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At least 775 records · Page 43

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NASA NTRS1990

Observations of CH in comets P/Brorsen-Metcalf and P/Halley

A common feature in the visual spectra of comets is the A squared delta - chi squared pi transition of CH at 4314 A (delta v = 0). This feature is very weak and is easily lost in the continuum or noise. However, the oscillator strength is very small, so even a weak feature indicates a large amount of CH. Understanding the parent of the CH in the comae of comets is very important for understanding the chemistry of comets and, thus, the early solar nebula. Potential parents for the CH are CH4 or more complex hydrocarbons, including polyoxy methanes (POMs). The ratio of CH4 to H2O is indicative of possible sites of formation of the comets. Past observations of comets have shown that the CH is present in the coma. However, because of the intrinsic weakness of the feature and the ease of photodissociating CH, the distribution of the CH in the coma has only been traced in the inner coma, where the fall-off is still 1/p, where p is the impact parameter. The first data sets tracing the distribution of CH to large distances from the nucleus in two comets is presented. Some preliminary models are presented pertaining to the parent of the CH.

Cochran, Anita L.↗

NASA NTRS1990

A methane flux transect along the trans-Alaska pipeline haul road

This paper reports and analyzes methane flux measurements made during the summer of 1987 at 10 km intervals along a north-south direction from Prudhoe Bay to the Arctic Circle in Alaska. Mean CH4 flux from the arctic tundra was 52 mg/sq m/d while that from high-latitude taiga was 11 mg/sq m/d. Fluxes in mg/sq m/d for various plant communities were: wet tundra, 90; low brush-muskeg bog, 45; moist tundra, 31; freshwater ponds, 21; spruce forest, 4.6; and alpine tundra, 0.6. Annual CH4 emission from global tundra and taiga environments is estimated at 38 Tg and 15 Tg, respectively. This is about 46 percent of the wetland emission term of 10 percent of the global atmospheric input.

Whalen, S. C.↗

NASA NTRS1991

The consequences of global biomass burning

Global biomass burning encompasses forest burning for land clearing, the annual burning of grasslands, the annual burning of agricultural stubble and waste after harvests, and the burning of wood as fuel. These activities generate CO2, CH4 and other hydrocarbons, CO, H2, NO, NH3, and CH3Cl; of these, CO, CH4 and the hydrocarbons, and NO, are involved in the photochemical production of tropospheric O3, while NO is transformed to NO2 and then to nitric acid, which falls as acid rain. Biomass burning is also a major source of atmospheric particulates and aerosols which affect the transmission of incoming solar radiation and outgoing IR radiation through the atmosphere, with significant climatic effects.

Levine, Joel S.↗

NASA NTRS1990

Idealized tip-to-tail waverider model

The flow field of an idealized cone-derived waverider is axisymmetric. This forebody feature is preserved for the rest of the vehicle, including the inlet, cowl, combustor, and nozzle. There is thus an inviscid, tip-to-tail model in which both the external and internal flows are axisymmetric. The assumption of axial symmetry provides a major simplification for the analysis and allows for a systematic integration of the propulsion unit with the aerodynamics. The code is an initial formulation that provides only the most basic engineering data, such as lift, thrust, drag, and fuel consumption for a point-designed vehicle that may be cruising at a low hypersonic Mach number. The user may specify flight altitude and Mach number, a multiple shock configuration for the inlet, a few basic geometric parameter, H2 or CH4 as fuel, the fuel/air ratio, etc. A new design concept is used for the nozzle that avoids shock waves, minimizes the nozzle length, and may maximize its thrust. A general description of the model is provided with emphasis on the design of the nozzle and fins. Preliminary results are presented that compare the cruise flight range using H2 or CH4 as the fuel.

Emanuel, G.↗

NASA NTRS1991

The Jovian ionospheric E region

A model of the Jovian ionosphere was constructed, that includes direct photoionization of hydrocarbon molecules. A high-resolution solar spectrum was synthesized from Hinteregger's solar maximum spectrum (F79050N), and high-resolution cross sections for photoabsorption by H2 bands in the range 842 to 1116 A were constructed. Two strong solar lines and about 30 percent of the continuum flux between 912 and 1116 A penetrate below the methane homopause despite strong absorption by CH4 and H2. It is found that hydrocarbons (mainly C2H2 are ionized at a maximum rate of 55/cu cm per sec at 320 km above the ammonia cloud tops. The hydrocarbon ions produced are quickly converted to more complex hydrocarbon ions through reactions with CH4, C2H2, C2H6, and C2H4. It is found that a hydrocarbon ion layer is formed near 320 km that is about 50 km wide with a peak density in excess of 10,000/cu cm.

