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At least 757 records · Page 42

Ratiometric vapor sensor

A ratiometric vapor sensor is described that includes a first sensor and a second sensor. The first sensor includes a first semiconductor component comprising a vapor-sensitive semiconducting organic compound, while the second sensor includes a second semiconductor component comprising a modified vapor-sensitive semiconducting organic compound including a modifying organic group. The ratiometric vapor sensor can be used to detect the presence of a vapor such as nitrogen dioxide, and determine the concentration of the vapor by comparing the outputs of electrodes connected to the first and second sensor.

47 OTHER INSTRUMENTATION↗

Gas sensor system

A gas sensing tube includes an outer surface, and an inner surface defining a passage. A sensor node is arranged along the sensing tube. The sensor node includes an inlet fluidically connected to the passage, an outlet fluidically connected to the passage, and an interior chamber arranged between the inlet and the outlet. A sensor cable extends along the sensing tube. The sensor cable includes a first conduit having a first connector coupled to the sensor node at the inlet and a second conduit having a second connector connected to the sensor node at the outlet. The sensor cable has a first conductor extending through the first conduit and being coupled to the first connector and a second conductor extending through the second conduit and being coupled to the second connector.

Challener, William Albert↗

Anomalous behavior detection by an artificial intelligence-enabled system with multiple correlated sensors

Multi-metric artificial intelligence (AI)/machine learning (ML) models for detection of anomalous behavior of a machine/system are disclosed. The multi-metric AI/ML models are configured to detect anomalous behavior of systems having multiple sensors that measure correlated sensor metrics such as coolant distribution units (CDUs). The multi-metric AI/ML models perform the anomalous system behavior detection in a manner that enables both a reduction in the amount of sensor instrumentation needed to monitor the system's operational behavior as well as a corresponding reduction in the complexity of the firmware that controls the sensor instrumentation. As such, AI-enabled systems and corresponding methods for anomalous behavior detection disclosed herein offer a technical solution to the technical problem of increased failure rates of existing multi-sensor systems, which is caused by the presence of redundant sensor instrumentation that necessitates complex firmware for controlling the sensor instrumentation.

Serebryakov, Sergey↗

Characterization of Intrinsic Fiber Optic Temperature Sensors by In-core and Furnace Testing

Increased research and development in nuclear technology has raised the demand for novel sensors and instrumentation to meet data objectives, and survive in different conditions and environments, beyond conventional light water reactor (LWR) environments. Expediting the deployment of advanced nuclear technologies by developing, demonstrating, and qualifying advanced reactor fuel forms necessitates a deeper understanding of how irradiation affects fuels and materials' performance. To achieve a more comprehensive understanding of fuels and materials performance, researchers require more specialized experiments and measurements. The demand for innovative sensors to support nuclear fuel development arises from the complexity of materials' behavior under irradiation and the challenges of deploying instrumentation in Material Test Reactors (MTRs) for irradiation tests. Additionally, measurements of material properties require integrated measurement systems to characterize thermal properties, mechanical properties, chemistry, and microstructure [1]. Among the potential measurement techniques, optical fiber-based sensors have been identified as potential sensors to measure different physical phenomena such as temperature, strain, pressure, and fluid level. Optical fiber sensors have the capability to provide multi-sensing and multiplexing instrumentation, allowing the measurement of different physical parameters within a single sensor configuration, and transmitting data collected at multiple locations through a single fiber. They offer immunity to electromagnetic interference, electrical passivity, compatibility with various sensing methodologies, and cost-effectiveness. Beyond their widespread use in telecommunications, silica fiber-based instruments are utilized in industrial applications, even at temperatures reaching 300?400°C, such as distributed temperature sensing in oil and gas recovery. The Department of Energy (DOE) is interested in using fiber optics to support fuel cycle development [2]. Fiber optics are an excellent candidate for harsh environment sensing, including sensing at very high temperatures (1900oC for sapphire optical fibers). Distributed fiber optic sensing has been deployed in other harsh environments like coal gasification plants [3]. Distributed strain sensing, which operates similarly to distributed temperature sensing, has been deployed to monitor underground mines and fibers have been imbedded in soil to monitor sink-hole development [4][5]. The application of fiber optic sensors to advanced reactor development is a promising area of research.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Distributed Coaxial Cable Sensors for In-Situ Condition Based Monitoring of Coal-Fired Boiler Tubes

