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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Atomically Precise Graphene Nanoribbon Transistors with Long-Term Stability and Reliability

Atomically precise graphene nanoribbons (GNRs) synthesized from the bottom-up exhibit promising electronic properties for high-performance field-effect transistors (FETs). The feasibility of fabricating FETs with GNRs (GNRFETs) has been demonstrated, with ongoing efforts aimed at further improving their performance. However, their long-term stability and reliability remain unexplored, which is as important as their performance for practical applications. In this work, we fabricated short-channel FETs with nine-atom-wide armchair GNRs (9-AGNRFETs). We revealed that the on-state (/ ON ) current performance of the 9-AGNRFETs deteriorates significantly over consecutive full transistor on and off logic cycles, which has neither been demonstrated nor previously considered. To address this issue, we deposited a thin ~10 nm thick atomic layer deposition (ALD) layer of aluminum oxide (Al 2 O 3 ) directly on these devices. The integrity, compatibility, electrical performance, stability, and reliability, of the GNRFETs before and/or after Al 2 O 3 deposition were comprehensively studied. The results indicate that the observed decline in electrical device performance is most likely due to the degradation of contact resistance over multiple measurement cycles. We successfully demonstrated that the devices with the Al 2 O 3 layer operate well up to several thousand continuous full cycles without any degradation. Our study offers valuable insights into the stability and reliability of GNR transistors, which could facilitate their large-scale integration into practical applications.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Near and long-term perspectives on strategies to decarbonize China's heavy-duty trucks through 2050

China needs to drastically reduce carbon dioxide (CO 2 ) emissions from heavy-duty trucks (HDTs), a key emitter in the growing transport sector, in order to address energy security concerns and meet its climate targets. We address existing research gaps by modeling feasibility, applicability, and energy and emissions impacts of multiple decarbonization strategies at different points in time. China still relies heavily on coal power, so impacts of new HDT technologies depend on the timing of their introduction relative to progress toward non-fossil power. We use a bottom-up model to simulate HDT energy consumption and CO 2 emissions through 2050. Results show that beginning to deploy battery electric and fuel-cell HDTs as early as 2020 and 2035, respectively, could achieve significant and the largest CO 2 emissions reduction by 2050 with a decarbonized power sector. However, viable near-term strategies-improving efficiency and logistics, switching to liquefied natural gas-could halve HDTs' current diesel consumption and CO 2 emissions by 2050. Our results underscore the need for a mix of near- and long-term policy and technology options to decarbonize China's HDTs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS2000

A Unified Satellite-Observation Polar Stratospheric Cloud (PSC) Database for Long-Term Climate-Change Studies

This report summarizes the project team's activity and accomplishments during the period 12 February, 1999 - 12 February, 2000. The primary objective of this project was to create and test a generic algorithm for detecting polar stratospheric clouds (PSC), an algorithm that would permit creation of a unified, long term PSC database from a variety of solar occultation instruments that measure aerosol extinction near 1000 nm The second objective was to make a database of PSC observations and certain relevant related datasets. In this report we describe the algorithm, the data we are making available, and user access options. The remainder of this document provides the details of the algorithm and the database offering.

Fromm, Michael↗
DOE OSTI2025

Long-Term Photovoltaic System Performance in Cold, Snowy Climates

As countries around the world transition towards renewable energy, there is increasing interest in using photovoltaic (PV) technologies to help decarbonize northern and alpine communities due to their scalability and affordability. However, a barrier to large-scale adoption of PV in cold climates is long-term performance uncertainty under snowfall, freeze-thaw cycles, low temperatures, and high winds. In this work, we provide a comprehensive review of published silicon degradation rates in cold Koppen-Geiger climate classifications of Dfb (humid continental), Dfc (subarctic), and ET (tundra). We first analyze the system degradation rates of three subarctic ground-mounted photovoltaic sites in North America using the RdTools year-on-year method: an Al-BSF double-axis tracking site in Fairbanks, Alaska (65degrees N); a PERC and silicon heterojunction bifacial vertical and south-tilted site in Fairbanks, Alaska; and a PERC south-facing fixed-tilt site in Fort Simpson, Northwest Territories (62degrees N). Degradation rates of these newly analyzed sites vary between -0.4%/year and -1.5%/year. Combining these data with previously reported cold climate degradation rates, we show that the distribution of cold climate degradation peaks at -0.1%/year to -0.2%/year but has a large tail with rates above -0.5%/year. The average reported cold climate degradation rate is -0.45%/year, whereas the median value is -0.33%/year. These results suggest that despite frequent freeze-thaw cycles and potential exposure to high wind and snow loads, PV systems in cold climates tend to degrade slower than PV systems in warmer climates. The limited sample size of reported degradation rates in cold climates (27) motivates the need for further data acquisition and monitoring efforts as new technologies are deployed.

