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At least 775 records · Page 43
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Materials Selection and Their Characteristics as Used in Rapid Prototyping

NASA's Marshall Space Flight Center (MSFC) conducted a program to evaluate six technologies used in Rapid Prototyping (RP) to produce investment casting patterns. In this paper, RP refers to the collective additive fabrication technologies known as Solid Free-Form Fabrication. Such technologies are being used with increasing frequency in manufacturing applications, due in part to their rapidly expanding capabilities to fabricate models from many types of materials. This study used ABS plastic, polycarbonate, TrueForm PM6, epoxy resin, paper, starch, and wax. The baseline model was a semi-complex prototype fuel pump housing, intended for use in the X-33 reusable launch vehicle. All models were shelled in a production- grade colloidal silica ceramic. Primary coats were zircon-base flour with zircon backup, while secondary coats were silica grains with a tabular alumina backup. Each model was shelled in an identical manner, using the same atmospheric conditions and drying times, as well as the same number of layers. Bake-outs and firing cycles were consistent with the leach ability of each material. Preheat and bath temperatures were also kept consistent. All molds were cast in vacuum using a hydrogen-resistant superalloy (NASA- 23) that was developed in-house. The final technical evaluation included detailed measurements of the model and the final casting, in order to determine any dimensional changes caused by different pattern materials, as well as documentation of all defects and any obvious refractory/model reactions. Prototype production costs were estimated for each method and taken into consideration during trade-off analysis.

Cooper, K.↗
NASA NTRS1971

Techniques for Measurement of Nitrate Movement in Soils

Contamination of surface and ground waters with nitrate usually involves leaching through soil of nitrate produced by mineralization of soil organic matter, decomposition of animal wastes or plant residues, or derived from fertilizers. Nitrate concentrations in the soil solution may be measured by several chemical procedures or by the nitrate electrode. since nitrate is produced throughout the soil mass it is difficult to identify a source of nitrate contamination by conventional means. This problem can be solved by use of N-15-enriched or N-15-depleted materials as tracers. The latter is particularly attractive because of the negligible possibility of the tracer hazardous to health.

Broadbent, F. E.↗
NASA NTRS1998

Mineral Mapping with Imaging Spectroscopy: The Ray Mine, AZ

Mineral maps generated for the Ray Mine, Arizona were analyzed to determine if imaging spectroscopy can provide accurate information for environmental management of active and abandoned mine regions. The Ray Mine, owned by the ASARCO Corporation, covers an area of 5700 acres and is situated in Pinal County, Arizona about 70 miles north of Tucson near Hayden, Arizona. This open-pit mine has been a major source of copper since 1911, producing an estimated 4.5 million tons of copper since its inception. Until 1955 mining was accomplished by underground block caving and shrinkage stope methods. (excavation by working in stepped series usually employed in a vertical or steeply inclined orebody) In 1955, the mine was completely converted to open pit method mining with the bulk of the production from sulfide ore using recovery by concentrating and smelting. Beginning in 1969 a significant production contribution has been from the leaching and solvent extraction-electrowinnowing method of silicate and oxide ores. Published reserves in the deposit as of 1992 are 1.1 billion tons at 0.6 percent copper. The Environmental Protection Agency, in conjunction with ASARCO, and NASA/JPL obtained AVIRIS data over the mine in 1997 as part of the EPA Advanced Measurement Initiative (AMI) (Tom Mace, Principal Investigator). This AVIRIS data set is being used to compare and contrast the accuracy and environmental monitoring capabilities of remote sensing technologies: visible-near-IR imaging spectroscopy, multispectral visible and, near-IR sensors, thermal instruments, and radar platforms. The goal of this effort is to determine if these various technologies provide useful information for envirorunental management of active and abandoned mine sites in the arid western United States. This paper focuses on the analysis of AVIRIS data for assessing the impact of the Ray Mine on Mineral Creek. Mineral Creek flows to the Gila River. This paper discusses our preliminary AVIRIS mineral mapping and environmental findings.

