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At least 757 records · Page 42

SHAPES - Spatial, High-Accuracy, Position-Encoding Sensor for multi-point, 3-D position measurement of large flexible structures

An electro-optical position sensor for precise simultaneous measurement of the 3-D positions of multiple points on large space structures is described. The sensor data rate is sufficient for most control purposes. Range is determined by time-of-flight correlation of short laser pulses returned from retroreflector targets using a streak tube/CCD detector. Angular position is determined from target image locations on a second CCD. Experimental verification of dynamic ranging to multiple targets is discussed.

Nerheim, N. M↗

Demonstration of a Modular, Scalable, Laser Communication Terminal for Manned Spaceflight Missions

Free-space laser communication systems are increasingly implemented on state of the art satellites for their high-speed connectivity. This work outlines the design, analysis and test of the Modular, Agile, Scalable Optical Terminal (MAScOT) we have developed to support Low-Earth Orbit (LEO) to deep-space communication links. In LEO, the MAScOT will be implemented on the International Space Station to support the Integrated Laser Communications Relay Demonstration (LCRD) LEO User Modem and Amplifier Terminal (ILLUMA-T) program. ILLUMA-T’s overarching objective is to demonstrate high bandwidth data transfer between LEO and a ground station via a geosynchronous (GEO) relay satellite. Outside of GEO, MAScOT will also be implemented on the Artemis-II mission to demonstrate high data rate optical communications to and from the moon as part of the Orion EM-2 Optical Communications (O2O) program. Both missions leverage the same modular architecture despite varying structural, thermal, and optical requirements. To achieve sufficient performance, the optical terminal relies on a coarse/fine nested tracking loop to realize sub-arcsecond pointing across +/- 120 deg elevation and +/- 175 deg azimuth field of regard. An integrated analysis of the MAScOT in support of both missions will be outlined in addition to scalable versions of this terminal for future missions.

Steven R. Gillmer↗

Demonstration of a Modular, Scalable, Laser Communication Terminal for Manned Spaceflight Missions

Free-space laser communication systems are increasingly implemented on state of the art satellites for their high-speed connectivity. This work outlines a demonstration of the Modular, Agile, Scalable Optical Terminal(MAScOT) we have developed to support Low-Earth Orbit (LEO) to deep-space communication links. In LEO, the MAScOT will be implemented on the International Space Station to support the Integrated Laser Communications Relay Demonstration (LCRD) LEO User Modem and Amplifier Terminal (ILLUMA-T) program. ILLUMA-Ts overarching objective is to demonstrate high bandwidth data transfer between LEO and a ground station via a geosynchronous (GEO) relay satellite. Outside of GEO, MAScOT will also be implemented on the Artemis-II mission to demonstrate high data rate optical communications to and from the moon as part of theOrion EM-2 Optical Communications (O2O) program. Both missions leverage the same modular architecture despite varying structural, thermal, and optical requirements. To achieve sufficient performance, the optical terminal relies on a nested tracking loop to realize sub-arcsecond pointing across±120◦elevation and±175◦azimuth field of regard.

optical communications↗

Ternary molecular switching in a single-crystal optical actuator with correlated crystal strain

A growing portfolio of single-crystal optical actuators is forging a new class of photonic materials that hold prospects for quantum technologies. Ruthenium-based complexes that exhibit this phenomenon via SO 2 -linkage photoisomerisation are of particular interest since they display multiple metastable states, once induced by green light; yet, complete photoconversion into each SO 2 -isomeric state is rarely achieved. We discover a new complex, trans-[Ru(SO 2 )(NH 3 ) 4 (4-bromopyridine)]tosylate 2 , that produces 100% photoconverted η 1 -OSO isomeric crystal structures at 90 K, which fully transition into η 2 -(OS)O photoisomers upon warming to 100 K, while the dark-state η 1 -SO 2 structure is wholly recovered by heating the crystal to room temperature. Crystal structures and optical-absorption profiles of each state are captured via in-situ light-induced single-crystal X-ray diffraction and optical-absorption spectroscopy. Results show that both photoisomeric species behave as optical switches, but with distinct optical properties. The photoisomerisation process causes thermally-reversible micro- and nanoscopic crystal strain, as characterised by optical microscopy and in-situ light-induced atomic-force microscopy.

