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At least 757 records · Page 42

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DOE OSTI2012

Electro-diffusion in a plasma with two ion species

Electric field is a thermodynamic force that can drive collisional inter-ion-species transport in a multicomponent plasma. In an inertial confinement fusion capsule, such transport causes fuel ion separation even with a target initially prepared to have equal number densities for the two fuel ion species. Unlike the baro-diffusion driven by ion pressure gradient and the thermo-diffusion driven by ion and electron temperature gradients, electro-diffusion has a critical dependence on the charge-to-mass ratio of the ion species. Specifically, it is shown here that electro-diffusion vanishes if the ion species have the same charge-to-mass ratio. An explicit expression for the electro-diffusion ratio is obtained and used to investigate the relative importance of electro- and baro-diffusion mechanisms. In particular, it is found that electro-diffusion reinforces baro-diffusion in the deuterium and tritium mix, but tends to cancel it in the deuterium and helium-3 mix.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2015

Stabilization of electron-scale turbulence by electron density gradient in national spherical torus experiment

Theory and experiments have shown that electron temperature gradient (ETG) turbulence on the electron gyro-scale, k{sub ⊥}ρ{sub e} ≲ 1, can be responsible for anomalous electron thermal transport in NSTX. Electron scale (high-k) turbulence is diagnosed in NSTX with a high-k microwave scattering system [D. R. Smith et al., Rev. Sci. Instrum. 79, 123501 (2008)]. Here we report on stabilization effects of the electron density gradient on electron-scale density fluctuations in a set of neutral beam injection heated H-mode plasmas. We found that the absence of high-k density fluctuations from measurements is correlated with large equilibrium density gradient, which is shown to be consistent with linear stabilization of ETG modes due to the density gradient using the analytical ETG linear threshold in F. Jenko et al. [Phys. Plasmas 8, 4096 (2001)] and linear gyrokinetic simulations with GS2 [M. Kotschenreuther et al., Comput. Phys. Commun. 88, 128 (1995)]. We also found that the observed power of electron-scale turbulence (when it exists) is anti-correlated with the equilibrium density gradient, suggesting density gradient as a nonlinear stabilizing mechanism. Higher density gradients give rise to lower values of the plasma frame frequency, calculated based on the Doppler shift of the measured density fluctuations. Linear gyrokinetic simulations show that higher values of the electron density gradient reduce the value of the real frequency, in agreement with experimental observation. Nonlinear electron-scale gyrokinetic simulations show that high electron density gradient reduces electron heat flux and stiffness, and increases the ETG nonlinear threshold, consistent with experimental observations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2016

Volatility Studies of Lanthanide Hexafluoroacetylacetone Chelates

Nuclear forensics has become very important to the field of nuclear security, where there is considerable interest in developing rapid separations of radionuclides and isotopes. Although prevention and detection form the foundation of nuclear security science, in the unfortunate event of detonation of a nuclear device, the fallout debris can be analyzed for signature isotopes that may provide evidence on the origin and type of nuclear materials. This is of considerable political importance to many governing bodies and this information is desired in a timely manner. One method of analysis is the rapid gas phase separation of rare earth metals from other components of the debris via isothermal thermochromatography. Lanthanides cover a portion of the fission product curve with varying yields dependent on a number of variables (e.g. neutron energy, fissile parent, etc), motivating the chromatographic separation of these elements. In previous work, 1,1,1,5,5,5 - hexafluoroacetylacetone (hfac) has been shown to produce volatile complexes with lanthanides. Thermochromatography is a gas phase separation method that utilizes temperature gradients on a column to vary adsorption location or constant column temperatures to vary retention time. The adsorption time of a compound on a column, i.e. retention time, is dependent on the thermodynamics, most notably the adsorption enthalpy. Studies of heavy metals have generated empirical correlations between adsorption enthalpy on a quartz column and sublimation enthalpy of the solid material. Thermogravimetric analysis (TGA) is useful in the characterization of the thermodynamics of materials, especially the sublimation enthalpy. Many methods analyze weight loss curves as a function of a constant heating rate. Another method introduced by Ashcroft analyzes weight loss curves over isothermal heating regions. Work presented here focuses on the determination of the sublimation enthalpies of thirteen lanthanide hfac complexes via the latter method. Additionally, there is investigation into the degradation of the compound via constant heating TGA up to higher temperatures. This provides information on the onset and end-set temperatures of degradation stages, as well as the peak temperature at which total sublimation occurs. (authors)

