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NASA NTRS2016

Flux Cancellation Leading to CME Filament Eruptions

Solar filaments are strands of relatively cool, dense plasma magnetically suspended in the lower density hotter solar corona. They trace magnetic polarity inversion lines (PILs) in the photosphere below, and are supported against gravity at heights of up to approx.100 Mm above the chromosphere by the magnetic field in and around them. This field erupts when it is rendered unstable, often by magnetic flux cancellation or emergence at or near the PIL. We have studied the evolution of photospheric magnetic flux leading to ten observed filament eruptions. Specifically, we look for gradual magnetic changes in the neighborhood of the PIL prior to and during eruption. We use Extreme Ultraviolet (EUV) images from the Atmospheric Imaging Assembly (AIA), and magnetograms from the Helioseismic and Magnetic Imager (HMI), both on board the Solar Dynamics Observatory (SDO), to study filament eruptions and their photospheric magnetic fields. We examine whether flux cancellation or/and emergence leads to filament eruptions. We find that continuous flux cancellation was present at the PIL for many hours prior to each eruption. We present two CME-producing eruptions in detail and find the following: (a) the pre-eruption filament-holding core field is highly sheared and appears in the shape of a sigmoid above the PIL; (b) at the start of the eruption the opposite arms of the sigmoid reconnect in the middle above the site of (tether-cutting) flux cancellation at the PIL; (c) the filaments first show a slow-rise, followed by a fast-rise as they erupt. We conclude that these two filament eruptions result from flux cancellation in the middle of the sheared field, and thereafter evolve in agreement with the standard model for a CME/flare filament eruption from a closed bipolar magnetic field [flux cancellation (van Ballegooijen and Martens 1989 and Moore and Roumelrotis 1992) and runaway tether-cutting (Moore et. al 2001)].

filament↗

NASA NTRS2017

Unusual Oxidative Limitations for Al-MAX Phases

Alumina-forming MAX phases are well-known for their excellent oxidation resistance, rivaling many metallic NiAl, NiCrAl, and FeCrAl counterparts and with upper temperature capability possible to approximately1400C. However a number of limitations have been emerging that need to be acknowledged to permit robust performance in demanding applications. Ti2AlC and Ti3AlC2 possess excellent scale adhesion, cyclic oxidation/moisture/volatility resistance, and TBC compatibility. However they are very sensitive to Al content and flux in order to maintain an exclusive Al2O3 scale without runaway oxidation of ubiquitous TiO2 transient scales. Accelerated oxidation has been shown to occur for Al-depleted, damaged, or roughened surfaces at temperatures less than 1200C. Conversely, Cr2AlC is less sensitive to transients, but exhibits volatile losses at 1200C or above if common Cr7C3 impurity phases are present. Poor scale adhesion is exhibited after oxidation at 1150C or above, where spallation occurs at the Cr7C3 (depletion zone) interface. Delayed spallation is significant and suggests a moisture-induced phenomenon similar to non-adherent metallic systems. Re-oxidation of this surface does not reproduce the initial pure Al2O3 behavior, but initiates a less-protective scale. Cr2AlC has also been shown to have good long term bonding with superalloys at 800C, but exhibits significant Beta-NiAl + Cr7C3 diffusion zones at 1100C and above. This may set limits on Cr2AlC as a high temperature TBC bond coat on Ni-based superalloys, while improving corrosion resistance in lower temperature applications.

oxidation resistance↗

NASA NTRS2017

A Long Look at MCG-5-23-16 with NuSTAR. I. Relativistic Reflection and Coronal Properties

