SEARCH · Engineering Papers

Results for “exposure time”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 757 records · Page 42

All sources NASA NTRS DOE OSTI

NASA NTRS2020

Dim Prospects for Transmission Spectra of Ocean Earths Around M Stars

The search for water-rich Earth-sized exoplanets around low-mass stars is rapidly gaining attention because they represent the best opportunity to characterize habitable planets in the near future. Understanding the atmospheres of these planets and determining the optimal strategy for characterizing them through transmission spectroscopy with our upcoming instrumentation is essential in order to constrain their environments. For this study, we present simulated transmission spectra of tidally locked Earth-sized ocean-covered planets around late-M to mid-K stellar spectral types, utilizing GCM modeling results previously published by Kopparapu et al. (2017) as inputs for our radiative transfer calculations performed using NASA's Planetary Spectrum Generator (psg.gsfc.nasa.gov; Villanueva et al. (2018)). We identify trends in the depth of H2O spectral features as a function of planet surface temperature and rotation rate. These trends allow us to calculate the exposure times necessary to detect water vapor in the atmospheres of aquaplanets through transmission spectroscopy with the upcoming James Webb Space Telescope (JWST) as well as several future flagship space telescope concepts under consideration (LUVOIR and OST) for a target list constructed from the TESS Input Catalog (TIC). Our calculations reveal that transmission spectra for water-rich Earth-sized planets around low-mass stars will be dominated by clouds, with spectral features < 20 ppm, and only a small subset of TIC stars would allow for the characterization of an ocean planet in the Habitable Zone. We thus present a careful prioritization of targets that are most amenable to follow-up characterizations with next-generation instrumentation, in order to assist the community in efficiently utilizing precious telescope time.

exoplanet atmospheres↗

NASA NTRS2021

Pyrolysis Rate and Yield Strength Reduction Incarbon Fiber and Glass Fiber Composites Underreentry Heating Conditions

The behavior of composite materials, specifically carbon fiber reinforced plastic (CFRP) and glass fiber reinforced plastic (GFRP), under reentry conditions poses a problem for space debris reentry risk modeling. Since these materials pyrolyze rather than melt and their different components demise at different rates, modeling their destruction to determine ground impact risk is complex. Modern spacecraft are using these materials in ever-greater quantities owing to their superior strength-to-weight characteristics, and this has required that the orbital debris community improve its understanding of how these materials demise on reentry. The NASA Orbital Debris Program Office undertook an extensive test campaign to better understand the rate at which several types of GFRP and CFRP materials pyrolyze under reentry heating conditions and how that pyrolysis affects the ultimate strength of the material. GFRP with a polyester resin (G10/FR-4) and CFRP with epoxy, cyanate ester, vinyl ester, and phenolic resins were tested. The test campaign was carried out at the Inductively Coupled Plasma (ICP) Torch Facility at the University of Texas at Austin. Because the ICP facility operates in a shirt-sleeve environment, test samples can be changed within seconds or minutes, allowing many samples to be tested in a short period. Two heat flux rates, 20 W/m2 and 30W/m2, and two oxygen concentration conditions, 0% and 2% of atmospheric, were applied to all five types of material. To measure both the char rate and the effect of pyrolysis on the ultimate material strength, two types of test were carried out for each material: a char rate test on a ~10 mm thick sample of material and an in-situ bending stress test of a ~2 mm thick sample of material. Measurements of the char rate showed very similar average pyrolysis front velocity in epoxy resin CFRP as in G10 at 3.6 mm/min and 3.4 mm/min, respectively. However, the total mass loss rate in theG10 was nearly double that of the CFRP at 3.8 g/min and 2.2 g/min, respectively. This result represented a slow ablation rate of carbon fibers in the CFRP at the temperatures encountered in low Earth orbit reentry and a comparatively rapid removal of the glass fibers in G10 due to melting and spallation. Pyrolysis front velocity was more significantly affected by the type of plastic than the type of fiber, with the cyanate ester CFRP samples displaying an average pyrolysis front velocity of only 1.9 mm/min. Similarly, the effect of thermal exposure on the ultimate strength of the material depended heavily on the type of plastic and very little on the type of fiber in the material. Epoxy, vinyl ester, and polyester resins all behaved very similarly, with complete structural failure at between 400 J/g and 600 J/g of specific absorbed heat. Phenolic and cyanate ester resins, on the other hand, displayed a change in structural properties that was only barely measurable with the current apparatus even after the maximum exposure time tested. These data are being incorporated into a numerical model of the ablation and demise of composite materials that will be used to more accurately calculate the ground casualty risk of future spacecraft.

