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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42

Disentangling Coexisting Structural Order Through Phase Lock-In Analysis of Atomic-Resolution STEM Data

As a real-space technique, atomic-resolution STEM imaging contains both amplitude and geometric phase information about structural order in materials, with the latter encoding important information about local variations and heterogeneities present in crystalline lattices. Such phase information can be extracted using geometric phase analysis (GPA), a method which has generally focused on spatially mapping elastic strain. Here we demonstrate an alternative phase demodulation technique and its application to reveal complex structural phenomena in correlated quantum materials. As with other methods of image phase analysis, the phase lock-in approach can be implemented to extract detailed information about structural order and disorder, including dislocations and compound defects in crystals. Extending the application of this phase analysis to Fourier components that encode periodic modulations of the crystalline lattice, such as superlattice or secondary frequency peaks, we extract the behavior of multiple distinct order parameters within the same image, yielding insights into not only the crystalline heterogeneity but also subtle emergent order parameters such as antipolar displacements. When applied to atomic-resolution images spanning large (~0.5 × 0.5 μm 2 ) fields of view, this approach enables vivid visualizations of the spatial interplay between various structural orders in novel materials.

74 ATOMIC AND MOLECULAR PHYSICS↗

Spinodal enhancement of fluctuations in nucleus-nucleus collisions

Subensemble Acceptance Method (SAM) [1, 2] is an essential link between measured event-by-event fluctuations and their grand canonical theoretical predictions such as lattice QCD. The method allows quantifying the global conservation law effects in fluctuations. In its basic formulation, SAM requires a sufficiently large system such as created in central nucleus-nucleus collisions and sufficient space-momentum correlations. Directly in the spinodal region of the First Order Phase Transition (FOPT) different approximations should be used that account for finite size effects. Thus, we present the generalization of SAM applicable in both the pure phases, metastable and unstable regions of the phase diagram [3]. Obtained analytic formulas indicate the enhancement of fluctuations due to crossing the spinodal region of FOPT and are tested using molecular dynamics simulations. A rather good agreement is observed. Using transport model calculations with interaction potential we show that the spinodal enhancement of fluctuations survives till the later stages of collision via the memory effect [4]. However, at low collision energies the space-momentum correlation is not strong enough for this signal to be transferred to second and third order cumulants measured in momentum subspace. This result agrees well with recent HADES data on proton number fluctuations at $\sqrt{S_{NN}}$ = 2.4 GeV which are found to be consistent with the binomial momentum space acceptance [5].

Poberezhnyuk, Roman↗

Satellite Power Systems (SPS) concept definition study, exhibit C. Volume 2, part 2: System engineering, cost and programmatics

Volume 2, Part 2, of a seven volume Satellite Power Systems (SPS) report is presented. Part 2 covers cost and programmatics and is divided into four sections. The first section gives illustrations of the SPS reference satellite and rectenna concept, and an overall scenario for SPS space transportation involvement. The second section presents SPS program plans for the implementation of PHASE C/D activities. These plans describe SPS program schedules and networks, critical items of systems evolution/technology development, and the natural resources analysis. The fourth section presents summary comments on the methods and rationale followed in arriving at the results documented. Suggestions are also provided in those areas where further analysis or evaluation will enhance SPS cost and programmatic definitions.

Hanley, G. M.↗

Evaluation criteria for commercially oriented materials processing in space proposals

An approach and criteria for evaluating NASA funded experiments and demonstrations which have commercial potential were developed. Methods for insuring quick initial screening of commercial proposals are presented. Recommendations are given for modifying the current evaluation approach. New criteria for evaluating commercially orientated materials processing in space (MPS) proposals are introduced. The process for selection of qualified individuals to evaluate the phases of this approach and criteria is considered and guidelines are set for its implementation.

