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At least 775 records · Page 43

Preliminary Results from the HOTTech-2 Venus Weathering Experiment

Rocks exposed on the surface of Venus are subjected to extreme conditions. The most notable features of the planet’s atmosphere are its pressure (93 bars), its temperature (~460 degrees C), and the presence of oxidizing species such as SO 2 . In aggregate, these factors can be expected to alter exposed rocks over geologic timescales. Our understanding of the nature of this alteration is limited, as the conditions on the Venusian surface are unlike any encountered on the surface of Earth. Last summer, we initiated a multi-year experimental study of Venusian weathering processes. This project dovetails with the community’s Venus Exploration Roadmap, as it addresses priorities such as the study of Venus’ modern habitability and preparations for the upcoming VERITAS, DAVINCI+, and EnVision missions.

GEER↗

High-Pressure Oxygen Dryer (HPOD) FY 2023 Trade Study and Market Survey

A reliable source of dry, high-pressure oxygen is needed for future lunar missions to support nominal and contingency operations on the Surface Habitat (SH) and the Pressurized Rover (PR) in future Gateway missions. A High-Pressure Oxygen Dryer (HPOD) is needed to support potential use of primary oxygen generation systems, the High-Pressure Oxygen Generation Assembly (HPOGA) and the Skyre EOC, by drying the wet oxygen exiting the systems. The objective of this paper is to perform an architecture trade study and market survey of options to dry a continuous stream of 45°C, 4000 PSIG oxygen containing ~ 500 ppm H2O (dew point 52°C) down to < 7 ppm H2O (dew point -15°C) for both the 28-day and 365-day timeframe. A total of seven different technologies were identified as potential dryer candidates during the market survey, relying on one of three principles, adsorption, filtration, and cooling. During the sizing and trade study, it was found that several of the technologies aren’t sufficient for the extreme conditions and were eliminated. In the end, a single-use throw away adsorption bed traded the best for single mission use, while a pressure regenerative adsorption bed traded the best for a multiple mission scenario. The results of this analysis are intended to influence future design work for high-pressure oxygen drying applications.

High Pressure Oxygen↗

Biofilm Mitigation Testing Phase III

Biofilm is produced from bacterial or fungal organisms that can survive in extreme conditions. The microorganisms attach themselves to surfaces and produce an extracellular polymeric matrix that develops into a community structure and ecosystem. Biofilm has been known to cause blockage and clogging inside the Water Processor Assembly (WPA) and Water Recovery System (WRS) piping. The WPA and WRS on the International Space Station (ISS) is responsible for recycling humidity condensate and urine distillate to produce potable water for the astronauts to survive. The Environmental Control and Life Support System (ECLSS) department is developing a way to mitigate biofilm accumulation inside the wastewater tank.

Biofilm↗

High-Pressure Oxygen Dryer (HPOD) FY 2023 Trade Study and Market Survey

A reliable source of dry, high-pressure oxygen is needed for future lunar missions to support nominal and contingency operations on the Surface Habitat (SH) and the Pressurized Rover (PR) in future Gateway missions. A High-Pressure Oxygen Dryer (HPOD) is needed to support potential use of primary oxygen generation systems, the High-Pressure Oxygen Generation Assembly (HPOGA) and the Skyre EOC, by drying the wet oxygen exiting the systems. The objective of this paper is to perform an architecture trade study and market survey of options to dry a continuous stream of 45°C, 4000 PSIG oxygen containing ~ 500 ppm H 2 O (dew point 52°C) down to < 7 ppm H 2 O (dew point -15°C) for both the 28-day and 365-day timeframe. A total of seven different technologies were identified as potential dryer candidates during the market survey, relying on one of three principles, adsorption, filtration, and cooling. During the sizing and trade study, it was found that several of the technologies aren’t sufficient for the extreme conditions and were eliminated. In the end, a single-use throw away adsorption bed traded the best for single mission use, while a pressure regenerative adsorption bed traded the best for a multiple mission scenario. The results of this analysis are intended to influence future design work for high-pressure oxygen drying applications.