Kim, Y. H.↗

NASA NTRS1991

Methane and nitrous oxide fluxes in native, fertilized and cultivated grasslands

Measurements of CH4 uptake and N2O emissions in native, nitrogen-fertilized, and wheat-growing prairie soils from spring to late autumn, 1990 are reported. It is found that nitrogen fertilization and cultivation can both decrease CH4 uptake and increase N2O production, thereby contributing to the increasing atmospheric concentrations of these gases.

Mosier, A.↗

NASA NTRS1990

Thermal emission spectroscopy of the middle atmosphere

The general objective of this research is to obtain, via remote sensing, simultaneous measurements of the vertical distributions of stratospheric temperature, ozone, and trace constituents that participate in the catalytic destruction of ozone (NO(sub y): NO, NO2, NO3, HNO3, ClONO2, N2O5, HNO4; Cl(sub x): HOCl), and the source gases for the catalytic cycles (H2O, CH4, N2O, CF2Cl2, CFCl3, CCl4, CH3Cl, CHF2Cl, etc.). Data are collected during a complete diurnal cycle in order to test our present understanding of ozone chemistry and its associate catalytic cycles. The instrumentation employed is an emission-mode, balloon-borne, liquid-nitrogen-cooled Michelson interferometer-spectrometer (SIRIS), covering the mid-infrared range with a spectral resolution of 0.020 cm(exp -1). Cryogenic cooling combined with the use of extrinsic silicon photoconductor detectors allows the detection of weak emission features of stratospheric gaseous species. Vertical distributions of these species are inferred from scans of the thermal emission of the limb in a sequence of elevation angles. The fourth SIRIS balloon flight was carried out from Palestine, Texas on September 15-16, 1986 with 9 hours of nighttime data (40 km). High quality data with spectral resolution 0.022 cm(exp -1), were obtained for numerous limb sequences. Fifteen stratospheric species have been identified to date from this flight: five species from the NO(sub y) family (HNO3, NO2, NO, ClONO2, N2O5), plus CO2, O3, H2O, N2O, CH4, CCl3F, CCl2F2, CHF2Cl, CF4, and CCl4. The nighttime values of N2O5, ClONO2, and total odd nitrogen have been measured for the first time, and compared to model results. Analysis of the diurnal variation of N2O5 within the 1984 and 1986 data sets, and of the 1984 ClONO2 measurements, were presented in the literature. The demonstrated ability of SIRIS to measure all the major NO(sub y) species, and therefore to determine the partitioning of the nitrogen family over a continuous diurnal cycle, is a powerful tool in the verification and improvement of photochemical modeling.

Kunde, V. G.↗

NASA NTRS1992

Chemistry of the outer planets

Various aspects were studied of past or present chemistry in the atmospheres of the outer planets and their satellites using lab simulations. Three areas were studied: (1) organic chemistry induced by kinetically hot hydrogen atoms in the region of Jupiter's atmosphere containing the ammonia cirrus clouds; (2) the conversion of NH3 into N2 by plasmas associated with entry of meteors and other objects into the atmosphere of early Titan; and (3) the synthesis of simple hydrocarbons and HCN by lightning in mixtures containing N2, CH4, and NH3 representing the atmospheres of Titan and the outer planets. The results showed that: (1) hot H2 atoms formed from the photodissociation of NH3 in Jupiter's atmosphere could account for some of the atmospheric chemistry in the ammonia cirrus cloud region; (2) the thermalization of hot H2 atoms in atmospheres predominated by molecular H is not as rapid as predicted by elastic collision theory; (3) the net quantum loss of NH3 in the presence of a 200 fold excess of H2 is 0.02, much higher than was expected from the amount of H2 present; (4) the conversion of NH3 into N2 in plasmas associated with infalling meteors is very efficient and rapid, and could account for most of the N2 present on Titan; (5) the yields of C2H2 and HCN from lightning induced chemistry in mixtures of CH4 and N2 is consistent with quenched thermodynamic models of the discharge core; and (6) photolysis induced by the UV light emitted by the gases in the hot plasmas may account for some, if not most, of the excess production of C2H6 and the more complex hydrocarbons.

