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At least 757 records · Page 42

The reaction of a titanium alloy with hydrogen gas at low temperatures.

An investigation of the effect of temperature on the surface hydriding reaction of Ti-5Al-2.5Sn alloy exposed to hydrogen at 250 psig was made. The temperature range studied extended from 160 to -160 F. Reaction conditions were controlled so as to expose a vacuum-cleaned, oxide-free alloy surface to an ultra-pure hydrogen atmosphere. Reaction times up to 1458 hr were studied. The hydriding reaction was extremely sensitive to experimental variables and the reproducibility of reaction behavior was poor. However, it was demonstrated that the reaction proceeded quite rapidly at 160 F; as much as 1 mil surface hydriding was observed after exposure for 162 hr. The amount of hydriding was observed to decrease with decreasing temperature at 75, 36, and -76 F. No surface hydriding was detected either by vacuum fusion analysis or by metallographic examination after exposure for 1458 hr at -110 or -160 F.

Williams, D. N.↗

Titanium spallation cross sections between 30 and 584 MeV and Ar-39 activities on the moon

The production cross sections of Ar39 for Ti spallation at 45-, 319-, 433-, and 584-MeV proton energies were measured to be 0.37 + or - 0.09, 12.4 + or - 3.7, 9.1 + or - 2.7, and 17.8 + or - 6.2 mb, respectively. Normalized Ar39 production rates and activities are also derived for protons above 40 MeV and for three differential proton spectra of the type approximately E(- alpha). It is concluded that, even for samples of high-Ti content, Ti spallation by solar protons below 200-MeV energy does not contribute significantly to their Ar39 radioactivity.

Steinburnn, F.↗

Hydrogen transport in alpha titanium

Permeation experiments after nitriding the inlet surface of a hollow cylindrical membrane were conducted. Permeation data on two additional specimens given pre-oxidation or pre-nitriding treatments at both inlet and outlet surfaces are presented in terms of Arrhenius plots. Additionally, an analysis of geometry dependence on permeation rate was made for several specimens including the ones mentioned above. For simplicity in this report, the term as-polished is used to refer to a specimen which is either as-polished or is as-polished, pre-oxidized and annealed.

Johnson, D. L.↗

Role of pH on the stress corrosion cracking of titanium alloys

Stress corrosion cracking (SCC) experiments were conducted on Ti-8-1-1 wire specimens in hydrochloric and sulfuric acids of variable pH in order to determine the effect of pH on the susceptibility to cracking. The alloy exhibited increasing susceptibility with decreasing pH. By varying the applied potential, it was observed that susceptibility zones exist both in the cathodic and the anodic ranges. In the cathodic range, susceptibility also increased with decreasing applied potential. Corrosion potential-time data in hydrochloric acid (pH 1.7) and sulfuric acid (pH 1.7) indicate that chloride ions lower the corrosion potential of the specimen which, in turn, increases the susceptibility.

Khokhar, M. I.↗

Stress corrosion cracking of a titanium alloy in chloride-containing liquid environments

Ti-8 Al-1 Mo-1 V was tested in solvents containing chloride, bromide or iodide ions. It was found that the region II plateau velocity could be correlated with the inverse of the viscosity for several solvents. It seems most likely that this reflects the influence of the viscosity on the diffusion coefficient of some species involved in a mass transfer process which limits the crack growth. Associated tests were performed in which the potential, pH and concentration of Cl- were varied, in some of the same solutions as used for the viscosity tests. It is concluded from these tests that the absence of cathodic protection against cracking in solutions of low pH arises from an ohmic effect which isolates the crack tip from external potential control.

Smyrl, W. H.↗

Content of lithium, beryllium, boron, and titanium, and the isotopic composition of lithium, boron, and magnesium in Luna 16 regolith sample

The abundance of the following elements in the L 16-19 No. 118 regolith sample, zone V was determined by isotopic dilution using a mass spectrometer equipped with a scattering ion source: Li -- 9.8, Be -- 1.2, Be -- 2.6, and Ti -- 1.92 percent. For comparison, these same elements were measured in samples of surface material returned by Apollo 11, Apollo 12, and Apollo 14, and in the terrestrial reference standard diabase W-1. The content of Li, Be, and B in the Luna 16 sample is nearly the same as in the Apollo 11 surface material. The surface material returned by Apollo 12 and Apollo 14 contains two to four times more of these elements. However, the abundance ratios of Li, Be, and B are remarkably similar in the surface materials from the four different lunar regions. With respect to basaltic achondrites and especially with respect to chondrites, the lunar basalts are enriched in Li, Be, and B up to 100 times.

Eugster, O.↗

Effect of exposure cycle on hot salt stress corrosion of a titanium alloy

The influence of exposure cycle on the hot-salt stress-corrosion cracking resistance of the Ti-8Al-1Mo-1V alloy was determined. Both temperature and stress were cycled simultaneously to simulate turbine-powered aircraft service cycles. Temperature and stress were also cycled independently to determine their individual effects. Substantial increases in crack threshold stresses were observed for cycles in which both temperature and stress or temperature alone were applied for 1 hour and removed for 3 hours. The crack threshold stresses for these cyclic exposures were twice those determined for continuous exposure for the same total time of 96 hours.

Gray, H. R.↗

Titanium spallation cross sections between 30 and 584 MeV and Ar-39 activities on the moon

The production cross sections of Ar-39 for Ti spallation at 45-, 319-, 433-, and 584-MeV proton energies were measured to be 0.37 + or - 09, 12.4 + or - 3.7, 9.1 + or - 2.7, and 17.8 + or - 6.2 mb, respectively. Normalized Ar-39 production rates and activities are also derived for protons above 40 Mev and for three differential proton spectra. It is concluded that even for samples of high-Ti content, Ti spallation by solar protons below 200-MeV energy does not contribute significantly to their Ar-39 radioactivity.

Steinbrunn, F.↗

Machining titanium alloys

Study suggests ways of reducing chatte, increasing productivity, and reducing tool wear. Report also describes static and dynamic cutting tests and tool materials and finishes.

Sutherland, I. A.↗

Titanium and advanced composite structures for a supersonic cruise arrow wing configuration

Structural design studies were made, based on current technology and on an estimate of technology to be available in the mid 1980's, to assess the relative merits of structural concepts and materials for an advanced arrow wing configuration cruising at Mach 2.7. Preliminary studies were made to insure compliance of the configuration with general design criteria, integrate the propulsion system with the airframe, and define an efficient structural arrangement. Material and concept selection, detailed structural analysis, structural design and airplane mass analysis were completed based on current technology. Based on estimated future technology, structural sizing for strength and a preliminary assessment of the flutter of a strength designed composite structure were completed. An advanced computerized structural design system was used, in conjunction with a relatively complex finite element model, for detailed analysis and sizing of structural members.

Turner, M. J.↗

New advancements in titanium technology and their cost and weight benefits

A process that combines both the superplastic and diffusion bonding properties of metal into one concurrent operation is being developed. Estimates using this technology have indicated that this combined process will result in cost savings up to 70 percent when compared to conventional construction methods, while also saving weight. Many structural forms are possible including sandwich structures made by expanding face sheets and core against die forms. The classic difficulties normally associated with fabricating sandwich structures, such as parts fit-up, close tolerances, adhesive or braze alloy strength, do not exist with this technique. The total potential of Rockwell's patented new processes is limited only by the ingenuity of the designer and is expected to affect significantly future airplane concepts and criteria.

Ascani, L. A.↗