Grazing alters net ecosystem C fluxes and the global warming potential of a subtropical pasture
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Environmental Sciences & Ecology↗
SEARCH · Engineering Papers
Results for “EXCLUSIVE INTERACTIONS”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Assessing the difficulty of capturing the distribution function of neutrinos in neutron star merger simulations
The collision of two neutron stars is a rich source of information about nuclear physics. In particular, the kilonova signal following a merger can help us elucidate the role of neutron stars in nucleosynthesis, and informs us about the properties of matter above nuclear saturation. Approximate modeling of neutrinos remains an important limitation to our ability to make predictions for these observables. Part of the problem is the fermionic nature of neutrinos. By the exclusion principle, the expected value 𝑓 𝜈 for the number of neutrinos in a quantum state is at most 1. Any process producing neutrinos is suppressed by a blocking factor (1 −𝑓 𝜈 ). Recent simulations focused on neutrino physics mostly use a gray two-moment scheme to evolve neutrinos. This evolves integrals of 𝑓 𝜈 over momentum space, preventing direct calculations of blocking factors. Monte Carlo methods may be an attractive alternative, providing access to the full distribution of neutrinos. Their current implementation is, however, inadequate to estimate 𝑓 𝜈 : in our most recent simulations, a single Monte Carlo packet causes, in the worst cases, estimates of 𝑓 𝜈 to jump from 𝑓 𝜈 =0 to 𝑓 𝜈 ∼10 5 . While this is concerning, this brazen violation of the fermionic nature of neutrinos has been largely inconsequential, as the interactions used in simulations avoid direct calculations of 𝑓 𝜈 . We are, however, reaching a level of modeling at which this problem can no longer be ignored. Here, we discuss the relatively simple origin of this issue. We then show that very rough estimates of 𝑓 𝜈 can in theory be obtained in merger simulations, but that they will require a combination of unintuitive weighting schemes for Monte Carlo packets and smoothing of the neutrino distribution at coarser resolution than what the merger simulation uses.
79 ASTRONOMY AND ASTROPHYSICS↗
Search for the pair production of long-lived supersymmetric partners of the tau lepton in proton-proton collisions at $\sqrt{s}=13$ TeV
Gauge-mediated supersymmetry-breaking models provide a strong motivation to search for a supersymmetric partner of the tau lepton (stau) with a macroscopic lifetime. Long-lived stau decays produce tau leptons that are displaced from the primary proton-proton interaction vertex, leading to an unconventional signature. This paper presents a search for the direct production of long-lived staus decaying within the CMS tracker volume in proton-proton collisions at $\sqrt{s}=13$ TeV, performed for the first time with an identification algorithm based on a graph neural network dedicated to displaced tau leptons. The data sample, corresponding to an integrated luminosity of 138 fb −1 , was recorded with the CMS experiment at the CERN LHC between 2016 and 2018. This search excludes, at 95% confidence level, stau masses, m~ τ , in the 126–260 (90–425) GeV range for a proper decay length of 50 mm in the maximally mixed (mass-degenerate) scenario, while for m~ τ = 200 GeV, stau proper decay lengths are excluded in the range 21–94 (6–333) mm. These results improve the exclusion limits compared to previous searches, and extend the parameter space explored in the context of supersymmetry.
Hadron-Hadron Scattering↗
Insights into the Biogeochemical Cycling of Cobalt: Precipitation and Transformation of Cobalt Sulfide Nanoparticles under Low-Temperature Aqueous Conditions
Cobalt sulfide precipitates, key phases in the natural biogeochemical cycling of cobalt and in relevant remediation and resource recovery processes, remain poorly defined under low-temperature aqueous conditions. Here, we systematically studied the Co-(Fe) sulfides precipitated and aged in environmentally relevant solutions, defined by different combinations of pH, initial cobalt-to-iron ratios ([Co] aq /[Fe] aq ), with/without S 0 , and the presence/absence of sulfate-reducing bacteria. The initial abiogenic precipitates without Fe aq were composed exclusively of amorphous Co-sulfide hydrates (CoS· x H 2 O), whose estimated log K* was three orders of magnitude higher than that previously reported for crystalline Co-sulfides. The addition of S 0 , in combination with acidic pH and elevated temperature (60°C), resulted in the recrystallization of the amorphous precipitates into nanocrystalline jaipurite (hexagonal CoS) within one month (which otherwise remained stable for up to two months). In the presence of Fe(II) aq , the abiogenic precipitates were composed of more crystalline Co-sulfide hydrates and/or Co-rich mackinawite, the exact phase being dependent on the specific [Co] aq /[Fe(II)] aq . The biogenic precipitates displayed higher crystallinity for Co sulfides (up to the formation of nanocrystalline cobalt pentlandite, Co 9 S 8 ) and lower crystallinity for Co-rich mackinawite, suggestive of mineral-specific bacterial interaction. The revealed precipitation and transformation pathways of Co-(Fe-)sulfides in this study allows for predicting the prevalent Co-bearing phases in various natural and engineered environments.
