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At least 775 records · Page 43

Increasing temperature and flow management alter mercury dynamics in East Fork Poplar Creek

East Fork Poplar Creek (EFPC) is a mercury (Hg) contaminated creek in east Tennessee, USA. Stream restoration activities included the initiation of a flow management programme in 1996 in which water from a nearby lake was pumped to the head of the creek. We conducted regular water sampling for 2 years along the length of EFPC during active flow management and for 5 years after flow management stopped. Total Hg and total monomethylmercury (MMHg) concentration and flux decreased in the uppermost reaches of EFPC that were closest to the point of water addition. Most water quality parameters, including DOC concentration, remained unchanged after flow management termination. Nevertheless, SUVA 254 , a measure of dissolved organic matter (DOM) composition, increased and coincided with increased dissolved Hg (Hg D ) concentration and flux and decreased Hg solid-water partitioning coefficients throughout EFPC. Higher SUVA 254 and Hg D concentration have potential implications for bioavailability and MMHg production. Total and dissolved MMHg concentrations increased in lower reaches of EFPC after the end of flow management and these increases were most pronounced during spring and early summer when biota are more susceptible to exposure and uptake. A general warming trend in the creek after active flow management ended likely acted in concert with higher Hg D concentration to promote higher MMHg concentration. Total and dissolved MMHg concentrations were positively correlated with water temperature above a threshold value of 10°C. Concentration changes for Hg and MMHg could not be accounted for by changes in creek discharge that accompanied the cessation of flow management. In addition to the changing DOM composition in-stream, other watershed-scale factors likely contributed to the observed patterns, as these changes occurred over months rather than instantaneously after flow management stopped. Nevertheless, similar changes in MMHg have not been observed in a tributary to EFPC.

54 ENVIRONMENTAL SCIENCES↗

Exploring the Unknown

One of the most important developments of the twentieth century has been the movement of humanity into space with machines and people. The extension of human activity into outer space has been accompanied by a high degree of self-awareness of its historical significance. Because most of the activity in outer space was carried out under government sponsorship, it was accompanied by the documentary record required of public institutions, and there has been a spate of official and privately written histories of most major aspects of space achievement to date. When top leaders considered what course of action to pursue in space, their deliberations and decisions often were carefully put on the record. There is, accordingly, no lack of material for those who aspire to understand the origins and evolution of U.S. space policies and programs.This reality forms the rationale for this series. Precisely because there is so much historical material available on space matters, the National Aeronautics and Space Administration (NASA) decided in 1988 that it would be extremely useful to have easily available to scholars and the interested public a selective collection of many of the seminal documents related to the evolution of the U.S. civilian space program. While recognizing that much space activity has taken place under the sponsorship of the Department of Defense and other national security organizations, the U.S. private sector, and in other countries around the world, NASA felt that there would be lasting value in a collection of documentary material primarily focused on the evolution of the U.S. government s civilian space program, most of which has been carried out since 1958 under the Agency s auspices. As a result, the NASA History Office contracted with the Space Policy Institute of George Washington University's Elliott School of International Affairs to prepare such a collection. This is the sixth volume in the documentary history series; two additional ones containing documents and introductory essays related to human space flight, including microgravity research in Earth orbit, will follow. The documents collected during this research project were assembled from a diverse number of both public and private sources. A major repository of primary source materials relative to the history of the civil space program is the NASA Historical Reference Collection of the NASA History Office located at the Agency s Headquarters in Washington, DC.

