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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

Experimental and theoretical investigations of the quality factor for N/+/P silicon solar cells

Many N(+)P silicon solar cells made with silicon from different growth techniques have current-voltage relations of the form: I = I(0) (exp(qV/AkT) - 1), where the quality factor A is nonintegral, is greater than 1, and shows a temperature dependence. The dark forward characteristics of such cells have been measured over a range of temperatures and the behavior of the factor A derived from them. Lack of agreement with previous models has led to the development of a new model, in which N(+) conduction electrons tunnel to deep levels near that side, these levels being due to junction contamination by impurities. Electron recombination then occurs with holes thermally assisted into the junction from the P side. This mechanism involves increased I(0) values over those for diffusion diode processes and thus reduces the cell power conversion efficiency.

Garlick, G. F. J.↗
NASA NTRS1981

The influence of environmental effects on the mechanical properties of graphite/epoxy laminates

The time dependent deformational and creep rupture processes in graphite/epoxy laminates are examined as a function of temperature and stress level. The role of accelerated characterization of design materials is discussed, and the use of a nonlinear time-temperature-stress-superposition principle in the determination of compliance master curves as a function of stress and temperature is considered. Creep rupture analytical models are discussed as applied to polymer-matrix composites, and the data is shown to be in general agreement with a logarithmic stress and temperature-dependent delayed fracture model. Comparisons between creep and rupture experiments and phenomenological models are presented.

Brinson, H. F.↗
NASA NTRS1982

Analysis of the far infrared H2-He spectrum

Previous measurements of the far infrared absorption due to H2-He collisions at the temperatures of 77, 195, and 292 K are analyzed. The spectra are fitted by a semiempirical line shape representing the isotropic induced overlap component and combined anisotropic quadrupolar and overlap components. The experimental spectral moments are evaluated and compared with theory for several induced-dipole and potential models. From the isotropic contribution, the range and strength of the induced dipole is evaluated and compared with the results of ab initio calculations. Fitting parameters are obtained with physically plausible temperature dependences which allow simple and accurate representation of the spectra and of their moments at temperatures different from those of the measurements.

Cohen, E. R.↗
NASA NTRS1983

The effects of Ohmic heating and stable radiation on magnetic tearing

A study is made of the effect of a temperature-dependent Coulomb-like resistivity on the planar tearing mode. The local evolution of the temperature is described by an energy equation which includes Joule heating and optically thin radiation. The resulting system of coupled linear magnetohydrodynamic equations is solved numerically, and eigenfunctions and growth rates are obtained. In the absence of radiation, there are two distinct solutions above a critical value of the magnetic Reynolds number S, a tearing-like mode and a Joule-heating mode. Below this point, the growth rates coalesce into a conjugate-complex pair. When stable radiation (dR/dT greater than 0) is added, the heating mode disappears and a modified tearing excitation exists to much lower values of S before its growth is cut off by Ohmic heating. Examples are given for solar coronal parameters, and for those characteristic of fusion-research devices. The introduction of an effective value for the resistivity, in the presence of energy transport, allows a simple qualitative discussion of the different modes.

Tachi, T.↗
NASA NTRS1997

The rate of the reaction between CN and C2H2 at interstellar temperatures

The rate coefficient for the important interstellar reaction between CN and C2H2 has been calculated as a function of temperature between 10 and 300 K. The potential surface for this reaction has been determined through ab initio quantum chemical techniques; the potential exhibits no barrier in the entrance channel but does show a small exit channel barrier, which lies below the energy of reactants. Phase-space calculations for the reaction dynamics, which take the exit channel barrier into account, show the same unusual temperature dependence as determined by experiment, in which the rate coefficient at first increases as the temperature is reduced below room temperature and then starts to decrease as the temperature drops below 50-100 K. The agreement between theory and experiment provides strong confirmation that the reaction occurs appreciably at cool interstellar temperatures.