58 GEOSCIENCES↗
Demonstration and performance of an online data selection algorithm for liquid argon time projection chambers using MicroBooNE
The MicroBooNE detector is a liquid argon time projection chamber (LArTPC) that produces three-dimensional images of particle interactions using ionization charge collected by anode wire plane arrays and scintillation light collected by a light detection system. In addition to testing long-standing experimental neutrino anomalies and performing measurements of neutrino interactions with argon nuclei using the Fermilab Booster Neutrino Beam, MicroBooNE aims to develop methodologies for rare beyond the Standard Model and off-beam physics searches. Looking ahead to the upcoming Deep Underground Neutrino Experiment (DUNE), with MicroBooNE serving as a valuable testbed, achieving high sensitivity and livetime for off-beam physics while satisfying data processing and storage constraints will require data-driven, intelligent, and online or real-time data selection techniques. These techniques are essential for reducing data rates and preserving rare signals with high accuracy. In this paper, we describe a fast data selection algorithm suitable for online execution to identify electrons from stopping cosmic ray muons in the MicroBooNE detector utilizing ionization charge information, and present its performance. This represents the first demonstration of online data selection in a LArTPC using real data and charge information exclusively and provides an important proof-of-principle for applying such techniques to other LArTPC experiments such as the Short-Baseline Near Detector and DUNE.
Abratenko, P. [Tufts U. (main)]↗
Anomalously interacting new extra vector bosons and their first LHC constraints
In this review phenomenological consequences of the Standard Model extension by means of new spin-1 chiral fields with the internal quantum numbers of the electroweak Higgs doublets are summarized. The prospects for resonance production and detection of the chiral vector Z* and W*{sup ±} bosons at the LHC energies are considered on the basis of quantitative simulations within the CompHEP/CalcHEP package. The Z* boson can be observed as a Breit-Wigner resonance peak in the invariant dilepton mass distributions in the same way as the well-known extra gauge Z′ bosons. However, the Z* bosons have unique signatures in transverse momentum, angular and pseudorapidity distributions of the final leptons, which allow one to distinguish them from other heavy neutral resonances. In 2010, with 40 pb{sup −1} of the LHC proton-proton data at the energy 7 TeV, the ATLAS detector was used to search for narrow resonances in the invariant mass spectrum of e{sup +} e{sup −} and μ{sup +}μ{sup −} final states and high-mass charged states decaying to a charged lepton and a neutrino. No statistically significant excess above the Standard Model expectation was observed. The exclusion mass limits of 1.15 and 1.35 TeV/c{sup 2} were obtained for the chiral neutral Z* and charged W* bosons, respectively. These are the first direct limits on the W* and Z* boson production. Based on the above, a novel strategy for the chiral boson search in the LHC dijet data is discussed. For almost all currently considered exotic models the relevant signal is expected in the central dijet rapidity region y{sub 1,2} ≃ 0 and |y{sub 1} − y{sub 2}| ≃ 0. On the contrary, the chiral bosons do not contribute to this region but produce an excess of dijet events far away from it. In particular, for these bosons the appropriate kinematical restrictions lead to a dip in the centrality ratio distribution over the dijet invariant mass instead of a bump expected in the most exotic models.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Limits on the Existence of sub-MeV Sterile Neutrinos from the Decay of 7 Be in Superconducting Quantum Sensors
Sterile neutrinos are natural extensions to the standard model of particle physics and provide a possible portal to the dark sector. We report a new search for the existence of sub-MeV sterile neutrinos using the decay-momentum reconstruction technique in the decay of 7 Be. The experiment measures the total energy of the 7 Li daughter atom from the electron capture decay of 7 Be implanted into sensitive superconducting tunnel junction (STJ) quantum sensors. Here, this first experiment presents data from a single STJ operated at a low count rate for a net total of 28 days, and provides exclusion limits on sterile neutrinos in the mass range from 100 to 850 keV that improve upon previous work by up to an order of magnitude.
