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At least 775 records · Page 43

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NASA NTRS1972

A reliable all-silver front contact for silicon solar cells.

Methods have been found to apply an adherent and humidity resistant silver-only front contact to n on p silicon solar cells. The critical processing step was the removal of the diffused oxide layer. Humidity resistance is superior to present day commercial titanium-silver contacts and the electrical characteristics of the cells are excellent. Titanium, which is degraded by humidity and which is a source of heavy metal poisoning, has been eliminated from the contact.

Lamneck, J. H., Jr.↗

NASA NTRS1973

Some environmental considerations relating to the interaction of the solid rocket motor exhaust with the atmosphere: Predicted chemical composition of exhaust species and predicted conditions for the formation of HCl aerosol

The exhaust products of a solid rocket motor using as propellant 14% binder, 16% aluminum, and 70% (wt) ammonium perchlorate consist of hydrogen chloride, water, alumina, and other compounds. The equilibrium and some frozen compositions of the chemical species upon interaction with the atmosphere were computed. The conditions under which hydrogen chloride interacts with the water vapor in humid air to form an aerosol containing hydrochloric acid were computed for various weight ratios of air/exhaust products. These computations were also performed for the case of a combined SRM and hydrogen-oxygen rocket engine. Regimes of temperature and relative humidity where this aerosol is expected were identified. Within these regimes, the concentration of HCL in the aerosol and weight fraction of aerosol to gas phase were plotted. Hydrochloric acid aerosol formation was found to be particularly likely in cool humid weather.

Rhein, R. A.↗

NASA NTRS1973

The effect of thermal stratification and evaporation on geostrophic drag coefficient in the atmospheric boundary layer

It is shown that the fields of velocity, eddy viscosity, potential temperature, and specific humidity in a planetary boundary layer are decoupled by the introduction of a free parameter, Q, which combines the effects of thermal and humidity stratification. Solutions of the whole system are shown to be obtainable by the method of trial and error on Q. Results show good agreement when both the thermal and humidity stratification are accounted for.

Yeh, G.-T.↗

NASA NTRS1976

Improvement of black nickel coatings

Selectively absorbing black nickel coatings are among the most optically efficient low cost coatings for use on flat plate solar collectors. However, a current Ni-Zn-S-O coating in use is quite susceptible to a humid environment, degrading badly in less than ten days at 38 C (100 F) at 95 percent relative humidity. Therefore, a black nickel formula was developed which can withstand such exposures with no loss of optical efficiency, solar absorption of 0.92 and an infrared emittance (at 100 C) of 1.00 were still present after 14 days of humidity exposure. This compares to a solar absorptance of only 0.72 for the previous formula after a similar time period. The electroplating bath and conditions were changed to obtain the more stable coating configuration. The effect of bath composition, temperature, pH, and plating current density and time on the coating composition, spectral optical properties and durability were investigated systematically.

Peterson, R. E.↗

NASA NTRS1977

Sound-tube measurements of the relaxation frequency of moist nitrogen

At audible frequencies, the vibrational relaxation of nitrogen contributes significantly to the absorption of sound in still air. The accurate measurement of the humidity dependence of the relaxation frequency of nitrogen, as yet, has eluded careful measurement due to the difficulty in measuring small absorption at low frequencies. Recently, equipment has been constructed for measuring sound absorption in air as a function of humidity over the frequency range from 4 to 100 kHz. In the experiment described here, the temperature and humidity range of this equipment has been extended so that it can be used to study the relaxation absorption in nitrogen at temperatures from 311 K to 418 K. The results indicate that, over this temperature range, the frequency of maximum absorption in moist nitrogen, f, can be given by f/P = 260 x h, Hz/atm, where h is the percent mole fraction of water, and P is the pressure in atm. To the accuracy of the measurements reported here, f is independent of temperature over the range of temperatures at which the measurements were made.