NASA Discipline Exobiology↗
NASA NTRS2017

A Library of ATMO Forward Model Transmission Spectra for Hot Jupiter Exoplanets

We present a grid of forward model transmission spectra, adopting an isothermal temperature-pressure profile, alongside corresponding equilibrium chemical abundances for 117 observationally significant hot exoplanets (equilibrium temperatures of 547-2710 K). This model grid has been developed using a 1D radiative-convective-chemical equilibrium model termed ATMO, with up-to-date high-temperature opacities. We present an interpretation of observations of 10 exoplanets, including best-fitting parameters and X(exp 2) maps. In agreement with previous works, we find a continuum from clear to hazy/cloudy atmospheres for this sample of hot Jupiters. The data for all the 10 planets are consistent with subsolar to solar C/O ratio, 0.005 to 10 times solar metallicity and water rather than methane-dominated infrared spectra. We then explore the range of simulated atmospheric spectra for different exoplanets, based on characteristics such as temperature, metallicity, C/O ratio, haziness and cloudiness. We find a transition value for the metallicity between 10 and 50 times solar, which leads to substantial changes in the transmission spectra. We also find a transition value of C/O ratio, from water to carbon species dominated infrared spectra, as found by previous works, revealing a temperature dependence of this transition point ranging from approximately 0.56 to approximately 1-1.3 for equilibrium temperatures from approximately 900 to approximately 2600 K. We highlight the potential of the spectral features of HCN and C2H2 to constrain the metallicities and C/O ratios of planets, using James Webb Space Telescope (JWST) observations. Finally, our entire grid (approximately 460 000 simulations) is publicly available and can be used directly with the JWST simulator PandExo for planning observations.

techniques: spectroscopic – planets and satellit↗
NASA NTRS1985

Pressure dependence of the absolute rate constant for the reaction Cl + C2H2 from 210-361 K

In recent years, considerable attention has been given to the role of chlorine compounds in the catalytic destruction of stratospheric ozone. However, while some reactions have been studied extensively, the kinetic data for the reaction of Cl with C2H2 is sparse with only three known determinations of the rate constant k3. The reactions involved are Cl + C2H2 yields reversibly ClC2H2(asterisk) (3a) and ClC2H2(asterisk) + M yields ClC2H2 + M (3b). In the present study, flash photolysis coupled with chlorine atomic resonance fluorescence have been employed to determine the pressure and temperature dependence of k3 with the third body M = Ar. Room temperature values are also reported for M = N2. The pressure dependence observed in the experiments confirms the expectation that the reaction involves addition of Cl to the unsaturated C2H2 molecule followed by collisional stabilization of the resulting adduct radical.

Brunning, J.↗
NASA NTRS1976

Exciton coupling in molecular crystals

The implications of perfect exciton coupling and molecular vibrations were investigated, as well as the effect they have on the lifetime of singlet and triplet excitons coupled in a limiting geometry. Crystalline bibenzyl, Cl4Hl4, provided a situation in which these mechanisms involving exciton coupling can be studied in the limit of perfect coupling between units due to the crystal's geometry. This geometry leads to a coupling between the two halves of the molecule resulting in a splitting of the molecular excited states. The study reported involves an experimental spectroscopic approach and begins with the purification of the bibenzyl. The principal experimental apparatus was an emission spectrometer. A closed cycle cryogenic system was used to vary the temperature of the sample between 20 K and 300 K. The desired results are the temperature-dependent emission spectra of the bibenzyl; in addition, the lifetimes and quantum yields measured at each temperature reveal the effect of competing radiationless processes.

Ake, R. L.↗
NASA NTRS1976

TAP 1: A Finite Element Program for Steady-State Thermal Analysis of Convectively Cooled Structures

The program has a finite element library of six elements: two conduction/convection elements to model heat transfer in a solid, two convection elements to model heat transfer in a fluid, and two integrated conduction/convection elements to represent combined heat transfer in tubular and plate/fin fluid passages. Nonlinear thermal analysis due to temperature dependent thermal parameters is performed using the Newton-Raphson iteration method. Program output includes nodal temperatures and element heat fluxes. Pressure drops in fluid passages may be computed as an option. A companion plotting program for displaying the finite element model and predicted temperature distributions is presented. User instructions and sample problems are presented in appendixes.

Thornton, E. A.↗
NASA NTRS1980

Effect of blackbody radiation on the threshold for two-electron photodetachment of H/-/

The threshold law of the titled process, which is of the same form as that for electron-impact ionization of H, can experimentally be contaminated by simultaneous single photodetachment and Rydberg excitation of the residual atom, followed by ionization of the Rydberg atom by (room-temperature) blackbody photons. This gives a signal indistinguishable from direct double photodetachment. The correction is here calculated and shown to be finite at the double photodetachment threshold, and to have, possibly, an implication about the form of the threshold law itself. However, at room temperature its contribution is found to be small as it pertains to a recently initiated experiment at the Los Alamos Meson Physics Facility for available energies greater than a millivolt above threshold. The temperature dependence of the correction is shown to be large (k/B/T) to the 7/2; thus at higher temperatures the effect may be observable.