42 ENGINEERING↗
Recoil polarization in 𝐾 + 𝑌 electroproduction in the nucleon resonance region with CLAS12
Hyperon recoil polarization measurements for the exclusive electroproduction of 𝐾 + Λ and 𝐾 + Σ 0 final states from an unpolarized proton target have been carried out using the CLAS12 spectrometer at Jefferson Laboratory. The measurements at beam energies of 6.535 and 7.546 GeV span the range of four-momentum transfer 𝑄 2 from 0.3 to 4.5GeV 2 and invariant mass 𝑊 from 1.6 to 2.4 GeV, while covering the full center-of-mass angular range of the 𝐾 + . These new Λ polarization observables extend the existing data in a similar kinematic range but from a significantly larger dataset. However, they represent the first electroproduction measurements of this observable for the Σ 0 . These data will allow for better exploration of the reaction mechanism in strangeness production, for further understanding of the spectrum and structure of excited nucleon states that couple to 𝐾𝑌, and for improved insight into the strong interaction in the nonperturbative domain.
73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
Gold-rich R 3 Au 7 Sn 3 : Establishing the interdependence between electronic features and physical properties
Two new polar intermetallic compounds Y 3 Au 7 Sn 3 (I) and Gd 3 Au 7 Sn 3 (II) have been synthesized and their structures have been determined by single crystal X-ray diffraction (P6 3/m ; Z = 2, a = 8.148(1)/8.185(3), and c = 9.394(2)/9.415(3) for I/II, respectively). They can formally be assigned to the Cu 10 Sn 3 type and consist of parallel slabs of Sn centered, edge-sharing trigonal Au 6 antiprisms connected through R 3 (R = Y, Gd) triangles. Additional Au atoms reside in the centres of trigonal Au 6 prisms forming Au@Au 6 clusters with Au–Au distances of 2.906–2.960 Å, while the R–R contacts in the R 3 groups are considerably larger than the sums of their metallic radii. These exclusive structural arrangements provide alluring systems to study the synergism between strongly correlated systems, particularly, those in the structure of (II), and extensive polar intermetallic contacts, which has been inspected by measurements of the magnetic properties, heat capacities and electrical conductivities of both compounds. Gd 3 Au 7 Sn 3 shows an antiferromagnetic ordering at 13 K, while Y 3 Au 7 Sn 3 is a Pauli paramagnet and a downward curvature in its electrical resistivity at about 1.9 K points to a superconducting transition. DFT-based band structure calculations on R 3 Au 7 Sn 3 (R = Y, Gd) account for the results of the conductivity measurements and different spin ordering models of (II) provide conclusive hints about its magnetic structure. As a result, chemical bonding analyses of both compounds indicate that the vast majority of bonding originates from the heteroatomic Au–Gd and Au–Sn interactions, while homoatomic Au–Au bonding is evident within the Au@Au 6 clusters.
36 MATERIALS SCIENCE↗
Influence of Tall Fescue Epichloë Endophytes on Rhizosphere Soil Microbiome
Tall fescue (Lolium arundinaceum (Schreb.) S.J. Darbyshire) often forms a symbiotic relationship with fungal endophytes (Epichloë coenophiala), which provides increased plant performance and greater tolerance to environmental stress compared to endophyte-free tall fescue. Whether this enhanced performance of tall fescue exclusively results from the grass–fungus symbiosis, or this symbiosis additionally results in the recruitment of soil microbes in the rhizosphere that in turn promote plant growth, remain a question. We investigated the soil bacterial and fungal community composition in iron-rich soil in the southeastern USA, and possible community shifts in soil microbial populations based on endophyte infection in tall fescue by analyzing the 16s rRNA gene and ITS specific region. Our data revealed that plant-available phosphorus (P) was significantly (p < 0.05) influenced by endophyte infection in tall fescue. While the prominent soil bacterial phyla were similar, a clear fungal community shift was observed between endophyte-infected (E+) and endophyte-free (E−) tall fescue soil at the phylum level. Moreover, compared to E− soil, E+ soil showed a greater fungal diversity at the genus level. Our results, thus, indicate a possible three-way interaction between tall fescue, fungal endophyte, and soil fungal communities resulting in improved tall fescue performance.