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2012

Spatially resolving variations in giant magnetoresistance, undetectable with four-point probe measurements, using infrared microspectroscopy

Magnetorefractive infrared (IR) microspectroscopy is demonstrated to resolve spatial variations in giant magnetoresistance (GMR) and, by modelling, provide an insight into the origin of the variations. Spatial variations are shown to be masked in conventional four-point probe electrical or IR spectral measurements. IR microspectroscopy was performed at the SMIS beamline at the SOLEIL synchrotron, modified to enable measurements in magnetic fields. A GMR gradient was induced in a CoFe/Cu multilayer sample by annealing in a temperature gradient. Modelling revealed that variations in GMR at 900 Oe could be attributed to local variations in interlayer coupling locally changing the switching field.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NASA NTRS1982

Einstein Observatory solid state spectrometer observations of M87 and the Virgo cluster

X-ray observations of the galaxy M87 and of a region in the Virgo cluster displaced 7 arcmin from the center of M87 are reported. X-ray spectra were obtained at these two locations with the Solid State Spectrometer onboard the Einstein Observatory. Emission lines were observed in both locations, indicating the presence of heavy elements at abundances near solar. There is no strong abundance gradient, within the errors. A temperature gradient has been detected: T increases from about 1.4 keV at the position of M87 to about 3.35 keV 7 arcmin away. There is lower temperature thermal emission at the center of M87 with T about 0.6 keV, consistent with models for cooling flows in this cluster. A mass infall rate of nearly 20 solar masses/yr has been obtained. In addition to the thermal emission, a power-law component has been detected in the spectrum of M87, consistent with that observed by HEAO 1, indicating that this component probably originates in the galaxy itself. Comparison of the results with those of other observers and with theoretical models for this source indicates the presence of intracluster gas having density near 1/1000 per cu cm and temperature of about 30,000,000 K.

Lea, S. M.↗

NASA NTRS1999

Double Diffusive Convection in Materials Processing

A great number of crystals grown in space are plagued by convective motions which contribute to structural flaws. The character of these instabilities is not well understood but is associated with density variations in the presence of residual gravity (g-jitter). As a specific example, past HgCdTe crystal growth space experiments by Lehoczky and co-workers indicate radial compositional asymmetry in the grown crystals. In the case of HgCdTe the rejected component into the melt upon solidification is HgTe which is denser than the melt. The space grown crystals indicate the presence of three dimensional flow with the heavier HgTe-rich material clearly aligned with the residual gravity (0.55-1.55 micro g) vector. This flow stems from double-diffusive convection, namely, thermal and solutal buoyancy driven flow in the melt. The study of double-diffusive convection is multi-faceted and rather vast. In our investigation, we seek to focus on one specific aspect of this discipline that is of direct relevance to materials processing especially crystal growth, namely, the side ways heating regime. This problem has been widely studied, both experimentally and numerically, in the context of solar ponds wherein the system is characterized by a linear salt (solutal) gradient with an imposed lateral temperature gradient. The induced flow instabilities arise from the wide disparity between the fluid thermal diffusivity and the solute diffusivity. The extension of the analysis to practical crystal growth applications has however not been rigorously made and understood. One subtle but important difference in crystal growth systems is the fact that die system solute gradient is non-linear (typically exponential). Besides, the crystal growth problem has the added complexities of solidification, both lateral and longitudinal thermal gradients and segregation phenomena in systems where binary and ternary compounds are being grown. This paper treats the side ways heating problem alone in a model fluid system. Results from detailed numerical calculations, mainly two dimensional are provided. The interactions between a non-linear solute gradient and an imposed transverse thermal gradient are investigated. The buoyancy effects are treated in the traditional Boussinesq approximation and also in a more complete density formulation to address recent concerns of the first approach especially in simulations of the system response in a reduced gravity environment. Detailed flow, temperature and solute field plots along with heat and mass transfer results are presented in the paper. Implications to practical crystal growth systems as discerned from the modeling results are also explored and reported.