Logsdon, John M.↗

Localized basis set for plutonium

The implementation of optimal strictly localized atomic orbitals basis for plutonium (Pu) using norm-conserving pseudopotential density-functional theory (DFT) is presented. The basis set was applied to the α, β, γ, δ, δ', and ε phases of Pu, δ-Pu surface, and δ-PuGa alloys. The computed properties of the Pu phases and δ-Pu surface were in good agreement with both available experimental data and prior DFT calculations based on plane-wave methodologies. Results for the δ-PuGa alloys were also in good agreement with experimental data. Finally, the reliability of the basis set was further demonstrated by using ab initio molecular dynamics to model the diffusion coefficient and activation barrier for atomic diffusion in a δ-PuGa alloy.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Postfire Biogeochemical Processes: Implications to Source Water Quality in Fire-Influenced Watersheds

Forested watersheds are instrumental in providing purified and reliable water to millions of people worldwide. The changing climate has increased the frequency and severity of global fire events. Forested watersheds and their ecosystem functions are greatly disrupted during fire activity. Postfire concerns in forested watersheds include unpredictable and potentially simultaneous alterations in source water quality and hydro-biogeochemical processes. Here, the degree of fire severity can complexly modify water quality through the production of fire-transformed constituents on the burned forest floor (i.e., nutrients, metal(loid)s, dissolved organic matter, and the formation of disinfection byproducts). Correspondingly, fire severity and postfire rainfall patterns can refine hydro-biogeochemical processes that influence the transport of the fire-transformed constituents (i.e., vegetation function, soil structure, hydrological pathways, and microbial communities). Postfire alterations to water quality and hydro-biogeochemical processes introduce further complexity with varying temporal influence, which ranges from months to decades. As postfire water quality and watershed response research progresses, it is essential to homogenize interdisciplinary expertise to bridge knowledge gaps between fields ranging from forest ecology, hydrology, microbiology, and geochemistry. A multidisciplinary approach in wildfire research will facilitate a comprehensive perception of the diverse water quality risks associated with fire activity and mitigate fire concerns on a global level.

Disinfection Byproducts↗

Applying Model Based Systems Engineering to NASA's Space Communications Networks

System engineering practices for complex systems and networks now require that requirement, architecture, and concept of operations product development teams, simultaneously harmonize their activities to provide timely, useful and cost-effective products. When dealing with complex systems of systems, traditional systems engineering methodology quickly falls short of achieving project objectives. This approach is encumbered by the use of a number of disparate hardware and software tools, spreadsheets and documents to grasp the concept of the network design and operation. In case of NASA's space communication networks, since the networks are geographically distributed, and so are its subject matter experts, the team is challenged to create a common language and tools to produce its products. Using Model Based Systems Engineering methods and tools allows for a unified representation of the system in a model that enables a highly related level of detail. To date, Program System Engineering (PSE) team has been able to model each network from their top-level operational activities and system functions down to the atomic level through relational modeling decomposition. These models allow for a better understanding of the relationships between NASA's stakeholders, internal organizations, and impacts to all related entities due to integration and sustainment of existing systems. Understanding the existing systems is essential to accurate and detailed study of integration options being considered. In this paper, we identify the challenges the PSE team faced in its quest to unify complex legacy space communications networks and their operational processes. We describe the initial approaches undertaken and the evolution toward model based system engineering applied to produce Space Communication and Navigation (SCaN) PSE products. We will demonstrate the practice of Model Based System Engineering applied to integrating space communication networks and the summary of its results and impact. We will highlight the insights gained by applying the Model Based System Engineering and provide recommendations for its applications and improvements.

Bhasin, Kul↗

Benchmarking boron carbide equation of state using computation and experiment

Boron carbide ( B 4 C ) is of both fundamental scientific and practical interest due to its structural complexity and how it changes upon compression, as well as its many industrial uses and potential for use in inertial confinement fusion (ICF) and high-energy density physics experiments. Here, we report the results of a comprehensive computational study of the equation of state (EOS) of B 4 C in the liquid, warm dense matter, and plasma phases. Our calculations are cross-validated by comparisons with Hugoniot measurements up to 61 megabar from planar shock experiments performed at the National Ignition Facility (NIF). Our computational methods include path integral Monte Carlo, activity expansion, as well as all-electron Green's function Korringa-Kohn-Rostoker and molecular dynamics that are both based on density functional theory. We calculate the pressure-internal energy EOS of B 4 C over a broad range of temperatures ( ~ 6 × 10 3 – 5 × 10 8 K) and densities (0.025–50 g / cm 3 ). We assess that the largest discrepancies between theoretical predictions are ≲ 5 % near the compression maximum at 1– 2 × 10 6 K. This is the warm-dense state in which the K shell significantly ionizes and has posed grand challenges to theory and experiment. By comparing with different EOS models, we find a Purgatorio model (LEOS 2122) that agrees with our calculations. The maximum discrepancies in pressure between our first-principles predictions and LEOS 2122 are ~ 18 % and occur at temperatures between 6 × 10 3 – 2 × 10 5 K, which we believe originate from differences in the ion thermal term and the cold curve that are modeled in LEOS 2122 in comparison with our first-principles calculations. To account for potential differences in the ion thermal term, we have developed three new equation-of-state models that are consistent with theoretical calculations and experiment. We apply these new models to 1D hydrodynamic simulations of a polar direct-drive NIF implosion, demonstrating that these new models are now available for future ICF design studies.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Joint neutrino oscillation analysis from the T2K and NOvA experiments

