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At least 757 records · Page 42

Variability in observed stable water isotopes in snowpack across a mountainous watershed in Colorado

In this study, isotopic information from 81 snowpits was collected over a 5-year period in a large, Colorado watershed. Data spans gradients in elevation, aspect, vegetation, and seasonal climate. They are combined with overlapping campaigns for water isotopes in precipitation and snowmelt, and a land-surface model for detailed estimates of snowfall and climate at sample locations. Snowfall isotopic inputs, describe the majority of δ18O snowpack variability. Aspect is a secondary control, with slightly more enriched conditions on east and north facing slopes. This is attributed to preservation of seasonally enriched snowfall and vapour loss in the early winter. Sublimation, expressed by decreases in snowpack d-excess in comparison to snowfall contributions, increases at low elevation and when seasonal temperature and solar radiation are high. At peak snow accumulation, post-depositional fractionation appears to occur in the top 25 ± 14% of the snowpack due to melt-freeze redistribution of lighter isotopes deeper into the snowpack and vapour loss to the atmosphere during intermittent periods of low relative humidity and high windspeed. Relative depth of fractionation increases when winter daytime temperatures are high and winter precipitation is low. Once isothermal, snowpack isotopic homogenization and enrichment was observed with initial snowmelt isotopically depleted in comparison to snowpack and enriching over time. The rate of δ18O increase (d-excess decrease) in snowmelt was 0.02‰ per day per 100-m elevation loss. Isotopic data suggests elevation dictates snowpack and snowmelt evolution by controlling early snow persistence (or absence), isotopic lapse rates in precipitation and the ratio of energy to snow availability. Hydrologic tracer studies using stable water isotopes in basins of large topographic relief will require adjustment for these elevational controls to properly constrain stream water sourcing from snowmelt.

54 ENVIRONMENTAL SCIENCES↗

Data-driven analysis of relight variability of jet fuels induced by turbulence

For safety purposes, reliable reignition of aircraft engines in the event of flame blow-out is a critical requirement. Typically, an external ignition source in the form of a spark is used to achieve a stable flame in the combustor. However, such forced turbulent ignition may not always successfully relight the combustor, mainly because the state of the combustor cannot be precisely determined. Uncertainty in the turbulent flow inside the combustor, inflow conditions, and spark discharge characteristics can lead to variability in sparking outcomes even for nominally identical operating conditions. Prior studies have shown that of all the uncertain parameters, turbulence is often dominant and can drastically alter ignition behavior. For instance, even when different fuels have similar ignition delay times, their ignition behavior in practical systems can be completely different. In practical operating conditions, it is challenging to understand why ignition fails and how much variation in outcomes can be expected. The focus of this work is to understand relight variability induced by turbulence for two different aircraft fuels, namely Jet-A and a variant named C1. A detailed, previously developed simulation approach is used to generate a large number of successful and failed ignition events. Using this data, the cause of misfire is evaluated based on a discriminant analysis that delineates the difference between turbulent initial conditions that lead to ignition or failure. From the discriminant analysis, a compressed sensing algorithm is then applied to help pinpoint the locations of relevant turbulent features. Findings from the discriminant analysis are confirmed with the time history of near kernel properties. Next, a clustering strategy is used to identify ignition and misfire modes. With this approach, it was determined that the cause of ignition failure is different for the two fuels. While it was found that Jet-A is influenced by fuel entrainment, C1 was found to be more sensitive to small scale turbulence features. Finally, a larger variability is found in the ignition modes of C1, which can be subject to extreme events induced by kernel breakdown.