Scattergood, Thomas W.↗

NASA NTRS1991

Spectroscopy and chemistry of the atmosphere of Uranus

A comprehensive review of the chemistry and spectroscopy of the Uranian atmosphere is presented by means of earth-based, earth-orbital, and Voyager 2 observations covering the UV, visible, infrared, and radio wavelength regions. It is inferred from these observations, in concert with the average density of about 1.3 g/cu cm, that the Uranian atmosphere is enriched in heavy elements relative to solar composition. Pre-Voyager earth-based observations of CH4 bands in the visible region and Voyager radio occultation data imply a CH4/H2 volume mixing ratio of about 2 percent corresponding to an enrichment of approximately 24 times the solar value of 0.000835. In contrast to CH4, microwave observations indicate an apparent depletion of NH3 in the 155-to-200-K region of the atmosphere by 100 to 200 times relative to the solar NH3/H2 mixing ratio of -0.000174. It is suggested that the temporal and latitudinal variations deduced for the NH3/H2 mixing ratio in this region of the Uranian atmosphere are due to atmospheric circulation effects.

Fegley, Bruce, Jr.↗

NASA NTRS1992

Titan's greenhouse and antigreenhouse effects

Thermal mechanisms active in Titan's atmosphere are discussed in a brief review of data obtained during the Voyager I flyby in 1980. Particular attention is given to the greenhouse effect (GHE) produced by atmospheric H2, N2, and CH4; this GHE is stronger than that on earth, with CH4 and H2 playing roles similar to those of H2O and CO2 on earth. Also active on Titan is an antigreenhouse effect, in which dark-brown and orange organic aerosols block incoming solar light while allowing IR radiation from the Titan surface to escape. The combination of GHE and anti-GHE leads to a surface temperature about 12 C higher than it would be if Titan had no atmosphere.

Mckay, Christopher P.↗

NASA NTRS1991

Airborne tunable diode laser sensor for high-precision concentration and flux measurements of carbon monoxide and methane

An airborne tunable diode laser instrument is described that is capable of operating in two measurement modes. One mode provides high precision (0.1 percent CH4; 1 percent CO) measurements of CH4 and CO with a 5 second response time, and a second mode achieves the very fast response time that is necessary to make airborne eddy correlation flux measurements. Examples of data from atmospheric expeditions of the Global Tropospheric Experiment are presented.

Sachse, G. W.↗

NASA NTRS1991

Source gases: Concentrations, emissions, and trends

Source gases are defined as those gases that influence levels of stratospheric ozone (O3) by transporting species containing halogen, hydrogen, and nitrogen to the stratosphere. Examples are the CFC's, methane (CH4), and nitrous oxide (N2O). Other source gases that also come under consideration in an atmospheric O3 context are those that are involved in the O3 or hydroxyl (OH) radical chemistry of the troposphere. Examples are CH4, carbon monoxide (CO), and nonmethane hydrocarbons (NMHC's). Most of the source gases, along with carbon dioxide (CO2) and water vapor (H2O), are climatically significant and thus affect stratospheric O3 levels by their influence on stratospheric temperatures. Carbonyl sulphide (COS) could affect stratospheric O3 through maintenance of the stratospheric sulphate aerosol layer, which may be involved in heterogeneous chlorine-catalyzed O3 destruction. The previous reviews of trends and emissions of source gases, either from the context of their influence on atmospheric O3 or global climate change, are updated. The current global abundances and concentration trends of the trace gases are given in tabular format.

Fraser, Paul J.↗

NASA NTRS1992

Modification of primordial ices by cosmic rays as simulated by cyclotron irradiation

Frozen CH4 and CH4/Ar mixtures closed into metal cuvettes and open to the vacuum were irradiated at 15 and 77 K with 10 - 20 MeV p and He-3(2+) ions in order to simulate the effect of cosmic rays on solid organic matter in space. Ices exposed to vacuum represent surfaces of icy systems whereas closed systems stand for bulk ices. The products were analyzed by MS, SEM, RBS, ERDA, H-1-NMR, HPLC, GC-MS, NEXAFS, and FT-IR. Volatile products consisted of a mixture of low molecular species, e.g., C2H2, C2H4, C2H6, and long linear aliphatic and olefinic compounds. The formation of polycyclic aromatic hydrocarbons (PAH's) and related species in solid CH4 is due to a multi-center reaction within one collision cascade and is governed by energy density effects with critical linear energy transfer values L(sub T) between 2 and 10 keV/micron. Open ices exhibit preferential hydrogen release resulting in an increased carbonization as compared to more hydrogen rich molecules protected inside large icy bodies.

Kaiser, R. I.↗

NASA NTRS1993

Stratospheric circulation features deduced from SAMS constituent data

Further analyses of three years of SAMS data are used to investigate stratospheric circulation. Eddy effects on constituent transport are examined with two transport formulations - the transformed Eulerian mean formulation and the effective transport formulation. The transformed Eulerian mean formulation, together with calculated residual mean winds, is employed to delineate regions, or times, of significant eddy contributions to constituent transport. The effective transport formulation, which involves individual calculations of the effective-transport velocity for both CH4 and N2O, is used. Both gases reveal a descent in the tropics during northern spring and upwelling in the summer tropics of the stratosphere during solstice. The Northern Hemisphere upwelling appears to cause larger CH4 increases than corresponding Southern Hemisphere summer tropical upwelling.

