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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Providing Satellite-Assisted Particulate Matter (SAPM) Estimates for the Models, In situ, and Remote sensing of Aerosols (MIRA) Working Group

The Models, In situ, and Remote sensing of Aerosols (MIRA) Working Group is an international forum that promotes collaboration amongst researchers of these three atmospheric aerosol communities. MIRA currently consists of a collection of five interdisciplinary and independently funded Topic groups with focused goals and generally involve requests for additional scientific datasets. Participants of the MIRA Satellite-Assisted Particulate Matter (SAPM) Topic group study particulate matter with diameters smaller than 2.5 microns (PM2.5), because of its substantial role in air pollution and the resulting negative impacts on human health. SAPM seeks to provide intercomparisons of different methods and techniques for obtaining surface PM2.5 proxies using spaceborne passive and active remote sensors, aerosol models, and in situ observations. The ultimate motivation of SAPM is to provide greater PM2.5 coverage than in situ ground stations, which are limited in some areas of the contiguous United States and large regions throughout the globe. In this poster presentation, we provide an overview of the PM2.5 estimation techniques applied by current SAPM team members, as well as the strengths and limitations of each technique. These approaches include spaceborne lidar (Cloud-Aerosol Lidar with Orthogonal Polarization) only, combined spaceborne lidar (Cloud Aerosol Transport System) and a model (Goddard Earth Observing System), and using aerosol optical depth (AOD) from a spaceborne passive remote sensor (Moderate Resolution Imaging Spectroradiometer) to explore city trends in AOD and relate those to city trends in PM2.5. Also in this poster presentation, we highlight results of our SAPM study of India, a country characterized by high levels of PM2.5 concentrations. We show the temporal and spatial variability of PM2.5 over India derived using various approaches and validation with ground-based in situ PM2.5 observations. The SAPM Topic group actively seeks additional collaborators, including those working with in situ aerosol measurements, and is interested in aerosol datasets to improve and/or validate the PM2.5 estimates.

Travis D Toth↗
NASA NTRSDate not supplied

Developing Satellite-Assisted Particulate Matter (SAPM) Estimates over India for the MIRA Working Group

The Models, In Situ, and Remote Sensing of Aerosols (MIRA) Working Group is an international collective that encourages collaboration among researchers from these three atmospheric aerosol communities. MIRA currently comprises five interdisciplinary and independently funded Topic Groups, each with specific goals, and involves requests for additional scientific datasets. The Satellite-Assisted Particulate Matter (SAPM) Topic Group, as part of MIRA, focuses on studying particulate matter smaller than 2.5 microns in diameter (PM2.5) due to its significant contribution to air pollution and its harmful effects on human health. While the annual mean PM2.5 levels are typically low (~5-15 μg/m³) across most of the contiguous United States (CONUS), other countries experience much higher concentrations (e.g., India). SAPM aims to compare different methods and techniques for obtaining surface PM2.5 proxies using spaceborne passive and active remote sensors, aerosol models, and in situ measurements. Ultimately, SAPM aims to provide more extensive coverage of PM2.5 concentrations than what is currently available from in situ ground stations, which are limited in some parts of the CONUS and large regions worldwide. Current SAPM members are exploring PM2.5 estimation techniques using active sensors. This presentation offers an overview of these techniques and highlights the strengths and limitations of each approach. These techniques include 1) spaceborne lidar (CALIOP: Cloud-Aerosol Lidar with Orthogonal Polarization) alone, and 2) a combination of spaceborne lidar (CATS: Cloud Aerosol Transport System) and a global aerosol transport model (GEOS: Goddard Earth Observing System). Additionally, we present a case study featuring our SAPM research in India, a country with high levels of PM2.5 concentrations (i.e., state-level annual means of ~100-200 μg/m³). Consistent spatial patterns in PM2.5 over India are found from the in situ data, CALIOP-based, and CATS/model-based methods, with the highest concentrations found in northern India near New Delhi. The gridded PM2.5 analysis yields high R values between in situ and CATS/model (~0.7) and between in situ and CALIOP nighttime (~0.9), as well as good agreement between CATS/model and CALIOP nighttime PM2.5 estimates (R = ~0.8 and slope = ~0.9). For current and future efforts, the SAPM Topic Group is actively seeking new collaborators, especially those working with in situ aerosol measurements, and is interested in acquiring additional aerosol datasets to improve and validate the PM2.5 proxies.

