Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “chemical dynamics”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 757 records · Page 42

NLC-91

Noctilucent Clouds (NLC)-91 is a multinational rocket and radar program which will take place in Jul. - Aug. 1991 in northern Scandinavia and the Barents Sea. The main objective of the campaign is to determine with in situ experiments the dynamical, electrodynamical, physical, and chemical parameters of an NLC layer combined with ground based visible radar, lidar, and microwave experiments. The altitude resolution of ground based and in situ measurements in the cold mesopause region should be improved in NLC-91 compared to the previous campaigns below 100 m.

Kopp, E.↗

Episodic total ozone minima and associated effects on heterogeneous chemistry and lower stratospheric transport

Three-dimensional model simulations are used to describe the January 31, 1989 ozone minihole over Stavanger, Norway. This minihole is typical of many transient events in the lower stratosphere that arise because of cyclonic-scale disturbances in the troposphere. Although the ozone reduction is a short-lived reversible dynamical event, through heterogeneous chemical processes there can be a significant transfer of chlorine from reservoir molecules to active radicals. This chemically perturbed air is defined as processed air, and it is found that a single event can produce enough processed air to reduce the HCl in the entire polar vortex. Chemical processing on clouds associated with transient events is shown to be a major source of processed air in the polar vortex in December before background temperatures are cold enough for more uniform heterogeneous conversion.

Rood, Richard B.↗

Fluid/chemistry modeling for hypersonic flight analysis

Design studies are underway for a variety of hypersonic flight vehicles. The National Aero-Space Plane will provide a reusable, single-stage-to-orbit capability for routine access to low earth orbit. Flight-capable satellites will dip into the atmosphere to maneuver to new orbits, while planetary probes will decelerate at their destination by atmospheric aerobraking. To supplement limited experimental capabilities in the hypersonic regime, computational fluid dynamics is being used to analyze the flow about these configurations. The governing equations include fluid dynamic as well as chemical species equations, which are being solved with new, robust numerical algorithms. Examples of CFD applications to hypersonic vehicles suggest an important role this technology will play in the development of future aerospace systems. The computational resources needed to obtain solutions are large, but solution-adaptive grids, convergence acceleration, and parallel processing may make run times manageable.

Edwards, Thomas A.↗

CFD applications in hypersonic flight

Design studies are underway for a variety of hypersonic flight vehicles. The National Aero-Space Plane will provide a reusable, single-stage-to-orbit capability for routine access to low earth orbit. Flight-capable satellites will dip into the atmosphere to maneuver to new orbits, while planetary probes will decelerate at their destination by atmospheric aerobraking. To supplement limited experimental capabilities in the hypersonic regime, CFD is being used to analyze the flow about these configurations. The governing equations include fluid dynamic as well as chemical species equations, which are solved with robust upwind differencing schemes. Examples of CFD applications to hypersonic vehicles suggest an important role this technology will play in the development of future aerospace systems. The computational resources needed to obtain solutions are large, but various strategies are being exploited to reduce the time required for complete vehicle simulations.

Edwards, T. A.↗

Earth System science

Recent research has solidified a view of the Earth as a global-scale interactive system with complex chemical, physical, biological and dynamical processes that link the ocean, atmosphere, land (soils, ice, snow) and marine and terrestrial living organisms. These processes both within and between the major parts of the system help determine global and regional climate and control the biogeochemical and hydrologic cycles essential to life. The study of the Earth System requires measurements ranging from the scales of the smallest processes to the global scale. An ambitious satellite observational program, the Earth Observing System (EOS), carried out along with the complementary and ongoing World Climate Research Program (WCRP) and International Geosphere-Biosphere Program (IGBP) represents a major international effort to understand this System and predict its future changes. The complex and intriguing nature of the Earth System is discussed along with a number of closely coupled processes occurring within it. These are: clouds, precipitation and vegetation; ocean circulation, sea-surface temperature and phytoplankton; coupled oceanic and atmospheric circulation (the Southern Oscillation); biological activity, atmospheric chemistry and climate; and biological emissions and the ozone layer.