The landmark discovery that neutrinos have mass and can change type (or flavour) as they propagate—a process called neutrino oscillation—has opened up a rich array of theoretical and experimental questions being actively pursued today. Neutrino oscillation remains the most powerful experimental tool for addressing many of these questions, including whether neutrinos violate charge-parity (CP) symmetry, which has possible connections to the unexplained preponderance of matter over antimatter in the Universe. Oscillation measurements also probe the mass-squared differences between the different neutrino mass states (Δ$m^2$), whether there are two light states and a heavier one (normal ordering) or vice versa (inverted ordering), and the structure of neutrino mass and flavour mixing. Here we carry out the first joint analysis of datasets from NOvA and T2K, the two currently operating long-baseline neutrino oscillation experiments (hundreds of kilometres of neutrino travel distance), taking advantage of our complementary experimental designs and setting new constraints on several neutrino sector parameters. This analysis provides new precision on the $Δm_{32}^2$ mass difference, finding $-2.43_{−0.03}^{+0.04}$ x $10^{-13}$ $\textrm{eV}^2$ in the normal ordering and $-2.43^{+0.03}_{-0.04}$ x $10^{-13}$ $\textrm{eV}^2$ in the inverted ordering, as well as a 3σ interval on δ CP of [−1.38π, 0.30π] in the normal ordering and [−0.92π, −0.04π] in the inverted ordering. The data show no strong preference for either mass ordering, but notably, if inverted ordering were assumed true within the three-flavour mixing model, then our results would provide evidence of CP symmetry violation in the lepton sector.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Physical origins of the varying performance and unusual transport behaviors among thermoelectric A Mg 2 Sb 2 materials ( A = Ca, Sr, Sm, Yb, and Mg)

Contrary to the similar thermoelectric performance among both AZn 2 Sb 2 and AMg 2 Bi 2 compounds, their isostructural counterparts, AMg 2 Sb 2 , can exhibit thermoelectric figure of merit values that vary by orders of magnitude with different A elements. Here, we reveal physical origins accounting for the significantly differing performance among AMg 2 Sb 2 -based compounds (A = Ca, Sr, Sm, Yb, and Mg) through comprehensive analyses, where it is shown that the dispar- ities in performance at the macroscale essentially originate from the widely varying activation energies that equal amounts of dopant can induce. Meanwhile, a few unusual transport behaviors regarding electrical conductivity, carrier concentration, or lattice thermal con- ductivity among these compounds have been identified, and we also present their rationales in depth. Furthermore, this mechanism-focused study can not only promote further understanding of the complex transport behaviors in condensed matter but be instrumental in rationally tun- ing the physical properties of materials as well.