MCG-5-23-16 was targeted in early 2015 with a half mega-second observing campaign using NuSTAR. Here we present the spectral analysis of these data sets along with an earlier observation and study the relativistic reflection and the primary coronal source. The data show strong reflection features in the form of both narrow and broad iron lines plus a Compton reflection hump. A cutoff energy is significantly detected in all exposures. The shape of the reflection spectrum does not change in the two years spanned by the observations, suggesting a stable geometry. A strong positive correlation is found between the cutoff energy and both the hard X-ray flux and spectral index. The measurements imply that the coronal plasma is not at the runaway electron-positron pair limit, and instead contains mostly electrons. The observed variability in the coronal properties is driven by a variable optical depth. A constant heating-to-cooling ratio is measured, implying that there is a feedback mechanism in which a significant fraction of the photons cooling the corona are due to reprocessed hard X-rays.

black hole physics â€“ galaxies: active â€“ galaxi↗

NASA NTRS2017

Planetesimals Born Big by Clustering Instability?

Roughly 100km diameter primitive bodies (today's asteroids and TNOs; [1]) are thought to be the end product of so-called "primary accretion". They dominated the initial mass function of planetesimals, and precipitated the onset of a subsequent stage, characterized by runaway gravitational effects, which proceeded onwards to planetary mass objects, some of which accreted massive gas envelopes. Asteroids are the parents of primitive meteorites; meteorite data suggest that asteroids initially formed directly from freelyfloating nebula particles in the mm-size range. Unfortunately, the process by which these primary 100km diameter planetesimals formed remains problematic. We review the most diagnostic primitive parent body observations, highlight critical aspects of the nebula context, and describe the issues facing various primary accretion models. We suggest a path forward that combines current scenarios of "turbulent concentration" (TC) and "streaming instabilities" (SI) into a triggered formation process we call clustering instability (CI). Under expected conditions of nebula turbulence, the success of these processes at forming terrestrial region (mostly silicate) planetesimals requires growth by sticking into aggregates in the several cm size range, at least, which is orders of magnitude more massive than allowed by current growth-by-sticking models using current experimental sticking parameters [2-4]. The situation is not as dire in the ice-rich outer solar system; however, growth outside of the snowline has important effects on growth inside of it [4] and at least one aspect of outer solar system planetesimals (high binary fraction) supports some kind of clustering instability.

Cuzzi, Jeffrey N.↗

NASA NTRS2017

Modeling a Packed Bed Reactor Utilizing the Sabatier Process

A numerical model is being developed using Python which characterizes the conversion and temperature profiles of a packed bed reactor (PBR) that utilizes the Sabatier process; the reaction produces methane and water from carbon dioxide and hydrogen. While the specific kinetics of the Sabatier reaction on the RuAl2O3 catalyst pellets are unknown, an empirical reaction rate equation1 is used for the overall reaction. As this reaction is highly exothermic, proper thermal control is of the utmost importance to ensure maximum conversion and to avoid reactor runaway. It is therefore necessary to determine what wall temperature profile will ensure safe and efficient operation of the reactor. This wall temperature will be maintained by active thermal controls on the outer surface of the reactor. Two cylindrical PBRs are currently being tested experimentally and will be used for validation of the Python model. They are similar in design except one of them is larger and incorporates a preheat loop by feeding the reactant gas through a pipe along the center of the catalyst bed. The further complexity of adding a preheat pipe to the model to mimic the larger reactor is yet to be implemented and validated; preliminary validation is done using the smaller PBR with no reactant preheating. When mapping experimental values of the wall temperature from the smaller PBR into the Python model, a good approximation of the total conversion and temperature profile has been achieved. A separate CFD model incorporates more complex three-dimensional effects by including the solid catalyst pellets within the domain. The goal is to improve the Python model to the point where the results of other reactor geometry can be reasonably predicted relatively quickly when compared to the much more computationally expensive CFD approach. Once a reactor size is narrowed down using the Python approach, CFD will be used to generate a more thorough prediction of the reactors performance.

Reactor↗

NASA NTRS2017

Planetesimals Born Big by Clustering Instability?