Clark, Roger N.↗
NASA NTRS2000

Update on Terrestrial Ages of Antarctic Meteorites

Terrestial ages are presented for 70 Antarctic meteorites, based on cosmogenic Be-10, Al-26 and Cl-36 in the metal phase. Also, results of leaching experiments are discussed to study possible contamination of stony meteorites with atmospheric Be-10

Welten, K. C.↗
NASA NTRS2001

Impact and Collisional Processes in the Solar System

A series of impact experiments on anhydrite CaSO4, in which vaporized sample accelerates an element in a velocity interferometer, generate velocity data that we have recently reanalyzed using an explicit entropy generating finite difference code. The shock pressure required from the onset, and complete vaporization of 30% porous and 70% crystal density anhydrite is 52 +/- 3 and 122 +/- 13 GPa. Using observed acid leaching in non-marine K/T ejecta in North America, and the sharp global increase in Sr-87/Sr-86 ratios recorded at 65 Ma in marine rocks, we demonstrated that global acidification is primarily due to the SO2 released by anhydrite volatilization, and not HNO3 formed from bolide-induced air pyrolysis. Shock temperatures for crystal CaCO3 are measured from 3000 to 7000 K in the 90 to 160 GPa pressure range. These temperatures are much lower than calculated theoretically indicating that possibly bond breakdown at the shock front is occurring. This is the first mineral in which this effect has ever been seen. New data defining the ion species which are produced upon impact of volatilization of metals and minerals using a pulse ultraviolet laser to simulate intense shock heating from a projectile impact indicate that in shock experiments we can for the first time study the speciation of neutrals using a moderate resolution time-of-flight mass spectrometer. Measurements of the gas species from a series of proposed impact experiments appear to be quite feasible. We will attempt these experiments in the next year. Measurements of the impact induced shock wave decay in SiO2 and GeO2 glass are underway to measure these pure oxide properties. Predictive calculations indicate that the pressure will decay as r(exp -2.7) in the phase transition regime, versus a much lower rate of r(exp -1.18), if a phase transition does not occur.

Ahrens, Thomas J.↗
NASA NTRS2001

Chemical Aging of Environmentally Friendly Cleaners

Use of cleaners in the manufacturing area demands bottles that will hold a sufficient amount of material and allow for easy and controlled dispensing by the operator without contamination or material leaching from the bottle. The manufacturing storage conditions are also a factor that may affect cleaner chemical integrity and its potential to leave a residue on the part. A variety of squeeze bottles stored in mild (72 F, 10% R.H., dark) and harsh (105 F, 50% R.H., fluorescent lighting) conditions were evaluated to determine the effect of environment and bottle exposure on ozone depleting chemicals (ODC) cleaners chemical composition. Low Density Polyethylene (LDPE) bottles were found to be quite permeable to all the cleaners evaluated in this study indicating this bottle type should not be used in the manufacturing area. Fluorinated Polyethylene (FLPE) bottles showed little cleaner loss and change in cleaner chemical composition over time suggesting these bottles would be acceptable for use. Chemical analysis indicates limonene containing cleaners show increased non-volatile residue (NVR) content with storage under harsh conditions. Some cleaners use BHT (butylated hydroxytoluene) as stabilizer and to protect against limonene oxidation. Under harsh conditions, BHT was quickly depleted resulting in higher NVR levels.

Biegert, L. L.↗
NASA NTRS2001

Astrobiology Investigations at a Martian Hematite Site

Christensen et al, using data from the Mars Global Surveyor Thermal Emission Spectrometer (TES), have identified gray crystalline hematite in a 350 km by 750 km region near Sinus Meridiani. The deposit corresponds closely to the low-albedo highlands unit 'sm', mapped as a wind-eroded, ancient, subaqueous sedimentary deposit. Christensen et al interpreted the Sinus Meridiani deposit to be 'an in-place, rock-stratigraphic sedimentary unit characterized by smooth, friable layers composed primarily of basaltic sediments with approximately 10 to 15 % crystalline gray hematite.' Christensen et al discussed five possible mechanisms for the formation of this deposit: direct precipitation from standing, oxygenated, Fe-rich water; precipitation from Fe-rich hydrothermal fluids; low-temperature dissolution and precipitation through mobile groundwater leaching; surface weathering and coatings; thermal oxidation of magnetite-rich lavas. Four of these mechanisms involve the interactions of rock with water, and thus have implications in the search for evidence of microbial life.