The increasing contributions of renewable energy sources present new challenges to the operation and maintenance of the existing coal-fired power plants. One of the major operational risks is the unexpected failure of superheater boiler tubes, leading to the most unplanned power plant outrages. The boiler tube failure is difficult to predict due to the harsh operating environments. Therefore, condition-based monitoring (CBM) with a reliable high temperature sensor becomes necessary to produce a meaningful assessment of the health condition of boiler tubes and their remaining lifetime. In this work, the stainless-steel and quartz coaxial cable sensor (SSQ-CCS) is proposed for in-situ distributed monitoring of the boiler tube temperatures in existing coal-fired power plants. Comprehensive tests have been conducted with an in-house testing facility at Clemson University to study and evaluate the sensors’ performance in the temperature range of 100℃ to 600℃. The results indicated that the measurement resolution of the SSQ-CCS sensor is better than 1℃, and the drift is less than 2% over long-period testing. Meanwhile, multi-physics finite element analysis has been conducted to optimize the design and evaluate the safety of the SSQ-CCS temperature sensor under various operational conditions. Based on the performance obtained in the laboratory-scale testing, a field test has been implemented at a power plant. Four SSQ-CCS temperature sensors were installed for in-situ monitoring of the temperatures of a power plant’s superheat tube assembles. The data acquisition system has been successfully set up and collected sensing signals for more than three months. The sensing signals have been post-processed, and the monitored temperature history through the SSQ-CCS temperature sensor has been validated and compared with the conventional high temperature thermal couple data.

Jiao, Xinyu↗

Passive Temperature Sensors for Nuclear Applications

In April 2007, the Department of Energy (DOE) designated the Advanced Test Reactor (ATR) a National Scientific User Facility (NSUF) to advance US leadership in nuclear science and technology. By attracting new users from universities, laboratories, and industry, this program supports basic and applied nuclear research to help address the nation's energy security needs. In support of this program, the Idaho National Laboratory (INL) established in-house capabilities to develop, fabricate, test, and qualify new and enhanced temperature sensors for irradiation testing. This effort is continuing today through the DOE?s Advanced Sensors and Instrumentation (ASI) program. Although most efforts emphasize sensors capable of providing real-time data, selected tasks have been completed to enhance passive sensors for irradiations where instrumentation leads cannot be included. These sensors include silicon carbide (SiC) monitors, melt wires and the sublime temperature monitor. SiC monitors are available to detect peak irradiation temperatures between 200°C and 800°C in reactor locations where instrumentation leads cannot be used. SiC monitors may be evaluated using specialized equipment installed at INL?s Measurement Sciences Laboratory (MSL). A melt wire inventory is also maintained at MSL. This inventory contains wires for specific use in irradiation experiments ranging in temperatures from 30°C to 1500°C. Melt wires and SiC monitors have had decades of research and application. Recent research has produced a passive monitor known as the sublime temperature monitor. This passive sensor has the capability of recording temperature gradients. This paper will discuss passive temperature sensors currently being researched and implemented under the ASI program.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Wearable Microfluidic Diaphragm Pressure Sensor for Health and Tactile Touch Monitoring