Benton R. Greene↗

NASA NTRS1995

Exposure of the Cassini Spacecraft to Horseshoe and Tadpole Particle Zones

Regions called "horseshoes" and "tadpoles" exist along the orbits of Saturn's satellites, within which particles can be trapped by gravitational interactions of Saturn and the satellites. While the extent of particle accumulation is not known, trapped particles might pose a hazard to the Cassini Spacecraft. Methods of reducing exposure time and effects of these methods on science return are discussed.

Cassini↗

NASA NTRS1994

(abstract) Pluto Integrated Camera-Spectrometer (PICS): a Low Mass, Low Power Instrument for Planetary Exploration

The concept we describe is an integrated instrument (a Pluto Integrated Camera-Spectrometer -- PICS) that will perform the functions of all three optical instruments required by the Pluto Fast Flyby Mission: the near-IR spectrometer, the camera, and the UV spectrometer. This integrated approach minimizes mass and power use. It also forced us early in the conceptual design to consider integrated observational sequences and integrated power management, thus ensuring compatible duty cycles (i.e., exposure times, readout rates) to meet the composite requirements for data collection, compression, and storage. Based on flight mission experience we believe that this integrated approach will result in substantial cost savings, both in reworking instrument designs during accommodation, as well as in sequence planning and integration. Finally, this integrated payload automatically yields a cohesive mission data set, optimized for correlative analysis. The presentation will provide details of the PICS instrument design and describe the fabrication and testing of the integrated SiC structure and optics at SSG Inc. Final integration and test plans for the prototype will also be described.

Pluto↗

NASA NTRS2018

Picometer Differential Wavefront Metrology by Nonlinear Zernike Wavefront Sensing for LUVOIR

We propose the Nonlinear Zernike wavefront sensor (NLZWFS) for out-of-band diﬀerential wavefront sensing to augment primary mirror stability on LUVOIR and similar mission concepts during exoplanet coronagraphy. This new data analysis paradigm involving a full polychromatic scalar physical optics model for the phase-shifting Zernike wavefront sensor removes the linearity assumptions which would otherwise prevent accurate sensing. We show Monte-Carlo simulations of NLZWFS and focus-diverse phase retrieval to understand the exposure times necessary to achieve picometer-level stability in the telescope wavefront.

Redding, David C.↗

NASA NTRS2019

A NICER view of PSR J0030+0451: Implications for the Dense Matter Equation of State

Both the mass and radius of the millisecond pulsar PSRJ0030+0451 have been inferred via pulse-profile modeling of X-ray data obtained by NASA’s Neutron Star Interior Composition Explorer (NICER) mission. In this Letter we study the implications of the mass–radius inference reported for this source by Riley et al. for the dense matter equation of state (EoS), in the context of prior information from nuclear physics at low densities. Using a Bayesian framework we infer central densities and EoS properties for two choices of high-density extensions: a piecewise-polytropic model and a model based on assumptions of the speed of sound in dense matter. Around nuclear saturation density these extensions are matched to an EoS uncertainty band obtained from calculations based on chiral effective field theory interactions, which provide a realistic description of atomic nuclei as well as empirical nuclear matter properties within uncertainties. We further constrain EoS expectations with input from the current highest measured pulsar mass; together, these constraints offer a narrow Bayesian prior informed by theory as well as laboratory and astrophysical measurements. The NICER mass–radius likelihood function derived by Riley et al. using pulse-profile modeling is consistent with the highest-density region of this prior. The present relatively large uncertainties on mass and radius for PSR J0030+0451 offer, however, only a weak posterior information gain over the prior. We explore the sensitivity to the inferred geometry of the heated regions that give rise to the pulsed emission, and find a small increase in posterior gain for an alternative (but less preferred) model. Lastly, we investigate the hypothetical scenario of increasing the NICER exposure time for PSRJ0030+0451.