Allen, Carlton, C.↗
NASA NTRS2001

Chemical Aging of Environmentally Friendly Cleaners

Use of cleaners in the manufacturing area demands bottles that will hold a sufficient amount of material and allow for easy and controlled dispensing by the operator without contamination or material leaching from the bottle. The manufacturing storage conditions are also a factor that may affect cleaner chemical integrity and its potential to leave a residue on the part. A variety of squeeze bottles stored in mild (72 F, 10 % R.H., dark) and harsh (105 F, 50 % R.H., fluorescent lighting) conditions were evaluated to determine the effect of environment and bottle exposure on the chemical composition of TCA (1,1,1 trichloroethane) replacement solvents. Low Density Polyethylene (LDPE) bottles were found to be quite permeable to all the cleaners evaluated in this study indicating this bottle type should not be used in the manufacturing area. Fluorinated Polyethylene (FLPE) bottles showed little cleaner loss and change in cleaner chemical composition over time suggesting these bottles would be acceptable for use. Chemical analysis indicates limonene-containing cleaners show increased non-volatile residue (NVR) content with storage under harsh conditions. Some cleaners use BHT (butylated hydroxytoluene) as stabilizer and to protect against limonene oxidation. Under harsh conditions, BHT was quickly depleted resulting in higher NVR levels.

Evans, K.↗
NASA NTRS2000

Cleaner Landfills

Osmotek, Inc. developed the Direct Osmosis treatment system through SBIR funding from Ames Research Center. Using technology originally developed for flight aboard the Space Station, the company brought it to their commercial water purification treatment system, Direct Osmosis. This water purification system uses a direct osmosis process followed by a reverse osmosis treatment. Because the product extracts water from a waste product, Osmotek is marketing the unit for use in landfills. The system can treat leachate (toxic chemicals leached into a water source), by filtering the water and leaving behind the leahcate. The leachate then becomes solidified into substance that can not seep into water.

Source record↗
NASA NTRS2003

Meridiani Planum Hematite Deposit: Potential for Preservation of Microfossils

Christensen et al., using data from the Mars Global Surveyor Thermal Emission Spectrometer (TES), have identified gray crystalline hematite in a 350 km by 750 km region near Meridiani Planum. The deposit corresponds closely to the low-albedo highlands unit sm, mapped as a wind-eroded, ancient, subaqueous sedimentary deposit. Christensen et al. interpreted the Meridiani Planum deposit to be an in-place, rock-stratigraphic sedimentary unit characterized by smooth, friable layers composed primarily of basaltic sediments with approximately 10 to 15% crystalline gray hematite. The Meridiani Planum hematite deposit has recently been designated as the prime landing site for one of the two Mars Exploration Rover (MER) spacecraft. The MER landings are scheduled for January, 2004. Christensen et al. discussed five possible mechanisms for the formation of this deposit: direct precipitation from standing, oxygenated, Fe-rich water; precipitation from Fe-rich hydrothermal fluids; low-temperature dissolution and precipitation through mobile groundwater leaching; surface weathering and coatings; thermal oxidation of magnetite-rich lavas. Four of these mechanisms involve the interactions of rock with water, and thus have implications in the search for evidence of microbial life.

C C Allen↗
NASA NTRS2003

Fine-grained Goethite as a Precursor for Martian Gray Hematite

Several isolated deposits of gray, crystalline hematite on Mars were discovered using data returned from the Thermal Emission Spectrometer (TES) instrument aboard the Mars Global Surveyor spacecraft. Christensen et al. provided five testable hypotheses regarding the formation of crystalline hematite on Mars: 1) low-temperature precipitation of Fe oxides/hydroxides from standing, oxygenated, Fe-rich water, followed by subsequent alteration to gray hematite, 2) low-temperature leaching of iron-bearing silicates and other materials leaving a Fe-rich residue laterite-style weathering) which is subsequently altered to gray hematite, 3) direct precipitation of gray hematite from Fe-rich circulating fluids of hydrothermal or other origin, 4) formation of gray hematitic surface coatings during weathering, and 5) thermal oxidation of magnetite-rich lavas. Since this initial work, several authors have examined the hematite deposits to determine their formation mechanism. Lane et al. cited the absence of a 390/ cm absorption in the martian hematite spectrum as evidence for platy hematite grains. Their model for the formation of the deposits includes deposition of any of a variety of iron oxides or oxyhydroxides by aqueous or hydrothermal fluids, burial and metamorphosis to gray platy hematite grains, and exhumation in recent times. Based on a detailed geomorphic examination of the Sinus Meridiani region, Hynek et al. conclude that the most likely method of hematite formation was either emplacement by a hydrothermal fluid or oxidation of a magnetite-rich pyroclastic deposit. Similarly, Arvidson et al., favor a model involving the alteration of pyroclastic deposits by aqueous or hydrothermal fluids. Finally, based on geochemical modeling and an examination of Aram Chaos, Catling and Moore favor emplacement by hydrothermal fluids with a minimum temperature of 100 C. Comparison of the average martian hematite spectrum measured by TES to hematite emissivity spectra for a variety of naturally occurring hematites shows small but potentially important differences. In particular, band shapes, positions and relative band emissivities of hematite spectra vary over the range of samples. These differences imply that the natural variability of thermal infrared hematite spectra has not been fully characterized, especially with respect to the reaction pathway and crystal structure.