Prinn, R. G.↗

STS-69 Flight Day 3 Highlights

On the third day of the STS-69 mission, the flight crew (Cmdr. Dave Walker, Pilot Ken Cockrell, and Mission Specialists Jim Voss, Mike Gernhardt, and Jim Newman) test the Orbital Maneuvering System and prepare for the retrieval of the SPARTAN satellite with a checkout procedure of the space shuttle's robot arm. Physiological and chemical experiments on fluid dynamics are conducted as part of the Sea Lab project. Urine and blood samples from the crew are collected and studied under microgravity conditions, and a slime mold experiment is conducted to determine the properties of motion, growth, and chemistry in zero gravity conditions. Earth views include cloud cover, a hurricane, and a close-up of its eye.

Source record↗

Observations of Dynamic Strain Aging in Polycrystalline NiAl

Dynamic strain aging has been investigated at temperatures between 77 and 1100 K in eight polycrystalline NiAl alloys. The 0.2% offset yield stress and work hardening rates for these alloys generally decreased with increasing temperature. However, local plateaus or maxima were observed in conventional purity and carbon doped alloys at intermediate temperatures (600-900 K). This anomalous behavior was not observed in low interstitial high-purity, nitrogen doped, or in titanium doped materials. Low or negative strain rate sensitivities (SRS) were also observed in all eight alloys in this intermediate temperature range. Coincident with the occurrence of negative SRS was the occurrence of serrated flow in conventional purity alloys containing high concentrations of Si in addition to C. These phenomena have been attributed to dynamic strain aging (DSA). Chemical analysis of the alloys used in this study suggests that the main species causing strain aging in polycrystalline NiAl is C but indicate that residual Si impurities can enhance the strain aging effect.

Weaver, M. L.↗

Manifestations of Dynamic Strain Aging in Soft-Oriented NiAl Single Crystals

The tensile and compressive properties of six NiAl-base single-crystal alloys have been investigated at temperatures between 77 and 1200 K. The normalized critical resolved shear stresses (CRSS/E) and work-hardening rates (Theta/E) for these alloys generally decreased with increasing temperature. However, anomalous peaks or plateaus for these properties were observed in conventional purity (CPNiAl), Si-doped (NiAl-Si), C-doped low Si (UF-NiAl1), and Mo-doped (NiAl-Mo) alloys at intermediate temperatures (600 to 1000 K). This anomalous behavior was not observed in high-purity, low interstitial material (HP-NiAl). Low or negative strain-rate sensitivities (SRS) also were observed in all six alloys in this intermediate temperature range. Coincident with the occurrence of negative strain-rate sensitivities was the observation of serrated stress-strain curves in the CPNiAl and NiAl-Si alloys. These phenomena have been attributed to dynamic strain aging (DSA). Chemical analysis of the alloys used in this study suggests that the main specie responsible for strain aging in NiAl is C but indicate that residual Si impurities can enhance the strain aging effects. The corresponding dislocation microstructures at low temperatures (300 to 600 K) were composed of well-defined cells. At intermediate temperatures (600 to 900 K), either poorly defined cells or coarse bands of localized slip, reminiscent of the vein structures observed in low-cycle fatigue specimens deformed in the DSA regime, were observed in conventional purity, Si-doped, and in Mo-doped alloys. In contrast, a well-defined cell structure persisted in the low interstitial, high-purity alloy. At elevated temperatures (greater than or equal to 1000 K), more uniformly distributed dislocations and sub-boundaries were observed in all alloys. These observations are consistent with the occurrence of DSA in NiAl single-crystal alloys at intermediate temperatures.

