as an electrolyte additive for high voltage lithium-ion batteries based on LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC622)//Graphite with an upper cutoff voltage of 4.4 V. Density Functional Theory (DFT) modeling indicates that the unique structure of PyDMA could be effective in preventing the hydrolysis of LiPF 6 in a carbonate electrolyte, mitigating issues related to HF formation. The calculations also indicated that the additive would oxidize at lower potentials than typical electrolyte solvents, which could lead to protective films at the cathode surface. These expectations were tested using Nuclear Magnetic Resonance (NMR) and extensive electrochemical characterization. NMR studies confirmed the superb dehydrating capability of PyDMA, which successfully prevents HF formation even at high water content. Addition of 0.5 wt% PyDMA resulted in improved capacity retention in full-cells, and also in lower levels of transition metal dissolution from the cathode. Incremental capacity (dQ/dV) analysis indicates that benefits of PyDMA at low concentration (0.5–1 wt%) are associated with decreased rates of Li + -trapping reactions, and that higher concentrations of the additive can lead to isolation of cathode domains. Furthermore, our study indicates that PyDMA could be a promising electrolyte additive for high voltage lithium-ion batteries at a low concentration.

25 ENERGY STORAGE↗
DOE OSTI2023

Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite

In the search for environmentally friendly materials with a wide range of properties, polymer composites have emerged as a promising alternative due to their multifunctional properties. This study focuses on the synthesis of composite materials consisting of four components: bacterial nanocellulose (BNC) modified with magnetic Fe 3 O 4 , and a mixture of BaTiO 3 (BT) and polyvinylidene fluoride (PVDF). The BT powder was mechanically activated prior to mixing with PVDF. The influence of BT mechanical activation and BNC with magnetic particles on the PVDF matrix was investigated. The obtained composite films’ structural characteristics, morphology, and dielectric properties are presented. This research provides insights into the relationship between mechanical activation of the filler and structural and dielectric properties in the PVDF/BT/BNC/Fe 3 O 4 system, creating the way for the development of materials with a wide range of diverse properties that support the concept of green technologies.

36 MATERIALS SCIENCE↗
NASA NTRS1974

Prospects for the development of phototelevision methods in space studies

In-space imaging of the surface of celestial bodies can be carried out by both television and photographic equipment. Television equipment of various types has the important property of being capable of transmitting imagery in real time. Frequently this is not possible because of the nature of information transmission over the spacecraft-ground communication line. The inadequate energy handling capacity of the communication lines usually requires storage of the video information aboard the spacecraft for subsequent transmission at a definite time and rate. For this purpose, the television camera can be connected with a magnetic memory, or the television imagery may be stored on photographic film. The television/photographic film system has been termed phototelevision. The choice of a system of one type or the other is dictated by several considerations, the most important of which are the size and weight characteristics, other conditions being the same (power consumption, reliability, etc.). The advantages and disadvantages of the two systems are discussed and examples are given of types of satellites on which the two types have been employed.

Selivanov, A. S.↗
NASA NTRS1976

Optical mass memories

Optical and magnetic variants in the design of trillion-bit read/write memories are compared and tabulated. Components and materials suitable for a random access read/write nonmoving memory system are examined, with preference given to holography and photoplastic materials. Advantages and deficiencies of photoplastics are reviewed. Holographic page composer design, essential features of an optical memory with no moving parts, fiche-oriented random access memory design, and materials suitable for an efficient photoplastic fiche are considered. The optical variants offer advantages in lower volume and weight at data transfer rates near 1 Mbit/sec, but power drain is of the same order as for the magnetic variants (tape memory, disk memory). The mechanical properties of photoplastic film materials still leave much to be desired.

Bailey, G. A.↗
DOE OSTI2022

Absorption of transverse spin current in ferromagnetic NiCu: Dominance of bulk dephasing over spin-flip scattering

In ferromagnetic metals, transverse spin currents are thought to be absorbed via dephasing—i.e., destructive interference of spins precessing about the strong exchange field. Yet, due to the ultrashort coherence length of ≈1 nm in typical ferromagnetic thin films, it is difficult to distinguish dephasing in the bulk from spin-flip scattering at the interface. Here, to assess which mechanism dominates, we examine transverse spin-current absorption in ferromagnetic NiCu alloy films with reduced exchange fields. We observe that the coherence length increases with decreasing Curie temperature, as weaker dephasing in the film bulk slows down spin absorption. Moreover, nonmagnetic Cu impurities do not diminish the efficiency of spin-transfer torque from the absorbed spin current. Our findings affirm that the transverse spin current is predominantly absorbed by dephasing inside the nanometer-thick ferromagnetic metals, even with high impurity contents.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