Flexible pressure sensors have many potential applications in wearable electronics, robotics, health monitoring, and more. In particular, liquid-metal-based sensors are especially promising as they can undergo strains of over 200% without failure. However, current liquid-metal-based strain sensors are incapable of resolving small pressure changes in the few kPa range, making them unsuitable for applications such as heart-rate monitoring, which require a much lower pressure detection resolution. In this paper, a microfluidic tactile diaphragm pressure sensor based on embedded Galinstan microchannels (70 µm width × 70 µm height) capable of resolving sub-50 Pa changes in pressure with sub-100 Pa detection limits and a response time of 90 ms is demonstrated. An embedded equivalent Wheatstone bridge circuit makes the most of tangential and radial strain fields, leading to high sensitivities of a 0.0835 kPa -1 change in output voltage. The Wheatstone bridge also provides temperature self-compensation, allowing for operation in the range of 20–50 °C. Finally, as examples of potential applications, a polydimethylsiloxane (PDMS) wristband with an embedded microfluidic diaphragm pressure sensor capable of real-time pulse monitoring and a PDMS glove with multiple embedded sensors to provide comprehensive tactile feedback of a human hand when touching or holding objects are demonstrated.

47 OTHER INSTRUMENTATION↗

Laboratory testing methods to evaluate the reliability of occupancy sensors for commercial building applications

The energy performance of commercial buildings is greatly influenced by occupants which are highly variable and among the most unpredictable components of a building's operation. While most building control systems use fixed, predetermined occupancy schedules, these fixed occupancy levels can be quite different from actual occupancy. This can cause unnecessary energy consumption, particularly from heating, ventilation, and air conditioning (HVAC) and lighting systems which are responsible for approximately 60% of commercial buildings' energy use. The use of occupancy counting sensor systems integrated with building management system controls is one method that can be used to improve the energy-consuming performance of buildings. However, there is no standardized universal methodology and metrics to evaluate their reliability. The aim of this research is to develop a uniform evaluation methodology to assess the reliability of occupancy counting sensor systems in a controlled laboratory environment. The developed testing methodology includes both “typical” scenarios representing the occupancy scenarios of a typical commercial building, and “failure” testing scenarios which represent a range of potential scenarios that may impact a sensor system's reliability. These methods were then implemented in a case study to evaluate the performance of two novel occupancy counting sensor systems (i.e., door-centric, and camera-based). Results suggest that typical testing results can be used to compare the overall performance of the occupancy counting sensor systems; however, failure testing is also important to understand the weaknesses of the sensor system in order to select the suitable one for the intended use of the commercial building. In addition, the proposed methodology includes a modified confusion matrix which enables the ability to identify if failures are caused by over or under counting occupants and to what extent this occurs over the testing period.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Characterization of a selective, zero power sensor for distributed sensing of hydrogen in energy applications

The use of hydrogen as a clean and renewable energy source is increasing rapidly for both vehicle and stationary applications. There are safety concerns for the locations in which hydrogen is made, used, and transported (i.e., pipelines and tanker trucks). Sensors are needed to comply with safety regulations and to enable a smooth and safe rollout of hydrogen as an alternative energy. However, hydrogen sensors do not yet exist that have the combined features of small size and low power for easy deployment coupled with high-volume manufacturability and low cost. This is necessary to accommodate the emerging fixed and mobile markets while retaining critical metrological metrics, including measurement range, detection limits, selectivity, fast response, stability, and long lifetime. An amperometric gas sensor for hydrogen (AGS) has been developed using an innovative manufacturing method. The sensor was designed using scalable fabrication strategies based on “Printed Electronics” (PE) methodology which are compatible with large-scale production. Prototype sensors were batch fabricated with multiple individual elements on a substrate compatible in size with a standard 8-inch wafer to enable high-volume, low-cost manufacturing, thereby leveraging PE and semiconductor fabrication infrastructure. This novel AGS was instrumented with control circuitry and evaluated for hydrogen detection in the range of 0–5000 ppmv H2 in air. Specific performance evaluations included assessment of the sensor measurement range, repeatability, and selectivity.