High Pressure Oxygen↗

New Tools for Automating Arcjet Sample Recession Tracking and Analysis

Arcjet Computer Vision (arcjetCV) has been significantly upgraded to enhance accuracy and performance in tracking material recession and shock-material standoff in test videos. These improvements include integrating new machine learning models, developing a specialized edge detection class, and incorporating a more comprehensive training dataset. These upgrades have refined the software’s ability to automate time-resolved recession tracking, making it more precise and reliable for analyzing complex physical processes. In parallel, a new tool called STARscan (Spatial Targeting and Alignment Rig for Scanning) is being developed to capture detailed 3D surface data before and after testing. By comparing these pre- and post-test scans with arcjetCV’s automated video analysis results, users can achieve a more comprehensive assessment of material recession. This method enables cross-validation of results, improving confidence in the analysis of tested materials. The expanded capabilities of arcjetCV have been successfully demonstrated on videos from various facilities, including the NASA Ames arcjets, UIUC’s PlasmatronX, and the VKI Plasmatron. It has been adopted as a new standard for in-situ recession tracking by the Mars Sample Return Project and Orion. ArcjetCV’s improved efficiency and accuracy are critical for reducing testing uncertainties and validating heatshield material performance under extreme conditions. The software’s user-friendly graphical interface ensures ease of use, enabling seamless processing and precise analysis of arcjet videos, providing deeper insights into material behavior in hypersonic environments. ArcjetCV is now available on both PyPI and Conda, allowing easy installation via "pip install arcjetCV" or through the Conda package manager, ensuring broad accessibility and streamlined deployment for users across various platforms.

Ablation↗

Erosion Behavior of Ti-hBN Multifunctional Coatings in A Custom-Made Planetary Test Rig at Extreme Lunar Temperatures

Spacecraft landings and takeoffs on the lunar surface, along with extreme temperature variations between day and night (-196 to 150° C), cause high-velocity dust impacts and erosion, resulting in the premature failure of structures. Ti/2 vol% hBN coatings were deposited using atmospheric (APS) and vacuum plasma spray (VPS) using cryo-milled powder feedstock to protect the structural components. The erosion performance of coatings at extreme lunar temperature regimes (-150 to 150° C) was evaluated in a custom-made planetary erosion test rig (PETR) at low (50 mph) and high impact velocities (250 mph). The mass loss of VPS coatings was reduced by 50% compared to the APS coatings and 40% compared to the Ti6Al4V substrate. The cryogenic temperature induces brittleness in the material, rendering it susceptible to extreme conditions of material loss. The particle impact-deformation behavior was captured using a high-speed camera to study the erosion mechanism. This analysis revealed chipping in substrates and brittle APS coatings, while particles rebounding and embedding were observed in VPS coatings. Energy calculations, aided by particle trajectory tracking from the high-speed camera, have conclusively shown that VPS coatings absorb 5–10% more energy than APS coatings during erosion tests. A modified erosion index was developed incorporating the fracture toughness and temperatures. New erosion models for brittle and ductile target materials are proposed for developing erosion-resistant material systems.

Abhijith Kunneparambil Sukumaran↗

Spatially-Resolved Characterization Techniques and Their Implications for Nuclear Debris Formation.

Debris from nuclear tests has a complex formation process and can inform multiple fields of study such as geology, atmospheric science, shock physics, and chemistry under extreme conditions. Macroscopic nuclear debris forms as the result of fireball interaction with surrounding materials (e.g., structural and environmental component), which rapidly undergo melting and vaporization followed by condensation, convective/diffusive mixing, and solidification over the course of seconds. In atmospheric events, some of this material may disperse over long distances, but much of the material is deposited close-in to ground zero, often in multicomponent, partially (or entirely) amorphous debris formations. During the U.S. nuclear testing program, this material was collected and analyzed, particularly for radionuclide composition. Fallout formation models were developed from nuclear test data based on such radionuclide compositional analyses. These models were not just used to understand fallout dispersion (i.e. the spread of radioactivity over geographical regions) but also guide radiochemical interpretations of historical nuclear tests.6 Developments in analytical techniques over the past several decades have made it possible to make new analyses on historical debris, some of which may be more than a half-century old. For example, inductively-coupled plasma mass spectrometry (ICP-MS) has been used to look at the trace elements in glassy fallout material from aboveground nuclear tests (including the Trinity test). Advanced analyses using X-ray absorption allowed for the measurement of oxidation state of fallout constituents, including actinides. The ability to measure trace actinides and their subsequent oxidation state is important to understanding how the surrounding environment may have influenced the resultant fallout composition and may have implications for why certain fractionation trends have been observed. Here we present data from historic nuclear test debris illustrating the power of spatially resolved methods to connect interaction of the near-field environment with the explosion and provide new insights into nuclear debris formation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dynamic Properties of FeCrMnNi, a High Entropy Alloy