Crystal orientation dependence of interfacial magnetic anisotropy at heavy-metal/magnetic-garnet interfaces

Ferrimagnetic insulators capped with a heavy metal are becoming an increasingly interesting materials system in spintronics due to their unique ability for electrical manipulation and detection of magnetic states and spin textures via spin-orbit torques. The ability to engineer magnetic anisotropy is a powerful tool for tuning the recently discovered phenomena in these bilayers such as electrical switching or the stabilization of topological magnetic textures. Here, we observe large shifts in the magnetic anisotropy in Tm 3 Fe 5 O 13 and Y 3 Fe 5 O 12 thin films due to heavy-metal capping layers, which strongly depends on the orientation of the substrate and therefore the orientation of the epitaxial films. This work suggests large Rashba spin-orbit coupling at the metal/ferrimagneticinsulator interface, which can be engineered in spintronic devices that utilize spin-orbit torques for electrical control of the magnetization in magnetic insulators.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

K 2 CoS 2 : A two-dimensional in-plane antiferromagnetic insulator

Recent discovery of two-dimensional (2D) magnetic materials has brought magnetism to the flatland and opened up exciting opportunities for the exploration of fundamental physics as well as novel device applications. Here, we predict a thermodynamically stable 2D magnetic material, ${\mathrm{K}}_{2}{\mathrm{CoS}}_{2}$, which retains its in-plane bulk antiferromagnetic (AFM) order down to the monolayer and bilayer limits. Magnetic moments $(2.5{{\mu}}_{B}/\mathrm{Co})$ are found to form a quasi-one-dimensional antiferromagnetically ordered chain of Co atoms. The nonmagnetic electronic spectrum of the monolayer film is found to host flatbands and van Hove singularities, which play a key role in stabilizing the magnetic ground state. Based on classical Monte Carlo simulations, we estimate the Neel temperature for the AFM monolayer to be ${\approx}15\mathrm{K}$. Our study demonstrates that ${\mathrm{K}}_{2}{\mathrm{CoS}}_{2}$ hosts a robust AFM state which persists from the monolayer limit to the bulk material.

2-dimensional systems↗
DOE OSTI2022

Quantum Sensing and Imaging of Spin–Orbit-Torque-Driven Spin Dynamics in the Non-Collinear Antiferromagnet Mn 3 Sn

Novel non-collinear antiferromagnets with spontaneous time-reversal symmetry breaking, non-trivial band topology, and unconventional transport properties have received immense research interest over the past decade due to their rich physics and enormous promise in technological applications. One of the central focuses in this emerging field is exploring the relationship between the microscopic magnetic structure and exotic material properties. Nanoscale imaging of both spin–orbit-torque-induced deterministic magnetic switching and chiral spin rotation in non-collinear antiferromagnet Mn 3 Sn films using nitrogen-vacancy (NV) centers are reported. Direct evidence of the off-resonance dipole–dipole coupling between the spin dynamics in Mn 3 Sn and proximate NV centers is also demonstrated by NV relaxometry measurements. These results demonstrate the unique capabilities of NV centers in accessing the local information of the magnetic order and dynamics in these emergent quantum materials and suggest new opportunities for investigating the interplay between topology and magnetism in a broad range of topological magnets.

36 MATERIALS SCIENCE↗
NASA NTRS1971

Thermomagnetic recording and magnetic-optic playback system

A magnetic recording and magneto-optic playback system is disclosed wherein thermomagnetic recording is employed. A transparent isotropic film is heated along a continuous path by a focused laser beam. As each successive area of the path is heated locally to the vicinity of its Curie point in the presence of an applied magnetic field, a magneto-optic density is established proportional to the magnetic field and fixed in place as the area cools once the laser beam moves on to an adjacent area. To play back the recorded data, the intensity of the laser beam is reduced to avoid reaching the vicinity of the Curie point of the film as it is scanned by the laser beam in the same manner as for recording. A Faraday effect analyzer and photo detector are employed as a transducer for producing an output signal.

Lewicki, G. W.↗
NASA NTRS2000

Remote query measurement of pressure, fluid-flow velocity, and humidity using magnetoelastic thick-film sensors

Free-standing magnetoelastic thick-film sensors have a characteristic resonant frequency that can be determined by monitoring the magnetic flux emitted from the sensor in response to a time varying magnetic field. This property allows the sensors to be monitored remotely without the use of direct physical connections, such as wires, enabling measurement of environmental parameters from within sealed, opaque containers. In this work, we report on application of magnetoelastic sensors to measurement of atmospheric pressure, fluid-flow velocity, temperature, and mass load. Mass loading effects are demonstrated by fabrication of a remote query humidity sensor, made by coating the magnetoelastic thick film with a thin layer of solgel deposited Al2O3 that reversibly changes mass in response to humidity. c2000 Elsevier Science S.A. All rights reserved.