actuators↗

Linear analysis of opto-mechanical systems

A general framework is presented for the matrix-form, linear optical model analysis of controlled optomechanical systems; the models are conjoined with linear models of structures and controls to compute system performance as a function of optics, structures, and control parameters. Covariance analysis, optimization, and estimation/simulation are used. Attention is given to a tolerancing example for the Hubble Space Telescope's Wide Field and Planetary Camera, which involves the creation of a linear model of residual pupil shear.

Redding, David C.↗

Glass sample preparation and performance investigations

This final report details the work performed under this delivery order from April 1991 through April 1992. The currently available capabilities for integrated optical performance modeling at MSFC for large and complex systems such as AXAF were investigated. The Integrated Structural Modeling (ISM) program developed by Boeing for the U.S. Air Force was obtained and installed on two DECstations 5000 at MSFC. The structural, thermal and optical analysis programs available in ISM were evaluated. As part of the optomechanical engineering activities, technical support was provided in the design of support structure, mirror assembly, filter wheel assembly and material selection for the Solar X-ray Imager (SXI) program. As part of the fabrication activities, a large number of zerodur glass samples were prepared in different sizes and shapes for acid etching, coating and polishing experiments to characterize the subsurface damage and stresses produced by the grinding and polishing operations. Various optical components for AXAF video microscope and the x-ray test facility were also fabricated. A number of glass fabrication and test instruments such as a scatter plate interferometer, a gravity feed saw and some phenolic cutting blades were fabricated, integrated and tested.

Johnson, R. Barry↗

B2 1141 + 37 - A giant radio galaxy with remarkable radio and optical properties

Observations of the giant radio galaxy B2 1141+37, which has a widely separated two-component radio structure and is optically identified with a tight chain of galaxies, are reported. The source was observed at 4900 MHz with the VLA at an effective integration time of 17 min. The map obtained shows two radio lobes with maxima coinciding with those in a previous 1415 MHz map and intensities about 1.5 times smaller than those obtained by extrapolating the spectrum defined by the flux density at 408 and 1415 MHz. Measurements of the redshifts of the two brightest galaxies identified with the radio source with an image intensified dissector scanner result in values of 0.1145 and 0.1155, which imply, with a Hubble constant of 50 km/sec per Mpc, a distance of 687 Mpc to the radio source and a separation of 1.0 Mpc between the lobes making it one of the largest radio sources known.

Ulrich, M. H.↗

The structure of the BAL QSO 1700 + 518

The paper presents 0.5-arcsec-resolution optical images of the low-redshift, bright, broad-absorption-line QSO 1700 + 518. A bright arc 2 arcsec is found to the NE of the nucleus which is redder than the surrounding host galaxy. There is also a faint radial structure to the SE, which is aligned with the core radio structure. The principal radio structure is a slightly resolved component coincident with the optical nucleus and an unresolved lobe 1 arcsec to the W which has no corresponding optical structure. The morphological and other properties of the QSO are discussed.

