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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43

Exploring the relationship between solvent-assisted ball milling, particle size, and sintering temperature in garnet-type solid electrolytes

Garnet-type solid electrolytes, such as Li 6.4 La 3 Zr 1.4 Ta 0.6 O 12 (LLZTO), are promising materials for solid-state batteries, but processing remains a challenge, in part due to the high sintering temperature required for densification. Additionally, this temperature can be lowered by decreasing the initial particle size via solvent-assisted ball milling, but the relationship between solvent choice, particle properties, sintering behavior, and ionic conductivity is not well understood. In this work, we systematically explore these parameters, showing that milling in commonly used protic solvents, such as alcohols, effectively decreases the particle size but results in lithium loss (through Li + /H + exchange) that leads to poor sintering. By contrast, milling in aprotic solvents with surfactant reduces the particle size to ~220 nm without lithium loss, enabling the fabrication of dense samples (5.1 g/cm 3 ) with good ionic conductivity (0.43 mS/cm at 25 °C) at a lower sintering temperature (1000 °C). We compare ionic conductivities and activation energies for samples prepared with different particle sizes and sintering temperatures and use multiphase-field simulations to identify the mass transport and microstructural mechanisms responsible for the observed sintering dependence on particle size. These results further clarify the relationship between processing parameters and performance and represent important progress toward overcoming fabrication challenges for these materials.

25 ENERGY STORAGE↗

Shielding Considerations for CubeSat Structures During Solar Maximum

The purpose of this lessons learned is to communicate the utility of shielding in small spacecraft planning for the support of mission assurance and reliability. Numerous SmallSats have been flying in polar low earth orbit for scientific, communications, technology demonstrations, and imaging with academic, commercial, and government interests. Shielding has been part of mission assurance and reliability from the advent of long duration spacecraft missions. The Shields-1 CubeSat has been operating in polar low earth orbit since 16 December 2018 with atomic number (Z)-grade radiation shielding and demonstrates shielding effectiveness. Shields-1 has collected a representative example of solar minimum data in 2019 with 8 Teledyne dosimeters over varying shielding effectiveness. It serves as current experimental data and has been compared with NOVICE Shielding estimates using the AP8 –AE8 trapped radiation model with the Shields-1 CAD and generic CubeSat 3 unit (U) models. Using NOVICE model radiation analysis coding, the shielding effectiveness's, based on a generic CubeSat 3U structure with 4 electronic boards, were estimated for aluminum wall thicknesses ranging from 0.204 cmto4.44 cm (0.550 g/cm2–12.0 g/cm2) thick aluminum. For modeled polar orbiting spacecraft, solar maximum total ionizing dose (TID)increases by nearly a magnitude for thin-walled aluminum 0.550g/cm2-0.686 g/cm2(0.204 cm –0.254 cm) typical CubeSat structures. The shielding effectiveness by NOVICE Sigma estimates, which is a shielding sphere approximation around a detector, showed a linear relationship with wall thickness, which increased over the wall thickness by a ratio of 1.43 determined by linear regression analysis. Using NOVICE Adjoint Monte-Carlo Modeling of solar minimum and solar maximum with the inclusion of a worst-case solar particle event over a one year mission without geomagnetic shielding, the TID for minimum and maximum conditions for a generic 3U with a wall thickness of 0.254 cm is 158 RAD and 1540 RAD, respectively. The modeled total solar maximum TID is over estimated, because at low orbital latitudes a spacecraft will have shielding from Earth's magnetic field. However, TID will still be significant at high latitudes over the poles, where a spacecraft is exposed in a solar particle event. In contrast, to a thin walled generic 3U CubeSat, Shields-1 electronics enclosure has a shielding effectiveness of 21.3 g/cm2from NOVICE Sigma modeling and is expected to show reduced total ionizing dose increases during the present active Solar Cycle 25 period. Because solar particle events during solar maximum increase TID on electronic parts with thin-walled shielding in short periods of time, it is a mission assurance and reliability consideration on the spacecraft’s mission value versus adding shielding for risk reduction of premature spacecraft or instrument payload loss. Since the volumes of many instruments and system electronics have reduced with small spacecraft, shielding material costs and weight penalties have diminished. A small spacecraft project budget and schedule may limit traditional radiation-hardened part use and radiation testing requirements, where shielding can contribute to mission assurance and reliability with reduced costs.