42 ENGINEERING↗

A Probabilistic Model for Global EMIC Wave Activity Using Van Allen Probes Observations

Electromagnetic ion cyclotron (EMIC) waves play a key role in radiation belt dynamics through resonant interactions. However, their low occurrence probability, high variability, and spatial intermittency pose challenges for accurate modeling. In this study, we present a machine learning (ML)-based global EMIC wave model built on the entire data set from the Van Allen Probes mission. To capture the distinct statistical characteristics of wave occurrence and amplitude, the model is separated into two modules: an occurrence model trained using ML techniques, and a wave amplitude model sampled from observed probability distributions. The input parameters are limited to real-time or predictable variables to ensure practical applicability. Our model shows strong performance across the entire test set and demonstrates improved predictive capability over a baseline random occurrence model, particularly during quiet geomagnetic conditions. Evaluation during both quiet and active periods confirms the model's ability to represent the clustered and intermittent nature of EMIC wave activity. Furthermore, the model provides global estimates of wave power, enabling integration with radiation belt electron data and showing signatures consistent with wave-induced scattering. We found a good correlation between the global wave activity from the model and relativistic electron observation by Van Allen Probes, regardless of the availability of in situ wave observations. The modular structure of the model also allows for straightforward expansion for additional wave properties, such as wave frequency, which can be modeled independently. This flexible, event-sensitive approach offers a promising framework for data-driven radiation belt simulations and space weather applications.

79 ASTRONOMY AND ASTROPHYSICS↗

Rapid assessment of the creep rupture life of metals: A model enabling experimental design

Prediction of the creep rupture life of engineering metals is critical for qualification and design of new materials. The use of long-term creep tests and the need to quantify the performance variability in a priori similar systems hinder the rapid creep assessment of a given material. Therefore, it is essential to develop methods that can extrapolate the long-term performance of alloys and the associated variability from short-term experiments. To this end, this study introduces a new model which enables the estimation of the rupture life of a material for a given stress and temperature. This model relies on two components. First, a new relation for the minimum creep rate (MCR) of materials is introduced. It includes a stress dependent stress exponent allowing the model to capture the variation of MCR across a wide range of temperatures and stresses. Second, employing the Monkman-Grant (MG) law, we establish a relation between stress, temperature and creep rupture life. Together, these two elements yield a new closed-form mathematical expression for the Larson Miller parameter as a function of stress and temperature. This expression captures the creep rupture time for many metals (Gr91, Copper, Gr122 and 347H) and compares favorably with alternate empirical approaches. The model is then used to assess the minimum duration of creep rates necessary to qualify the material up to 100000h. Furthermore, it is found that depending on the material system, creep tests as few as five limited to 5000 h for steels (Gr91, Gr122, 347H) and 100 h for copper are sufficient to model creep lifetimes. Finally, using a Bayesian inference-based approach to calibrate the model, we demonstrate that variability in rupture life can be captured via the quantification of the uncertainty in the model parameters and extrapolated from a limited number of short to moderately short creep tests; thereby paving the way for accelerated creep testing.

36 MATERIALS SCIENCE↗

Biomass Burning Emissions of Black Carbon over the Maritime Continent and ENSO Variability

Fire emissions from the Maritime Continent (MC) over the western tropical Pacific are strongly influenced by El Niño–Southern Oscillation (ENSO), posing various climate effects to the Earth system. Here, in this study, we show that the historical biomass burning emissions of black carbon (BC bb ) aerosol in the dry season from the MC are strengthened in El Niño years due to the dry conditions. The eastern Pacific type of El Niño exerts a stronger modulation in BC bb emissions over the MC region than the central Pacific type of El Niño. Based on simulations using the fully coupled Community Earth System Model (CESM), the impacts of increased BC bb emissions on ENSO variability and frequency are also investigated in this study. With BC bb emissions from the MC scaled up by a factor of 10, which enables the identification of climate response from the internal variability, the increased BC bb heats the local atmosphere and changes land–sea thermal contrast, which suppresses the westward transport of the eastern Pacific surface water. It leads to an increase in sea surface temperature in the eastern tropical Pacific, which further enhances ENSO variability and increases the frequency of extreme El Niño and La Niña events. This study highlights the potential role of BC bb emissions on extreme ENSO frequency, and this role may be increasingly important in the warming future with higher wildfire risks.