T D Glotch↗
NASA NTRS2003

Electrical Breakdown in a Martian Gas Mixture

The high probability for dust interactions during Martian dust storms and dust devils combined with the cold, dry climate of Mars most likely result in airborne dust that is highly charged. On Earth, potential gradients up to 5 kV/m have been recorded and in some cases resulted in lightning. Although the Martian atmosphere is not conducive to lightning generation, it is widely believed that electrical discharge in the form of a corona occurs. In order to understand the breakdown of gases, Paschen measurements are taken which relate the minimum potential required to spark across a gap between two electrodes. The minimum potential is plotted versus the pressure-distance value for electrodes of a given geometry. For most gases, the potential decreases as the pressure decreases. For CO2, the minimum in the curve happens to be at Mars atmospheric pressures (5-7 mm Hg) for many distances and geometries. However, a very small amount (<0.1%) of mixing gases radically changes the curve, as noted by Leach. Here, we present the first experimental results of a Paschen curve for a Mars gas mixture compared with 100% pure CO2.

Buhler, C. R.↗
NASA NTRS2003

Endemic Ru Isotopic Anomalies in Iron Meteorites and in Allende

Small variations for Mo isotopes have been observed recently in the Allende meteorite and in iron meteorites, mesosiderites, and pallasites, using ICPMS. Large effects for Mo have been reported for leaches of Orgueil and in SiC and graphite from Murchison. Variations for Mo in bulk Allende and in Murchison have also been presented by NTIMS. Effects in Ru isotopes can define further the preserved exotic r, s, and p contributions in this mass region, and possible effects in Ru-98 and Ru-99 from Tc-98 (4.2 Ma half-life) and Tc-99 (0.21 Ma half-life). Previous attempts at determination of Ru isotopes yielded no resolved effects. The present work represents a substantial improvement in precision over the earlier work. Chemical and mass spectrometric analytical techniques are presented to determine the Ru isotope compositions in terrestrial standards and in meteorites.

Chen, J. H.↗
NASA NTRS2004

Chemical Weathering Records of Martian Soils Preserved in the Martian Meteorite EET79001

Impact-melt glasses, rich in Martian atmospheric gases, contain Martian soil fines (MSF) mixed with other coarse-grained regolith fractions which are produced during impact bombardment on Mars surface. An important characteristic of the MSF fraction is the simultaneous enrichment of felsic component accompanied by the depletion of mafic component relative to the host phase in these glasses. In addition, these glasses yield large sulfur abundances due to the occurrence of secondary mineral phases such as sulfates produced during acid-sulfate weathering of the regolith material near the Martian surface. Sulfurous gases released into atmosphere by volcanoes on Mars are oxidized to H2SO4 which deposit back on the surface of Mars as aerosol particles. Depending on the water availability, sulfuric acids dissolve into solutions which aggressively decompose the Fe-Mg silicates in the Martian regolith. During chemical weathering, structural elements such as Fe, Mg and Ca (among others) are released into the transgressing solutions. These solutions leach away the soluble components of Mg, Ca and Na, leaving behind insoluble iron as Fe3(+) hydroxysulfate mixed with poorly crystalline hydroxide- precipitates under oxidizing conditions. In this study, we focus on the elemental distribution of FeO and SO3 in the glass veins of EET79001, 507 sample, determined by Electron Microprobe and FE SEM measurements at JSC. This glass sample is an aliquot of a bigger glass inclusion ,104 analysed by where large concentrations of Martian atmospheric noble gases are found.