Temkin, A.↗
NASA NTRS1990

High Tc composite silver/oxide superconductors

Factors involved in the strong flux pinning effect of high-Tc YBa2Cu3O7/AgO (Y-123/AgO) composite and other REE-123/AgO composites were investigated. Samples of superconducting REE-123 and REE-123/AgO (where REE was Nd, Sm, Eu, Gd, Dy, Ho, Er, or Y) were prepared and used to obtain magnetic moments, critical field, and microstructure data. The optimum heat treatment conditions for the formation of strong flux-pinning REE-123/AgO composites were found to be different for different REE-123 compounds. It was found that the annealing temperature depends on the ionic size of the REE, with larger rare-earth ions requiring higher temperature. It was also found that strong flux-pinning REE-123/AgO composites form only in a narrow annealing temperature range.

Curreri, P. A.↗
NASA NTRS1991

Annealing of linear birefringence in single-mode fiber coils - Application to optical fiber current sensors

Annealing procedures that greatly reduce linear birefringence in single-mode fiber coils are described. These procedures have been successfully applied to coils ranging from 5 mm to 10 cm in diameter and up to 200 or more turns. They involve temperature cycles that last 3-4 days and reach maximum temperatures of about 850 C. The residual birefringence and induced loss are minimized by proper selection of fiber. The primary application of these coils is optical fiber current sensors, where they yield small sensors that are more stable than those achieved by other techniques. A current sensor with a temperature stability of 8.4 x 10 to the -5th/K over the range from -75 to 145 C has been demonstrated. This is approximately 20 percent greater than the temperature dependence of the Verdet constant. Packaging degrades the stability, but a packaged sensor coil with a temperature stability of about 1.6 + 10 to the -4th/K over the range from -20 to 120 C has also been demonstrated.

Tang, Dingding↗
NASA NTRS1994

ASTM E 1559 method for measuring material outgassing/deposition kinetics has applications to aerospace, electronics, and semiconductor industries

The American Society for Testing and Materials has published a new standard test method for characterizing time and temperature-dependence of material outgassing kinetics and the deposition kinetics of outgassed species on surfaces at various temperatures. This new ASTM standard, E 1559(1), uses the quartz crystal microbalance (QCM) collection measurement approach. The test method was originally developed under a program sponsored by the United States Air Force Materials Laboratory (AFML) to create a standard test method for obtaining outgassing and deposition kinetics data for spacecraft materials. Standardization by ASTM recognizes that the method has applications beyond aerospace. In particular, the method will provide data of use to the electronics, semiconductor, and high vacuum industries. In ASTM E 1559 the material sample is held in vacuum in a temperature-controlled effusion cell, while its outgassing flux impinges on several QCM's which view the orifice of the effusion cell. Sample isothermal total mass loss (TML) is measured as a function of time from the mass collected on one of the QCM's which is cooled by liquid nitrogen, and the view factor from this QCM to the cell. The amount of outgassed volatile condensable material (VCM) on surfaces at higher temperatures is measured as a function of time during the isothermal outgassing test by controlling the temperatures of the remaining QCM's to selected values. The VCM on surfaces at temperatures in between those of the collector QCM's is determined at the end of the isothermal test by heating the QCM's at a controlled rate and measuring the mass loss from the end of the QCM's as a function of time and temperature. This reevaporation of the deposit collected on the QCM's is referred to as QCM thermogravimetric analysis. Isothermal outgassing and deposition rates can be determined by differentiating the isothermal TML and VCM data, respectively, while the evaporation rates of the species can be obtained as a function of temperature by differentiating the QCM thermogravimetric analysis data.