54 ENVIRONMENTAL SCIENCES↗

High-pressure neutron powder diffraction study of an arsenolite deuterium inclusion compound: structure and formation kinetics

High-pressure variable-temperature neutron powder diffraction was employed to investigate the synthesis and structural properties of arsenolite (As 4 O 6 ), a cubic arsenic( III ) oxide polymorph, and its inclusion compound with deuterium. The compound forms with the stoichiometry As 4 O 6 ·2D 2 , consistent with earlier findings. At 295 K and 1.96(2) GPa, D 2 molecules occupy the 16c site (0, 0, 0) and are aligned along the <111> direction. The diffraction data suggest that the D 2 molecules at this site become rotationally disordered upon decompression to 0.78(2) GPa at 120 K, while no occupancy is observed at the 8a position (⅛, ⅛, ⅛) under any of the studied conditions. The kinetic data of the high-pressure inclusion compound synthesis at 1.56(2) and 1.96(2) GPa were analyzed using the Avrami model. The Avrami exponent, 0.135(16), remains invariant with pressure, demonstrating that the reaction topochemistry is unaffected by compression. Similarly, the reaction rates, 0.29(3) and 0.23(3) min −0.135 at 1.56(2) and 1.96(2) GPa, respectively, exhibit negligible pressure dependence and suggest a surprisingly low activation volume of 1.6 cm 3 mol −1 for the reaction. These results provide detailed insight into the structural dynamics and kinetics of deuterium inclusion in arsenolite under high pressure.

Guńka, Piotr A. [Warsaw University of Technology (↗

Mechanical detwinning device for anisotropic resistivity measurements in samples requiring dismounting for particle irradiation

Uniaxial stress is used to detwin samples of orthorhombic iron based superconductors to study their intrinsic electronic anisotropy. Here we describe the development of a new detwinning setup enabling variable-load stress-detwinning with easy sample mounting/dismounting without the need to re-solder the contacts. It enables the systematic study of the anisotropy evolution as a function of an external parameter when the sample is modified between the measurements. In our case, the external parameter is the dose of 2.5 MeV electron irradiation at low temperature. We illustrate the approach by studying resistivity anisotropy in single crystals of Ba 1-x K x Fe 2 As 2 at x =0.25 where the much discussed unusual re-entrance of tetragonal C 4 phase, C 4 → C 2 → C 4 , is observed on cooling. With the described technique we found a significant anisotropy increase in C 2 phase after electron irradiation with dose of 2.35 C/cm 2 .

47 OTHER INSTRUMENTATION↗

A seamless approach for evaluating climate models across spatial scales

In regions of the world where topography varies significantly with distance, most global climate models (GCMs) have spatial resolutions that are too coarse to accurately simulate key meteorological variables that are influenced by topography, such as clouds, precipitation, and surface temperatures. One approach to tackle this challenge is to run climate models of sufficiently high resolution in those topographically complex regions such as the North American Regionally Refined Model (NARRM) subset of the Department of Energy’s (DOE) Energy Exascale Earth System Model version 2 (E3SM v2). Although high-resolution simulations are expected to provide unprecedented details of atmospheric processes, running models at such high resolutions remains computationally expensive compared to lower-resolution models such as the E3SM Low Resolution (LR). Moreover, because regionally refined and high-resolution GCMs are relatively new, there are a limited number of observational datasets and frameworks available for evaluating climate models with regionally varying spatial resolutions. As such, we developed a new framework to quantify the added value of high spatial resolution in simulating precipitation over the contiguous United States (CONUS). To determine its viability, we applied the framework to two model simulations and an observational dataset. We first remapped all the data into Hierarchical Equal-Area Iso-Latitude Pixelization (HEALPix) pixels. HEALPix offers several mathematical properties that enable seamless evaluation of climate models across different spatial resolutions including its equal-area and partitioning properties. The remapped HEALPix-based data are used to show how the spatial variability of both observed and simulated precipitation changes with resolution increases. This study provides valuable insights into the requirements for achieving accurate simulations of precipitation patterns over the CONUS. It highlights the importance of allocating sufficient computational resources to run climate models at higher temporal and spatial resolutions to capture spatial patterns effectively. Furthermore, the study demonstrates the effectiveness of the HEALPix framework in evaluating precipitation simulations across different spatial resolutions. This framework offers a viable approach for comparing observed and simulated data when dealing with datasets of varying spatial resolutions. By employing this framework, researchers can extend its usage to other climate variables, datasets, and disciplines that require comparing datasets with different spatial resolutions.