Hutchings, J. B.↗

Pathway toward Optical Cycling and Laser Cooling of Functionalized Arenes

Rapid and repeated photon cycling has enabled precision metrology and the development of quantum information systems using atoms and simple molecules. Extending optical cycling to structurally complex molecules would provide new capabilities in these areas, as well as in ultracold chemistry. Increased molecular complexity, however, makes realizing closed optical transitions more difficult. Building on already established strong optical cycling of diatomic, linear triatomic, and symmetric top molecules, recent work has pointed the way to cycling of larger molecules, including phenoxides. The paradigm for these systems is an optical cycling center bonded to a molecular ligand. Theory has suggested that cycling may be extended to even larger ligands, like naphthalene, pyrene, and coronene. For this paper, we study optical excitation and fluorescent vibrational branching of CaO-[illus. chemical structure], SrO-[illus. chemical structure], and CaO-[illus. chemical structure] and find only weak decay to excited vibrational states, indicating a promising path to full quantum control and laser cooling of large arene-based molecules.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Fabrication of MgF2 and LiF windows for the Hubble Space Telescope Imaging Spectrograph

Two prototype test windows (MgF2 and LiF) to be used on the 75-mm UV MAMA detector tubes for the Hubble Space Telescope Imaging Spectrograph are described. The spatial and optical constraints of this instrument dictate that the thickness of the window materials be no greater than 2-3 mm to achieve a minimum 50-percent transmission at hydrogen Lyman alpha (121.6 nm), and that the window must be domed to minimize optical aberrations and provide structural strength. The detector window has an input diameter of about 100 mm with a radius-of-curvature of 70 mm. The manufacturing processes involved in the fabrication of these windows is discussed, as well as test programs (optical and structural) to be performed at Goddard Space Flight Center.

Gormley, Daphne↗

Precise laser frequency scanning using frequency-synthesized optical frequency sidebands - Application to isotope shifts and hyperfine structure of mercury

Based on an efficient broadband electrooptic modulator producing RF optical sidebands locked to a stable cavity, a tunable dye laser can be scanned under computer control with frequency-synthesizer precision. Cavity drift is suppressed in software by using a strong feature in the spectrum for stabilization. Mercury isotope shifts are measured with a reproducibility of about 50 kHz. This accuracy of about 1/300 of the linewidth illustrates the power of the technique. Derived hyperfine-structure constants are compared with previous atomic-beam data.

Rayman, M. D.↗

Optical Sensing using Fiber Bragg Gratings for Monitoring Structural Damage in Composite Over-Wrapped Vessels

Composite Over-Wrap Vessels are widely used in the aerospace community. They are made of thin-walled bottles that are over wrapped with high strength fibers embedded in a matrix material. There is a strong drive to reduce the weight of space borne vehicles and thus pushes designers to adopt COPVs that are over wrapped with graphite fibers embedded in its epoxy matrix. Unfortunately, this same fiber-matrix configuration is more susceptible to impact damage than others and to make matters worse; there is a regime where impacts that damage the over wrap leave no visible scar on the COPV surface. In this paper FBG sensors are presented as a means of monitoring and detecting these types of damage. The FBG sensors are surface mounted to the COPVs and optically interrogated to explore the structural properties of these composite pressure vessels. These gratings optically inscribed into the core of a single mode fiber are used as a tool to monitor the stress strain relation in the composite matrix. The response of these fiber-optic sensors is investigated by pressurizing the cylinder up to its burst pressure of around 4500 psi. A Fiber Optic Demodulation System built by Blue Road Research, is used for interrogation of the Bragg gratings.

Grant, Joseph↗

Understanding the Hydronium Cation in the Solid State: A Study in Synthetic Hydronium Uranyl Phosphate and Arsenate Mineral Systems and Their Irradiation Stability