Rao, M. N.↗
NASA NTRS2002

Near-term lander experiments for growing plants on Mars: requirements for information on chemical and physical properties of Mars regolith

In order to support humans for long-duration missions to Mars, bioregenerative Advanced Life Support (ALS) systems have been proposed that would use higher plants as the primary candidates for photosynthesis. Hydroponic technologies have been suggested as the primary method of plant production in ALS systems, but the use of Mars regolith as a plant growth medium may have several advantages over hydroponic systems. The advantages for using Mars regolith include the likely bioavailability of plant-essential ions, mechanical support for plants, and easy access of the material once on the surface. We propose that plant biology experiments must be included in near-term Mars lander missions in order to begin defining the optimum approach for growing plants on Mars. Second, we discuss a range of soil chemistry and soil physics tests that must be conducted prior to, or in concert with, a plant biology experiment in order to properly interpret the results of plant growth studies in Mars regolith. The recommended chemical tests include measurements on soil pH, electrical conductivity and soluble salts, redox potential, bioavailability of essential plant nutrients, and bioavailability of phytotoxic elements. In addition, a future plant growth experiment should include procedures for determining the buffering and leaching requirements of Mars regolith prior to planting. Soil physical tests useful for plant biology studies in Mars regolith include bulk density, particle size distribution, porosity, water retention, and hydraulic conductivity.

NASA Center JSC↗
NASA NTRS2001

Fabrication of poly(ethylene glycol) hydrogel microstructures using photolithography

The fabrication of hydrogel microstructures based upon poly(ethylene glycol) diacrylates, dimethacrylates, and tetraacrylates patterned photolithographically on silicon or glass substrates is described. A silicon/silicon dioxide surface was treated with 3-(trichlorosilyl)propyl methacrylate to form a self-assembled monolayer (SAM) with pendant acrylate groups. The SAM presence on the surface was verified using ellipsometry and time-of-flight secondary ion mass spectrometry. A solution containing an acrylated or methacrylated poly(ethylene glycol) derivative and a photoinitiator (2,2-dimethoxy-2-phenylacetophenone) was spin-coated onto the treated substrate, exposed to 365 nm ultraviolet light through a photomask, and developed with either toluene, water, or supercritical CO2. As a result of this process, three-dimensional, cross-linked PEG hydrogel microstructures were immobilized on the surface. Diameters of cylindrical array members were varied from 600 to 7 micrometers by the use of different photomasks, while height varied from 3 to 12 micrometers, depending on the molecular weight of the PEG macromer. In the case of 7 micrometers diameter elements, as many as 400 elements were reproducibly generated in a 1 mm2 square pattern. The resultant hydrogel patterns were hydrated for as long as 3 weeks without delamination from the substrate. In addition, micropatterning of different molecular weights of PEG was demonstrated. Arrays of hydrogel disks containing an immobilized protein conjugated to a pH sensitive fluorophore were also prepared. The pH sensitivity of the gel-immobilized dye was similar to that in an aqueous buffer, and no leaching of the dye-labeled protein from the hydrogel microstructure was observed over a 1 week period. Changes in fluorescence were also observed for immobilized fluorophore labeled acetylcholine esterase upon the addition of acetyl acholine.

NASA Discipline Life Sciences Technologies↗
NASA NTRS2000

Ozonation and alkaline-peroxide pretreatment of wheat straw for Cryptococcus curvatus fermentation

Crop residues in an Advanced Life Support System (ALS) contain many valuable components that could be recovered and used. Wheat is 60% inedible, with approximately 90% of the total sugars in the residue cellulose and hemicellulose. To release these sugars requires pretreatment followed by enzymatic hydrolysis. Cryptococcus curvatus, an oleaginous yeast, uses the sugars in cellulose and hemicellulose for growth and production of storage triglycerides. In this investigation, alkaline-peroxide and ozonation pretreatment methods were compared for their efficiency to release glucose and xylose to be used in the cultivation of C. curvatus. Leaching the biomass with water at 65 degrees C for 4 h prior to pretreatment facilitated saccharification. Alkaline-peroxide and ozone pretreatment were almost 100% and 80% saccharification efficient, respectively. The sugars derived from the hydrolysis of alkaline-peroxide-treated wheat straw supported the growth of C. curvatus and the production of edible single-cell oil.

Non-NASA Center↗
NASA NTRS1996

The importance of new processing techniques in tissue engineering

The use of polymer scaffolds in tissue engineering is reviewed and processing techniques are examined. The discussion of polymer-scaffold processing explains fiber bonding, solvent casting and particulate leaching, membrane lamination, melt molding, polymer/ceramic fiber composite-foam processing, phase separation, and high-pressure processing.

Non-NASA Center↗