Chang, D.↗

NASA NTRS1978

Transonic flow past an airfoil with condensation

In connection with investigations conducted to determine the influence of water vapor on experiments in wind tunnels, the question arose as to what changes due to vapor condensation might be expected in airfoil measurements. Density measurements on circular-arc airfoils aided by an interferometer in choked tunnels with parallel walls show that increasing humidity produces increasing changes in the flow field. The flow becomes nonstationary at high humidity. At the airfoil, however, the influence of the condensation is only felt, inasmuch as the shock bounding the local supersonic region moves upstream with increasing humidity while its intensity decreases. The density distribution upstream of the shock remains unchanged. Even if the flow becomes nonstationary in the vicinity of the airfoil, no changes occur at the airfoil.

Schmidt, B.↗

NASA NTRS1978

A scheme for computing surface layer turbulent fluxes from mean flow surface observations

A physical model and computational scheme are developed for generating turbulent surface stress, sensible heat flux and humidity flux from mean velocity, temperature and humidity at some fixed height in the atmospheric surface layer, where conditions at this reference level are presumed known from observations or the evolving state of a numerical atmospheric circulation model. The method is based on coupling the Monin-Obukov surface layer similarity profiles which include buoyant stability effects on mean velocity, temperature and humidity to a force-restore formulation for the evolution of surface soil temperature to yield the local values of shear stress, heat flux and surface temperature. A self-contained formulation is presented including parameterizations for solar and infrared radiant fluxes at the surface. Additional parameters needed to implement the scheme are the thermal heat capacity of the soil per unit surface area, surface aerodynamic roughness, latitude, solar declination, surface albedo, surface emissivity and atmospheric transmissivity to solar radiation.

Hoffert, M. I.↗

NASA NTRS1977

Characterization of terrestrial service environments - The simultaneous occurrence of combined conditions of solar insolation and climatic variables

Computational methods for occurrences of combined environmental and pollution variables are compared. General statistical data and diurnal statistics on 24 environmental variables are treated. Combinations of variables dealt with include: air temperature, relative humidity, wind speed, total insolation; air temperature and weather event (rain, fog); air pollutant and weather event; wind speed, wind direction, and weather event; air temperature, total insolation, and weather event; air temperature, relative humidity, wind speed, computed direct insolation levels; air temperature, relative humidity, air pollution.

Thomas, R. E.↗

NASA NTRS1978

Fretting wear of iron, nickel, and titanium under varied environmental conditions

Fretting wear experiments were conducted on high purity iron, nickel and titanium in air under conditions of varied humidity and temperature, and in nitrogen. For iron and titanium, maximum fretting occurred at 10 and 30 percent relative humidity respectively. Nickel showed a minimum in fretting wear at about 10 percent relative humidity. With increasing temperature, all three metals initially showed reduced fretting wear, with increasing wear observed as temperatures increased beyond 200-300 C. For titanium, dramatically reduced fretting wear was observed at temperatures above 500 C, relatable to a change in oxidation kinetics. All three metals showed much less fretting wear in N2 with the presence of moisture in N2 having a proportionally stronger effect than in air.

Bill, R. C.↗

NASA NTRS1979

Fretting wear of iron, nickel, and titanium under varied environmental conditions

Fretting wear experiments were conducted on high-purity iron, nickel and titanium in air under conditions of varied humidity and temperature, and in nitrogen. For iron and titanium, maximum fretting occurred at 10 and 30 percent relative humidity respectively. Nickel showed a minimum in fretting wear at about 10% relative humidity. With increasing temperature, all three metals initially showed reduced fretting wear, with increasing wear observed as temperatures increased beyond 200-300 C. For titanium, dramatically reduced fretting wear was observed at temperatures above 500 C, relatable to a change in oxidation kinetics. All three metals showed much less fretting wear in N2 with the presence of moisture in N2 having a proportionally stronger effect than in air.