Ramachandra, Narayanan↗

DOE OSTI2014

Magneto-Seebeck effect in spin-valve with in-plane thermal gradient

We present measurements of magneto-Seebeck effect on a spin valve with in-plane thermal gradient. We measured open circuit voltage and short circuit current by applying a temperature gradient across a spin valve stack, where one of the ferromagnetic layers is pinned. We found a clear hysteresis in these two quantities as a function of magnetic field. From these measurements, the magneto-Seebeck effect was found to be same as magneto-resistance effect.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Atmospheric Turbulent Intermittency Over the Arctic Sea‐Ice Surface During the MOSAiC Expedition

Turbulent motions in the Arctic stable boundary layer are characterized by intermittency, but they are rarely investigated due to limited observations, in particular over the sea‐ice surface. In the present study, we explore the characteristics of turbulent intermittency over the Arctic sea‐ice surface using data collected during the Multidisciplinary drifting Observation for the Study of Arctic Climate expedition from October 2019 to September 2020. We first develop a new algorithm, which performs well in identifying the spectral gap over the Arctic sea‐ice surface. Then the characteristics of intermittency are investigated. It is found that the strength of intermittency increases under the conditions of light surface wind speed, small surface wind speed gradient, and strong surface air temperature gradient. The momentum flux, sensible heat flux, and latent heat flux calculated by raw eddy‐covariance fluctuations are overestimated by 3%, 10%, and 24%, respectively, because submesoscale motions are included. Furthermore, the characteristics of the atmospheric boundary layer structure under various intermittency conditions reveal that strong low‐level jets are favorable to surface turbulent motions that result in weak intermittency, while strong temperature inversions above the surface layer suppress surface turbulent motions and lead to strong intermittency.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2015

Nanoscale temperature mapping in operating microelectronic devices

We report that modern microelectronic devices have nanoscale features that dissipate power nonuniformly, but fundamental physical limits frustrate efforts to detect the resulting temperature gradients. Contact thermometers disturb the temperature of a small system, while radiation thermometers struggle to beat the diffraction limit. Exploiting the same physics as Fahrenheit’s glass-bulb thermometer, we mapped the thermal expansion of Joule-heated, 80-nanometer-thick aluminum wires by precisely measuring changes in density. With a scanning transmission electron microscope (STEM) and electron energy loss spectroscopy (EELS), we quantified the local density via the energy of aluminum’s bulk plasmon. Rescaling density to temperature yields maps with a statistical precision of 3 kelvin/hertz ₋1/2 , an accuracy of 10%, and nanometer-scale resolution. Lastly, many common metals and semiconductors have sufficiently sharp plasmon resonances to serve as their own thermometers.

47 OTHER INSTRUMENTATION↗

NASA NTRS1976

Flight 1 technical report for experiment 74-36: Thermal migration of bubbles and their interaction with solidification interfaces

Specimens of gas saturated carbon tetrabromide were directionally solidified in a transparent furnace using a gradient freeze technique. The original temperature gradient was 5 C/cm and the cooling rate was 40 C/h. Progress of the experiment was monitored photographically. Gas bubbles were generated at the advancing solidification front in each of the three specimens. The gas bubbles were observed to increase in size, coalesce, and eventually be grown into the solid specimen under low gravity conditions. No bubble detachment from the interface was observed. Identical specimens processed in the laboratory showed bubble nucleation, bubble growth, and eventual bubble detachment due to buoyancy forces. Examination of the specimens showed a significantly greater void content in the low gravity processed samples. The grain size was observed to be finer in the low gravity processed samples.