Shields-1↗

Dust in the Sky: Atmospheric Composition. Modeling of Aerosol Optical Thickness

Aerosol is any small particle of matter that rests suspended in the atmosphere. Natural sources, such as deserts, create some aerosols; consumption of fossil fuels and industrial activity create other aerosols. All the microscopic aerosol particles add up to a large amount of material floating in the atmosphere. You can see the particles in the haze that floats over polluted cities. Beyond this visible effect, aerosols can actually lower temperatures. They do this by blocking, or scattering, a portion of the sun's energy from reaching the surface. Because of this influence, scientists study the physical properties of atmospheric aerosols. Reliable numerical models for atmospheric aerosols play an important role in research.

Chin, Mian↗

Solar activity influence on cosmic ray penetration in the middle atmosphere

A new improved model for cosmic rays-middle atmosphere interaction is developed. The ionization q(h)-profile dependence on penetrating high energy particles composition (protons, alpha-particles and heavier nuclei) and energy spectra (solar activity modulation included) are investigated. A computer program, realizing the Gaussian algorithm for solving of multidimensional integrals is created. The corresponding electron density profiles N(h) at solar minimum and maximum are obtained.

Vellinov, P. I.↗

Variations in Venus cloud particle properties: A new view of Venus's cloud morphology as observed by Galileo Near-Infrared Mapping Spectrometer

Using Venus nightside data obtained by the Galileo Near-Infrared Mapping Spectrometer (NIMS), we have studied the correlation of 1.74 and 2.30 micrometer radiation which is transmitted through the clouds. Since the scattering and absorption properties of the cloud particles are different at these two wavelengths, one can distinguish between abundance variations and variations in the properties of the cloud particles themselves. The correlation of intensities shows a clustering of data into five distinct branches. Using radiative transfer calculations, we interpret these branches as regions of distinct but different mixes of Mode 2' and 3 particles. The data and calculations indicate large differences in these modal ratios, the active cloud regions varying in content from nearly pure Mode 2' particles to almost wholly Mode 3. The spatial distribution of these branches shows large scale sizes and both hemispheric symmetries and asymmetries. High-latitude concentrations of large particles are seen in both hemispheres and there is banded structure of small particles seen in both the North and South which may be related. The mean particle size in the Northern Hemisphere is greater than found in the South. If these different branch regions are due to mixing of vertically stratified source regions (e.g. photochemical and condensation source mechanisms), then the mixing must be coherent over very large spatial scales.

Carlson, R. W.↗

Energetic Charged Particle Component or the NO(y) Budget of the Polar Middle Atmosphere

Analysis of nitrates measured in polar ice cap snow at a high resolution shows large variations in the nitrates. It has been shown that the nitrate signal may contain a signature of solar activity [Zeller and Dreschhoff, 19951. Reactive odd nitrogen production associated with solar particle events (SPEs) and auroral activity may be a source of some of the nitrate anomalies observed in the polar ice caps. Periods of large SPEs can lead to a production of polar atmospheric odd nitrogen in excess of the ambient sources in the polar stratosphere and mesosphere, and may leave a large nitrate signal stratified in the polar ice cap. Auroral electrons and photoelectrons produce odd nitrogen in the thermosphere, some of which may be transported to the polar (>50 degrees) mesosphere and stratosphere. Sources of odd nitrogen in the polar middle atmosphere associated with SPEs, galactic cosmic rays, and auroral electron precipitation have been quantified. The relative contributions by the energetic particles sources to the Noy budget of the polar middle atmosphere (from tropopause to 50 km, from 50 degrees to 90 degrees latitude) are compared with the nitrates observed in the polar ice sheets.