High entropy alloys (HEAs) represent a new class of materials that potentially possess an ideal combination of high strength and ductility and may be candidate materials that can withstand high amounts of damage before failure, especially under extreme conditions. To this end, a series of shock/spall loading experiments were conducted on an Fe/Cr/Mn/Ni HEA to assess not only its equation of state (EOS) but also its resistance to damage and failure. A single-stage light gas gun was used to conduct a series of flyer plate symmetric impact experiments coupled with recovery of the samples for post-mortem microstructural analysis to obtain fundamental understanding regarding the damage morphology. Our results show that the measured EOS for this alloy was in reasonable agreement with an estimated Hugoniot value. Additionally, the spall strength of these alloys was found to vary between 1.4 and 1.9 GPa within the same plate but was comparable to other iron-based conventional alloys. DOE/NV/03624--1059

36 MATERIALS SCIENCE↗

A Multiplexed Hybrid Velocimeter

Optical velocimetry systems play a crucial role in studying the dynamic behavior of materials under extreme conditions. Two prominent systems used at the Nevada National Security Site are the velocity interferometer system for any reflector(VISAR) and the photon Doppler velocimeter (PDV) system. Their ability to accurately measure surface motion ranging from 0 to > 20km=s without interacting with material flow enables experimenters to construct thermodynamic equations of state for materials of interest. A number of modifications to VISAR and PDV have taken place over the past five decades, leading to improved performance, increased recording capacity, and a reduction in operational burden. Prior efforts to develop a hybrid velocimeter combining the advantages of both PDV and VISAR into a single diagnostic did not take into account progress in PDV technology or new optical components that had not been developed. This thesis describes the design and implementation of a multiplexed hybrid velocimeter (MHV) based on time-multiplexing techniques, an optical hybrid, and polarization-maintaining fiber and components. Data from experiments, compared with current velocity systems, serve to demonstrate the hybrid's performance.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Aligning Electric Vehicle Customer Charging with Grid Needs

This talk to the National Association of Regulatory Utility Commissioners (NARUC) focuses on "Aligning Electric Vehicle Customer Charging with Grid Needs" to highlight the opportunities associated with managed electric vehicle charging and its value for consumers and the power system. Electric vehicles (EVs) are experiencing a rapid rise in popularity and adoption, and growing EV adoption offers an opportunity to increase electricity demand. With expected widespread EV adoption, supporting charging will require investments in generation, transmission, and distribution systems. Uncoordinated charging of EVs will lead to increased system peak load, possibly exceeding the maximum power that can be supported by distribution systems and generally increasing power system stress. However, vehicles are underutilized assets parked ~96% of the time: managed EV charging can satisfy mobility needs while also supporting the grid. EVs are not a burden for the grid, but a resource: The demand-side flexibility provided by managed EV charging offers significant potential benefits for the grid over multiple timescales and applications., especially for high-renewable systems. Managed charging can support power system planning and operations during normal and extreme conditions, benefitting EV owners and other electricity consumers. Managed charging is shown to consistently provide hundreds of dollars in cost savings per EV each year.