14 SOLAR ENERGY↗
DOE OSTI2021

Understanding long-term groundwater flow at Pahute Mesa and vicinity, Nevada National Security Site, USA, from naturally occurring geochemical and isotopic tracers

Abstract Recently collected naturally occurring geochemical and isotopic groundwater tracers were combined with historic data from the Pahute Mesa area of the Nevada National Security Site (NNSS), Nevada, USA, to provide insights into long-term regional groundwater flow patterns, mixing and recharge. Pahute Mesa was the site of 85 nuclear detonations between 1965 and 1992, many of them deeply buried devices that introduced radionuclides directly into groundwater. The dataset examined included major ions and field measurements, stable isotopes of hydrogen (δ 2 H), oxygen (δ 18 O), carbon (δ 13 C) and sulfur (δ 34 S), and radioisotopes of carbon ( 14 C) and chloride ( 36 Cl). Analysis of the patterns of groundwater 14 C data and the δ 2 H and δ 18 O signatures indicates that groundwater recharge is predominantly of Pleistocene age, except for a few localized areas near major ephemeral drainages. Steep gradients in sulfate (SO 4 ) and chloride (Cl) define a region near the western edge of the NNSS where high-concentration groundwater flowing south from north of the NNSS merges with dilute groundwater flowing west from eastern Pahute Mesa in a mixing zone that coincides with a groundwater trough associated with major faults. The 36 Cl/Cl and δ 34 S data suggest that the source of the high Cl and SO 4 in the groundwater was a now-dry, pluvial-age playa lake north of the NNSS. Patterns of groundwater flow indicated by the combined data sets show that groundwater is flowing around the northwest margin of the now extinct Timber Mountain Caldera Complex toward regional discharge areas in Oasis Valley.

58 GEOSCIENCES↗
DOE OSTI2021

Long-term cyclability of Li 4 Ti 5 O 12 /LiMn 2 O 4 cells using carbonate-based electrolytes for behind-the-meter storage applications

Li 4 Ti 5 O 12 /LiMn 2 O 4 (LTO/LMO) chemistry was evaluated as a potential candidate for behind-the-meter storage (BTMS) applications. Its long-term cycle performance at 45 °C was tested using ethylene carbonate (EC) and propylene carbonate (PC) solvent electrolytes. Over 1000 cycles, LTO/LMO cells exhibited ~80% capacity retention and Coulombic efficiency higher than 99.96%. Electrochemical test results showed the major degradation mode of LTO/LMO cells arises from continuous electrolyte decomposition at the LTO anode and loss of Li inventory. EC and PC electrolytes created distinct surface layers, where the EC reduction products were more effective in passivating the LTO electrode surface. Dissolution and migration of Mn from the cathode was probed as Mn 2+ species distributed throughout the surface layer at the anode. By utilizing a prelithiated LTO electrode, the LTO/LMO cell performance was significantly enhanced with EC electrolyte. On the other hand, PC electrolyte resulted in accelerated electrolyte decomposition at the lithiated LTO surface due to the lack of surface passivation. Thus, mitigating parasitic reactions at the LTO electrode is the key to developing successful LTO/LMO cells.

25 ENERGY STORAGE↗
NASA NTRS1997

The Effects of Long Term Cure on Offgassed Products of Coatings

The Environmental Chemistry and Compatability Team at The Marshall Space Flight Center conducts toxic offgassing analysis on materials and flight hardware for use in habitable environments aboard the Space Shuttle and the International Space Station. As part of Research and Development, the Toxic Offgassing Laboratory conducted a long term cure study on four polyurethane coatings which are slated for potential use on Space Station. This study demonstrates the effects of cure time and temperature on the total tox value (sum T) and the maximum usage weight for each coating. All analysis was conducted according to test procedures outlined specifically for Space Station environments. Therefore, the ratings and weight limits generated for these materials are most applicable to space environments. However, this test does give some indication of time frames for solvent removal and is therefore of interest to, the environmental community as a whole.