Asteroids↗

NASA NTRS2017

Understanding Breaks in Flare X-Ray Spectra: Evaluation of a Cospatial Collisional Return-Current Model

Hard X-ray (HXR) spectral breaks are explained in terms of a one-dimensional model with a cospatial return current. We study 19 flares observed by the Ramaty High Energy Solar Spectroscopic Imager with strong spectral breaks at energies around a few deka-keV, which cannot be explained by isotropic albedo or non-uniform ionization alone. We identify these breaks at the HXR peak time, but we obtain 8 s cadence spectra of the entire impulsive phase. Electrons with an initially power-law distribution and a sharp low-energy cutoff lose energy through return-current losses until they reach the thick target, where they lose their remaining energy through collisions. Our main results are as follows. (1) The return-current collisional thick-target model provides acceptable fits for spectra with strong breaks. (2) Limits on the plasma resistivity are derived from the fitted potential drop and deduced electron-beam flux density, assuming the return current is a drift current in the ambient plasma. These resistivities are typically 2-3 orders of magnitude higher than the Spitzer resistivity at the fitted temperature, and provide a test for the adequacy of classical resistivity and the stability of the return current. (3) Using the upper limit of the low-energy cutoff, the return current is always stable to the generation of ion-acoustic and electrostatic ion-cyclotron instabilities when the electron temperature is nine times lower than the ion temperature. (4) In most cases, the return current is most likely primarily carried by runaway electrons from the tail of the thermal distribution rather than by the bulk drifting thermal electrons. For these cases, anomalous resistivity is not required.

Alaoui, Meriem↗

NASA NTRS2018

Simplified Aid for Extra-Vehicular Activity Rescue (SAFER) Battery Assessment

In 2013, the Boeing Company model 787-8 Dreamliner commercial aircraft experienced three catastrophic lithium (Li) battery failures. The cause of each failure resulted in a single-cell thermal runaway (TR) condition, which propagated to adjacent battery cells. Two of the failures involved rechargeable lithium-ion (Li-Ion) batteries, and the third event involved a nonrechargeable lithium-manganese dioxide (Li-MnO2) battery. In response to these Li battery failures, the NASA Engineering and Safety Center (NESC) approved a technical assessment of the International Space Station Simplified Aid for Extra-Vehicular Activity Rescue (SAFER) Li non-rechargeable battery. This assessment was conducted to evaluate the SAFER Li nonrechargeable battery safety design features against Boeing 787 Dreamliner Li battery failure lessons learned. Specifically, this investigation focused on assessing the severity of a SAFER battery TR hazard conditions.

Iannello, Christopher J.↗

NASA NTRS2018

Trends in 18650 Lithium-Ion Battery Cell Safety for Spacecraft Applications

Highly popular due to their high energy density lithium-ion battery cells have increased in energy density approximately 2.5 times since their commercial debut in 1991. As a result, the hazard severity of a sudden inadvertent release of stored energy has greatly increased. The high energy density of lithium-ion battery cells coupled with the flammable toxic electrolytes they contain and unique failure modes can lead to a potentially catastrophic thermal runaway. This can result in spewing flames even while setting on a shelf unused. The metal oxide cathodes in lithium-ion battery cells can release their oxygen into the cells when they overheat. There is enough oxygen contained in the metal oxide cathodes to combust up to 20 percent of the electrolytes in the cells without any outside oxygen sources. These cells can therefore be viewed as miniature rocket motors capable of venting a considerable blow-torch type flame and up to 2.5 liters of hot flammable toxic gases per cell. This presents special challenges for spaceflight safety. In this paper we will examine roots causes of 18650 lithium-ion battery cell failures and how to best mitigate them at the cell and battery assembly levels. We will also look at some promising future trends that could yield both much greater stored energy and safety.