Travis D Toth↗
DOE OSTI2021

Energetics of surface melt in West Antarctica

We use reanalysis data and satellite remote sensing of cloud properties to examine how meteorological conditions alter the surface energy balance to cause surface melt that is detectable in satellite passive microwave imagery over West Antarctica. This analysis can detect each of the three primary mechanisms for inducing surface melt at a specific location: thermal blanketing involving sensible heat flux and/or longwave heating by optically thick cloud cover, all-wave radiative enhancement by optically thin cloud cover, and föhn winds. We examine case studies over Pine Island and Thwaites glaciers, which are of interest for ice shelf and ice sheet stability, and over Siple Dome, which is more readily accessible for field work. During January 2015 over Siple Dome we identified a melt event whose origin is an all-wave radiative enhancement by optically thin clouds. During December 2011 over Pine Island and Thwaites glaciers, we identified a melt event caused mainly by thermal blanketing from optically thick clouds. Over Siple Dome, those same 2011 synoptic conditions yielded a thermal-blanketing-driven melt event that was initiated by an impulse of sensible heat flux and then prolonged by cloud longwave heating. The December 2011 synoptic conditions also generated föhn winds at a location on the Ross Ice Shelf adjacent to the Transantarctic Mountains, and we analyze this case with additional support from automatic weather station data. In contrast, a late-summer thermal blanketing period over Pine Island and Thwaites glaciers during February 2013 showed surface melt initiated by cloud longwave heating and then prolonged by enhanced sensible heat flux. One limitation thus far with this type of analysis involves uncertainties in the cloud optical properties. Nevertheless, with improvements this type of analysis can enable quantitative prediction of atmospheric stress on the vulnerable Antarctic ice shelves in a steadily warming climate.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2022

L-Band Microwave Satellite Data and Model Simulations Over the Dry Chaco to Estimate Soil Moisture, Soil Temperature, Vegetation and Soil Salinity

The Dry Chaco in South America is a semi-arid ecoregion prone to dryland salinization. In this region, we investigated coarse-scale surface soil moisture (SM), soil temperature, soil salinity and vegetation, using L-band microwave brightness temperature (TB) observations and retrievals from the Soil Moisture Ocean Salinity (SMOS) and Soil Moisture Active Passive (SMAP) satellite missions, Catchment Land Surface Model (CLSM) simulations, and in situ measurements within 26 sampled satellite pixels. Across these 26 sampled pixels, the satellite-based SM outperformed CLSM SM compared to field data, and forward L-band TB simulations derived from in situ SM and temperature performed better than those derived from CLSM estimates relative to SMOS TB observations. The surface salinity for the sampled pixels was on average only 4 mg/g and only locally influenced the TB simulations, when including salinity in the dielectric mixing model of the forward radiative transfer model (RTM) simulations. To explore the potential of retrieving salinity together with other RTM parameters to optimize TB simulations over the entire Dry Chaco, the RTM was inverted using 10 years of multi-angular SMOS TB data and constraints of CLSM SM and temperature. However, the latter modeled SM was not sufficiently accurate and factors such as open surface water were missing in the background constraints, so that the salinity retrievals effectively represented a bulk correction of the dielectric constant, rather than salinity per se. However, the retrieval of vegetation, scattering albedo and surface roughness resulted in realistic values.

L-Band↗
NASA NTRSDate not supplied

Assessing Degradation of Advanced Coatings for Carbon/Carbon Composites

Carbon/carbon (C/C) composites are a well-utilized material system for hot structures to enable hypersonic flight. However, C/C materials are susceptible to attack by environmental degradation mechanisms, notably oxidation, which can limit the durability of components resulting in premature failure. Environmental barrier coatings (EBCs) have been developed to mitigate deleterious oxidation. Coating compositions based on silicon carbide (SiC) offer promise as a protective coating material for C/C composites. Under particular hypersonic flight conditions, a passivating silica scale can form at the surface of the EBC, acting as a barrier that can protect the underlying coating and substrate. However, the transition from passive to active oxidation, which varies with temperature and pressure, causes the formation of gaseous SiO that volatilizes leading to detrimental consumption of the SiC coating. In this work, arc-jet testing of SiC-based coatings developed to protect Advanced C/C-6 (ACC-6) was performed under a range of conditions to replicate varying oxidation conditions. In-situ optical emission spectroscopic measurements of the gas-surface interactions were collected and evaluated to render compositional degradation of the coating and underlying composite during arc-jet testing. Specimens were evaluated before, during and after arc-jet testing using destructive and non-destructive materials characterization methods, including optical and scanning electron microscopy and energy dispersive spectroscopy.