Here, we present neutron diffraction, electronic structure calculations, and optical vibrational spectroscopic characterization of hydronium uranyl phosphate (HUP), the synthetic analog of chernikovite ((H 3 O)(UO 2 )(PO 4 )·3H 2 O) to gain insight into structural features of the hydronium cation in the solid state. HUP crystallizes in P2 1 /c instead of previously reported P4/ncc 1 at room temperature and Pccn below 302 K. Lower symmetry was required due to hydronium and interstitial water positions within the structure. Crystallographic positions of hydronium cations determined from powder neutron diffraction data are bolstered by Raman and attenuated total reflectance infrared spectroscopic measurements and are further informed by density functional theory with phonon eigenvector analysis for spectral assignments. Finally, HUP and its arsenate analog (trogerite, (H 3 O)(UO 2 )(AsO 4 )·3H 2 O), (HUAs) were studied using He 2+ irradiation as an analog for α radiolysis to investigate the irradiation stability of these phases and the stability of hydronium cations in the solid state. Dose studies were employed wherein each sample was irradiated to 5, 10, 15, 25, and 50 MGy. Structural insight regarding irradiated materials is gained using optical vibrational spectroscopy and powder X-ray diffraction. Surprising irradiation stability of HUAs was found up to 50 MGy of dose, which may have important implications for understanding and modeling the geologic stability of legacy U.

actinides↗

Emerging Functionality in Transition-Metal Compounds Driven by Spatial Confinement and Broken Symmetry

This research project investigates the emerging functionality in transition-metal-compounds (TMCs) driven by spatial confinement and broken symmetry. It combines advanced growth capabilities with cutting-edge characterization and first principles theory to probe and control the properties of TMC interfaces, including the utilization and development of state-of-the-art atomically resolved electron microscopy and spectroscopy to determine the structure, composition, and bonding at TMC interfaces. The proposed research will focus on four challenging areas: 1) manipulate interfaces to design new material phases such as magnetic metals with unique polar structure (net dipole) to achieve multiple functionality; 2) explore electronic mismatch or screening at interfaces of insulating/poor metal TMCs to produce novel electronic and magnetic properties; 3) elucidate and exploit the role of defects, both point and extended, on the functionality of interfaces; 4) develop advanced electron microscopy/spectroscopy techniques to explore temperature dependent phase transitions and couple these structural tools with new nonlinear optical probes of the electronic structure. The research team aims to close the materials-by-design loop of make, measure, model, and modify. The program promises to enhance our ability to engineer the desired physical properties at interfaces, superlattices (periodic arrays of films of different compounds), and heterostructures of TMCs.

36 MATERIALS SCIENCE↗

Density Functional Tight Binding Insights into Plasmonic Silver–Platinum Nanoparticles and Alloys for Enhanced Photocatalysis

Developing accurate and efficient Slater-Koster (SK) tight-binding parameter sets is essential for quantum plasmonic studies of alloyed metal nanoparticles, as conventional time dependent density functional theory (TD-DFT) calculations are computationally prohibitive for larger clusters. In this work, we develop and validate density functional tight binding (DFTB) parameter sets for both ground state (GS-SK) and excited state (ES-SK) calculations to study the structural, electronic, and optical properties of silver (Ag), platinum (Pt), and Ag–Pt nanoalloys. Our investigation of the ground state properties demonstrates that the GS-SK parameters enable DFTB to closely reproduce the electronic structures of platinum clusters with diverse sizes and geometries – showing qualitative agreement with DFT for density of states (DOS) profiles and energy levels. The ES-SK parameters accurately describe excited-state properties compared to TD-DFT reference calculations, including the broad, featureless absorption profiles of Pt that are dominated by interband transitions. Using the ES-SK parameters within a real-time TD-DFTB framework, we compute size-dependent optical absorption spectra of Ag, Pt and Ag-Pt nanocubes containing up to 1099 atoms (size ∼4.18 nm). A detailed study of Ag–Pt and Pt-Ag core–shell nanoparticles shows quenching of the Ag plasmon resonance even at monolayer coverage for Ag-Pt, but not for Pt-Ag. We also show how to define submonolayer Ag-core Pt-shell cubic structures that have similar optical properties to those generated experimentally for much larger particles, which offers potential for describing plasmon-enhanced photocatalysis. Collectively, the GS-SK and ES-SK parameter sets provide an accurate, computationally efficient approach for modeling the complex optical and electronic behavior of noble–transition metal nanostructures and their alloys.

SPR↗