Engle, Ginger↗
NASA NTRS2009

Long-term reliability of hand-soldering M55365 Ta capacitors

This is a continuation of the report “Effects of Hand Soldering MIL-PRF-55365 Tantalum Capacitors,” which discusses the parametric effects of convection reflow soldering, JPL standard hand soldering, and optimized hand soldering on solid tantalum capacitors. The current focus is determining the long-term reliability effects of the various soldering techniques. Unfortunately, the 100-piece sample size chosen for the highly accelerated life tests was too small to reliably determine the effects of the different soldering techniques on the lifespan of the parts. In hindsight, this likely could have been predicted based on the large alphas and small betas of the Weibull failure distributions discovered during the scouting trials. Now that the effects of inadequate sample size are better understood, an opportunity exists to not only discover whether there are real differences in the reliability associated with the various soldering techniques, but also the potential to discover the voltage acceleration model and the temperature acceleration effect for these capacitors. It is recommended that the testing be repeated with a more appropriate sample size to capture this useful information.

Spence, Penelope↗
DOE OSTI2025

Skipper CCD Long-Term Vacuum Chamber

The Skipper CCD is a high-sensitivity Charge Coupled Device (CCD) sensor designed at Fermilab that has extremely low readout noise. The Skipper can only be operated at pressures below 10-4Torr (about a millionth of an atmosphere). The purpose of this project was to investigate whether a long-term vacuum chamber could be used for the Skipper CCD, which would require only being re-pumped once a year. This would allow the Skipper to be fully integrated here at Fermilab and then be transported anywhere for immediate use.

Struven, Wolfgang↗
DOE OSTI2022

Characterization of Long-term Service Coal Combustion Power Plant Extreme Environment Materials

The technical goal of this project is to develop a comprehensive database of mechanical properties, alloy microstructures, and to a lesser extent, the oxidation/corrosion behavior of coal-fired power plant components, such as boiler tubing, steam headers and steam piping, which have been in long-term service (at least 100,000 operating hours, and preferably more than 200,000 operating hours) under the operating conditions of high temperatures and high mechanical stresses where creep, fatigue, steam-side oxidation, and fireside corrosion are life-limiting factors. The components included in the database will include the following types of high temperature alloys: creep strength enhanced ferritic (CSEF) steels, 300-series H-grade stainless steels, and dissimilar metal welds (DMWs).

Characterization↗
NASA NTRS2020

Determination of Lidar Ratio for Major Aerosol Types over Western North Pacific Based on Long-Term MPLNET Data

East Asia is the most complex region in the world for aerosol studies, as it encounters a lot of varieties of aerosols, and aerosol classification can be a challenge in this region. In the present study, we focused on the relationship between aerosol types and aerosol optical properties. We analyzed the long-term (2005–2012) data of vertical profiles of aerosol extinction coefficients, lidar ratio (Sp), and other aerosol optical properties obtained from a NASA Micro-Pulse Lidar Network and Aerosol Robotic Network site in northern Taiwan, which frequently receives Asian continental outflows. Based on aerosol extinction vertical profiles, the profiles were classified into two types: type 1 (single-layer structure) and type 2 (two-layer structure). Fall season (October–November) was the prevailing season for the Type 1, whereas type 2 mainly happened in spring (March–April). In type 1, air masses normally originated from three regional sectors, i.e., Asia continental (AC), Pacific Ocean (PO), and Southeast Asia (SA). The mean Sp values were 39 ± 17 sr, 30 ± 12 sr, and 38 ± 18 sr for the AC, PO, and SA sectors, respectively. The Sp results suggested that aerosols from the AC sector contained dust and anthropogenic particles, and aerosols from the PO sector were most likely sea salts. We further combined the EPA dust event database and backward trajectory analysis for type 2. Results showed that Sp was 41 ± 14 sr and 53 ± 21 sr for dust storm and biomass-burning events, respectively. The Sp for biomass-burning events in type 2 showed two peaks patterns. The first peak occurred within range of 30–50 sr corresponding to urban pollutant, and the second peak occurred within range of 60–80 sr in relation to biomass burning. Finally, our study summarized the Sp values for four major aerosol types over northern Taiwan, viz., urban (42 ± 18 sr), dust (34 ± 6 sr), biomass-burning (69 ± 12 sr), and oceanic (30 ± 12 sr). Our findings provide useful references for aerosol classification and air pollution identification over the western North Pacific.