ADVANCED PROPULSION SYSTEMS↗

Phase Stability of Yttrium Titanium Oxide

This proposed study aims at elevating Idaho National Laboratory (INL)’s portfolio in nuclear material research on two major fronts: 1) expanding INL’s material characterization capabilities to provide holistic microstructural and microchemical characterization ranging from atomic scale to millimeter scale, and 2) filling the knowledge gap on the effect of microstructural evolution on material phase stability at extreme conditions resembling those inside nuclear reactors, using Yttrium-Titanium-Oxide (YTO) as a model material. Previous research indicated the kinetics of phase transition of YTO materials varies between bulk samples and powder samples, suggesting that microstructural characteristics such as defect, micro-strain, and crystallite size could play a significant role in phase transition. The effect of crystallite size on the thermodynamics of phase transition has been well documented for other ceramic materials at nanometer crystallite size, with potential impacts from surface and strain energy and defects. In this proposed study, we will perform microstructural (micro-strain, crystallite size, defects, phase) and microchemical (elemental mapping) analyses through in-situ high temperature measurements using X-ray diffraction (XRD; at millimeter scale for powder and bulk samples) and transmission electron microscopy (TEM, at nanometer scale and atomic scale for powder and thin foil samples), to provide a comprehensive view of the effect of microstructural and microchemical evolution on phase transition and phase stability of YTO materials. These findings will also establish a roadmap and provide new insights on the phase stability of other materials that are critical to nuclear energy and other renewable energy infrastructure. Besides advancing our understanding of this fundamental material science question, this project will also enable the development of state-of-the-art material characterization capabilities at INL/MFC for microstructural and microchemical analysis at high temperature conditions. The new collaboration between the High-Resolution Materials Characterization group at INL and the Electron Microscopy group at the University of Florida (UF) in this project will open the possibilities for more fruitful and synergetic cutting-edge nuclear material research in the future.

36 MATERIALS SCIENCE↗

Impact of Fill Factor on Electro-slag Remelting Operations

Vacuum induction melting (VIM), electro-slag remelting (ESR) and vacuum arc remelting (VAR) are all techniques used to make high quality ingots of complex chemistries. In some cases, all three are used, e.g., alloys for aerospace applications and increasingly those for fossil power applications under extreme conditions. Electroslag remelting operation is a complicated endeavor, dependent upon several factors including operating current, voltage, and geometry. A research scale 440 lb capacity ESR furnace was used to melt low carbon steel (1018 steel) electrodes of different diameters using various melt rates. This was used to assess melt parameters and sidewall and other quality aspects of the product ingots. These observations were compared to results from ESR modeling using MeltFlow-ESR. It was found that fill factor had a significant impact on operating voltage while current had a significant impact on melt rate. Ultimately, a combination of fill factor and power gave the best prediction of melt rate during steady state.

Jablonski, Paul↗

Additive Manufacture of Multi-Functional, Large-Scale Components

The poster summarizes the main results for a LDRD focused on developing a arc-based additive manufacturing (AM) system capable of fabricating large components with a composition gradient otherwise known as functionally graded materials (FGMs). FGMs are capable of addressing local extreme conditions in an optimal and cost-effective manner. The AM system (referred to as multi-Wire Arc Additive Manufacturing or m-WAAM) consisted of modifying a standard automated gas tungsten arc welding system to deliver multiple welding wires to the weld pool at controlled rates to deposit desired alloy compositions at critical locations. Numerous shapes and composition gradients were fabricated with the system and the effect of various deposition parameters on the nature of the composition profile were evaluated. Additionally, heat treatment of the FGM was performed to develop graded microstructures which should enhance dynamic impact performance of inexpensive steels. The project highlights the potential of m-WAAM to efficiently fabricate FGMs. However, this project only explored the science behind the technique and additional development work will be required to develop a fully-functional system that can build more complex components.

36 MATERIALS SCIENCE↗

Making Every Microgram Count: Nanocalorimetry for Nuclear and Ultra-Rare Materials

The thermal analysis of nuclear and ultra-rare materials plays an important role in nuclear energy, planetary, environmental, and technological settings. Heat effects associated with the sample temperature, heat capacity, phase transformation, radiation damage and crystallographic defects are some of the thermochemistry measurements made with conventional differential scanning calorimeters. However, the measurement capabilities of the of traditional DSCs are often restricted when studying limited ultra-rare accessory minerals or materials submitted to extreme conditions, such as radiation in the nuclear fuel cycle and high pressure. We investigate the usage of nanocalorimetry for the energetic analysis of nuclear or ultra-rare materials, such as irradiated materials and high-pressure phases, with an emphasis on radiation damage and heat capacity measurements. Examples of how nanocalorimetry has been previously used for phase transitions, melting, and nucleation in ultra-fast heating and cooling rates are presented. Finally, an outlook of the field and future work, including beneficial safety and environmental outcomes from the potential usage of nanocalorimetry, are shown.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Inaugural Molten Salt Technologies Workshop Powering the Future