Bill, R. C.↗

NASA NTRS1980

Ground cloud hydrogen chloride measurements from three Titan launches at the Kennedy Space Center during 1978 and 1979

Total hydrogen chloride and gaseous hydrogen chloride concentrations were measured in the exhaust cloud produced at three Titan 3 launches at the Kennedy Space Center in March 1978, December 1978, and November 1979 to determine the degree of hydrogen chloride partitioning in a solid rocket exhaust cloud between gaseous hydrogen chloride and hydrochloric acid aerosol as a function of ambient relative humidity. Moderately low relative humidity conditions were present during a daytime launch on Mar 25, 1978, and high relative humidity conditions were present during a nighttime launch on December 13, 1978. Gaseous hydrogen chloride concentrations and meteorological data, as a function of time after launch, are presented. Hydrogen chloride is present in both the gaseous and aerosol phase in the exhaust cloud. Total HCl concentrations ranged from 18 parts per million by volume (ppm) several minutes after launch down to 1 ppm after the cloud stabilization period, depending on the meteorological conditions. Gaseous HCl concentrations ranged from 2 to 3 ppm several minutes after launch to less than 1 ppm after cloud stabilization. These measured concentrations indicated significant HCl aerosol formation.

Seabacher, D. I.↗

NASA NTRS1981

Ultra-high modulus organic fiber hybrid composites

An experimental organic fiber, designated Fiber D, was characterized, and its performance as a reinforcement for composites was investigated. The fiber has a modulus of 172 GPa, tensile strength of 3.14 GPa, and density of 1.46 gm/cu cm. Unidirectional Fiber D/epoxy laminates containing 60 percent fiber by volume were evaluated in flexure, shear, and compression, at room temperature and 121 C in both the as fabricated condition and after humidity aging for 14 days at 95 percent RH and 82 C. A modulus of 94.1 GPa, flexure strength of 700 MPa, shear strength of 54 MPa, and compressive strength of 232 MPa were observed at room temperature. The as-fabricated composites at elevated temperature and humidity aged material at room temperature had properties 1 to 20 percent below these values. Combined humidity aging plus evaluated temperature testing resulted in even lower mechanical properties. Hybrid composite laminates of Fiber D with Fiber FP alumina or Thornel 300 graphite fiber were also evaluated and significant increases in modulus, flexure, and compressive strengths were observed.

Champion, A. R.↗

NASA NTRS1981

Effect of water vapor on sound absorption in nitrogen at low frequency/pressure ratios

Sound absorption measurements were made in N2-H2O binary mixtures at 297 K over the frequency/pressure range f/P of 0.1-2500 Hz/atm to investigate the vibrational relaxation peak of N2 and its location on f/P axis as a function of humidity. At low humidities the best fit to a linear relationship between the f/P(max) and humidity yields an intercept of 0.013 Hz/atm and a slope of 20,000 Hz/atm-mole fraction. The reaction rate constants derived from this model are lower than those obtained from the extrapolation of previous high-temperature data.

Zuckerwar, A. J.↗

NASA NTRS1981

Dependence of tropospheric temperature on the parameterization of cumulus convection in the GLAS model of the general circulation

Analysis of the simulation of seasonal change by the GLAS model of the general circulation reveals deficiencies in the simulation of tropospheric temperature and of convective cloud cover. These interrelated deficiencies are due to a spurious doubling from January to July in the convective cloud cover of the Northern Hemisphere. The spurious doubling, in turn, is due to the oversensitivity of cumulus convection, in the GLAS model, to the specific humidity of the lower atmosphere. The oversensitivity is enhanced by a feedback mechanism which perpetuates the existence of deep, penetrative convective clouds at certain preferred locations. The cumulus parameterization scheme has been modified to more realistically relate the onset of cumulus convection to the relative humidity of the lower atmosphere. The modified parameterization has improved the simulation of tropospheric temperature, planetary albedo and convective cloud cover as well as their seasonal variations. Comparison of this experiment with its control has shown a high degree of interrelation among these fields in the GLAS model and has demonstrated the sensitivity of the atmospheric heat budget to the design of the cumulus parameterization scheme. Also, the modification to the cumulus scheme has demonstrated a plausible mechanism to explain the correlation between convective cloud cover and relative humidity in the real atmosphere.