G Raaijmakers↗

NASA NTRS2020

The Chandra Deep Wide-field Survey: A New Chandra Legacy Survey in the Bootes Field. I. X-ray Point Source Catalog, Number Counts, and Multiwavelength Counterparts

We present a new, ambitious survey performed with the Chandra X-ray Observatory of the 9.3 deg2 Boötes field of the NOAO Deep Wide-Field Survey. The wide field probes a statistically representative volume of the universe at high redshift. The Chandra Deep Wide-field Survey exploits the excellent sensitivity and angular resolution of Chandra over a wide area, combining 281 observations spanning 15 yr, for a total exposure time of 3.4 Ms, and detects 6891 X-ray point sources down to limiting fluxes of 4.7 × 10−16, 1.5 × 10−16, and 9 × 10−16 erg cm−2 s−1 in the 0.5–7, 0.5–2, and 2–7 keV bands, respectively. The robustness and reliability of the detection strategy are validated through extensive, state-of-the-art simulations of the whole field. Accurate number counts, in good agreement with previous X-ray surveys, are derived thanks to the uniquely large number of point sources detected, which resolve 65.0% ± 12.8% of the cosmic X-ray background between 0.5 and 2 keV and 81.0% ± 11.5% between 2 and 7 keV. Exploiting the wealth of multiwavelength data available on the field, we assign redshifts to ∼94% of the X-ray sources, estimate their obscuration, and derive absorption-corrected luminosities. We provide an electronic catalog containing all of the relevant quantities needed for future investigations.

Catalogs↗

NASA NTRS2021

The Role of Hydrated Minerals and Space Weathering Products in the Bluing of Carbonaceous Asteroids

The surfaces of airless bodies such as lunar and S-type asteroids typically become spectrally redder in visible to near-infrared reflectance with longer exposures to space weathering. However, some carbonaceous asteroids instead become spectrally bluer. Space weathering experiments on carbonaceous meteorites have provided some clues as to the space weathering products that could produce spectral bluing. We applied these experimental results to our Hapke radiative transfer model, with which we modeled spectral data from the OSIRIS-REx mission in order to determine whether these space weathering products—specifically, nanophase and microphase metallic iron, troilite, and magnetite—could explain the globally blue spectrum of the carbonaceous asteroid (101955) Bennu. The model suggests that the surface of Bennu has microphase iron, nanophase magnetite, and nanophase and microphase troilite. Considering previous space weathering experiments together with our spectral modeling of Bennu, we posit that the presence of nanophase magnetite is what causes a carbonaceous asteroid to become spectrally bluer with exposure time. Nanophase magnetite can form on asteroids that have Fe-bearing hydrated minerals (phyllosilicates). On anhydrous carbonaceous asteroids, nanophase iron forms instead of magnetite, leading to spectral reddening. We therefore predict that samples returned by the OSIRIS-REx mission from Bennu will have more nanophase magnetite than nanophase iron with nanophase and microphase sulfides, whereas samples returned by the Hayabusa2 mission from the carbonaceous asteroid (162173) Ryugu, which is spectrally red, will contain nanophase and microphase sulfides as well as more nanophase iron than nanophase magnetite.

David Trang↗

NASA NTRS2020

Texas Spectroscopic Search for Lyα Emission at the End of Reionization. III. The Lyα Equivalent-width Distribution and Ionized Structures at z > 7