Sheng-Hsiang Wang↗
DOE OSTI2024

The path to 2060: Saudi Arabia's long-term pathway for GHG emission reduction

Saudi Arabia, as part of its Saudi Green Initiative, has announced its goal to achieve net zero green-house gas emissions by 2060. This ambitious target underscores the nation's dedication to address-ing climate change. However, there is a significant gap in comprehensive analysis regarding the long-term effects of Saudi Arabia's climate policies and their collective contribution towards the net-zero objective. This study endeavors to bridge this gap through a detailed examination using the GCAM-KSA, a specialized version of the Global Change Analysis Model tailored for Saudi Arabia, employing a multi-sectoral methodology that integrates economic, energy, and land use systems within a coherent framework to assess the impact of climate policies on GHG emissions. Our anal-ysis reveals that reaching net-zero GHG emissions by 2060 is a complex challenge requiring con-certed efforts across all sectors of the economy. While transitioning to low-carbon electricity and improving energy efficiency offer considerable emission reductions, fully decarbonizing the indus-trial and transportation sectors poses a significant hurdle. Our findings suggest that Saudi Arabia must triple its emission reduction commitments in its next Nationally Determined Contributions (NDCs) update to align with its 2060 net-zero goal. Early action and increased ambition could avoid the chances of getting locked into the high emission assets and give enough time to transform the energy system. Furthermore, the adoption and integration of Carbon Dioxide Removal (CDR) tech-nologies are identified as crucial for offsetting residual emissions, especially in sectors that might continue to rely on fossil fuels.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2025

Instrumentation and Control Digital Modernization Research Plan for Long-Term Sustainability in the Nuclear Industry

This report, developed by Idaho National Laboratory (INL) in collaboration with Oak Ridge National Laboratory (ORNL), outlines a comprehensive research plan to support the digital modernization of safety-related instrumentation and control (I&C) systems in the U.S. nuclear industry. The modernization effort is critical to ensuring the long-term safety, reliability, and economic viability of both existing and future nuclear power plants (NPPs), particularly as aging analog systems become increasingly obsolete and difficult to maintain.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1975

Lunar heat-flow experiment: Long term temperature observations on the lunar surface at Apollo sites 15 and 17

Several investigators of the Apollo lunar experiments have observed gradual increases in the mean temperatures recorded by various surface thermometers. Similar effects were noticed in the temperatures of the thermometers of the Apollo 15 and 17 Heat Flow Experiments. An analysis of the long term temperature histories of the heat flow experiment thermometers is presented. These data show that no change in mean surface temperature at the Apollo 15 and 17 sites has occurred, and suggest that the slow increase in mean temperatures of thermometers in the electronics housing are due to changes in radiative properties of the housing's surfaces.

Peters, K.↗
NASA NTRS2002

Use of TRMM Rainfall Information in Improving Long-Term, Satellite-Based Global Precipitation Analyses

The TRMM rainfall products are inter-compared among themselves and to the 23 year, monthly, globally complete precipitation analysis of the World Climate Research Program's (WCRP/ GEWEX) Global Precipitation Climatology Project (GPCP). Ways in which the TRMM-based estimates can be used to improve the long-term data set are described. These include improvement of the passive microwave algorithm that is applied to the 15 year SSM/I record and calibration or adjustment of the current GPCP fields utilizing the 4-5 year overlap of TRMM and GPCP. A comparison of the GPCP monthly surface precipitation fields and the TRMM-based multi-satellite analyses indicates that the two are similar, but have significant differences that relate to the different input data sets. Although on a zonal average basis over the ocean the two analyses are similar in the deep Tropics, there are subtle differences between the eastern and western Pacific Ocean in the relative magnitudes. In mid-latitudes the GPCP has somewhat larger mean precipitation than TRMM. Statistical comparisons of TRMM and GPCP monthly fields are carried out in terms of histogram matching for both ocean and land regions and for small areas to diagnose differences. These comparisons form the basis for a TRMM calibration of the GPCP fields using matched histograms over regional areas as a function of season. Although final application of this procedure will likely await the Version 6 of the TRMM products, tests using Version 5 are shown that provide a TRMM-calibrated GPCP version that will produce an improved climatology and a more accurate month-to-month precipitation analysis for the last 20 years.