54 ENVIRONMENTAL SCIENCES↗

The role of oak species in long-term soil P loss in a humid river bottomland

There is a gap in our understanding of if and how bottomland forest type will affect long-term nutrient cycling and loss. This study aims to determine how different forests affect soil hydrologic variability and whole-soil P loss in a humid-subtropical setting. Here, we used replicate-sampling and measured soil physical, chemical, and mineralogical properties at 12 sites in two forest ecosystems, post oak (Quercus stellata) and cherry bark oak (Quercus pagoda) in Clarks River National Wildlife Refuge in Western Kentucky. We hypothesize that wetting–drying events in redox soils of forested bottomlands can cause positive feedback in whole-soil P loss. Trees with greater P demand (e.g., post oak) take up more water creating more frequent and pronounced episodes in swelling and shrinking of expandable clays. Repeated swelling and shrinking of clays occlude the surface of Fe-Mn oxides from further adsorption of P in acidic soil. This can lead to greater loss or plant uptake of available P. Our results show (i) a significant difference in mean whole-soil P loss between the oak species with more loss in soils underlying the post oak forest, and (ii) a difference in the total P found in the sap- and heartwood of the two oak species. Soil analysis reveals that the clay mineralogy of the post and cherry bark oak sites are similar, and thus, may only play a minor role in governing the whole-soil P loss difference. However, the leaf data analysis suggests that the post oak site could be P and nitrogen-limited, while the cherry bark is only nitrogen limited. Our study shows that differences in the oak forest ecosystem may affect the long-term balance in water and nutrient uptake and may alter the redistribution of nutrients in the canopy and the underlying soils.

58 GEOSCIENCES↗

Event Horizon Telescope imaging of the archetypal blazar 3C 279 at an extreme 20 microarcsecond resolution

3C 279 is an archetypal blazar with a prominent radio jet that show broadband flux density variability across the entire electromagnetic spectrum. We use an ultra-high angular resolution technique – global Very Long Baseline Interferometry (VLBI) at 1.3 mm (230 GHz) – to resolve the innermost jet of 3C 279 in order to study its fine-scale morphology close to the jet base where highly variable γ-ray emission is thought to originate, according to various models. The source was observed during four days in April 2017 with the Event Horizon Telescope at 230 GHz, including the phased Atacama Large Millimeter/submillimeter Array (ALMA), at an angular resolution of ∼20 μas (at a redshift of z = 0.536 this corresponds to ∼0.13 pc ∼ 1700 Schwarzschild radii with a black hole mass MBH = 8 × 108 M⊙). Imaging and model-fitting techniques were applied to the data to parameterize the fine-scale source structure and its variation. We find a multicomponent inner jet morphology with the northernmost component elongated perpendicular to the direction of the jet, as imaged at longer wavelengths. The elongated nuclear structure is consistent on all four observing days and across different imaging methods and model-fitting techniques, and therefore appears robust. Owing to its compactness and brightness, we associate the northern nuclear structure as the VLBI “core”. This morphology can be interpreted as either a broad resolved jet base or a spatially bent jet. We also find significant day-to-day variations in the closure phases, which appear most pronounced on the triangles with the longest baselines. Our analysis shows that this variation is related to a systematic change of the source structure. Two inner jet components move non-radially at apparent speeds of ∼15 c and ∼20 c (∼1.3 and ∼1.7 μas day−1, respectively), which more strongly supports the scenario of traveling shocks or instabilities in a bent, possibly rotating jet. The observed apparent speeds are also coincident with the 3C 279 large-scale jet kinematics observed at longer (cm) wavelengths, suggesting no significant jet acceleration between the 1.3 mm core and the outer jet. The intrinsic brightness temperature of the jet components are ≲1010 K, a magnitude or more lower than typical values seen at ≥7 mm wavelengths. The low brightness temperature and morphological complexity suggest that the core region of 3C 279 becomes optically thin at short (mm) wavelengths.Key words: galaxies: active / galaxies: jets / galaxies: individual: 3C 279 / techniques: interferometric⋆ The data are only available at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/cat/J/A+A/640/A69 and at https://eventhorizontelescope.org/for-astronomers/data⋆⋆ Deceased.