36 MATERIALS SCIENCE↗

Leaf functional traits highlight phenotypic variation of two tree species in the urban environment

Urbanization is transforming landscapes globally, altering environmental conditions that affect ecosystem functioning, particularly in urban areas where trees are crucial for regulating microclimates, improving air quality, and sustaining biodiversity. This study investigates the environmental differences and tree leaf structure and morphology in urban and suburban sites in the Chicago Metropolitan Region. The leaf functional traits of Norway Maple and Little − leaved Linden were studied in three locations in the summer of 2023: an urban park (University of Illinois Chicago, Chicago, IL), a suburban park (Morton Arboretum, Lisle, IL), and a suburban residential site (Lombard, IL). The urban site had higher daytime and nighttime air, and land surface temperatures compared to the suburban sites with significant fluctuations observed across the sites. Cumulative growing degree days, a measure of potential photosynthetically active days, were also higher in the urban park than in the suburban sites between March and August. Norway Maple trees growing in the urban site displayed higher specific leaf area (SLA) and lower leaf dry matter content (LDMC) than in the suburban sites, resulting in thinner leaves. Similarly, Little−leaved Linden trees in the suburban residential site displayed higher SLA and lower LDMC than those in the suburban park. The values of gas exchange traits − namely photosynthetic assimilation, transpiration rates, and stomatal conductance − of Norway Maple were higher at the urban site compared to suburban sites as temperatures increased during the summer. Norway Maple gas exchange values decreased as the growing season progressed, as expected by ontogeny. In contrast, Little−leaved Linden maintained similar leaf gas exchange values throughout the growing season. Both species in the urban site exhibited lower instantaneous water use efficiency and reduced LDMC, suggesting greater water loss in response to elevated temperatures compared to suburban park and residential sites. Comparisons with existing global trait databases emphasize the need for localized data to accurately capture site−specific responses. Although some traits aligned with database values, others deviated significantly, underscoring the importance of comprehensive, site−specific datasets for robust ecosystem modeling and management strategies.

Cho, Ahram↗

Radio emission from binary stars

Radio emission from binary star systems; characteristics of the binary systems inferred from the radio observations; and the reasons for the activity are reviewed. Binary stars with two main sequence stars, with one normal star and a white dwarf, and those containing a neutron star or a black hole are described. Energy may be directly available as matter falls into the potential well of a compact object. Electromagnetic induction effects may occur due to relative motions of magnetic fields and matter. By enforcing rapid rotation, binaries can induce strong dynamo action and hence generate free energy in the form of intense, complex, evolving magnetic fields. Whatever the source of energy, the observations at radio and X-ray wavelengths demonstrate that electrons are accelerated to high energies (mildly relativistic and, ultrarelativistic). Observed or inferred radio brightness temperatures range up to 10 to the 15th power K or more, implying coherent emission for sources brighter than 10 billion K.

Dulk, George A.↗

Infrared properties of nearby radio galaxies

The IRAS data for a sample of nearby radio galaxies (z less than 0.13) are analyzed. Comparison of the infrared, radio, and optical data suggests that most of the long-wavelength infrared emission comes from cool interstellar dust for almost all of the galaxies; these galaxies may contain large amounts (10 to the 8th - 10 to the 10th solar masses of interstelar matter. About 15 percent of the galaxies show evidence for a hotter thermal component emitting at the shorter IRAS wavelengths; this could be due to dust in the inner regions of the galaxy heated by the active galactic nucleus.

Knapp, G. R.↗

Exploring the High Energy Universe: GLAST Mission and Science

GLAST, the Gamma-Ray Large Area Space Telescope, is NASA's next-generation high-energy gamma-ray satellite scheduled for launch in Autumn 2007. GLAST will allow measurements of cosmic gamma-ray sources in the 10 MeV to 100 GeV energy band to be made with unprecedented sensitivity. Amongst its key scientific objectives are to understand particle acceleration in Active Galactic Nuclei, Pulsars and Supernovae Remnants, to provide high resolution measurements of unidentified gamma-ray sources, to study transient high energy emission from objects such as gamma-ray bursts, and to probe Dark Matter and the early Universe. Dr. McEnery will present an overview of the GLAST mission and its scientific goals.