Weaver, M. L.↗

Delta Clipper-Experimental In-Ground Effect on Base-Heating Environment

A quasitransient in-ground effect method is developed to study the effect of vertical landing on a launch vehicle base-heating environment. This computational methodology is based on a three-dimensional, pressure-based, viscous flow, chemically reacting, computational fluid dynamics formulation. Important in-ground base-flow physics such as the fountain-jet formation, plume growth, air entrainment, and plume afterburning are captured with the present methodology. Convective and radiative base-heat fluxes are computed for comparison with those of a flight test. The influence of the laminar Prandtl number on the convective heat flux is included in this study. A radiative direction-dependency test is conducted using both the discrete ordinate and finite volume methods. Treatment of the plume afterburning is found to be very important for accurate prediction of the base-heat fluxes. Convective and radiative base-heat fluxes predicted by the model using a finite rate chemistry option compared reasonably well with flight-test data.

Wang, Ten-See↗

Experimental Investigation of Organic Synthesis in Hydrothermal Environments

Seafloor hydrothermal systems may be the most likely locations on the early Earth for the emergence of life. Because of the disequilibrium inherent in such dynamic, mixing environments, abundant chemical energy would have been available for formation of the building blocks of life. In addition, theoretical studies suggest that organic compounds in these conditions would reach metastable states, due to kinetic barriers to the formation of stable equilibrium products (CO2 and methane). The speciation of organic carbon in metastable states is highly dependent on the oxidation state, pH, temperature, pressure and bulk composition of the system. The goal of our research is to investigate the effects of a number external variables on the formation, transformation, and stability of organic compounds at hydrothermal conditions. We have begun experimental work to attempt to control the oxidation state of simulated hydrothermal systems by using buffers composed of mineral powders and gas mixtures. We are also beginning to test the stability of organic compounds under these conditions. The experiments are being performed using the hydrothermal bomb apparatus at the U.S. Geological Survey in Menlo Park, CA and the supercritical water oxidizer (SCWO) at NASA Ames Research Center in Moffet Field, CA. The amino acids decomposed rapidly. Even after the approximately 15 minutes between addition of the amino acids and the first sampling, no amino acids were detected in the PPM system by GC- MS, while in the FeFeO system the amino acids were present at a level of less than 50% of original. Carboxylic acids, ammonia, and CO2 were the main products, along with some unidentified compounds. The ratios of carboxylic acids and concentrations of other products seem to have remained stable during the experiments, consistent with observations of other metastable systems and theoretical predictions.

Shock, Everett L.↗

Experimental Investigation of Organic Synthesis in Hydrothermal Environments

The results of the investigation were presented at a Astrobiology Institute General Meeting. Seafloor hydrothermal systems may be the most likely locations on the early Earth for the emergence of life. Because of the disequilibrium inherent in such dynamic, mixing environments, abundant chemical energy would have been available for formation of the building blocks of life. In addition, theoretical studies suggest that organic compounds in these conditions would reach metastable states, due to kinetic barriers to the formation of stable equilibrium products (CO2 and methane). The speciation of organic carbon in metastable states is highly dependent on the oxidation state, pH, temperature, pressure and bulk composition of the system. The goal of our research is to investigate the effects of a number external variables on the formation, transformation, and stability of organic compounds at hydrothermal conditions. We have begun experimental work to attempt to control the oxidation state of simulated hydrothermal systems by using buffers composed of mineral powders and gas mixtures. We are also beginning to test the stability of organic compounds under these conditions.

Shock, Everett L.↗

Synoptic Mapping of Chemical Composition, Thermal Structure, and Air Motion from UARS Observations