Mahmud, Kishan↗
OVERVIEW OF THE COOPERATION BETWEEN THE CHERNOBYL CENTER'S INTERNATIONAL RADIOECOLOGY LABORATORY IN SLAVUTYCH, UKRAINE AND U.S. RESEARCH CENTERS BETWEEN 2000-2010
The International Radioecology Laboratory (IRL) located in Slavutych, Ukraine was created in 1999 under the initiative of the United States Government and the Government of Ukraine in the framework of international cooperation on evaluation and minimization of consequences of the Chernobyl nuclear power plant (ChNPP) accident. Since the time the IRL was founded, it has participated in a large number of projects, including the following: (1) study of radionuclide accumulation, distribution, and migration in components of various ecological systems of the Chernobyl Exclusion Zone (ChEZ); (2) radiation dose assessments; (3) study of the effects of radiation influence on biological systems; (4) expert analysis of isotopic and quantitative composition of radioactive contaminants; (5) development of new methods and technologies intended for radioecological research; (6) evaluation of future developments and pathways for potential remediation of the ChEZ areas; (7) assistance in provision of physical protection systems for ionizing irradiation sources at Ukrainian enterprises; (8) reviews of open Russian language publications on issues associated with consequences of the ChNPP accident, radioactive waste management, radioecological monitoring, and ChNPP decommissioning; (9) conduct of training courses on problems of radioecology, radiation safety, radioecological characterization of test sites and environmental media, and on research methods; (10) conduct of on-site scientific conferences and workshops on the ChEZ and radioecology problems; participation in off-site scientific conferences and meetings; and (11) preparation of scientific and popular science publications, and interactions with mass media representatives. This article provides a brief overview of the major achievements resulting from this cooperation between the IRL and U.S. research centers.
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
New insight into knockout reactions from the two-proton halo nucleus 17 Ne
The unexplained disagreement in the dependence of spectroscopic factors (𝐶2𝑆 exp ) on the binding energy obtained by nucleon knockout using different targets is still a puzzle that needs to be addressed. To find an explanation of this riddle through exclusive measurements using different targets. The exclusive measurements were performed by using a 17 Ne beam with an energy of 500 MeV/u incident on C and CH 2 targets. Through the standard theoretical approach, 𝐶 2 𝑆 exp were derived from the analysis of the experimental data on proton ejection from the proton halo in 17 Ne as well as from its core 15 O. For the C target, proton ejection from the proton halo gave 𝐶 2 𝑆 exp about 37% smaller than for the H target. But when protons are ejected from the core of 17 Ne, 𝐶 2 𝑆 exp are identical within statistical uncertainties. An explanation for the difference in 𝐶 2 𝑆 exp could be the removal of both halo protons, a more important reaction pathway for the C target. The 𝐶 2 𝑆 exp values obtained by analyzing the proton ejection from the core indicate that it is not affected by the interaction with the halo protons.
6 ≤ A ≤ 19↗
Structural insights into the RNA methyltransferase domain of METTL16
N 6 -methyladenosine (m 6 A) is an abundant modification in messenger RNA and noncoding RNAs that affects RNA metabolism. Methyltransferase-like protein 16 (METTL16) is a recently confirmed m 6 A RNA methyltransferase that methylates U6 spliceosomal RNA and interacts with the 3'-terminal RNA triple helix of MALAT1 (metastasis-associated lung adenocarcinoma transcript 1). Here, we present two X-ray crystal structures of the N-terminal methyltransferase domain (residues 1–291) of human METTL16 (METTL16_291): an apo structure at 1.9 Å resolution and a post-catalytic S-adenosylhomocysteinebound complex at 2.1 Å resolution. The structures revealed a highly conserved Rossmann fold that is characteristic of Class I S-adenosylmethionine-dependent methyltransferases and a large, positively charged groove. This groove likely represents the RNA-binding site and it includes structural elements unique to METTL16. In-depth analysis of the active site led to a model of the methyl transfer reaction catalyzed by METTL16. In contrast to the major m 6 A methyltransferase heterodimer METTL3/ METTL14, full-length METTL16 forms a homodimer and METTL16_291 exists as a monomer based on size-exclusion chromatography. A native gel-shift assay shows that METTL16 binds to the MALAT1 RNA triple helix, but monomeric METTL16_291 does not. Our results provide insights into the molecular structure of METTL16, which is distinct from METTL3/METTL14.