Papazian, J. M.↗

NASA NTRS1975

Solar activity observed in X-rays and the EUV from OSO 7

Spectroheliograms obtained with the EUV spectroheliograph aboard OSO 7 between 1.7 and 400 A with a spatial resolution of at least 20 x 20 arc seconds are described, and results of an initial analysis of the Goddard X-ray polarimeter measurements are given and discussed in the light of current flare theories. The EUV observations are consistent with a picture in which coronal enhancement overlying an active region is made up of a nested set of arches or loops, with foot-points in regions of opposite magnetic polarity. The outermost arches are coolest, while those nearer the center are hotter. Along a given field line there is a temperature gradient such that the highest temperature occurs at the highest point of the magnetic arch. Polarimeter data provide evidence for polarization of about 20% in a number of X-ray bursts.

Thomas, R. J.↗

NASA NTRS1989

Critical transport parameters for porous media subjected to counterflow

Experimental and theoretical studies have been conducted to determine critical parameters at the onset of nonlinear counterflow in He II below the lambda point of He-4. Critical temperature differences have been measured in porous media for zero net mass flow and for Darcy permeabilities in the order of magnitude range from 10 to the -10th to 10 to the -8th sq cm. The normalized critical temperature gradients, which covered the liquid temperature range of 1.5 K to the lambda temperature, are found to vary with T proportional to the ratio of the superfluid density to the normal fluid density. This liquid temperature dependence appears to be consistent with duct data which are limited at low temperature by a Reynolds number criterion.

Frederking, T. H. K.↗

NASA NTRS1992

Effects of g-jitter and cross-diffusion on the onset of convection in doubly diffusive systems

The effects of a modulated gravity field in doubly diffusive layers with and without cross-diffusion are studied. Attention is focused on the determination of linear stability criteria for such systems. Floquet theory is used to establish the stability criteria by a systematic analysis of the topology of the neutral curves from which stability boundaries can be constructed. Convective stability boundaries for gravity-modulated doubly cross-diffusive systems are presented for the cases of dynamically free and rigid boundaries. Two physically different forms of layer stratification are considered: (1) imposed independent gradients of two components and (2) a solute gradient induced by a fixed temperature gradient.

Terrones, Guillermo↗

NASA NTRS1994

Elevated Temperature Crack Propagation

This paper is a summary of two NASA contracts on high temperature fatigue crack propagation in metals. The first evaluated the ability of fairly simple nonlinear fracture parameters to correlate crack propagation. Hastelloy-X specimens were tested under isothermal and thermomechanical cycling at temperatures up to 980 degrees C (1800 degrees F). The most successful correlating parameter was the crack tip opening displacement derived from the J-integral. The second evaluated the ability of several path-independent integrals to correlate crack propagation behavior. Inconel 718 specimens were tested under isothermal, thermomechanical, temperature gradient, and creep conditions at temperatures up to 650 degrees C (1200 degrees F). The integrals formulated by Blackburn and by Kishimoto correlated the data reasonably well under all test conditions.

Orange, Thomas W.↗

DOE OSTI2016

Understanding the breakdown of classic two-phase theory and spray atomization at engine-relevant conditions