79 ASTRONOMY AND ASTROPHYSICS↗

Numerical Modeling and Optimization of the iProTech Pitching Inertial Pump (PIP) Wave Energy Converter (WEC) (Cooperative Research and Development Final Report, CRADA Number: CRD-22-22968)

This work generated a first-of-its-kind automated workflow to couple time-domain simulations of wave energy converters written in one software language with a set of design generation and evaluation scripts written in another software language. This automated workflow used an existing optimization package to analyze the sensitivity of different design parameters on the power output of a specific WEC, iProTech’s Pitching Inertial Pump (PIP). Geometric, inertial, and power take-off variables were all varied and optimized to find values that produced the highest amount of power generated over varying wave conditions. The findings on these parameter sensitivity studies are used to inform future design iterations of the PIP WEC. Including more design variables in the optimizations will only increase computational run time and further software development is needed to analyze a larger optimization.

16 TIDAL AND WAVE POWER↗

Tencoder: tensor-product encoder-decoder architecture for predicting solutions of PDEs with variable boundary data

It is widely hoped that artificial intelligence will boost data-driven surrogate models in science and engineering. However, fundamental spatial aspects of AI surrogate models remain under-studied. We investigate the ability of neural-network surrogate models to predict solutions to PDEs under variable boundary values. We do not wish to retrain the model when the boundary values change but to make them inputs to the model and infer the solution of the PDE under those boundary conditions. Such a capability is essential to making AI-based surrogate models practically useful. While simple feedforward networks are used for one-dimensional (1D) Poisson equation, an encoder-decoder architecture with a tensor-product layer is developed for the two-dimensional Poisson equation posed on a rectangular domain. We show that it is indeed possible to infer solutions to PDEs from variable boundary data using neural networks in this relatively simple setting, and point to future directions.

Kashi, Aditya↗

Optimization of Triply Periodic Minimal Surface Heat Exchanger to Achieve Compactness, High Efficiency, and Low-Pressure Drop

With advancements in additive manufacturing (AM) techniques, high-quality triply periodic minimal surface (TPMS) structures can now be produced. TPMS walled heat exchangers (HX) hold significant potential for industrial applications and are receiving increasing attention. This paper explores the impact of various TPMS design variables on flow and thermal performance to optimize TPMS heat exchangers for compactness, high efficiency, and low pressure drop. The design variables examined include the type of TPMS lattice, unit cell size, wall thickness, aspect ratio, TPMS orientation, and equivalent thickness. The study reveals that the flow and heat transfer performance of TPMS structures are significantly affected by these design variables. For the Gyroid, Diamond, and SplitP lattices, performance is nearly identical when the surface-to-volume ratio is kept constant. The average velocity of the fluid in the TPMS HX should be 0.3 m/s. The corresponding Re is between 300~800. Thin wall thickness, small equivalent thickness, and flat lattice configurations can significantly reduce pressure drop while maintaining the overall heat transfer coefficient. Additionally, the angle between the flow direction and TPMS orientation can increase pressure drop. Three aluminum heat exchangers were successfully printed using an AM machine, and testing results are comparable with theoretical prediction.