08 HYDROGEN↗

High-Temperature Microwave Acoustic Vibration Sensor

High-temperature vibration sensors are desired in a number of contemporary harsh-environment applications, namely: power plants, metallurgy, aerospace, and defense. The detection of vibrations in these applications is important for providing condition-based maintenance (CBM) for electronic, mechanical, and structural systems, thus reducing operating and maintenance costs, improving industry efficiency, and increasing safety. Microwave surface acoustic wave resonator (MSAWR) sensors have the potential of being used as high-temperature vibration sensors due to their proven harsh-environment operation, small size, battery-free, and wireless capability. This paper explores the MSAWR as a vibration sensor mounted and tested up to 500°C. A 193MHz langasite-based MSAWR sensor was attached to a custom-designed constant-stress Inconel cantilever test beam using a high-temperature capable Al 2 O 3 -based adhesive. The beam was mounted in a box furnace and exposed to vibrations using a stainless-steel rod attached to a vibration generator outside the furnace. Here, the resulting measurements at high-temperatures reported in this paper confirm the viability of the MSAWR sensor to detect both vibration frequency and magnitude for high temperature industrial, defense, aerospace, and power sector applications.

42 ENGINEERING↗

Flow Enhanced Electrochemical Sensor Performance in Complex Salt Systems

To advance MSR MC&A practices, Argonne National Laboratory developed and optimized robust flow enhanced electrochemical sensors (FEES) and multielectrode array voltammetry sensors (MAVS) which provide accurate near-real time measurements of actinides in molten salts. Flow-enhanced electrochemical sensors are installed directly into MSR flow conduits for inline salt chemistry measurement, while MAVS are deployed in quiescent salt conditions enabling online species concentration determination in stationary salt vessels. This report summarizes efforts to improve electrochemical sensor technological readiness through (1) sensor testing in complex, high concentration molten salt systems to demonstrate low uncertainty actinide measurements in MSR-representative solutions and (2) demonstrations of sensor performance in challenging real-world conditions in collaboration with partner MSR institutions.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Leveraging Optimal Sparse Sensor Placement to Aggregate a Network of Digital Twins for Nuclear Subsystems

Nuclear power plants (NPPs) require continuous monitoring of various systems, structures, and components to ensure safe and efficient operations. The critical safety testing of new fuel compositions and the analysis of the effects of power transients on core temperatures can be achieved through modeling and simulations. They capture the dynamics of the physical phenomenon associated with failure modes and facilitate the creation of digital twins (DTs). Accurate reconstruction of fields of interest (e.g., temperature, pressure, velocity) from sensor measurements is crucial to establish a two-way communication between physical experiments and models. Sensor placement is highly constrained in most nuclear subsystems due to challenging operating conditions and inherent spatial limitations. This study develops optimized data-driven sensor placements for full-field reconstruction within reactor and steam generator subsystems of NPPs. Optimized constrained sensors reconstruct field of interest within a tri-structural isotropic (TRISO) fuel irradiation experiment, a lumped parameter model of a nuclear fuel test rod and a steam generator. The optimization procedure leverages reduced-order models of flow physics to provide a highly accurate full-field reconstruction of responses of interest, noise-induced uncertainty quantification and physically feasible sensor locations. Accurate sensor-based reconstructions establish a foundation for the digital twinning of subsystems, culminating in a comprehensive DT aggregate of an NPP.