Helfand, H. M.↗

NASA NTRS1981

Comparison of observed and computed brightness temperatures for the HIRS2 and MSU sounders on TIROS-N

Given the radiosonde temperature and humidity profile, brightness temperatures for the temperature sounding IR channels on HIRS 2 were calculated. The temperature profile was interpolated to 53 levels between 1000 and 30 mb assuming temperature to be linear in the logarithm of the pressure between the mandatory levels. The 11 levels above 30 mb were extrapolated according to climatology. The surface was taken to be the climatological sea surface temperature. The specific humidity was interpolated between mandatory levels assuming a p(n) dependence. A specific humidity corresponding to a climatological water vapor mixing ratio of 2 ppmv was assumed at and above 100 mb. Zonally averaged climatological ozone profiles were used to compute the ozone component of the transmittance.

Susskind, J.↗

NASA NTRS1982

Calculation of composition distribution of ultrafine ion-H2O-H2SO4 clusters using a modified binary ion nucleation theory

Thomson's ion nucleation theory was modified to include the effects of curvature dependence of the microscopic surface tension of field dependent, nonlinear, dielectric properties of the liquid; and of sulfuric acid hydrate formation in binary mixtures of water and sulfuric acid vapors. The modified theory leads to a broadening of the ion cluster spectrum, and shifts it towards larger numbers of H2O and H2SO4 molecules. Whether there is more shifting towards larger numbers of H2O or H2SO4 molecules depends on the relative humidity and relative acidity of the mixture. Usually, a broadening of the spectrum is accompanied by a lowering of the mean cluster intensity. For fixed values of relative humidity and relative acidity, a similar broadening pattern is observed when the temperature is lowered. These features of the modified theory illustrate that a trace of sulfuric acid can facilitate the formation of ultrafine, stable, prenucleation ion clusters as well as the growth of the prenucleation ion clusters towards the critical saddle point conditions, even with low values of relative humidity and relative acidity.

Singh, J. J.↗

NASA NTRS1981

A moisture analysis procedure utilizing surface and satellite data

Four analyses have been produced by a moisture analysis procedure which uses satellite, precipitation and surface specific humidity data to augment the standard radiosonde observations (RAOB) of moisture: (1) using RAOB data only, (2) using RAOB data supplemented by data obtained from the surface observations of specific humidity, (3) using RAOB data supplemented only by satellite and precipitation data, and (4) employing all sources of data. Penn State University Mesoscale Model forecasts were performed to determine the effect of the high-resolution moisture analyses. For the data set used, supplementary satellite and rainfall data was found to improve the precipitation forecast more than surface humidity data and permitted the model to produce rain rates during the first four hours of the forecast that were 100% larger and more realistic than those produced without these data.

Wolcott, S. W.↗

NASA NTRS1983

Propagation of sound through the Earth's atmosphere

The data collected at a pressure of one atmosphere for the different temperatures and relative humidities of the air-water vapor mixtures is summarized. The dew point hygrometer used in these measurements did not give reliable results for dew points much above the ambient room temperature. For this reason measurements were not attempted at the higher temperatures and humidities. Viscous wall losses in the resonant tube at 0 C so dominate the molecular relaxation of nitrogen, in the air-water vapor mixture, that reliable data could not be obtained using the free decay method in a resonant tube at one atmosphere. In an effort to obtain viable data at these temperatures, measurements were performed at a pressure of 10 atmospheres. Since the molecular relaxation peak is proportional to the pressure and the viscous losses are proportional to the inverse square root of the pressure the peak height should be measurable at the higher pressure. The tradeoff here is that at 10 atmospheres; the highest relative humidity attainable is 10 percent. The data collected at 10 atmospheres is also summarized.

Meredith, R. W.↗