McEnery, Julie↗

The Advanced Energetic Pair Telescope for Gamma-Ray Polarimetry

The Advanced Energetic Pair Telescope (AdEPT), a future NASA/GSFC MIDEX mission, is being developed to perform high-sensitivity medium-energy (5-200 MeV) astronomy and revolutionary gamma-ray polarization measurements. The enabling technology for AdEPT is the Three- Dimensional Track Imager (3-DTI), a large volume gaseous time projection chamber with 2- dimentional micro-well detector (MWD) readout. The low density and high spatial resolution of the 3-DTI allows AdEPT to achieve high angular resolution (~0.5 at 67.5 MeV) and, for the first time, exceptional gamma-ray polarization sensitivity. These capabilities enable a wide range of scientific discovery potential for AdEPT. The key science goals of the AdEPT mission include: 1) Explore fundamental processes of particle acceleration in active astrophysical objects, 2) Reveal the magnetic field configuration of the most energetic accelerators in the Universe, 3) Explore the origins and acceleration of cosmic rays and the Galactic MeV diffuse emission, 4) Search for dark matter in the Galactic center, and 5) Test relativity with polarization measurements. We report on the latest developments of the MWDs for the 3-DTI.

Hunter, Stanley D.↗

A Performance Analysis on Soil Dielectric Models Over Organic Soils in Alaska for Passive Microwave Remote Sensing of Soil Moisture

Passive microwave remote sensing of soil moisture (SM) requires a physically based dielectric model that quantitatively converts the volumetric SM into the soil bulk dielectric constant. Mironov 2009 is the dielectric model used in the operational SM retrieval algorithms of the NASA Soil Moisture Active Passive (SMAP) and the ESA Soil Moisture and Ocean Salinity (SMOS) missions. However, Mironov 2009 suffers a challenge in deriving SM over organic soils, as it does not account for the impact of soil organic matter (SOM) on the soil bulk dielectric constant. To this end, we presented a comparative performance analysis of nine advanced soil dielectric models over organic soil in Alaska, four of which incorporate SOM. In the framework of the SMAP single-channel algorithm at vertical polarization (SCA-V), SM retrievals from different dielectric models were derived using an iterative optimization scheme. The skills of the different dielectric models over organic soils were reflected by the performance of their respective SM retrievals, which was measured by four conventional statistical metrics, calculated by comparing satellite-based SM time series with in-situ benchmarks. Overall, SM retrievals of organic-soil-based dielectric models tended to overestimate, while those from mineral-soil-based models displayed dry biases. All the models showed comparable values of unbiased root-mean-square error (ubRMSE) and Pearson Correlation (R), but Mironov 2019 exhibited a slight but consistent edge over the others. An integrated consideration of the model inputs, the physical basis, and the validated accuracy indicated that the separate use of Mironov 2009 and Mironov 2019 in the SMAP SCA-V for mineral soils (SOM < 15%) and organic soils (SOM ≥ 15%) would be the preferred option.

Soil Moisture↗

SPRUCE Warming Promotes the Use of Organic Matter as an Electron Acceptor in a Peatland: Supporting Data

These data are provided in support of the publication: Warming Promotes the Use of Organic Matter as an Electron Acceptor in a Peatland (Rush et al., 2021). Rush et al. (2021) reported on the effect of temperature on microbial organic matter reduction at the SPRUCE study site and S1 bog. Specifically, electron shuttling capacity (ESC), CH4 production, CO2 production, and acetate concentration were measured to explore both direct and indirect (through changes in soil quality and water-table level) effects of warming on microbial activity. Samples were collected in the summer of 2016 and 2017 depending on the experiment. This dataset contains five files in comma separated (*.csv) format. The SPRUCE Experiment Site is located in a Picea mariana [black spruce] Sphagnum spp. bog forest in northern Minnesota, 40 km north of Grand Rapids, in the USDA Forest Service Marcell Experimental Forest (MEF). This ecosystem, which is located at the southern margin of the boreal forest, is considered especially vulnerable to climate change and anticipated to be near its tipping point.