59 BASIC BIOLOGICAL SCIENCES↗
Extracellular vesicles from Paracoccidioides pathogenic species transport polysaccharide and expose ligands for DC-SIGN receptors
Extracellular vesicles (EVs) mediate non-conventional transport of molecules across the fungal cell wall. We aimed at describing the carbohydrate composition and surface carbohydrate epitopes of EVs isolated from the pathogenic fungi Paracoccidioides brasiliensis and P. lutzii using standard procedures. Total EV carbohydrates were ethanol-precipitated from preparations depleted of lipids and proteins, then analyzed by chemical degradation, gas chromatography-mass spectrometry, nuclear magnetic resonance and size-exclusion chromatography. EV glycosyl residues of Glc, Man, and Gal comprised most probably two major components: a high molecular mass 4,6-α-glucan and a galactofuranosylmannan, possibly an oligomer, bearing a 2-α-Manp main chain linked to β-Galf (1,3) and α-Manp (1,6) end units. The results also suggested the presence of small amounts of a (1→6)- Manp polymer, (1→3)-glucan and (1→6)-glucan. Glycan microarrays allowed identification of EV surface lectin(s), while plant lectin microarray profiling revealed terminal Man and GlcNAc residues exposed at the EVs surface. Mammalian lectin microarray profiling showed that DC-SIGN receptors recognized surface carbohydrate in Paracoccidioides EVs. Our results suggest that oligosaccharides, cytoplasmic storage, and cell wall polysaccharides can be exported in fungal EVs, which also expose surface PAMPs and lectins. As a result, the role of these newly identified components in the interaction with the host remains to be unraveled.
59 BASIC BIOLOGICAL SCIENCES↗
Diffractive exclusive production of Higgs boson and heavy quark pairs at high energy proton-proton collisions
We discuss exclusive double diffractive (EDD) production of Higgs boson and heavy quark-heavy antiquark pairs at high energies. Differential distributions for cc-bar at {radical}(s) = 1.96 GeV and for bb-bar at {radical}(s) = 14 TeV are shown and discussed. Irreducible leading-order bb-bar background to Higgs production is calculated in several kinematical variables. The signal-to-background ratio is shown and several improvements are suggested by imposing cuts on b(b-bar) transverse momenta and rapidities.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Substitutions into the trigonal bipyramidal site of InGaCuO{sub 4}
Solid solutions of InMCu{sub 1-x}Mg{sub x}O{sub 4} (M=Ga{sup 3+}, Al{sup 3+}) have been synthesized to understand the influence of the trigonal bipyramidal (TBP) crystallographic M{sup 3+}/Cu{sup 2+} site of the YbFe{sub 2}O{sub 4}-type structure through powder X-ray and neutron diffraction, dielectric and magnetism measurements. The addition of Mg{sup 2+} in the InGaCuO{sub 4} lattice results in a decrease of the dielectric constant, but the dielectric loss is not affected until the concentration of Mg{sup 2+} is above x=0.50. The shift in the diffraction peaks, and subsequently the change in the lattice parameters, cannot be exclusively explained by the change in ionic radii. These results show the first observation of the reduction in axial bond lengths for TBP Cu{sup 2+} in a YbFe{sub 2}O{sub 4}-type crystal lattice. - Graphical abstract: Solid solutions of InMCu{sub 1-x}Mg{sub x}O{sub 4} (M=Ga{sup 3+}, Al{sup 3+}) have been synthesized and analyzed with powder X-ray and neutron diffraction, dielectric and magnetism measurements. A shift in the lattice parameters that cannot be explained by the change in ionic radii is addressed through a study of the trigonal bipyramidal site. Highlights: Black-Right-Pointing-Pointer Solid solutions of InMCu{sub 1-x}Mg{sub x}O{sub 4} (M=Ga{sup 3+}, Al{sup 3+}) have been synthesized. Black-Right-Pointing-Pointer The observed dielectric properties decreased with the dilution of Cu{sup 2+}. Black-Right-Pointing-Pointer Antiferromagnetic interactions, without ordering, were observed in InGaCu{sub 1-x}Mg{sub x}O{sub 4}. Black-Right-Pointing-Pointer A reduction in the axial TBP bond lengths produced a large change in the c/a ratio. Black-Right-Pointing-Pointer Orbital overlap across the TBP layers greatly affected the observed properties.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