The inaugural “Molten Salt Technologies – Powering the Future” Workshop marked a significant convergence of minds from diverse industries, each harnessing molten-salt technologies in innovative ways. Participants from sectors such as solar, geothermal, and advanced nuclear energy, as well as those involved in cutting-edge applications like thermal transport and rare-earth metals extraction, gathered to discuss their shared technical challenges and opportunities. Industry leaders in metal extraction and recycling, alongside experts in high-temperature sensor technology and advanced material manufacturing, also brought their unique perspectives to the table. This workshop served as a crucial platform for these varied industries to delve into the engineering intricacies that molten salt technologies entail. Common challenges such as understanding the thermophysical properties of salts, tackling corrosion mechanisms in harsh environments, and enhancing material resilience under extreme conditions were at the forefront of discussions. These technical sessions highlighted the critical need for cross-industry collaboration to address issues like salt life-cycle process engineering, impurity mitigation, and the development of durable, high-performance materials. By bringing together academia, industry, and representatives from national laboratories and the U.S. Department of Energy (DOE), the workshop facilitated a rich exchange of knowledge and experiences. This interaction not only fostered new partnerships but also strengthened the network among existing collaborators, setting the stage for joint solutions to the complex problems faced by all sectors using molten salt technologies. The event underscored the importance of collaborative efforts in overcoming common engineering challenges and advancing the application of molten-salt technologies across various industries. The workshop not only provided an essential forum for networking and idea exchange but also highlighted the collective drive towards innovative solutions that could benefit multiple fields.

Department of Energy↗

FFTF HT9 Cladding Microstructure Characterization

The sodium-cooled fast reactor (SFR) is a promising candidate for next generation nuclear reactors, operating at extreme conditions which include high temperatures (>500?C core outlet temperature) and significant neutron damage. High-Cr martensitic HT9 steel is an excellent candidate for SFR cladding and duct material due to its compatibility with liquid sodium, good thermal conductivity, resistance to void swelling, and strong creep rupture strength [1-4].However, the harsh in-core environment of SFRs can cause complex microstructural changes and mechanical property degradation in HT-9. Ensuring the safe use of HT9 cladding for metallic fuel requires both a thorough understanding of its mechanical response to microstructure evolution as well as reliable microstructure-sensitive modeling predictions. Microstructure-sensitive modeling of high temperature creep behavior in HT9 cladding for SFR applications currently lack experimental data to model the phenomena accurately. To fill this need, methods to perform microstructural characterization have been developed and performed on HT9.

36 MATERIALS SCIENCE↗

Inaugural Molten Salt Technologies Workshop Powering the Future

The inaugural “Molten Salt Technologies – Powering the Future” Workshop marked a significant convergence of minds from diverse industries, each harnessing molten-salt technologies in innovative ways. Participants from sectors such as solar, geothermal, and advanced nuclear energy, as well as those involved in cutting-edge applications like thermal transport and rare-earth metals extraction, gathered to discuss their shared technical challenges and opportunities. Industry leaders in metal extraction and recycling, alongside experts in high-temperature sensor technology and advanced material manufacturing, also brought their unique perspectives to the table. This workshop served as a crucial platform for these varied industries to delve into the engineering intricacies that molten salt technologies entail. Common challenges such as understanding the thermophysical properties of salts, tackling corrosion mechanisms in harsh environments, and enhancing material resilience under extreme conditions were at the forefront of discussions. These technical sessions highlighted the critical need for cross-industry collaboration to address issues like salt life-cycle process engineering, impurity mitigation, and the development of durable, high-performance materials. By bringing together academia, industry, and representatives from national laboratories and the U.S. Department of Energy (DOE), the workshop facilitated a rich exchange of knowledge and experiences. This interaction not only fostered new partnerships but also strengthened the network among existing collaborators, setting the stage for joint solutions to the complex problems faced by all sectors using molten salt technologies. The event underscored the importance of collaborative efforts in overcoming common engineering challenges and advancing the application of molten-salt technologies across various industries. The workshop not only provided an essential forum for networking and idea exchange but also highlighted the collective drive towards innovative solutions that could benefit multiple fields.

Department of Energy↗