We present a generalized framework for multi-component liquid injections to understand and predict the breakdown of classic two-phase theory and spray atomization at engine-relevant conditions. The analysis focuses on the thermodynamic structure and the immiscibility state of representative gas-liquid interfaces. The most modern form of Helmholtz energy mixture state equation is utilized which exhibits a unique and physically-consistent behavior over the entire two-phase regime of fluid densities. It is combined with generalized models for non-linear Gradient Theory and for liquid injections to quantify multi-component two-phase interface structures in global thermal equilibrium. Then, the Helmholtz free energy is minimized which determines the interfacial species distribution as a consequence. This minimal free energy state is demonstrated to validate the underlying assumptions of classic two-phase theory and spray atomization. However, under certain engine-relevant conditions for which corroborating experimental data is presented, this requirement for interfacial thermal equilibrium becomes unsustainable. A rigorously derived probability density function quantifies the ability of the interface to develop internal spatial temperature gradients in the presence of significant temperature differences between injected liquid and ambient gas. Then, the interface can no longer be viewed as an isolated system at minimal free energy. Instead, the interfacial dynamics become intimately connected to those of the separated homogeneous phases. Hence, the interface transitions toward a state in local equilibrium whereupon it becomes a dense-fluid mixing layer. A new conceptual view of a transitional liquid injection process emerges from a transition time scale analysis. Close to the nozzle exit, the two-phase interface still remains largely intact and more classic two-phase processes prevail as a consequence. Further downstream, however, the transition to dense- fluid mixing generally occurs before the liquid length is reached. The significance of the presented modeling expressions is established by a direct comparison to a reduced model, which utilizes widely-applied approximations but fundamentally fails to capture the physical complexity discussed in this paper.

42 ENGINEERING↗

DOE OSTI2014

In situ investigation of explosive crystallization in a-Ge: Experimental determination of the interface response function using dynamic transmission electron microscopy

The crystallization of amorphous semiconductors is a strongly exothermic process. Once initiated the release of latent heat can be sufficient to drive a self-sustaining crystallization front through the material in a manner that has been described as explosive. Here, we perform a quantitative in situ study of explosive crystallization in amorphous germanium using dynamic transmission electron microscopy. Direct observations of the speed of the explosive crystallization front as it evolves along a laser-imprinted temperature gradient are used to experimentally determine the complete interface response function (i.e., the temperature-dependent front propagation speed) for this process, which reaches a peak of 16 m/s. Fitting to the Frenkel-Wilson kinetic law demonstrates that the diffusivity of the material locally/immediately in advance of the explosive crystallization front is inconsistent with those of a liquid phase. This result suggests a modification to the liquid-mediated mechanism commonly used to describe this process that replaces the phase change at the leading amorphous-liquid interface with a change in bonding character (from covalent to metallic) occurring in the hot amorphous material.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

NASA NTRS1981

Estimation of surface temperature variations due to changes in sky and solar flux with elevation

The magnitude of elevation effects due to changes in solar and sky fluxes, on interpretation of single thermal images and composite products such as temperature difference and thermal inertia, are examined. Simple expressions are derived for the diurnal behavior of the two parameters, by fitting field observations in one tropic (Hawaii) and two semi-arid climates (Wyoming and Colorado) (Hummer-Miller, 1981). It is shown that flux variations with elevation can cause changes in the mean diurnal temperature gradient from -4 to -14 degrees C/km, evaluated at 2000 m. Changes in the temperature-difference gradient of 1 to 2 degrees C/km are also produced which is equivalent to an effective thermal-inertia gradient of 100 W s(exp 1/2)/sq m-K-km. An example is presented showing an elevation effect of 12 degrees C on the day and night thermal scenes of a test site in Arizona.

Hummer-Miller, S.↗

DOE OSTI2013

Impurity transport in trapped electron mode driven turbulence

Trapped electron mode turbulence is studied by gyrokinetic simulations with the GYRO code and an analytical model including the effect of a poloidally varying electrostatic potential. Its impact on radial transport of high-Z trace impurities close to the core is thoroughly investigated, and the dependence of the zero-flux impurity density gradient (peaking factor) on local plasma parameters is presented. Parameters such as ion-to-electron temperature ratio, electron temperature gradient, and main species density gradient mainly affect the impurity peaking through their impact on mode characteristics. The poloidal asymmetry, the safety factor, and magnetic shear have the strongest effect on impurity peaking, and it is shown that under certain scenarios where trapped electron modes are dominant, core accumulation of high-Z impurities can be avoided. We demonstrate that accounting for the momentum conservation property of the impurity-impurity collision operator can be important for an accurate evaluation of the impurity peaking factor.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