An operational mapping algorithm was developed to process measurements of individual species observed by different satellite instruments on board UARS. Based on Fast Fourier Synoptic Mapping (FFSM), the algorithm accounts for the precessing orbit of UARS, the error of individual instruments, and gaps associated with instrument duty cycle and the satellite yaw maneuver. It provides synoptic structure and evolution on periods as short as 1 day, derived collectively from all observations of an individual species. The algorithm was applied to synoptically map temperature, thickness, and several chemical constituents observed by the instruments: MLS, CLAES, ISAMS, and HALOE. Each field variable observed by these instruments was mapped twice-daily in continuous global time series several months long. Mapped behavior produced via FFSM was compared against standard archived products generated via Kalman filtering. The standard map products reveal similar behavior, but are limited to features of larger scale. Tracer structure that develops through flow deformation and attending transport is therefore represented in those products more coarsely, eventually being sheared down to scales that are no longer represented properly. The synoptic time series also reveal a diurnal cycle for several of the constituents, one that emerges clearly in their space-time spectra. The zonal and meridional structure of diurnal variability was mapped by filtering the space-time spectrum, an intermediate product of FFSM, to those scales resolved by the UARS sampling. Geographical variations of the diurnal cycle have also been evaluated in its seasonal-mean structure by compositing distributions at individual local times. Both were compared to diurnal variations in chemical models and in dynamical models that account for transport by the diurnal tide. Diurnal variations were found to introduce spurious behavior into the archived products generated via Kalman filtering, behavior that is misrepresented in those synoptic time series. Aliasing by under-sampled diurnal variations introduces a bias into the time-mean structure of archived products. That systematic error is manifested as anomalous wave structure in the time-mean fields. By contrast, synoptic time series generated via FFSM faithfully represent such behavior as varying diurnally, so it does not corrupt time-mean structure. Tracer structure mapped via the above algorithm was being applied to determine the Brewer-Dobson circulation of the stratosphere through Lagrangian considerations. Preliminary results are encouraging: They reveal diabatic ascent in the tropics, balanced by diabatic descent over the winter hemisphere. This Lagrangian description of transport derived from UARS tracer measurements would be potentially valuable for diagnosing interannual changes of transport, specifically, in relation to interannual changes of total ozone. Regrettably, support was reduced to 50% of the approved funding level, leaving this component incomplete.

Salby, Murry L.↗

A Search for Supernova in Star-Burst Galaxies

The rate at which massive supernovae occur in galaxies can be related directly to the rate of formation of massive stars this rate in turn can be computed from measurements and theoretical models of stellar mss distributions. Other measurements such as chemical composition and the dynamical structure of galaxies can also be used to infer the rate of massive supernovae. Various lines of reasoning using these measurements and theories of star formation have predicted a supernova rate which might be as much as ten times the rate of supernovae that had been observed using optical telescopes. The unseen supernovae were thought to be undetected due to a variety of circumstances, with the primary problem being extinction imposed by dust along the line of observation. This research used new infrared observations of the Infrared Space Observatory (ISO) space craft to explore active galaxies with a technique unhindered by dust extinction. New image processing algorithms for ISO point source analysis and cosmic ray deglitching were developed in order to search through a fairly complete set of the ISO data.

Rank, David M.↗

Models of Fallback

The impact of a typical Shoemaker-Levy 9 fragment produced three light peaks as seen from Earth. The first peak is related to the entry of the fragment into the jovian atmosphere. The second peak occurs when the exploding fireball rises above Jupiter's limb into direct view from Earth. The third peak, much the brightest, occurs when the ejecta plume falls back on the atmosphere. Here we present a simple, highly idealized model of a ballistic plume, which we then use to fit the observed light curve of the R impact as recorded at Mauna Kea and Mt.Palomar. The nominal R fragment has diameter 500 m and mass 3x10(sup)13 g, with energy release of 5x10(sup)26 ergs. The largest events were about three times more energetic. These sizes agree with those deduced by Ashaug and Benz from the dynamics of tidal disruption. Chemical products of the reentry shock included the sulfur compounds S2, CS, and CS2. These were emplaced very high in the atmosphere (ca. 100 microbars). The yield of the reduced compounds CS and CS2, coupled with the apparent absence of the oxidized compounds SO and SO2, indicate that the explosions occurred above the jovian water clouds.

Zahnle, Kevin↗

Advanced Computational Modeling of Vapor Deposition in a High-pressure Reactor

In search of novel approaches to produce new materials for electro-optic technologies, advances have been achieved in the development of computer models for vapor deposition reactors in space. Numerical simulations are invaluable tools for costly and difficult processes, such as those experiments designed for high pressures and microgravity conditions. Indium nitride is a candidate compound for high-speed laser and photo diodes for optical communication system, as well as for semiconductor lasers operating into the blue and ultraviolet regions. But InN and other nitride compounds exhibit large thermal decomposition at its optimum growth temperature. In addition, epitaxy at lower temperatures and subatmospheric pressures incorporates indium droplets into the InN films. However, surface stabilization data indicate that InN could be grown at 900 K in high nitrogen pressures, and microgravity could provide laminar flow conditions. Numerical models for chemical vapor deposition have been developed, coupling complex chemical kinetics with fluid dynamic properties.