42 ENGINEERING↗

Mechanistic Studies of an Iron-Catalyzed Intermolecular C–H Amination Reaction under Catalytic Conditions and Having a Large KIE

The conversion of C–H bonds into amines by nitrene insertion is an attractive transformation since it is both atom- and step-economical, and provides a direct route to functionalizing hydrocarbons. Using an iron catalyst [{( tBu pyrr) 2 pyr}Fe(OEt 2 )] (1-OEt 2 ) (( tBu pyrr) 2 pyr 2– = 3,5- t Bu 2 -bis(pyrrolyl)pyridine), we recently demonstrated the catalytic conversion of weak C–H bonds into secondary amines using aryl azides as the nitrene source [Zars, E.; Angew. Chem., Int. Ed. 2023, 62, e202311749]. Here, we describe detailed mechanistic studies of this intermolecular C–H amination reaction under catalytic conditions. We find by Variable Time Normalization Analysis (VTNA) that the conversion of xanthene (2-H 2 ) and 2,4,6-trimethyl-phenyl azide ( Me 3) catalyzed by 1-OEt 2 is an overall 3/2 order process, being 1 st order in 2-H 2 and half order in Me 3. A kinetic isotope effect study (KIE) using 2-d 2 results in a significant decrease in the rate (KIE = 61(15)), which clearly implicates the C–H insertion step as rate-determining. Furthermore, treatment of 1-OEt 2 with one equivalent of N 3 -2,6- i Pr 2 –C 6 H 3 yields the mixed-valence C–N coupled product [( tBu pyrr) 2 pyrFe-N═C(2,6 i Pr 2 –Ph)═N-(2,6 i Pr 2 –Ph))Fe tBu pyrrpyr(2-H-pyrr)] (5 iPr ). Quantum chemical calculations confirm the electronic structure of the mixed-valence dimer in 5 iPr and rationalize the Hammett correlation by a delicate balance in the dinuclearization of the catalytically active monomers. Calculations further indicate significant tunneling for the pivotal H atom abstraction by the iron-imidyl complex. Combining all these results allows us to propose a mechanism consisting of imido formation in equilibrium with a radical-coupled diiron system, followed by stepwise C–H insertion via a linear H atom abstraction transition state and subsequent radical rebound.

azides↗

Evaluation of Global Fire Simulations in CMIP6 Earth System Models

Fire is the primary form of terrestrial ecosystem disturbance on a global scale and an important Earth system process. Most Earth system models (ESMs) have incorporated fire modeling, with 19 of them submitting model outputs of fire-related variables to the Coupled Model Intercomparison Project Phase 6 (CMIP6). This study provides the first comprehensive evaluation of CMIP6 historical fire simulations by comparing them with multiple satellite-based products and charcoal-based historical reconstructions. Our results show that most CMIP6 models simulate the present-day global burned area and fire carbon emissions within the range of satellite-based products. They also capture the major features of observed spatial patterns and seasonal cycles, the relationship of fires with precipitation and population density, and the influence of the El Niño–Southern Oscillation (ENSO) on the interannual variability of tropical fires. Regional fire carbon emissions simulated by the CMIP6 models from 1850 to 2010 generally align with the charcoal-based reconstructions, although there are regional mismatches, such as in southern South America and eastern temperate North America prior to the 1910s and in temperate North America, eastern boreal North America, Europe, and boreal Asia since the 1980s. The CMIP6 simulations have addressed three critical issues identified in CMIP5: (1) the simulated global burned area being less than half of that of the observations, (2) the failure to reproduce the high burned area fraction observed in Africa, and (3) the weak fire seasonal variability. Furthermore, the CMIP6 models exhibit improved accuracy in capturing the observed relationship between fires and both climatic and socioeconomic drivers and better align with the historical long-term trends indicated by charcoal-based reconstructions in most regions worldwide. However, the CMIP6 models still fail to reproduce the decline in global burned area and fire carbon emissions observed over the past 2 decades, mainly attributed to an underestimation of anthropogenic fire suppression, and the spring peak in fires in the Northern Hemisphere midlatitudes, mainly due to an underestimation of crop fires. In addition, the model underestimates the fire sensitivity to wet–dry conditions, indicating the need to improve fuel wet-ness estimation. Based on these findings, we present specific guidance for fire scheme development and suggest a postprocessing methodology for using CMIP6 multi-model outputs to generate reliable fire projection products.