Moore, W. F.↗

Cluster analysis of multiple planetary flow regimes

A modified cluster analysis method was developed to identify spatial patterns of planetary flow regimes, and to study transitions between them. This method was applied first to a simple deterministic model and second to Northern Hemisphere (NH) 500 mb data. The dynamical model is governed by the fully-nonlinear, equivalent-barotropic vorticity equation on the sphere. Clusters of point in the model's phase space are associated with either a few persistent or with many transient events. Two stationary clusters have patterns similar to unstable stationary model solutions, zonal, or blocked. Transient clusters of wave trains serve as way stations between the stationary ones. For the NH data, cluster analysis was performed in the subspace of the first seven empirical orthogonal functions (EOFs). Stationary clusters are found in the low-frequency band of more than 10 days, and transient clusters in the bandpass frequency window between 2.5 and 6 days. In the low-frequency band three pairs of clusters determine, respectively, EOFs 1, 2, and 3. They exhibit well-known regional features, such as blocking, the Pacific/North American (PNA) pattern and wave trains. Both model and low-pass data show strong bimodality. Clusters in the bandpass window show wave-train patterns in the two jet exit regions. They are related, as in the model, to transitions between stationary clusters.

Mo, Kingtse↗

Active control synthesis for flexible space structures excited by persistent disturbances

Both classical and state-space synthesis methods for active control of flexible space structures in the presence of persistent disturbances are presented. The methods exploit the so-called internal model principle for asymptotic disturbance rejection. A generic example of flexible space structures is used to illustrate the simplicity of the proposed design methodologies. The concept of a disturbance rejection filter dipole is introduced from a classical control viewpoint. It is shown that the proposed design methods will invariably make use of non-minimum-phase compensation for a class of noncolocated control problems. The need for tradeoffs between performance and parameter robustness is discussed.

Wie, Bong↗

New approaches in interferometric SAR data processing

It is well established that interferometric synthetic aperture radar (SAR) images can be inverted to perform surface elevation mapping. Among the factors critical to the mapping accuracy are registration of the interfering SAR images and phase unwrapping. A novel registration algorithm is presented that determines the registration parameters through optimization. A new figure of merit is proposed that evaluates the registration result during the optimization. The phase unwrapping problem is approached through a new method involving fringe line detection. The algorithms are tested with two SEASAT SAR images of terrain near Yellowstone National Park. These images were collected on Seasat orbits 1334 and 1420, which were very close together in space, i.e., less than 100 m. The resultant elevation map is compared with the USGS digital terrain elevation model.

Lin, Qian↗

Conservative Analytical Collision Probability for Design of Orbital Formations

The literature offers a number of approximations for analytically and/or efficiently computing the probability of collision between two space objects. However, only one of these techniques is a completely analytical approximation that is suitable for use in the preliminary design phase, when it is more important to quickly analyze a large segment of the trade space than it is to precisely compute collision probabilities. Unfortunately, among the types of formations that one might consider, some combine a range of conditions for which this analytical method is less suitable. This work proposes a simple, conservative approximation that produces reasonable upper bounds on the collision probability in such conditions. Although its estimates are much too conservative under other conditions, such conditions are typically well suited for use of the existing method.

Carpenter, J. Russell↗

Conservative Analytical Collision Probabilities for Orbital Formation Flying

The literature offers a number of approximations for analytically and/or efficiently computing the probability of collision between two space objects. However, only one of these techniques is a completely analytical approximation that is suitable for use in the preliminary design phase, when it is more important to quickly analyze a large segment of the trade space than it is to precisely compute collision probabilities. Unfortunately, among the types of formations that one might consider, some combine a range of conditions for which this analytical method is less suitable. This work proposes a simple, conservative approximation that produces reasonable upper bounds on the collision probability in such conditions. Although its estimates are much too conservative under other conditions, such conditions are typically well suited for use of the existing method.

Carpenter, J. Russell↗

Transit Reconfigurable Exerciser - Intern Exit Abstract

The Transit Resistive Exerciser (TREX) was developed during a 16 week period in which a clutch device filled with smart material was built and began the testing phase. The clutch serves as a passive method of creating resistance. When paired with a series of springs, the device creates a rowing machine also capable of resistive exercise configurations. The device has loading profiles similar to the exercise devices used on the International Space Station today. The prototype created was designed in a modular fashion to support parallel development on various aspects of the project. Hardware and software are currently in development and make use of commercially available parts. Similar technologies have been used in the automotive industry but have never been explored in the context of countermeasure systems for space flight. If the work done leads to successful testing and further development, this technology has the potential to cut the size and weight of exercise devices by an order of magnitude or more.