Coatings, Hypersonics, Composites↗
NASA NTRS1991

Magellan imaging radar mission to Venus

The Magellan imaging-radar mapping mission has collected and processed data from the spacecraft in an elliptical orbit around Venus. A brief description is given of the mission and the spacecraft, followed by a more detailed description of the radar system design, which used earth-orbiting SAR experience and several innovations in its design to operate from an orbit around another planet. The radar sensor, ground processing, and data products are described. This multimode radar is the only science instrument on the mission and has the objective of mapping at least 70 percent of the planet surface. It has three modes: SAR, altimetry, and passive radiometry. The radar system has produced maps of almost all of the Venusian surface with a resolution better than 600-m equivalent optical line pair, and the best resolution obtained is equivalent to less than 300 m. Some of the early radar images are shown.

Johnson, William T. K.↗
DOE OSTI2020

PERC silicon PV infrared to ultraviolet optical model

Here, optical modeling of aluminum back surface field (Al-BSF) and passivated emitter and rear contact (PERC) silicon wafer solar cells are extended into the infrared wavelength range (300–2500 nm). The model incorporates ray tracing to account for pyramidal texture of the front silicon surface, free carrier absorption in the front emitter; bulk silicon wafer, BSF; and Lambertian scattering at the silicon back contact. Total reflectance of pyramidal textured cells with different contact geometries with and without encapsulation are simulated. Simulated reflectance and short circuit current density match well with experimental values. These physics-based optical models serve as input for evaluating optical and thermal management strategies for silicon wafer solar cells.

14 SOLAR ENERGY↗
DOE OSTI2021

Investigation of the Selectivity of Carrier Transport Layers in Wide-Bandgap Perovskite Solar Cells

Excellent contact passivation and selectivity are prerequisites to realize the full potential of high-material-quality perovskite solar cells, first to maximize the internal voltage (or quasi-Fermi-level separation) iV within the absorber, then to translate this high internal voltage into a high external voltage V. Experimental quantification of contact passivation and selectivity is, thus, key to improving device performance. Here, open-circuit measurements of iV oc and V oc , combined with surface photovoltage measurements, are used to systematically quantify the passivation—using iVoc as a metric—and the selectivity—defined as Soc=V oc /iV oc —of a range of common carrier transport layers to wide-bandgap (1.67 eV) perovskite absorbers. The resulting solar cells suffer from large voltage deficits, particularly when NiO x is used as the hole transport layer, even though it provides better passivation than its polymer-based counterparts (PTAA and PTAA/PFN). This indicates a poor selectivity of NiO x (Soc<0.81 for NiO x -based devices), whereas devices using polymer-based hole transport layers exhibit high selectivity (S oc =0.94–0.95). In agreement with recent reports, this low selectivity is attributed to the formation of an interlayer of non-perovskite material with high resistance to holes at the perovskite/NiO x interface. These measurements also imply that the selectivity of the C60-based electron transport layers is relatively good.

carrier transport layers↗
NASA NTRS2018

Passive Thermal Management Systems Employing Shape Memory Alloys

A thermal management system includes a first substrate having a first conductive inner surface. A second substrate has a second conductive inner surface. A connecting structure is attached to the first and second substrates to space apart the first and second inner surfaces defining an insulating space for a single architecture. One or more passively-acting elements are attached to the inner surface of at least one substrate and including a shape memory material such as a shape memory alloy (SMA). The SMA passively reacts to the temperature of the first substrate by thermally contacting or separating from the second inner surface of the second substrate for the control of the conduction of heat energy in either direction.

Trigwell, Steven↗
NASA NTRS1972

Microwave emission measurements of sea surface roughness, soil moisture, and sea ice structure

In order to demonstrate the feasibility of the microwave radiometers to be carried aboard the Nimbus 5 and 6 satellites and proposed for one of the earth observatory satellites, remote measurements of microwave radiation at wavelengths ranging from 0.8 to 21 cm have been made of a variety of the earth's surfaces from the NASA CV-990 A/C. Brightness temperatures of sea water surfaces of varying roughness, of terrain with varying soil moisture, and of sea ice of varying structure were observed. In each case, around truth information was available for correlation with the microwave brightness temperature. The utility of passive microwave radiometry in determining ocean surface wind speeds, at least for values higher than 7 meters/second has been demonstrated. In addition, it was shown that radiometric signatures can be used to determine soil moisture in unvegetated terrain to within five percentage points by weight. Finally, it was demonstrated that first year thick, multi-year, and first year thin sea ice can be distinguished by observing their differing microwave emissivities at various wavelengths.