Vitt, F. M.↗

Gas pressure and electron density at the level of the active zone of hollow cathode arc discharges

A model for the longitudinal variations of the partial pressures of electrons, ions, and neutral particles is proposed as a result of an experimental study of pressure variations at the level of the active zone as a function of the various discharge parameters of a hollow cathode arc. The cathode region where the temperature passes through its maximum is called active zone. The proposed model embodies the very important variations which the partial electron and neutral particles pressures undergo at the level of the active zone.

Minoo, M. H.↗

Electrochemical Imaging of Precisely‐Defined Redox and Reactive Interfaces

Abstract Understanding the diverse electrochemical reactions occurring at electrode‐electrolyte interfaces (EEIs) is a critical challenge to developing more efficient energy conversion and storage technologies. Establishing a predictive molecular‐level understanding of solid electrolyte interphases (SEIs) is challenging due to the presence of multiple intertwined chemical and electrochemical processes occurring at battery electrodes. Similarly, chemical conversions in reactive electrochemical systems are often influenced by the heterogeneous distribution of active sites, surface defects, and catalyst particle sizes. In this mini review, we highlight an emerging field of interfacial science that isolates the impact of specific chemical species by preparing precisely‐defined EEIs and visualizing the reactivity of their individual components using single‐entity characterization techniques. We highlight the broad applicability and versatility of these methods, along with current state‐of‐the‐art instrumentation and future opportunities for these approaches to address key scientific challenges related to batteries, chemical separations, and fuel cells. We establish that controlled preparation of well‐defined electrodes combined with single entity characterization will be crucial to filling key knowledge gaps and advancing the theories used to describe and predict chemical and physical processes occurring at EEIs and accelerating new materials discovery for energy applications.

Edgecomb, Joseph↗

Electrochemical Imaging of Precisely‐Defined Redox and Reactive Interfaces

Abstract Understanding the diverse electrochemical reactions occurring at electrode‐electrolyte interfaces (EEIs) is a critical challenge to developing more efficient energy conversion and storage technologies. Establishing a predictive molecular‐level understanding of solid electrolyte interphases (SEIs) is challenging due to the presence of multiple intertwined chemical and electrochemical processes occurring at battery electrodes. Similarly, chemical conversions in reactive electrochemical systems are often influenced by the heterogeneous distribution of active sites, surface defects, and catalyst particle sizes. In this mini review, we highlight an emerging field of interfacial science that isolates the impact of specific chemical species by preparing precisely‐defined EEIs and visualizing the reactivity of their individual components using single‐entity characterization techniques. We highlight the broad applicability and versatility of these methods, along with current state‐of‐the‐art instrumentation and future opportunities for these approaches to address key scientific challenges related to batteries, chemical separations, and fuel cells. We establish that controlled preparation of well‐defined electrodes combined with single entity characterization will be crucial to filling key knowledge gaps and advancing the theories used to describe and predict chemical and physical processes occurring at EEIs and accelerating new materials discovery for energy applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Decoupling size and surface effects of intermetallic CuPd nanocrystals for electrocatalytic nitrate reduction to ammonia

Nitrate pollution poses a major environmental challenge, but its electrochemical conversion to ammonia offers a sustainable waste-to-value solution. Here, in this study, we synthesized monodisperse, size-tunable B2-phase CuPd intermetallic nanocrystals (6–46 nm) and studied their performance in the electrochemical nitrate reduction reaction (eNO 3 RR). By using bromide ions to modulate Pd reduction and applying mild annealing, we achieved phase-pure B2 structures across all sizes. Catalytic testing revealed a volcano-like trend in ammonia yield, peaking at 33 nm nanocubes with a rate of 6.97 mol h −1 g −1 at −0.6 V vs. reversible hydrogen electrode (RHE). This optimum reflects a balance between the increased surface area of smaller particles and the enhanced exposure of active (100) facets in larger ones. Theoretical calculations indicated that the B2-CuPd (100) facet is favorable for nitrate adsorption, thereby supporting the high activity of nanocubes. Our results highlight the critical role of tuning both nanoparticle size and surface structure to maximize eNO 3 RR efficiency.