Stanford, J. L.↗

NASA NTRS1993

HALOE Antarctic observations in the spring of 1991

HALOE observations of O3, CH4, HF, H2O, NO, NO2, and HCl collected during the October 1991 Antarctic spring period are reported. The data show a constant CH4 mixing ratio of about 0.25 ppmv for the altitude range from 65 km down to about 25 km at the position of minimum wind speed in the vortex: i.e., the vortex center, and depressions in pressure versus longitude contours of NO, NO2, HF, and HCl in this same region. Water vapor, HF, and HCl enhancement are also observed in the vortex center region above about 25 km. Between 10 and 20 km, the expected mixing ratio signatures exist within the vortex, i.e., low ozone and dehydration. The water vapor increased by 50 percent, and the ozone level doubled inside the vortex between October 11 and 24 in the 15-20 km layer. These changes imply a time constant for recovery from ozone hole conditions of 19 and 30 days for O3 and H2O, respectively. The data further show the presence of air inside the vortex between 3 and 30 mb which has mixing ratios characteristic of midlatitudes.

Russell, James M., III↗

NASA NTRS1991

Aircraft laser infrared absorption spectrometer (ALIAS) for polar ozone studies

The ALIAS instrument is a very high resolution (0.0003/cm) scanning, tunable diode laser spectrometer designed to make direct, simultaneous measurements of NO2, HNO3, HCl, CH4, and either O3 or N2O (including vertical profiles of CH4 and N2O) in the polar stratosphere at sub-part-per-billion level sensitivities over integration times from 3 to 30 s. Unique features include a sample inlet/throttle system designed to achieve near-isokinetic sampling, in PSC events, an in-flight wavelength reference cell rack, mechanical fringe-spoilers, a four-laser/four-detector dewar with 24-hr hold-time operating at a fixed temperature without electrical regulation, and in-flight fast correlation routines for spectral drift compensation prior to spectral addition. Instrument design and test flight results are discussed in the light of ALIAS's role in the Winter 1991 Arctic aircraft stratospheric ozone campaigns out of Fairbanks, Alaska, and Bangor, Maine.

Webster, C. R.↗

NASA NTRS1993

The Halogen Occultation Experiment

The Halogen Occultation Experiment (HALOE) uses solar occultation to measure vertical profiles of O3, HCl, HF, CH4, H2O, NO, NO2, aerosol extinction, and temperature versus pressure with an instantaneous vertical field of view of 1.6 km at the earth limb. Latitudinal coverage is from 80 deg S to 80 deg N over the course of 1 year and includes extensive observations of the Antarctic region during spring. The altitude range of the measurements extends from about 15 km to about 60-130 km, depending on channel. Experiment operations have been essentially flawless, and all performance criteria either meet or exceed specifications. Internal data consistency checks, comparisons with correlative measurements, and qualitative comparisons with 1985 atmospheric trace molecule spectroscopy (ATMOS) results are in good agreement. Examples of pressure versus latitude cross sections and a global orthographic projection for the September 21 to October 15, 1992, period show the utility of CH4, HF, and H2O as tracers, the occurrence of dehydration in the Antarctic lower stratosphere, the presence of the water vapor hygropause in the tropics, evidence of Antarctic air in the tropics, the influence of Hadley tropical upwelling, and the first global distribution of HCl, HF, and NO throughout the stratosphere. Nitric oxide measurements extend through the lower thermosphere.

Russell, James M., III↗

NASA NTRS1993

Air-, N2-, and O2-broadening and shift coefficients in the nu(3) spectral region of (C-12)H4

Results are presented of an analysis of 29 room-temperature laboratory absorption spectra of a dilute CH4 sample in dry air, N2, and O2 at total pressures ranging from 60 to 550 torr, yielding values of pressure-broadening and pressure-induced-shift coefficients for more than 450 vibration-rotation transitions in the nu(3), nu(2) + nu(4), and 2nu(2)-super-2 bands of (C-12)H4. Comparisons of the present results for the nu(3) and nu(2) + nu(4) bands with previous measurements on other bands and isotopes of CH4 show that, for a given transition, broadening by air and N2 are nearly equal, and broadening by O2 is smaller by less than 10 percent. It is also found that the pressure shift coefficients are more vibrational dependent than the pressure broadening coefficients.

Benner, D. C.↗