Allison, Gregory H.↗

NASA NTRS2018

Guidelines for Safe, High Performing Li-Ion Battery Designs for Manned Vehicles

New design features and test methods are in development at NASA to take advantage of the newest high power and energy dense commercial Li-ion cell designs and to achieve passively thermal runaway (TR) propagation resistant (PPR) designs for manned missions requiring high power/voltage. The goal is to minimize the parasitic mass and volume of the battery components; thus reaching a balance between high battery specific power (W/kg) and energy (Wh/kg) as well as power (W/L) and energy density (Wh/L). Current 18650 cell designs achieve greater than 275 Wh/kg, greater than 725 Wh/L, but present high risks of side wall breaching during TR which can defeat many other safety features resulting in nearly immediate TR propagation. This work seeks to better understand the phenomena of cell side wall breaches and to determine the effectiveness of promising battery design features for achieving safe, high performing battery designs for high voltage/power applications.

Darst, John J.↗

NASA NTRS2017

Habitable Moist Atmospheres on Terrestrial Planets near the Inner Edge of the Habitable Zone Around M Dwarfs

Terrestrial planets in the habitable zones (HZs) of low-mass stars and cool dwarfs have received significant scrutiny recently. Transit spectroscopy of such planets with the James Webb Space Telescope (JWST) represents our best shot at obtaining the spectrum of a habitable planet within the next decade. As these planets are likely tidally locked, improved 3D numerical simulations of such planetary atmospheres are needed to guide target selection. Here we use a 3D climate system model, updated with new water-vapor absorption coefficients derived from the HITRAN 2012 database, to study ocean-covered planets at the inner edge of the HZ around late M to mid- K stars (2600 K less than or equal to T(sub eff) less than or equal to 4500 K). Our results indicate that these updated water-vapor coefficients result in significant warming compared to previous studies, so the inner HZ around M dwarfs is not as close as suggested by earlier work. Assuming synchronously rotating Earth-sized and Earth-mass planets with background 1 bar N2 atmospheres, we find that planets at the inner HZ of stars with T(sub eff) greater than 3000 K undergo the classical ''moist greenhouse'' (H2O mixing ratio greater than 10(exp -3) in the stratosphere) at significantly lower surface temperature (approx. 280 K) in our 3D model compared with 1D climate models (approx. 340 K). This implies that some planets around low-mass stars can simultaneously undergo water loss and remain habitable. However, for stars with T(sub eff) less than or equal to 3000 K, planets at the inner HZ may directly transition to a runaway state, while bypassing the moist greenhouse water loss entirely. We analyze transmission spectra of planets in a moist greenhouse regime and find that there are several prominent H2O features, including a broad feature between 5 and 8 micron, within JWST MIRI instrument range. Thus, relying only on standard Earth-analog spectra with 24 hr rotation period around M dwarfs for habitability studies will miss the strong H2O features that one would expect to see on synchronously rotating planets around M dwarf stars, with JWST.

Kopparapu, Ravi kumar↗

NASA NTRS2014

On the Frequency of Potential Venus Analogs from Kepler Data

The field of exoplanetary science has seen a dramatic improvement in sensitivity to terrestrial planets over recent years. Such discoveries have been a key feature of results from the Kepler mission which utilizes the transit method to determine the size of the planet. These discoveries have resulted in a corresponding interest in the topic of the Habitable Zone and the search for potential Earth analogs. Within the solar system, there is a clear dichotomy between Venus and Earth in terms of atmospheric evolution, likely the result of the large difference (approximately a factor of two) in incident flux from the Sun. Since Venus is 95% of the Earth's radius in size, it is impossible to distinguish between these two planets based only on size. In this Letter we discuss planetary insolation in the context of atmospheric erosion and runaway greenhouse limits for planets similar to Venus. We define a "Venus Zone" in which the planet is more likely to be a Venus analog rather than an Earth analog. We identify 43 potential Venus analogs with an occurrence rate (η♀) of 0.32 (+0.05/-0.07) and 0.45 (+0.06/-0.09) for M dwarfs and GK dwarfs, respectively.