Gloersen, P.↗
DOE OSTI2021

Role of Cation Ordering on Device Performance in (Ag,Cu)InSe 2 Solar Cells with KF Post-Deposition Treatment

CuInSe 2 (CIS) has been proposed as an attractive bottom cell candidate in tandem solar cells. However, to justify the coupling with high-performance top cells (e.g., perovskites, GaAs), significant work on improving the efficiency is required. To this extent, several authors have demonstrated the benefits of alkali post-deposition treatments (PDT) to increase device open-circuit voltage (V oc ) in CIS and how Ag alloying - (Ag,Cu)InSe 2 (ACIS) - reduces defect density and enhances current collection in devices. Herein, we present a detailed study of the role that KF-PDT plays on CIS and ACIS absorber composition and structure, and propose an explanation for the decreased V oc observed when silver and potassium coexist in the system (ACIS + KF). Through a suite of synchrotron-based techniques, we investigate the nanoscale chemical distribution of the films and the formation of secondary phases. Through photoluminescence imaging, we observed a high degree of passivation with the addition of KF, and synchrotron-based X-ray diffraction confirmed the absence of a KInSe 2 surface layer usually considered to be a passivating agent. Raman spectroscopy and synchrotron X-ray fluorescence show the increased presence of Cu- and Se-poor clusters in ACIS + KF, which are correlated to significantly reduced X-ray beam-induced current (XBIC). An increase in the intensity of the E/B 2 stretching mode of CIS is attributed to cation ordering near the junction and is found to track inversely to bulk V oc measurements. The cation ordering is hypothesized to arise from the formation and redistribution of defects that normally occur near the surfaces of CIS as a consequence of its polar character. Here, these defects compensate each other, and the overall inhomogeneity of the charge distribution generates electrostatic potential fluctuations that greatly increase the saturation current and hence reduce the open-circuit voltage of the device.

36 MATERIALS SCIENCE↗
NASA NTRS1989

Surface Tension Confines Cryogenic Liquid

New type of Dewar provides passive, constant-temperature cryogenic cooling for scientific instruments under normal-to low-gravity conditions. Known as Surface-Tension-Contained Liquid Cryogen Cooler (STCLCC), keeps liquid cryogen in known location inside the Dewar by trapping liquid inside spongelike material. Unique sponge material fills most of volume of inner tank. Sponge is all-silica, open-cell material similar to that used for Space Shuttle thermal-protection tiles.

Castles, Stephen H.↗
DOE OSTI2021

Facilitating Large‐Scale Snow Shedding from In‐Field Solar Arrays using Icephobic Surfaces with Low‐Interfacial Toughness

Abstract Large‐scale accrual of snow and ice on solar arrays in northern latitudes can cause significant power generation losses during winter. Depending on environmental conditions, snow can encompass a wide range in physical characteristics from dry snow (modulus ≈100 kPa and density ≈0.1 g cm −3 ) to bulk ice (modulus ≈8 GPa and density ≈0.9 g cm −3 ). This variation in snow morphology has made the development of a passive, broad‐spectrum, snow and ice‐shedding surface challenging. Here, the authors develop one of the first surfaces that simultaneously possesses both low‐interfacial strength ( τ˄ ice < 50 kPa) and toughness (Γ ice < 0.5 J m −2 ) with ice. These surfaces, fabricated via the addition of mobile polymer chains/oils to a thin polymeric coating, require extremely low detachment forces for ice, enabling its passive shedding at virtually any accretion length scale. Preliminary evidence that the new surfaces can shed different forms of snow and ice from field‐deployed solar arrays, over a range of subzero temperatures for several weeks, leading to significant increases in power generation is provided. The optically transparent surfaces are easily scalable and can be widely deployed by the solar industry in areas that see persistent snow. Other applications include automotive windshields, LIDAR covers for autonomous vehicles, and cold climate optical sensors.