Lyα emission from galaxies can be utilized to characterize the ionization state in the intergalactic medium (IGM). We report our search for Lyα emission at z > 7 using a comprehensive Keck/MOSFIRE near-infrared spectroscopic data set, as part of the Texas Spectroscopic Search for Lyα Emission at the End of Reionization Survey. We analyze data from 10 nights of MOSFIRE observations which together target 72 high-z candidate galaxies in the GOODS-N field, all with deep exposure times of 4.5–19 hr. Utilizing an improved automated emission-line search, we report 10 Lyα emission lines detected (>4σ) at z > 7, significantly increasing the spectroscopically confirmed sample. Our sample includes large equivalent-width (EW) Lyα emitters (>50 Å), and additional tentative Lyα emission lines detected at 3σ–4σ from five additional galaxies. We constrain the Lyα EW distribution at z ~ 7.6, finding a significant drop from z ≲ 6, suggesting an increasing fraction of neutral hydrogen (H I) in the IGM in this epoch. We estimate the Lyα transmission through the IGM (=EW(z)~7.6/EW(z~2–6)) and infer an IGM H I fraction (X(HI)) of 49 (+19,-19)% at z ~ 7.6, which is lower in modest tension (>1σ) with recent measurements at z ~ 7.6. The spatial distribution of the detected Lyα emitters implies the presence of a potential highly ionized region at z ~ 7.55, which hosts four Lyα emitters within a ∼40 cMpc spatial separation. The prominence of this ionized region in our data set could explain our lower inferred value of X(HI), though our analysis is also sensitive to the chosen reference Lyα EW distribution values and reionization models.

Intae Jung↗

NASA NTRSDate not supplied

A Model for Ice Accretion Roughness Evolution and Spatial Variations

Over the past decade, multiple investigations of ice accretion roughness and spatial variations have been performed in the Icing Research Tunnel (IRT) at the NASA Glenn Research Center. The early investigations used models of NACA 0012 airfoils with different chord sizes and focused on temporal scaling and primary cloud scaling parameters such as stagnation point collection efficiency. Subsequent investigations included the effects of model sweep, airfoil shape, airfoil lifting condition, and freestream static temperature. To develop a predictive model for roughness evolution in generalized icing situations, the maximum roughness values for the airfoils and conditions used in the angle of attack and freestream temperature investigations were scaled to eliminate the temporal variations. LEWICE simulations were employed to identify the local collection efficiency at the locations of maximum roughness, and a two-dimensional panel-method code was used to identify the local static pressure at the location of the maximum roughness. Because of the stochastic nature of ice accretion roughness, a physics-directed approach was employed to develop a multi-dimensional correlation based on the local pressure coefficient, the local total temperature, the cloud properties, and the cloud exposure time. The resulting correlation predictions are compared to ice shapes measured in the IRT for both a 21-in. NACA 0012 airfoil model and a 60-in. HAARP-II model. The resulting predictions indicate that the local freezing fraction must be included in the roughness predictive model. Implications regarding icing heat transfer predictions using the resulting roughness model are also discussed.

Icing↗

NASA NTRSDate not supplied

The Effects of Plasma Application on Radish Seeds with Implications for Space Crop Production

In extended space missions, the astronaut diet will consist mostly of prepackaged foods. This could result in nutritional deficiencies due to the gradual breakdown of certain vitamins. To address this deficiency, fresh produce must be grown from seed during spaceflight. Stored seeds, however, can be vulnerable to microbial contamination which could jeopardize plant health and crop food safety. To alleviate this concern, the current practice is to sanitize seeds on the ground before spaceflight to the International Space Station (ISS). Methods of seed sanitization include alcohol soaking and chlorine gas fumigation, which have harmful effects on the environment and human health. Plasma application is a new sanitization approach that avoids these negative side effects while potentially elevating germination rate and improving growth rate; yet plasma application requires specific exposure time, power, and pressure to achieve these benefits. In the present study, Raphanus sativus ‘Cherry Belle’ radish seeds were exposed to either low pressure (Diener) plasma or atmospheric pressure plasma for varying increments of time (30s-1200s). Data collected includes immediate germination rate (viability) and microbial log reduction. Additionally, seeds were stored for later germination rate testing. Microbial assay controls have highlighted variability in initial microbial load between individual seeds, and further work is being performed to determine the standard microbial load of an untreated seed. In some samples, a negative log reduction was observed after plasma treatment encouraging further study to determine if the plasma is perforating the seed coat and releasing endophytic microbes. Treatment with Diener plasma shows promising microbial log reduction, but lower viability. In contrast, treatment with atmospheric pressure plasma offers high viability, but poor microbial log reduction. Further study will aim at determining whether plasma treatment is effective at not only sanitization, but sterilization. This research was funded by a NASA grant at the Kennedy Space Center.