Garrett, J. W.↗
NASA NTRS2010

Development and Testing of an Ultracapacitor Based Uninterruptible Power Supply (UPS) System

The NASA Glenn Research Center (GRC) initiated the development and testing of an ultracapacitor based uninterruptible power supply (UPS) system as a means to provide backup power for the many critical NASA applications. A UPS system typically utilizes batteries for energy storage. The battery is the most vulnerable part of the UPS system, requiring regular maintenance and replacement. Battery performance is also extremely temperature dependent. Ultracapacitors are ideal for UPS systems where long life, maintenance free operation, and excellent low temperature performance is essential. State of the art symmetric ultracapacitors were used for these tests. The ultracapacitors were interconnected in an innovative configuration to minimize interconnection impedance, and to provide voltage balancing. Ultracapacitors can be charged extremely rapidly and supply high current, which are essential characteristics for an effective UPS system. Charging ultracapacitors is significantly less complex than charging batteries since there is no chemical reaction occurring while charging ultracapacitors. The report concludes that the implementation of symmetric ultracapacitors in a UPS system can provide significant improvements in power system performance and reliability.

Eichenberg, Dennis J.↗
NASA NTRS2016

Ab Initio Simulations of Phase Stability and Martensitic Transitions in NiTi

For NiTi based alloys, the shape memory effect is governed by a transition from a low-temperature martensite phase to a high-temperature austenite phase. Despite considerable experimental and computational work, basic questions regarding the stability of the phases and the martensitic phase transition remain unclear even for the simple case of binary, equiatomic NiTi. We perform ab initio molecular dynamics simulations to describe the temperature-dependent behavior of NiTi and resolve several of these outstanding issues. Structural correlation functions and finite temperature phonon spectra are evaluated to determine phase stability. We show that finite temperature, entropic effects stabilize the experimentally observed martensite (B19') and austenite (B2) phases while destabilizing the theoretically predicted (B33) phase. Free energy computations based on ab initio thermodynamic integration confirm these results and permit estimates of the transition temperature between the phases. In addition to the martensitic phase transition, we predict a new transition between the B33 and B19' phases. The role of defects in suppressing phase transformation temperatures is discussed.

Simulations↗
NASA NTRSDate not supplied

CFD Model Development of a Cryogenic Storage Tank Self-Pressurization in Normal Gravity and Validation against SHIIVER Experiment

Two-phase flow and heat transfer simulations with interfacial phase change of the Structural Heat Intercept, Insulation, and Vibration Evaluation Rig (SHIIVER) self-pressurization experiment were conducted using storage tank CFD model in the framework of the ANSYS Fluent CFD code. The simulations were performed for the 70% fill level case with MLI on domes and no vapor cooling. All the phase change calculations in these simulations were generated by in-house Schrage-based evaporation-condensation model. The calculations were performed using both the Volume of Fluid (VOF) and Sharp Interface multiphase 2D axisymmetric models. A number of parametric and sensitivity studies were performed to check the various aspects of the CFD model. These studies helped to understand the effects of varying several parameters on the tank pressure and temperature during self-pressurization. Turbulence modeling; turbulence damping at the interface; and using constant vs. temperature dependent fluid properties were shown to have the most profound influence on predicted tank pressures and temperatures. Current study indicates that including phase change at the interface into the computational model is crucial for accurate prediction of the tank self-pressurization process. The effect of accommodation coefficient was also studied. Tank pressure values predicted by the VOF, and Sharp Interface models are within 4% of the experimental ones.

Computational Fluid Dynamics↗
NASA NTRS1965

Temperature transducer has high output, is time stable

Compact, lightweight temperature transducer requires no amplification of its output signal and is time stable. It uses the temperature-dependent characteristics of a silicon transistor to provide a zero-to-five-volt signal proportional to temperature.

Follett, W. H.↗
NASA NTRS1973

Viscosity of liquid anorthite.

The viscosity of liquid anorthite has been determined over the temperature ranges between 1450 to 1620 C and 820 to 950 C. The high-temperature data agree well with previous experimental data and with predictions of the Bottinga and Weill model. The overall log (viscosity) versus 1/T relation exhibits pronounced and rather continuous curvature. The viscosity of anorthite is higher at any given temperature and more strongly temperature-dependent than that of the anorthite-rich lunar compositions 14259, 14310, and 15418. The room-temperature density of glassy anorthite (2.64 gm/cu cm) and the thermal expansion coefficients of glassy and liquid anorthite have also been determined. The volume expansion coefficient for the glass is about 0.000018 per deg C, and that for the liquid is about 0.000048 per deg C. These values are used to relate the high-temperature flow data to the predictions of free-volume theories.

Cukierman, M.↗