Wildfire, Earth system models↗

Rapid changes in coastal ocean microbiomes uncoupled with shifts in environmental variables

Disturbances, here defined as events that directly alter microbial community composition, are commonly studied in host–associated and engineered systems. Notably, in spite of global change both altering environmental averages and increasing extreme events, there has been relatively little research into the causes, persistence and population–level impacts of disturbance in the dynamic coastal ocean. Here, we utilize 3 years of observations from a coastal time series to identify disturbances based on the largest week–over–week changes in the microbiome (i.e. identifying disturbance as events that alter the community composition). In general, these microbiome disturbances were not clearly linked to specific environmental factors and responsive taxa largely differed, aside from SAR11, which generally declined. However, several disturbance metagenomes identified increased phage–associated genes, suggesting that unexplained community shifts might be caused by increased mortality. Furthermore, a category 1 hurricane, the only event that would likely be classified a priori as an environmental disturbance, was not an outlier in microbiome composition, but did enhance a bloom in seasonally abundant phytoplankton. Thus, as extreme environmental changes intensify, assumptions of what constitutes a disturbance should be re–examined in the context of ecological history and microbiome responses.

59 BASIC BIOLOGICAL SCIENCES↗

Development of A High-Resolution Dataset for Solar Resource Adequacy Studies

High-resolution, long-term solar dataset is essential for characterizing the variability of solar energy resources and for informing strategies that ensure grid reliability and resilience in grid systems with high levels of solar energy integration. We present the development of a new 4-km, hourly Earth system dataset for the contiguous United States (CONUS), using a statistical downscaling approach that integrates the National Solar Radiation Database (NSRDB) with regional Earth system model projections. The new high-resolution Earth system dataset includes key variables - GHI, DNI, DHI, surface air temperature, and wind speed - under two future scenarios. Preliminary results show a reasonable agreement with NSRDB observations, with nBias less than 1% for GHI across CONUS. The dataset is expected to support in-depth analyses of extreme weather impacts and provide input to resource adequacy for future energy systems with diverse generation sources.

14 SOLAR ENERGY↗

Persistent ocean anomalies as a response to Northern Hemisphere heating induced by biomass burning variability

Biomass burning aerosol (BBA) emissions in the Coupled Model Intercomparison Project Phase 6 (CMIP6) historical forcing fields have enhanced temporal variability during the years 1997–2014 compared to earlier periods. Recent studies document that the corresponding inhomogeneous shortwave forcing over this period can cause changes in clouds, permafrost, and soil moisture, which contribute to a net terrestrial Northern Hemisphere warming relative to earlier periods. Here, we investigate the ocean response to the hemispherically asymmetric warming, using a 100-member ensemble of the Community Earth System Model version 2 Large Ensemble forced by two different BBA emissions (CMIP6 default and temporally smoothed over 1990–2020). Differences between the two subensemble means show that ocean temperature anomalies occur during periods of high BBA variability and subsequently persist over multiple decades. In the North Atlantic, surface warming is efficiently compensated for by decreased northward oceanic heat transport due to a slowdown of the Atlantic Meridional Overturning Circulation. In the North Pacific, surface warming is compensated for by an anomalous cross-equatorial cell (CEC) that reduces northward oceanic heat transport. The heat that converges in the South Pacific through the anomalous CEC is shunted into the subsurface and contributes to formation of long-lasting ocean temperature anomalies. The anomalous CEC is maintained through latitude-dependent contributions from narrow western boundary currents and basin-wide near-surface Ekman transport. Furthermore, these results indicate that interannual variability in forcing fields may significantly change the background climate state over long timescales, presenting a potential uncertainty in CMIP6-class climate projections forced without interannual variability.

54 ENVIRONMENTAL SCIENCES↗