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NASA NTRS2001

Investigating Type I Polar Stratospheric Cloud Formation Mechanisms with POAM Satellite Observations

Type Ia PSCs are believed to be composed of nitric acid hydrate particles. Recent results from the SOLVE/THESEO 2000 campaign showed evidence that this type of PSC was composed of a small number of very large particles capable of sedimentary denitrification of regions of the stratosphere. It is unknown whether homogeneous or heterogeneous nucleation is responsible for the formation of these PSCs. Arctic winters are tending to be colder in response to global tropospheric warming. The degree to which this influences ozone depletion will depend on the freezing mechanism of nitric acid hydrate particles. If nucleation is homogeneous it implies that the freezing process is an inherent property of the particle, while heterogeneous freezing means that the extent of PSCs will depend in part on the number of nuclei available. The Polar Ozone and Aerosol Measurement (POAM)II and III satellites have been making observations of stratospheric aerosols and Polar Stratospheric Clouds (PSCs) since 1994. Recently, we have developed a technique that can discriminate between Type Ia and Ib PSCs using these observations. A statistical approach is employed to demonstrate the robustness of this approach and results are compared with lidar measurements. The technique is used to analyze observations from POAM II and II during Northern Hemisphere winters where significant PSC formation occurred with the objective of exploring Type I PSC formation mechanisms. The different PSCs identified using this method exhibit different growth curve as expressed as extinction versus temperature.

Strawa, Anthony W.↗

DOE OSTI2025

Correlation of optical properties with particle size, morphology, and polymorph of fine- and nano-particle formulations of titanium dioxide powders

Titanium dioxide (TiO 2 ) particulates are known to exhibit different visible and infrared optical properties compared to the bulk material, showing strong dependence on particle size, crystal structure, and morphology. In this study, the optical properties, sizes, and morphologies of TiO 2 particles from two different sources (nano and fine powders) having a) nominally different particle sizes and b) various crystal polymorph mixture fractions are compared using a combination of single particle mass spectrometry, optical spectroscopies, and aerosol characterization methods. The nano sample was found to be largely particles of the anatase polymorph (88% by mass), while the fine sample was found to consist largely of rutile particles (95% by mass). Two distinct particle morphologies (fractal and compact) were found in each powder sample and could be identified and separated in-situ based on particle aerodynamic properties. The attenuation of near-infrared, visible and ultraviolet light by TiO 2 particles shows strong dependence on particle morphology. Furthermore, while the fine particles were found to have larger near-infrared (675–800 nm) extinction coefficients by mass than the nanoparticles, the reverse was true in the ultraviolet and visible regions (370–675 nm). However, for polydisperse particles with different sizes and shapes, the optical behaviors are not straightforward to directly correlate to a combination of physical parameters.

Lockwood, Schuyler P. [Pacific Northwest National ↗

NASA NTRS2006

Advances in Raman Lidar Measurements of Water Vapor, Cirrus Clouds and Carbon Dioxide

Narrow-band interference filters with improved transmission in the ultraviolet have been developed under NASA-funded research and used in the Raman Airborne Spectroscopic Lidar (RASL) in ground- based, upward-looking tests. RASL is an airborne Raman Lidar system designed to measure water vapor mixing ratio, and aerosol backscatter/extinction/depolarization. It also possesses the capability to make experimental measurements of cloud liquid water and carbon dioxide. It is being prepared for first flight tests during the summer of 2006. With the newly developed filters installed in RASL, measurements were made of atmospheric water vapor, cirrus cloud optical properties and carbon dioxide that improve upon any previously demonstrated using Raman lidar. Daytime boundary layer profiling of water vapor mixing ratio is performed with less than 5% random error using temporal and spatial resolution of 2-minutes and 60 - 210, respectively. Daytime cirrus cloud optical depth and extinction- to-backscatter ratio measurements are made using 1-minute average. Sufficient signal strength is demonstrated to permit the simultaneous profiling of carbon dioxide and water vapor mixing ratio into the free troposphere during the nighttime. Downward-looking from an airborne RASL should possess the same measurement statistics with approximately a factor of 5 - 10 decrease in averaging time. A description of the technology improvements are provided followed by examples of the improved Raman lidar measurements.

Whiteman, David N.↗

NASA NTRS1998

Structural Loading on the QCM/SAW Instrument Aboard the ER-2 Used for Atmospheric Testing

Several experiments have been proposed to capture and evaluate samples of the atmosphere where SST's travel. One means to achieve this is to utilize the quartz crystal microbalance (QCM) / surface acoustical wave (SAW) instrument installed aboard the ER-2, formerly the U-2 reconnaissance aircraft. The QCM is a cascade impactor designed to perform in-situ, real-time measurements of aerosols and chemical vapors at an altitude of 60,000-70,000 feet. The primary use of the ER-2 is by NASA for Earth resources to test new sensor systems before being placed aboard satellites. One of the main reasons the ER-2 is used for this flight experiment is its capability to fly approximately twelve miles above the sea level (can reach an altitude of 78,000 feet). Because the ER-2 operates at such a high altitude, it is of special interest to scientists interested in space exploration or supersonic aircraft. The purpose of some of the experiments is to extinct data from the atmosphere around the ER-2. For the current CSTEA flight experiment, the housing of the QCM is in a frame that connects to an outer pod that attaches to the fuselage of the ER-2. Due to the location of the QCM within the housing frame and the location of the pod on the ER-2, the pod and its contents are subject to structural loads. In addition to structural loads, structural vibrations are also of importance because the QCM output data is based on the determination of beat frequencies between a pair of oscillators (one coated, the second uncoated, according to the chemical reaction being monitored). A structural analysis of this system can indicate whether potential resonances may exist between the (higher) structural modal frequencies and the beat frequencies. In addition undesirable deformations may result due to maximum expected static or dynamic loads during typical flight conditions. If the deformations are excessive they may adversely affect the accuracy the instrumentation output.