Cardelino, Beatriz H.↗

A Massively Parallel Particle Code for Rarefied Ionized and Neutral Gas Flows in Earth and Planetary Atmospheres, Ionospheres and Magnetospheres

In order to understand the global structure, dynamics, and physical and chemical processes occurring in the upper atmospheres, exospheres, and ionospheres of the Earth, the other planets, comets and planetary satellites and their interactions with their outer particles and fields environs, it is often necessary to address the fundamentally non-equilibrium aspects of the physical environment. These are regions where complex chemistry, energetics, and electromagnetic field influences are important. Traditional approaches are based largely on hydrodynamic or magnetohydrodynamic MHD) formulations and are very important and highly useful. However, these methods often have limitations in rarefied physical regimes where the molecular collision rates and ion gyrofrequencies are small and where interactions with ionospheres and upper neutral atmospheres are important.

Combi, Michael R.↗

A Massively Parallel Hybrid Dusty-Gasdynamics and Kinetic Direct Simulation Monte Carlo Model for Planetary Applications

In order to understand the global structure, dynamics, and physical and chemical processes occurring in the upper atmospheres, exospheres, and ionospheres of the Earth, the other planets, comets and planetary satellites and their interactions with their outer particles and fields environs, it is often necessary to address the fundamentally non-equilibrium aspects of the physical environment. These are regions where complex chemistry, energetics, and electromagnetic field influences are important. Traditional approaches are based largely on hydrodynamic or magnetohydrodynamic (MHD) formulations and are very important and highly useful. However, these methods often have limitations in rarefied physical regimes where the molecular collision rates and ion gyrofrequencies are small and where interactions with ionospheres and upper neutral atmospheres are important. At the University of Michigan we have an established base of experience and expertise in numerical simulations based on particle codes which address these physical regimes. The Principal Investigator, Dr. Michael Combi, has over 20 years of experience in the development of particle-kinetic and hybrid kinetichydrodynamics models and their direct use in data analysis. He has also worked in ground-based and space-based remote observational work and on spacecraft instrument teams. His research has involved studies of cometary atmospheres and ionospheres and their interaction with the solar wind, the neutral gas clouds escaping from Jupiter s moon Io, the interaction of the atmospheres/ionospheres of Io and Europa with Jupiter s corotating magnetosphere, as well as Earth s ionosphere. This report describes our progress during the year. The contained in section 2 of this report will serve as the basis of a paper describing the method and its application to the cometary coma that will be continued under a research and analysis grant that supports various applications of theoretical comet models to understanding the inner comae of comets (grant NAGS- 13239 from the Planetary Atmospheres program).

Combi, Michael R.↗

Advanced Computational Modeling of Vapor Deposition in a High-Pressure Reactor

In search of novel approaches to produce new materials for electro-optic technologies, advances have been achieved in the development of computer models for vapor deposition reactors in space. Numerical simulations are invaluable tools for costly and difficult processes, such as those experiments designed for high pressures and microgravity conditions. Indium nitride is a candidate compound for high-speed laser and photo diodes for optical communication system, as well as for semiconductor lasers operating into the blue and ultraviolet regions. But InN and other nitride compounds exhibit large thermal decomposition at its optimum growth temperature. In addition, epitaxy at lower temperatures and subatmospheric pressures incorporates indium droplets into the InN films. However, surface stabilization data indicate that InN could be grown at 900 K in high nitrogen pressures, and microgravity could provide laminar flow conditions. Numerical models for chemical vapor deposition have been developed, coupling complex chemical kinetics with fluid dynamic properties.

Cardelino, Beatriz H.↗