NASA Discipline Life Sciences Technologies↗
DOE OSTI2023

Low-energy electronic interactions in ferrimagnetic Sr 2 CrReO 6 thin films

We reveal in this study the fundamental low-energy landscape in the ferrimagnetic Sr 2 CrReO 6 double perovskite and describe the underlying mechanisms responsible for the three low-energy excitations below 1.4 eV. Here, based on resonant inelastic x-ray scattering and magnetic dynamics calculations, and experiments collected from both Sr 2 CrReO 6 powders and epitaxially strained thin films, we reveal a strong competition between spin-orbit coupling, Hund’s coupling, and the strain-induced tetragonal crystal field. Here, we also demonstrate that a spin-flip process is at the origin of the lowest excitation at 200 meV, and we bring insights into the predicted presence of orbital ordering in this material. We study the nature of the magnons through a combination of ab initio and spin-wave theory calculations, and show that two nondegenerate magnon bands exist and are dominated either by rhenium or chromium spins. The rhenium band is found to be flat at about 200 meV (±25 meV) through X-L-W-U high-symmetry points and is dispersive toward Γ.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Spin-Dependent Electrochemistry

Recent experiments that use spin polarized electron currents to improve the selectivity and enantioselectivity of electrochemical reactions are described. Electrochemical studies with both chiral working electrodes and with magnetic working electrodes are used to generate spin polarized electron currents. Studies with chiral electrodes, which are formed through the adsorption of chiral molecules and through the growth of chiral oxide films, are shown to improve the efficiency and selectivity of the oxygen evolution reaction and oxygen reduction reaction. These improvements are attributed to the exploitation of spin selection rules (triplet vs. singlet pathways) in the reaction mechanism. Studies with magnetic electrodes, which are formed through ferromagnetic/Au thin film electrodes, are reported to initiate enantioselective chemical transformations, and three different cases are discussed here (enantioresolution of a racemic mixture, enantioselective polymer grafting on electrode surfaces, and the generation of achiral carbon centers). The addition of spin control to the conventional control over charge currents provides an added dimension to electrochemistry and electrosynthesis.

Waldeck, David H↗
DOE OSTI2020

Dimensional crossover in spin Hall oscillators

Auto-oscillations of magnetization driven by direct spin current have been previously observed in multiple quasi-zero-dimensional (0D) ferromagnetic systems such as nanomagnets and nanocontacts. Recently, it was shown that pure spin Hall current can excite coherent auto-oscillatory dynamics in quasi-one-dimensional (1D) ferromagnetic nanowires but not in quasi-two-dimensional (2D) ferromagnetic films. Here we study the 1D to 2D dimensional crossover of current-driven magnetization dynamics in wire-based Pt/Ni 80 Fe 20 bilayer spin Hall oscillators via varying the wire width. We find that increasing the wire width results in an increase of the number of excited auto-oscillatory modes accompanied by a decrease of the amplitude and coherence of each mode. We also observe a crossover from a hard to a soft onset of the auto-oscillations with increasing wire width. The amplitude of auto-oscillations rapidly decreases with increasing temperature suggesting that interactions of the phase-coherent auto-oscillatory modes with incoherent thermal magnons play an important role in suppression of the auto-oscillatory dynamics. Our measurements in this work set the upper limit on the dimensions of an individual spin Hall oscillator and elucidate the mechanisms leading to suppression of coherent auto-oscillations with increasing oscillator size.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Universal orbital and magnetic structures in infinite-layer nickelates

We conducted a comparative study of the rare-earth infinite-layer nickelate films, RNiO 2 (R = La, Pr, and Nd), using resonant inelastic x-ray scattering (RIXS). We found that the gross features of the orbital configurations are essentially the same, with minor variations in the detailed hybridization. For low-energy excitations, we unambiguously confirm the presence of damped magnetic excitations in all three compounds. By fitting to a linear spin-wave theory, comparable spin exchange coupling strengths and damping coefficients are extracted, indicating a universal magnetic structure in the infinite-layer nickelates. Interestingly, while signatures of a charge order are observed in LaNiO 2 in the quasielastic region of the RIXS spectrum, it is absent in NdNiO 2 and PrNiO 2 . Furthermore, this prompts further investigation into the universality and the origins of charge order within the infinite-layer nickelates.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