36 MATERIALS SCIENCE↗

Inclusive photon production at forward rapidities in pp and p–Pb collisions at $\sqrt{{{s}}_{\textrm{NN}}}={5.02}$ TeV

A study of multiplicity and pseudorapidity distributions of inclusive photons measured in pp and p–Pb collisions at a center-of-mass energy per nucleon–nucleon collision of $\sqrt{s_{NN}}$ = 5.02 TeV using the ALICE detector in the forward pseudorapidity region 2.3 < η lab < 3.9 is presented. Measurements in p–Pb collisions are reported for two beam configurations in which the directions of the proton and lead ion beam were reversed. The pseudorapidity distributions in p–Pb collisions are obtained for seven centrality classes which are defined based on different event activity estimators, i.e., the charged-particle multiplicity measured at midrapidity as well as the energy deposited in a calorimeter at beam rapidity. The inclusive photon multiplicity distributions for both pp and p–Pb collisions are described by double negative binomial distributions. The pseudorapidity distributions of inclusive photons are compared to those of charged particles at midrapidity in pp collisions and for different centrality classes in p–Pb collisions. The results are compared to predictions from various Monte Carlo event generators. None of the generators considered in this paper reproduces the inclusive photon multiplicity distributions in the reported multiplicity range. The pseudorapidity distributions are, however, better described by the same generators.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Towards Unlocking Insights from Logbooks Using AI

Electronic logbooks contain valuable information about activities and events concerning their associated particle accelerator facilities. However, the highly technical nature of logbook entries can hinder their usability and automation. As natural language processing (NLP) continues advancing, it offers opportunities to address various challenges that logbooks present. This work explores jointly testing a tailored Retrieval Augmented Generation (RAG) model for enhancing the usability of particle accelerator logbooks at institutes like DESY, BESSY, Fermilab, BNL, SLAC, LBNL and CERN. The RAG model uses a corpus built on logbook contributions and aims to unlock insights from these logbooks by leveraging retrieval over facility datasets, including discussion about potential multimodal sources. Our goals are to increase the FAIR-ness (findability, accessibility, interoperability, and reusability) of logbooks by exploiting their information content to streamline everyday use, to enable macro-analysis for root cause analysis, and to facilitate problem-solving automation.

43 PARTICLE ACCELERATORS↗

A summary of the OV1-19 satellite dose, depth dose, and linear energy transfer spectral measurements

Measurements of the biophysical and physical parameters in the near earth space environment, specifically, the Inner Van Allen Belt are discussed. This region of space is of great interest to planners of the Skylab and the Space Station programs because of the high energy proton environment, especially during periods of increased solar activity. Many physical measurements of charged particle flux, spectra, and pitch angle distribution have been conducted and are programmed in the space radiation environment. Such predictions are not sufficient to accurately predict the effects of space radiations on critical biological and electronic systems operating in these environments. Some of the difficulties encountered in transferring from physical data to a prediction of the effects of space radiation on operational systems are discussed.

Cervini, J. T.↗

Narcosis studies and oxygen poisoning of mice

The research for a mechanism by which narcotic gases alter metabolism is reported. Possible sites of action by narcotic and anesthetic gases in isolated electron transport particles were explored. Using the relative activities of the NADH-oxygen, NADH-ferricyanide, succinate-cytochrome C and succinate-NAD oxidoreductase systems as parameters, the relative potency of volatile anesthetics were tested. Testing the relative ability of human subjects to contract and repay an oxygen debt while in the narcotic versus alert state, it was found that narcosis induced by 33% nitrous oxide increased the size of the oxygen debt contracted and the amount of oxygen required to repay it during recovery. Mice acclimatized to sea level (760 mm Hg), 5000 feet (632 mm Hg) or 15,000 feet 437 mm Hg) for from one to eight weeks were found to be more susceptible to convulsion and death as a function of altitude acclimatization when tested in hyperoxic environments. There were no reasonable explanations for the connection between hypoxia and oxygen poisoning but several practical implications for persons living at altitude are discussed.

Source record↗

Improved chemical vapor-deposition reactor

Formation of large particles on substrate is eliminated by actively exhausting reacted gases. Effluent gas backflow is prevented by pumping in curtain of nitrogen above fresh reactive gases from several directions.

Chern, S. S.↗