Dhyani, Abhishek↗
NASA NTRS1996

A Passive Cavity Concept for Improving the Off-Design Performance of Fixed-Geometry Exhaust Nozzles

An investigation was conducted in the model preparation area of the Langley 16-Foot Transonic Tunnel to study a passive cavity concept for improving the off-design performance of fixed-geometry exhaust nozzles. Passive cavity ventilation (through a porous surface) was applied to divergent flap surfaces and tested at static conditions in a sub-scale, nonaxisymmetric, convergent-divergent nozzle. As part of a comprehensive investigation, force, moment and pressure measurements were taken and focusing schlieren flow visualization was obtained for a baseline configuration and D passive cavity configurations. All tests were conducted with no external flow and high-pressure air was used to simulate jet-exhaust flow at nozzle pressure ratios from 1.25 to approximately 9.50. Results indicate that baseline nozzle performance was dominated by unstable shock-induced boundary-layer separation at off-design conditions, which came about through the natural tendency of overexpanded exhaust flow to satisfy conservation requirements by detaching from the nozzle divergent flaps. Passive cavity ventilation added the ability to control off-design separation in the nozzle by either alleviating separation or encouraging stable separation of the exhaust flow. Separation alleviation offers potential for installed nozzle performance benefits by reducing drag at forward flight speeds, even though it may reduce off-design static thrust efficiency as much as 3.2 percent. Encouraging stable separation of the exhaust flow offers significant performance improvements at static, low NPR and low Mach number flight conditions by improving off-design static thrust efficiency as much as 2.8 percent. By designing a fixed-geometry nozzle with fully porous divergent flaps, where both cavity location and percent open porosity of the flaps could be varied, passive flow control would make it possible to improve off-design nozzle performance across a wide operating range. In addition, the ability to encourage separation on one flap while alleviating it on the other makes it possible to generate thrust vectoring in the nozzle through passive flow control.

Asbury, Scott C.↗
NASA NTRS2017

Parabolic Flight Testing of Aeroponic Plant Growth Systems and Super Omniphobic Surface Coatings

The purpose of this project is to gain valuable data from three separate experiments. One being an aeroponics watering system, another being a PONDS passive watering system, and the last a super omniphobic surface coating apparatus.There are two aeroponics watering systems that feed water and nutrients to "plant roots" inside of a contained box. The walls inside of the contained boxes have different surface textures and shapes but each contain the same nozzle and compressor set up as a control.There is one PONDS passive watering system that feeds water from a reservoir to a porous substrate utilizing wicking materials. There is one super omniphobic surface coating apparatus that feeds water into an apparatus allowing the water to make contact with three individual compartments in which glass beads with different coatings are carefully placed between two glass slides. The outcome will contribute to the advancement in self sustainment for space exploration. The status of the project when I started was to get the system built and ready for flight come November. My intended contributions are to assist with the build of the system.

Blockey, Jamie Lynn↗
DOE OSTI2020

High-throughput synthesis and corrosion behavior of sputter-deposited nanocrystalline Al x (CoCrFeNi) 100-x combinatorial high-entropy alloys

High-entropy alloys (HEAs) are inherently complex and potentially span a vast composition space, making their research and discovery challenging. In the present study, high-throughput synthesis of an Al x (CoCrFeNi) 100-x combinatorial material library covering x = 4.5–40 atomic percent Al is achieved, using magnetron cosputtering. The effects of Al on the microstructure and corrosion behavior are investigated. With the increased amount of Al, crystal-structures of thin films transform from face-centered cubic (FCC) to body-centered cubic (BCC). Both the FCC and BCC thin films demonstrate a uniform elemental distribution. Corrosion characteristics of combinatorial samples immersed in the 3.5 wt% (wt%) NaCl solution are evaluated via electrochemical tests. Complementary X-ray photoelectron spectroscopy analysis reveals the compositional variation of passivated films formed on the sample surface after immersion. The results show that the Al x (CoCrFeNi) 100-x HEA thin films possess outstanding corrosion-resistant properties, but the resistance diminishes with the increasing Al content. The decreased corrosion resistance is revealed to be directly related to the constituents of passivated films.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Enabling bifacial thin film devices by developing a back surface field using Cu x AlO y

Bifacial solar cells have the potential to increase the energy yield per unit area over traditional monofacial devices without significant added cost, driving $/kWh costs lower and accelerating the adoption of solar photovoltaics. However, the performance of bifacial thin film solar cells significantly lags that achieved by crystalline silicon cells. Here we incorporate wide bandgap Cu x AlO y as a back buffer layer for CdTe devices and achieve a backside illuminated device with high current density and high fill factor. Moreover, these values remain nearly constant even as the absorber layer thickness changes, indicating that a fully-depleted device is not required for efficient charge collection. We show that this response is indicative of a back surface field, albeit with a persistent high back surface recombination velocity. By managing electron reflection, we achieved a backside illumination conversion efficiency of 7.1% and bifaciality of 0.55 for a 3.3 µm CdTe device and 8.0% and 0.62 for a 2 µm device. Future improvements can be made by identifying and incorporating a passivation material that reduces the back surface recombination velocity.

36 MATERIALS SCIENCE↗