Gebara, Christine A.↗

Knowledge Base for Distributed Spacecraft Mission Design Using the Trade-Space Analysis Tool for Constellations (TAT-C)

Opportunities for multi-point measurements, greater revisit frequency, failure robustness, and improved cost effectiveness motivate consideration of Distributed Spacecraft Missions (DSMs) for future Earth science missions. However, careful analysis is required to assess the distributed sensing capabilities of a constellation compared to more mature monolithic spacecraft while also considering other important dimensions such as cost and risk. The large combinatorial DSM design space limits existing mission analysis tools and exploration methods which emphasize monolithic design variables. The Trade-space Analysis Tool for Constellations (TAT-C) under development at Goddard seeks to enumerate and evaluate alternative mission architectures to minimize cost and maximize scientific return for pre-defined goals during pre-phase A analysis.Similar to other model-centric engineering efforts, efficient data management is a significant challenge for DSM mission analysis. In TAT-C, a Knowledge Base (KB) is envisioned as a cumulative central repository of information and meta-information about DSMs. Initial KB concepts store related data for reuse within or across mission analyses; however, over time, the KB is envisioned to be an important layer to coordinate actions of both human analysts and automated design agents to search a large design space for desirable mission alternatives. Preliminary KB research builds on a modern web technology stack to provide the following functionality: 1) storage of trade-space search requests which set requirements and constraints for DSM concepts, 2) storage of analysis results which quantify performance metrics for evaluated DSM concepts, 3) a RESTful application programming interface (API) for scripted access to data from TAT-C modules, 4) web-based graphical user interface (GUI) for manual access to underlying data, and 5) access control and management restrictions relevant to data protection and security. These efforts have culminated in a prototype KB used by the research team during TAT-C development to assess opportunities for future work.

Pattern Recognition↗

Resources from Water-Rock Interactions for Future Human Exploration of Mars

One of the most exciting endeavors in modern space exploration is extended human exploration of the Moon and Mars. We have entered a new phase in the human venture where we seek to expand our "...presence deeper into space and to the Moon for sustainable long-term exploration and utilization". With this endeavor come new challenges. Among them is the requirement for In Situ Resource Utilization (ISRU) methods to supplement or replace materials transported from Earth. The energy required to leave Earth's gravity well is immense, as is well illustrated by the nearly 3000 metric ton Saturn V required to deliver a payload of less than 50 metric tons to the Moon during the Apollo era. Much of this mass is propellant. Launch vehicles from Earth into space are generally 85 to 95% propellant (oxidizer + fuel) by mass. Potential ascent vehicles from Mars would also need to be approximately 80% propellant by mass to return to Earth. ISRU of fuel reactants could exchange delivered fuel mass directly for payload mass on the order of several metric tons. Devices like MOXIE are being designed to address the oxidizer component. However, 40% of the propellant mass in an ascent vehicle is the fuel reactant, and ISRU of this component has not been addressed for Mars or the Moon. Toward addressing this need, we have begun to develop and optimize methods to generate and recover fuel components, including H2, from Lunar and Martian relevant materials as potential in situ resources for future extended human missions. Hydrogen is an ideal resource to target. Not only can H2 be used directly as part of a propellant, it can also be used as a component in other fuels, such as methane. It is useful agriculturally for fixing nitrogen and can be oxidized to produce heat and water.

Adcock, C. T.↗

Fast and flexible control of beam longitudinal phase space for high-repetition-rate x-ray free-electron lasers

The wide-ranging requirements for the photon properties from multiple beamlines in superconducting based free-electron lasers (FELs) demand more challenging beam manipulation techniques. Shot-by-shot control of electron beam bunch length and peak current at high repetition rate up to megahertz is highly desired. In this paper, we present a comprehensive study of a method based on a 2-m-long normal conducting radio-frequency cavity to achieve fast and flexible control of beam compression and realize the full potential of the facility, including theoretical analysis, beam dynamics simulations, and conceptual cavity design for the Linac Coherent Light Source II and its high-energy upgrade. We illustrate the physical mechanism of the chirping cavity on the control of the final beam compression and propose methods to lower the requirements for the cavity parameters. The application of this method will allow tailored photon properties of individual beamlines to optimize their performance and drastically improve the multiplexing capabilities of a high-repetition rate FEL facility.