Plasma↗

NASA NTRSDate not supplied

The Effects of Plasma Application on Radish Seeds with Implications for Space Crop Production

Space Crop Production↗

NASA NTRS2021

First Observations from the SPICE EUV Spectrometer on Solar Orbiter

Aims. We present first science observations taken during the commissioning activities of the Spectral Imaging of the Coronal Environment (SPICE) instrument on the ESA/NASA Solar Orbiter mission. SPICE is a high-resolution imaging spectrometer operating at extreme ultraviolet (EUV) wavelengths. In this paper we illustrate the possible types of observations to give prospective users a better understanding of the science capabilities of SPICE. Methods. We have reviewed the data obtained by SPICE between April and June 2020 and selected representative results obtained with different slits and a range of exposure times between 5 s and 180 s. Standard instrumental corrections have been applied to the raw data. Results. The paper discusses the first observations of the Sun on different targets and presents an example of the full spectra from the quiet Sun, identifying over 40 spectral lines from neutral hydrogen and ions of carbon, oxygen, nitrogen, neon, sulphur, magnesium, and iron. These lines cover the temperature range between 20,000 K and 1 million K (10MK in flares), providing slices of the Sun’s atmosphere in narrow temperature intervals. We provide a list of count rates for the 23 brightest spectral lines. We show examples of raster images of the quiet Sun in several strong transition region lines, where we have found unusually bright, compact structures in the quiet Sun network, with extreme intensities up to 25 times greater than the average intensity across the image. The lifetimes of these structures can exceed 2.5 hours. We identify them as a transition region signature of coronal bright points and compare their areas and intensity enhancements. We also show the first above-limb measurements with SPICE above the polar limb in C III,O VI, and Ne VIII lines, and far off limb measurements in the equatorial plane in Mg IX, Ne VIII, and O VI lines. We discuss the potential to use abundance diagnostics methods to study the variability of the elemental composition that can be compared with in situ measurements to help confirm the magnetic connection between the spacecraft location and the Sun’s surface, and locate the sources of the solar wind. Conclusions. The SPICE instrument successfully performs measurements of EUV spectra and raster images that will make vital contributions to the scientific success of the Solar Orbiter mission

Sun: UV radiation↗

NASA NTRS2021

Validation of Small Satellite Dynamics Simulation Modules using ASTERIA Flight Data

ASTERIA (Arcsecond Space Telescope Enabling Research in Astrophysics) was a CubeSat space telescope that operated in low-Earth orbit, having been deployed from the International Space Station in 2017. The spacecraft has achieved sub-arcsecond pointing stability and millikelvin thermal stability over 20-minute observations. A key enabling feature of the ASTERIA mission is the low level of pointing error that has been demonstrated under ASTERIA’s fine pointing control mode. Prior to launch, the ASTERIA mission performed analysis and simulations to estimate the in-flight pointing performance. This analysis used reaction wheel models provided by JPL’s Small Satellite Dynamics Testbed (SSDT), which had performed Kistler table testing to characterize the jitter caused by the reaction wheels of the Blue Canyon Technologies XACT attitude control unit within ASTERIA. These models were subsequently incorporated into the SSDT simulation. The main source of jitter, the high-frequency attitude disturbance over the camera exposure time, on ASTERIA is the set of rotating reaction wheels that are used for maintaining fine pointing during observations. The reaction wheels impart disturbance forces and torques continuously that cause unwanted motion during imaging. Increased jitter consequently leads to blurring of the image. Therefore, to benefit all SmallSat missions devoted to photometric or spectroscopic astrophysics applications, an on-orbit flight data acquisition and jitter testing campaign was performed in an attempt to help validate the SSDT’s simulation models. This paper describes the process used to validate several simulation models and attempt to characterize the ASTERIA jitter by analyzing the size of the resulting spot size for the target stars as a function of wheel speed, having commanded four wheel speeds for each of three stars of known brightness. After summarizing the on-orbit observation and jitter level measurement process, this paper compares the results obtained from the flight operational environment to the corresponding set of simulation jitter levels. Though the flight data obtained during this experiment was not sufficient to validate the simulation’s jitter model, other models have been validated with flight data, including the magnetic field, orbit propagation, sun position, and long-duration orbit decay models, which may be used by all other projects that use the SSDT’s simulation to increase system capability knowledge.