Starr, David OC.↗
NASA NTRS1992

Long-term particle flux variability indicated by comparison of Interplanetary Dust Experiment (IDE) timed impacts for LDEF's first year in orbit with impact data for the entire 5.75-year orbital lifetime

The electronic sensors of the Interplanetary Dust Experiment (IDE) recorded precise impact times and approximate directions for submicron to approximately 100-micron size particles on all six primary sides of the spacecraft for the first 346 days of the Long Duration Exposure Facility (LDEF) orbital mission. Previously-reported analyses of the timed impact data have established their spatio-temporal features, including the demonstration that a preponderance of the particles in this regime are orbital debris and that a large fraction of the debris particles are encountered as megameter-size clouds, some of which persist for long times. Short-term fluxes within such clouds can rise several orders of magnitude above the long-term average. These finding are consistent with the results of the first catastrophic hypervelocity laboratory impacts on a real satellite, recently reported in the press. Analysis continues on the geometric and evolutionary characteristics of these clouds, as well as on the isolation and characterization of the natural micrometeoroid component in the IDE data, but the unexpectedly large short-term variations in debris flux raises the question of how representative an indication of the multi-year average flux is given by the nearly one year of timed data. It has, therefore, always been one of the goals of IDE to conduct an optical survey of the craters on the IDE detectors, to obtain full-mission fluxes for comparisons with the timed data. This work is underway, and the results presently in hand are significant. Optical scanning of the ram and wake (East and West) panels is complete, and it is clear that the first year was in some respects not representative of the subsequent years. The 5.75-year average flux on East panel was 90 percent of the value predicted by the average flux recorded during the first year, while it was only 34 percent on West panel. This suggests that western hemisphere spacecraft launches are a major contributor to the long-term flux and that their contribution is primarily in the smaller end of the size distribution. This conclusion follows from the fact that a closely-spaced series of launch failures (Titan, Delta, Ariane, and Challenger) caused a virtual hiatus in launch activity during a large part of the later years of the LDEF mission. We hope to provide a quantification of the particle size distribution function in this case.

Mulholland, J. Derral↗
DOE OSTI2026

Quantifying Sources of Long-Term Voltage Decay for Rutile Iridium Oxide Anodes in Proton Exchange Membrane Water Electrolysis

To achieve aggressive hydrogen cost targets for proton exchange membrane water electrolysis (PEMWE), it is necessary to develop catalyst systems that reduce precious metal loadings while maintaining performance over extended operation. While amorphous iridium (Ir) -based catalysts exhibit high initial activity, their long-term stability remains a key limitation. In this study, the behavior of a rutile IrO2 catalyst is investigated over 4000 h of durability testing and compared to past efforts evaluating a more amorphous material. This study finds that rutile IrO2 results in a smaller decay rate (4.9 ..mu..V h-1) than an amorphous catalyst (28 ..mu..V h-1); additionally, the rutile IrO2 results in a smaller degree of Ir migration (20% to the membrane and cathode) than an amorphous catalyst (35%). This research emphasizes rutile IrO2 as a promising avenue for the development of durable, low-iridium anodes that can meet lifetime and cost targets for next-generation electrolyzer systems.

08 HYDROGEN↗
DOE OSTI2022

Oxidation Lifetime Modeling of 625 and 120 Foils After Long-term Exposure in Flowing Air + 10% ${\hbox {H}_2\hbox {O}}$ at 700 and 800 $^\circ$C

A model describing oxidation kinetics considering simultaneous oxidation and volatilization of external oxide scales was integrated with a CALPHAD-based coupled thermodynamic and kinetic approach to predict the oxidation-induced lifetime of foils of alloys 625 and 120. Long-term exposures in flowing air +10% H 2 O at 700 and 800 °C under two flow velocities were used to validate the modeling results. The time to a critical Cr concentration of 10 wt% at the oxide/alloy interface, t 10 , was shown to correlate with the breakdown of the Cr 2 O 3 scale for the studied experimental conditions. Finally, the modeling approach was extended to consider time-dependent oxidation and volatilization rate constants to develop a more appropriate lifetime criterion for microturbine recuperator foils.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