42 ENGINEERING↗

Implementation and extension of the impulse transfer function method for future application to the space shuttle project. Volume 2: Program description and user's guide

The data processing procedures and the computer programs were developed to predict structural responses using the Impulse Transfer Function (ITF) method. There are three major steps in the process: (1) analog-to-digital (A-D) conversion of the test data to produce Phase I digital tapes (2) processing of the Phase I digital tapes to extract ITF's and storing them in a permanent data bank, and (3) predicting structural responses to a set of applied loads. The analog to digital conversion is performed by a standard package which will be described later in terms of the contents of the resulting Phase I digital tape. Two separate computer programs have been developed to perform the digital processing.

Patterson, G.↗

Diversity of Energy Generation and Storage Methods on the Lunar Surface

Solar light, solar wind, differences between temperatures of the lunar surface, solar photosphere, and deep space, as well as noticeable changes of surface temperature in the absence of atmosphere provide opportunities for energy production and storage on the Moon using generators ranging from solar panels and thermocouples to devices using phase transitions or magnetism. There are multiple and diverse possibilities for energy generation and storage. Compositions of the relevant materials can be compared to abundances of chemical elements in lunar regolith.

Energy↗

Generation of Large-Volume High-Pressure Plasma by Spatio-Temporal Control of Space Charge

Due to the fundamental limitations of scaling, very little progress has been made towards achieving a large-volume dense non-equilibrium plasma near atmospheric pressures. Commercially available state-of-the art glow-like atmospheric plasma devices for industrial applications are either narrow tubes or wide slits with narrow openings. Often multiple sources are put together in various configurations to process larger surfaces. The traditional methods of exciting electrodes create spatially fixed electric fields. As a result, the space charge at atmospheric pressure tends to be spatially confined resulting in non-uniformity which eventually leads to instability as the discharge is scaled. Theoretical work done under this project showed that it is possible to generate a spatially rotating electric field by exciting a set of electrodes with phase staggered sinusoidal waveforms. The modeling and simulations were done using plasma fluid models. It was shown that such a field can produce a uniform plasma. At the conclusion of the project, experimental proof of concept with an eight-electrode system in various gases (Air, Helium and Argon) was demonstrated. Power measurements and spectral investigation show that the concept can be used to generate a uniform stable plasma. This plasma source has the potential of opening new applications of nonthermal plasma including combustion of carbon-free fuel. The current limitation of the proposed method in scaling to higher volume and pressure is the need for multiple high voltage amplifiers.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Estimation of End-of-Life Solar Absorptivity for Complex, Multi-Phased Space Missions

Solar absorptivity degradation over time is an important contributor to the thermal performance of a spacecraft at the end of its life. When environments are complex and include many different factors known to impact solar absorptivity degradation, such as UV, charged particles, contamination, or lunar dust coverage, combining data from several different studies can be done to estimate total degradation. While the most conservative way is to stack delta absorptivity from each factor to come up with a total delta, this may be overly conservative for long or complex missions with multiple mission phases. As absorptivity increases the rate of degradation decreases, and synergistic effects need to be taken into account. In this report an alternate method is proposed using Gateway materials as an example. This method determines which environmental factor will be dominant at what time (such as contamination or charged particles) and uses that degradation rate for that mission phase. For the next mission phase, the new absorptivity can be used instead of the original BOL absorptivity to determine degradation rate. This approach prevents overestimating optical degradation when considering degradation from interconnected sources.

thermo-optical properties↗

A Free‐Radical Prompted Barrierless Gas‐Phase Synthesis of Pentacene

Abstract A representative, low‐temperature gas‐phase reaction mechanism synthesizing polyacenes via ring annulation exemplified by the formation of pentacene (C 22 H 14 ) along with its benzo[ a ]tetracene isomer (C 22 H 14 ) is unraveled by probing the elementary reaction of the 2‐tetracenyl radical (C 18 H 11 . ) with vinylacetylene (C 4 H 4 ). The pathway to pentacene—a prototype polyacene and a fundamental molecular building block in graphenes, fullerenes, and carbon nanotubes—is facilitated by a barrierless, vinylacetylene mediated gas‐phase process thus disputing conventional hypotheses that synthesis of polycyclic aromatic hydrocarbons (PAHs) solely proceeds at elevated temperatures. This low‐temperature pathway can launch isomer‐selective routes to aromatic structures through submerged reaction barriers, resonantly stabilized free‐radical intermediates, and methodical ring annulation in deep space eventually changing our perception about the chemistry of carbon in our universe.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