42 ENGINEERING↗

Advanced Sensors and Instrumentation Issue 10

The Advanced Sensors and Instrumentation (ASI) program, on its seventh fiscal year, continues to address key technology gaps for future nuclear energy systems. ASI’s goal is to enable the advanced instrumentation and control (I&C) technologies essential to the Office of Nuclear Energy’s research and development (R&D) efforts needed to realize its mission goals. Information on our projects can be found in our ASI annual awards summaries, annual review webinars, and newsletters posted in the Office of Nuclear Energy website (energy.gov/ne). This year, we have initiated three newly awarded projects in the area of data analytics. We also initiated a project to develop and demonstrate a prototype passive wireless sensor network. This sensor will use advanced manufacturing and printing, and be tested and demonstrated at a U.S. nuclear power plant facility. In addition, we are developing a sensor database to capture advanced sensor and instrumentation technology that is applicable to nuclear power plants. Under the In-Pile Instrumentation program, we continue to develop unique in-pile sensors and instrumentation to provide real-time, accurate, and spatially resolved information regarding the performance of fuels and materials. Due to the closure of the Halden reactor, we are focusing our near-term research in providing equivalent capability for the instrumentation of irradiation experiments in the U.S. that are needed by the nuclear industry. As the ASI program continues to award projects through competitive solicitations, we encourage the I&C community to visit our website for current funding opportunity announcements, especially for the industry-focused solicitation entitled, “U.S. Industry Opportunities for Advanced Nuclear Technology Development.”

99 GENERAL AND MISCELLANEOUS↗

Porous Enzymatic Membrane for Nanotextured Glucose Sweat Sensors with High Stability toward Reliable Noninvasive Health Monitoring

Development of reliable glucose sensors for noninvasive monitoring without interruption or limiting users' mobility is highly desirable, especially for diabetes diagnostics, which requires routine/long-term monitoring. However, their applications are largely limited by the relatively poor stability. In this paper, a porous membrane is synthesized for effective enzyme immobilization and it is robustly anchored to the modified nanotextured electrode solid contacts, so as to realize glucose sensors with significantly enhanced sensing stability and mechanical robustness. To the best of our knowledge, this is the first report of utilizing such nanoporous membranes for electrochemical sensor applications, which eliminates enzyme escape and provides a sufficient surface area for molecular/ion diffusion and interactions, thus ensuring the sustainable catalytic activities of the sensors and generating reliable measureable signals during noninvasive monitoring. The as-assembled nanostructured glucose sensors demonstrate reliable long-term stable monitoring with a minimal response drift for up to 20 h, which delivers a remarkable enhancement. Moreover, they can be integrated into a microfluidic sensing patch for noninvasive sweat glucose monitoring. The as-synthesized nanostructured glucose sensors with remarkable stability can inspire developments of various enzymatic biosensors for reliable noninvasive composition analysis and their ultimate applications in predictive clinical diagnostics, personalized health-care monitoring, and chronic diseases management.

36 MATERIALS SCIENCE↗

A machine learning approach to water quality forecasts and sensor network expansion: Case study in the Wabash River Basin, United States

Abstract Midwestern cities require forecasts of surface nitrate loads to bring additional treatment processes online or activate alternative water supplies. Concurrently, networks of nitrate monitoring stations are being deployed in river basins, co‐locating water quality observations with established stream gauges. However, tools to evaluate the future value of expanded networks to improve water quality forecasts remains challenging. Here, we construct a synthetic data set of stream discharge and nitrate for the Wabash River Basin—one of the United States’ most nutrient polluted basins—using the established Agro‐IBIS and THMB models. Synthetic data enables rapid, unbiased and low‐cost assessment of potential sensor placements to support management objectives, such as near‐term forecasting. Using the synthetic data, we established baseline 1‐day forecasts for surface water nitrate at 12 cities in the basin using support vector machine regression (SVMR; RMSE 0.48–3.3 ppm). Next, we used the SVMRs to evaluate the improvement in forecast performance associated with deployment of additional nitrate sensors. We identified the optimal sensor placement to improve forecasts at each city, and the relative value of sensors at each candidate location. Finally, we assessed the co‐benefit realized by other cities when a sensor is deployed to optimize a forecast at one city, finding significant positive externalities in all cases. Ultimately, our study explores the potential for machine learning to make near‐term predictions and critically evaluate the improvement realized by expanding a monitoring network. While we use nitrate pollution in the Wabash River Basin as a case study, this approach could be readily applied to any problem where the future value of sensors and network design are being evaluated.