Mohan, Swati↗

NASA NTRSDate not supplied

Application of Digital Image Correlation in Wind Tunnel

Digital image correlation (DIC) is a non-contact measurement technique that has been used in various applications in multiple industries, from microscopic specimens all the way to large scale structures. This project involved using DIC to capture wing deflection under simulated wind loading at various angles of attack (AoA). A subscale model of a fixed-wing aircraft, shown in Figure 1, was used in the 14-footby 22-footsubsonicwind tunnel at the NASA Langley Research Center. The setup used two pairs of cameras mounted on the ceiling of the tunnel to view the starboard and port side wings. Aluminum framing was used to rigidly mount the cameras to beams in the ceiling. Camera setup challenges due to the confined space included obtaining even lighting and working around infrared (IR) cameras that were used to capture the flow over the wing. Remote connection was used to access data acquisition computers from computers in the control room. Eight measurement locations on each wing were made of 1-inch-diametercircular silver dry transfer decals that did not alter the air flow across the wing. These circles were speckled with a black ink pen and were used for the IR camera as well as for DIC systems. A mock setup outside the wind tunnel was used to optimize the camera setup and verify that the speckled tape provided sufficient correlation. DIC was used to track the position of seven locations as the AoA of the subscale model changed from −10 degrees to +10 degrees in 1-degree increments. The model was rotated at a fixed height about the center of the fuselage from −7 degrees to +10 degrees. The height of the model had to be lowered to achieve AoA slower than −7degrees due to geometric constraints of the cart supporting the model and the wind tunnel. The source of light was stationary relative to the model, so the exposure time had to be adjusted for different wing regions and AoA values. The three-dimensional (3D) visualization of the markings and the two-dimensional (2D) projection of these points onto the port wing at 0-degree AoA is shown in Figure 2.

Matlock Mennu↗

NASA NTRSDate not supplied

Thermochemical/Thermomechanical Synergies in High Temperature Solid Particle Erosion of CMAS-Exposed EBCs

Environmental barrier coatings (EBCs) are an enabling technology for the use of SiC-based ceramic matrix composites in next generation gas turbine engines. In the extreme engine environment, EBCs must be able to withstand a variety of individual damage mechanisms and their interactions with each other. Ingested particulates/debris can cause both thermochemical and thermomechanical degradation of EBCs. Siliceous debris primarily based on calcium magnesium aluminosilicates (CMAS) can melt and infiltrate and/or react with EBCs above >1200°C. Similarly, ingested debris can lead to mechanical damage and recession of coatings due to particulate erosion. Both modes of degradation can occur simultaneously during engine operation, and it is crucial to comprehensively understand the mechanisms of coating failure due to high-temperature particulate interactions. This study assesses the erosion durability of Yb2Si2O7-based EBCs exposed to CMAS of various loads in NASA Glenn’s Erosion Burner Rig Facility. CMAS exposures and erosion testing were carried out at 1316°C. The effects of CMAS loading and exposure time on EBC erosion durability were evaluated using Al2O3 as an erodent material.