54 ENVIRONMENTAL SCIENCES↗

A novel active veto prototype detector with an inner target for improved rare event searches

Here, we report the fabrication and performance of an annular, cryogenic, phonon-mediated veto detector that can host an inner target detector, allowing substantial reduction in radiogenic backgrounds for rare event search experiments. A germanium veto detector of mass ~500g with an outer diameter of 76 mm and an inner diameter of 28 mm was produced inside of which was mounted a 25 mm diameter germanium inner target detector of mass ~10g. The detector was designed using inputs from a GEANT4 based simulation, where it was modeled to be sandwiched between two germanium detectors. The simulation showed that the background rates (dominated by gamma interactions) could be reduced by >90%, and that such an arrangement is sufficient for aggressive background reduction needed for neutrino and dark matter search experiments. Operating at mK temperatures at the experimental site, the veto detector prototype achieved a baseline resolution of 1.24±0.02 keV while hosting a functional inner target detector. The baseline resolution of the inner target detector was 147±2 eV. The experimental results of an identical detector arrangement are in excellent agreement with the simulation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

How emissions uncertainty influences the distribution and radiative impacts of smoke from fires in North America

Fires and the aerosols that they emit impact air quality, health, and climate, but the abundance and properties of carbonaceous aerosol (both black carbon and organic carbon) from biomass burning (BB) remain uncertain and poorly constrained. We aim to explore the uncertainties associated with fire emissions and their air quality and radiative impacts from underlying dry matter consumed and emissions factors. To investigate this, we compare model simulations from a global chemical transport model, GEOS-Chem, driven by a variety of fire emission inventories with surface and airborne observations of black carbon (BC) and organic aerosol (OA) concentrations and satellite-derived aerosol optical depth (AOD). We focus on two fire-detection-based and/or burned-area-based (FD-BA) inventories using burned area and active fire counts, respectively, i.e., the Global Fire Emissions Database version 4 (GFED4s) with small fires and the Fire INventory from NCAR version 1.5 (FINN1.5), and two fire radiative power (FRP)-based approaches, i.e., the Quick Fire Emission Dataset version 2.4 (QFED2.4) and the Global Fire Assimilation System version 1.2 (GFAS1.2). We show that, across the inventories, emissions of BB aerosol (BBA) differ by a factor of 4 to 7 over North America and that dry matter differences, not emissions factors, drive this spread. We find that simulations driven by QFED2.4 generally overestimate BC and, to a lesser extent, OA concentrations observations from two fire-influenced aircraft campaigns in North America (ARCTAS and DC3) and from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network, while simulations driven by FINN1.5 substantially underestimate concentrations. The GFED4s and GFAS1.2-driven simulations provide the best agreement with OA and BC mass concentrations at the surface (IMPROVE), BC observed aloft (DC3 and ARCTAS), and AOD observed by MODIS over North America. We also show that a sensitivity simulation including an enhanced source of secondary organic aerosol (SOA) from fires, based on the NOAA Fire Lab 2016 experiments, produces substantial additional OA; however, the spread in the primary emissions estimates implies that this magnitude of SOA can be neither confirmed nor ruled out when comparing the simulations against the observations explored here. Given the substantial uncertainty in fire emissions, as represented by these four emission inventories, we find a sizeable range in 2012 annual BBA PM2.5 population-weighted exposure over Canada and the contiguous US (0.5 to 1.6 µg/cu. m). We also show that the range in the estimated global direct radiative effect of carbonaceous aerosol from fires (−0.11 to −0.048 W/sq. m) is large and comparable to the direct radiative forcing of OA (−0.09 W/sq. m) estimated in the Fifth Assessment Report (AR5) of the Intergovernmental Panel on Climate Change (IPCC). Our analysis suggests that fire emissions uncertainty challenges our ability to accurately characterize the impact of smoke on air quality and climate.

North America↗

Marching Microbes

Under an SBIR contract with Marshall Space Flight Center, Micro-Bac International developed a new system for the treatment of wastewater based on the metabolic activity of photorphic bacteria. These microorganisms are now being sold as a liquid product called Mega-Bac TF. It is currently used for septic systems and wastewater ponds, lakes and lagoons to degrade fat, oil, fecal matter and other biologically derived wastes. Potential applications include homes, agriculture, food processors and chemical manufacturing.

Source record↗