planetary systems↗

NASA NTRS2019

Metallized Plastic Current Collectors

Metallized plastic current collectors are an innovation patented by the Soteria Battery Innovation Group with the promise of isolating active material involved in an internal short by vaporizing and isolating the short from the rest of the cell electrode jellyroll or stack. Partnering with NREL, UCL, Coulometrics, and Soteria, NASA is leading a research effort into demonstrating the merits and understanding the phenomena of this safety innovation using prototype 18650 cylindrical cells vs control cells with standard metal foil current collectors. Cells with and without the plastic collector, with and without the on-demand internal short circuit device, and with polymer or cellulose separators were made. Safety evaluations were done with driving cells into thermal runaway (TR) with thermal and nail penetration triggers while inside our TR calorimeter and with ultra high speed X-ray videography provided at Synchrotrons. Preliminary results suggests that the thermally unstable plastic current collector innovation has great promise for preventing TR or reducing the severity of the TR output.

Li-ion cell↗

NASA NTRS2019

Characterization of Laptop Fires in Spacecraft

An accidental fire involving the Lithium-Ion (Li-ion) battery in a laptop computer is one of the most likely fire scenarios on-board a spacecraft. These fires can occur from a defect in the battery that worsens with time, over-charging the battery and leading to failure or accidental damage caused by thermal runaway. While this is a relatively likely fire scenario, very little is known about the how a laptop computer fire would impact a sealed spacecraft. The heat release would likely cause a pressure rise, possibly exceeding the pressure limit of the vehicle and causing a relief valve to open. The combustion products from the fire could pose a short-term and long-term health hazard to the crew and the fire itself could cause injury to the crew and damage to the spacecraft. Despite the hazard posed by a laptop fire, there is little quantitative data on the fire size, heat release and toxic product formation. This paper presents the results of initial attempts to quantify the fire resulting from a failed laptop fire tested at the NASA White Sands Test Facility (WSTF). The data from the testing is useful to attempt to determine the fire size and characteristics such as maximum heat release rate, total heat release, maximum temperatures and fire duration are determined. Using existing models and correlations for fires, the measured fire characteristics are extrapolated to laptop fires on a vehicle the approximate size of the Orion spacecraft.

Padilla, Rosa E.↗

NASA NTRS2019

Simulated Phase-dependent Spectra of Terrestrial Aquaplanets in M Dwarf Systems

Orbital phase-dependent variations in thermal emission and reflected stellar energy spectra can provide meaningful constraints on the climate states of terrestrial extrasolar planets orbiting M dwarf stars. Spatial distributions of water vapor, clouds, and surface ice are controlled by climate. In turn, water, in each of its thermodynamic phases, imposes significant modulations to thermal and reflected planetary spectra. Here we explore these characteristic spectral signals, based on 3D climate simulations of Earth-sized aquaplanets orbiting M dwarf stars near the habitable zone. By using 3D models, we can self-consistently predict surface temperatures and the location ofwater vapor, clouds, and surface ice in the climate system. Habitable zone planets in M dwarf systems are expected to be in synchronous rotation with their host star and thus present distinct differences in emitted and reflected energy fluxes depending on the observed hemisphere. Here we illustrate that icy, temperate, and incipient runaway greenhouse climate states exhibit phase-dependent spectral signals that enable their characterization.