EBC↗

NASA NTRS2020

The Old, Unique C1 Chondrite Flensburg – Insight Into the First Processes of Aqueous Alteration, Brecciation, and the Diversity of Water-Bearing Parent Bodies and Lithologies

On September 12, 2019 at 12:49:48 (UT) a bolide was observed by hundreds of eye-witnesses from the Netherlands, Germany, Belgium, Denmark and the UK. One day later a small meteorite stone was found by accident in Flensburg. The presence of short-lived cosmogenic radionuclides with half-lives as short as 16 days proves the recent exposure of the found object to cosmic rays in space linking it clearly to the bolide event. An exceptionally short exposure time of ∼5000 years was determined. The 24.5 g stone has a fresh black fusion crust, a low density of <2 g/cm(exp 3), and a magnetic susceptibility of logχ = 4.35 (χ in 10−9 m(exp 3)/kg). The rock consists of relict chondrules and clusters of sulfide and magnetite grains set in a fine-grained matrix. The most abundant phases are phyllosilicates. Carbonates (∼3.9 vol.%) occur as calcites, dolomites, and a Na-rich phase. The relict chondrules (often surrounded by sulfide laths) are free of anhydrous silicates and contain abundant serpentine. Lithic clasts are also surrounded by similar sulfide laths partly intergrown with carbonates. Mn-53-Cr-53 ages of carbonates in Flensburg indicate that brecciation and contemporaneous formation of the pyrrhotite-carbonate intergrowths by hydrothermal activities occurred no later than 4564.6 ± 1.0 Ma (using the angrite D'Orbigny as the Mn-Cr age anchor). This corresponds to 2.6 ± 1.0 or 3.4 ± 1.0 Ma after formation of CAIs, depending on the exact absolute age of CAIs. This is the oldest dated evidence for brecciation and carbonate formation, which likely occurred during parent body growth and incipient heating due to decay of Al-26. In the three oxygen isotope diagram, Flensburg plots at the 16O-rich end of the CM chondrite field and in the transition field to CV-CK-CR chondrites. The mass-dependent Te isotopic composition of Flensburg is slightly different from mean CM chondrites and is most similar to those of the ungrouped C2 chondrite Tagish Lake. On the other hand, Ti-50 and Cr-54 isotope anomalies indicate that Flensburg is similar to CM chondrites, as do the ∼10 wt.% H2O of the bulk material. Yet, the bulk Zn, Cu, and Pb concentrations are about 30% lower than those of mean CM chondrites. The He, Ne, and Ar isotopes of Flensburg show no solar wind contribution; its trapped noble gas signature is similar to that of CMs with a slightly lower concentration of Ne(sub tr)-20. Based on the bulk H, C, and N elemental abundances and isotopic compositions, Flensburg is unique among chondrites, because it has the lightest bulk H and N isotopic compositions of any type 1 or 2 chondrite investigated so far. Moreover, the number of soluble organic compounds in Flensburg is even lower than that of the brecciated CI chondrite Orgueil. The extraordinary significance of Flensburg is evident from the observation that it represents the oldest chondrite sample in which the contemporaneous episodes of aqueous alteration and brecciation have been preserved. The characterization of a large variety of carbonaceous chondrites with different alteration histories is important for interpreting returned samples from the OSIRIS-REx and Hayabusa 2 missions.

C1 chondrite↗

NASA NTRSDate not supplied

Thermochemical/Thermomechanical Synergies in High-Temperature Solid Particle Erosion of CMAS-Exposed EBCs

Environmental barrier coatings (EBCs) are an enabling technology for the use of SiC-based ceramic matrix composites in next generation gas turbine engines. In the extreme engine environment, EBCs must be able to withstand a variety of individual damage mechanisms and their interactions with each other. Ingested particulates/debris can cause both thermochemical and thermomechanical degradation of EBCs. Siliceous debris primarily based on calcium magnesium aluminosilicates (CMAS) can melt and infiltrate and/or react with EBCs above 1200°C. Similarly, ingested debris can lead to mechanical damage and recession of coatings due to particulate erosion. Both modes of degradation can occur simultaneously during engine operation, and it is crucial to comprehensively understand the mechanisms of coating failure due to high-temperature particulate interactions. This study assesses the erosion durability of Yb 2 Si 2 O 7 -based EBCs exposed to CMAS of various loads in NASA Glenn’s Erosion Burner Rig Facility. CMAS exposures and erosion testing were carried out at 1316°C. The effects of CMAS loading and exposure time on EBC erosion durability were evaluated using Al 2 O 3 as an erodent material.

CMAS↗