A Search For Weakly Interacting Massive Particles Utilizing A Profile Likelihood Ratio Technique With The Super CDMS Soudan Experiment
Dark matter accounts for ~26.8% of the universe’s mass and ~85% of the matter of the universe. The majority of dark matter is in the form of non-baryonic dark matter. Among all the dark matter particle candidates, the Weakly Interacting Massive Particle (WIMP) is considered the most promising. Tens of experiments around the world are under the searches of WIMPs. The Super Cryogenic Dark Matter Search (SuperCDMS) is one of the leading direct dark matter search experiments. Its latest experiment was located in the Soudan Underground Laboratory in northern Minnesota. By placing its germanium (Ge) detectors deep underground, it aimed at performing a rare-event search in the case that a WIMP would collide with a Ge nucleus and leave a Ge nuclear recoil signal in the detectors. These Ge detectors were operated at a temperature of ~50 mK to reduce the noise from disturbing the ionization and phonon signal collections. A high mass WIMP search analysis is performed on the recent collected data sets at Soudan. It aims at exploring WIMPs with masses from the order of 10 GeV/c 2 and above. With a raw exposure of 1657.54 kg-days, an exclusion limit is set on the spin-independent WIMP-nucleon cross section at 1.32 ×10 -44 cm 2 for a 75 GeV/c2 WIMP at a 90% confidence level by the profile likelihood ratio technique. Neutrons are the most dangerous background in a direct dark matter search experiment. The nuclear recoil signal that a neutron produces in a Ge detector is indistinguishable from vii that a WIMP produces. Protection against them is one of the key aspects for the next generation of SuperCDMS experiment at SNOLAB. An active neutron veto system was proposed to be implemented in this future experiment to make it more robust from neutrons. The feasibility of both the plastic and liquid neutron veto systems was studied.
Qiu, Hang↗
Metal–Ligand Bifunctional Catalysis: The “Accepted” Mechanism, the Issue of Concertedness, and the Function of the Ligand in Catalytic Cycles Involving Hydrogen Atoms
For years, following the ideas of Shvo and Noyori, the core assumption of metal–ligand bifunctional molecular catalysis has relied on the direct involvement of the chelating ligand in the catalytic reaction via a reversible proton (H + ) transfer through cleavage/formation of one of its X–H bonds (X = O, N, C). A recently revised mechanism of the Noyori asymmetric hydrogenation reaction (Dub, P. A. et al. J. Am. Chem. Soc. 2014, 136, 3505) suggests that the ligand is rather involved in the catalytic reaction via the stabilization of determining transition states through N–H···O hydrogen-bonding interactions (HBIs) and not via a reversible H + transfer, behaving in a chemically intact manner within the productive cycle or predominantly in a chemically intact manner within productive cycles. By reexamining selected examples of computational mechanistic studies involving bifunctional catalysts from the literature in the years between 2012–2017, the purpose of this paper is to point out common misconceptions in modeling concerted reactions and show that the actual stepwise nature of key transition states unveils a more complicated catalytic reaction pool (all conceivable catalytic pathways and their crossovers). Such a realization can not only potentially result in a reconsideration of the “accepted” mechanism but also lead us to a new conceptual understanding of the role that the ligand plays in the reaction. Finally, the ultimate goal of this paper is, therefore, to encourage the reader to reconsider the function of the ligand in catalytic cycles of hydrogenation/dehydrogenation with bifunctional catalysts, which until recently has relied almost exclusively on a chemically noninnocent ligand.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