Wolf, E. T.↗

NASA NTRS2019

Development of Solid State Electrolytes for Li-Metal Based High Capacity Battery

NASA future missions demand safe, high specific energy (>400 Wh/kg) batteries. Current state-of-the-art (SOA) lithium-ion batteries (LIBs) can only provide ~150-200 Wh/kg in energy capacity, which is unable to meet NASA's future energy goals, and also pose safety issues due to the use of liquid flammable electrolyte. There are intense on-going development activities to increase battery energy density. The use of Li metal as an anode material has emerged as one highly attractive option for achieving high-energy, next generation batteries. This is because Li has many advantages. It is the lightest metal, but also has the highest theoretical capacity. It also has the lowest potential, which boosts whole cell voltage, and Li metal is 100% active material and requires no binder. Thus, Li metal is an ideal anode material for high energy battery chemistries. Lithium metal based advanced battery chemistries are envisioned to be mission enhancing and, in many cases, mission enabling for future space and aeronautic applications. However, the reliable use of this exceptionally high capacity anode in a commercial rechargeable battery has not been achieved due to safety and reliability concerns resulting from thermal runaway and short-circuit issues due to dendritic growth on the Li metal anode from lithium plating during charge-discharge cycles. A solid state electrolyte, such as garnet/ceramic or solid polymer nanocomposite electrolyte, is a promising approach to make Li metal safely cycling. The solid state electrolyte is non-flammable and eliminates leakage and fire hazard by replacing the liquid flammable electrolyte. However, the low-ionic conductivity and high interfacial impedance are the key issues to be overcome. In this presentation, the research activities on solid state electrolyte development funded by the NASA Advanced Energy Storage System program and by the NASA Center Innovative Fund will be presented, and the progress and results will be also discussed.

Wu, James J.↗

NASA NTRS2019

Hazardous Product Detection and Environmental Clean-up Removal in Spacecraft Vehicles from Fire Induced Li-Ion Fires

A fire on-board the International Space Station (ISS) resulting from a commercial Surface Pro tablet Lithium-Ion (Li-ion) battery can be detrimental to the spacercraft and the astronauts. The Spacecraft Fire Safety Demonstration (Saffire) program is focused on identifying and quantifying the risks that potentially arise inside a space vehicle by conducting large fire experiments inside the Cygnus cargo vehicle upon re-entry to Earth. The potential candidate that will be flown on the ISS is a 4- cell Li-ion battery pack Surface Pro tablet (42 Wh). The tablets were tested at the White Sands Test Facility (WSTF) using a localized heating method to emulate the failing mechanism that leads the unit into thermal runaway. Measurements inside the test chamber were performed on aerosol mass concentrations and for specific toxic products (i.e. from CO, HCN, HCl and CO2). These toxic products depend on the size of the fire and energy content of the tablet. Comparisons will be made with the Dell XPS (97 Wh). The concentrations are then used to extrapolate to laptop fires on a vehicle at the approximate volumetric size of the Orion spacecraft. The presentation provides an analysis on the detection capability and the response time to trigger fire alarms aboard a vehicle by using the mass concentration levels. These results will consider the rate at which the life support system is able to filter the atmosphere in order to provide a hazardous free environment.

Padilla, Rosa E.↗

NASA NTRS2020

Possible Climate Histories of Venus Type Worlds

There are two well-known scenarios for Venus’ climate evolution. In one Venus had a long-lived magma ocean phase in its first 100Myr with a steam and CO2 dominated atmosphere. The faint young sun with its high XUV flux would cause photodissociation of the steam atmosphere and hydrodynamic escape would cause most of the hydrogen to escape & left-over oxygen would be absorbed by the magma ocean. Hence Venus would have started out hot and dry and the high D/H ratio measured by Pioneer Venus would be from this period of water loss. The other scenario is that Venus’ magma ocean lifetime would have been roughly the same length of time as Earth’s (~1Myr) and water would have condensed on its surface in its early history and had a short period of habitability before increasing solar insolation through time drove it into a runaway greenhouse. However, results from 2016 showed that if Venus remains in the slowly rotating climate dynamics regime (as seen in exoplanet related climate studies) its cloud albedo feedback would have kept it temperate for possibly billions of years. The only way to confirm which one of these scenarios occurred for Venus is to visit it and make the necessary measurements of noble and volatile gases. But exoplanet observations of young exo-Venus type worlds around young F,G,K dwarf stars may constrain which scenario is more probable for a population of such planets. We present a vision of Venus’ climate history that places it and its exoVenus cousins in an ‘Optimistic Venus Zone’ for ~3 billion years within the conventionally named ‘Venus Zone’ and hence encourage the exoplanet communit as possible habitable environments.

Way, M. J.↗