54 ENVIRONMENTAL SCIENCES↗

U-bend fiber optical sensor for magnetic field sensing

In this paper, we propose a method for fabricating a U-bend optical fiber magnetic field sensor. The working principle of the sensor is based on the use of bending to induce a whispering gallery mode. In experimental testing, a U-shaped optic fiber probe was fabricated using a lamping process and then coated on its surface with ferroferric oxide (Fe{sub 3}O{sub 4}), which served as the magnetic field sensing layer. The intensity of an applied magnetic field was then controlled by the vertical distance between an NbFeB magnet and the sensor. The magnetic field was monitored using a Gauss meter. As the external magnetic field was applied to the sensor, it produced magnetic attraction with the Fe{sub 3}O{sub 4}. The magnetic field intensity was increased from 0 to 900 Gauss, which in turn caused the magnetic attraction to become larger. This in turn caused the optic fiber sensor to deform, inducing changes in the bending radius. Therefore, the wavelength shifted toward a short wavelength and the transmission loss was gradually increased. The results show that the sensitivity of the sensor in the magnetic field experiment was − 0.00130 nm/Gauss and the linearity (R{sup 2}) was 0.888, while the corresponding average loss sensitivity was 0.00028 dB/Gauss and the corresponding linearity (R{sup 2}) was 0.942.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Characteristics of Hydrogen Sensors Based on Thin Tin Dioxide Films Modified with Gold

Effect of hydrogen in the concentration range from 10 to 2000 ppm on the characteristics of sensors based on thin films of tin dioxide modified with gold (Au/SnO{sub 2}:Sb, Au) is studied in the thermo-cyclic mode at temperatures from 623 to 773 K and absolute humidity from 2.5 to 20 g/m{sup 3}. Experimental data are discussed using expressions obtained within the framework of a model that takes into account the presence of three types of adsorbed particles (O¯, OH, and OH¯) on the surface of SnO{sub 2} nanocrystals. The characteristics of the sensors based on thin Pt/Pd/SnO{sub 2}:Sb films (the first series) are compared with those of Au/SnO{sub 2}:Sb, Au films (the second series). It is found that the degree of dissociation of molecular hydrogen into atoms during adsorption on the sensor under interaction with Au particles on the SnO{sub 2} surface is 4 times greater than that under interaction with Pt/Pd particles. The degree of dissociation of H{sub 2}O molecules into hydrogen atoms and hydroxyl groups in pure moist air on the surface of the sensors of the second series is 1.6 times greater than that for the sensors of the first series. Thus, gold is a more effective stimulator of the dissociation of H{sub 2} and H{sub 2}O molecules than platinum and palladium. A formula is obtained that describes more accurately the dependence of the response of the sensors of both series to the effect of hydrogen on the concentration of this gas and on the temperature of the measuring devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Investigation of Pt and Pd Modified WO{sub 3} and ZnO Based Thin Film Sensors for Ethanol Sensing

Ethanol sensors based on different WO{sub 3} and ZnO structures are studied in the present work. The XRD and SEM processes are used to characterize the sensing layer’s surface morphology which reveals the presence of nanoparticle in sensing layer. Further reducing the nanoparticle diameter by the addition of palladium (Pd) and platinum (Pt) for both the sensors (ZnO and WO{sub 3}) gives good results on sensitivity, operating temperature, response time and recovery time. Nanoparticle diameter for undoped WO{sub 3}, Pd-modified WO{sub 3} and Pt-modified WO{sub 3} based sensors is 11.8, 6 and 5.4 nm, whereas nanoparticle diameter for undoped, Pd-modified and Pt-modified ZnO based sensors is 20, 14 and 11 nm, respectively. Analysis of dynamic response of the sensors when exposed to different concentrations of ethanol vapour (from 500 to 10,000 ppm) and various temperatures indicate the improvement in sensitivity up to 77.2% for WO{sub 3} and 74.6% for ZnO based sensors.

77 NANOSCIENCE AND NANOTECHNOLOGY↗