Bainum, Peter M.↗

NASA NTRS2008

Radiative Susceptibility of Cloudy Atmospheres to Droplet Number Perturbations: 1. Theoretical Analysis and Examples from MODIS

Theoretical and satellite-based assessments of the sensitivity of broadband shortwave radiative fluxes in cloudy atmospheres to small perturbations in the cloud droplet number concentration (N) of liquid water clouds under constant water conditions are performed. Two approaches to study this sensitivity are adopted: absolute increases in N, for which the radiative response is referred to as absolute cloud susceptibility, and relative increases in N or relative cloud susceptibility. Estimating the former is more challenging as it requires an assumed value for either cloud liquid water content or geometrical thickness; both susceptibilities require an assumed relationship between the droplet volume and effective radius. Expanding upon previous susceptibility studies, present radiative calculations include the effect of AN perturbations on droplet asymmetry parameter and single-scattering albedo, in addition to extinction. Absolute cloud susceptibility has a strong nonlinear dependence on the droplet effective radius as expected, while relative cloud susceptibility is primarily dependent on optical thickness. Molecular absorption and reflecting surfaces both reduce the relative contribution of the cloud to the top-of-atmosphere (TOA) flux and therefore also reduce the TOA albedo susceptibility. Transmittance susceptibilities are negative with absolute values similar to albedo susceptibility, while atmospheric absorptance susceptibilities are about an order of magnitude smaller than albedo susceptibilities and can be either positive or negative. Observation-based susceptibility calculations are derived from MODIS pixel-level retrievals of liquid water cloud optical thickness, effective radius, and cloud top temperature; two data granule examples are shown. Susceptibility quantifies the aerosol indirect effect sensitivity in a way that can be easily computed from model fields. As such, susceptibilities derived from MODIS observations provide a higher-order test of model cloud properties used for indirect effect studies. MODIS-derived global distributions of cloud susceptibility and radiative forcing calculations are presented in a companion paper.

Platnick, Steven↗

NASA NTRS1991

Simulations of microphysical, radiative, and dynamical processes in a continental-scale forest fire smoke plume

The impact of a large forest fire smoke plume on atmospheric processes is studied through a numerical model of meteorology, aerosols, and radiative transfer. The simulated smoke optical depths at 0.63-micron wavelength are in agreement with analyses of satellite data and show values as high as 1.8. The smoke has an albedo of 35 percent, or more than double the clear-sky value, and cools the surface by as much as 5 K. An imaginary refractive index, n sub im, of 0.01 yields results which closely match the observed cooling, single scattering albedo, and the Angstrom wavelength exponent. An n exp im of 0.1, typical of smoke from urban fires, produces 9 K cooling. Coagulation causes the geometric mean radius by number to increase from the initial value of 0.08 micron to a final value of 0.15 micron, while the specific extinction and absorption increase by 40 and 25 percent, respectively.

Westphal, Douglas L.↗

DOE OSTI2021

Implementing a Stochastic Soot Model in a 3D Domain

In this document a highly detailed stochastic soot model limited to 0D simulations is coupled to 3D domains through the use of a Lagrangian parcel-Eulerian fluid method. Although both the stochastic soot model used and the Lagrangian parcel-Eulerian fluid method have long histories of development, their use, as described in this document, is novel and useful. Previous works significant to the model's development include documents from both the stochastic and simpler soot model genre and the fuel, aerosol, and other particle tracking and Lagrangian parcel-Eulerian fluid genres. Developing the theory behind the model is crucial to its implementation because of the unconventional Lagrangian parcel-Eulerian fluid representation. In fact, the Lagrangian parcel-Eulerian fluid coupling is only a means of simplifying the much more difficult theoretical model. Despite the accompanying assumptions, the complete model is validated from the bottom up and then again in a holistic fashion with promising results. Then the model is used in multiple case studies, showcasing capabilities not had by other models. The optical properties of soot generated in a Spray A simulation are calculated to find measured results are likely overpredicting the mass of soot along the central axis via KL extinction measurements. A thermophoresis submodel that calculates force based on the soot particles' shape is installed to find it has a high influence on the path of the heaviest soot particles. Investigations into the HACA mechanism for soot growth and the effect of syngas on soot in 3D domains are performed with much more detail than has been available before.

Strickland, Tyler↗

NASA NTRS2013

Ice Nucleation and Dehydration in the Tropical Tropopause Layer

Optically thin cirrus near the tropical tropopause regulate the humidity of air entering the stratosphere, which in turn has a strong influence on the Earth's radiation budget and climate. Recent highaltitude, unmanned aircraft measurements provide evidence for two distinct classes of cirrus formed in the tropical tropopause region: (i) vertically extensive cirrus with low ice number concentrations, low extinctions, and large supersaturations (up to approx. 70%) with respect to ice; and (ii) vertically thin cirrus layers with much higher ice concentrations that effectively deplete the vapor in excess of saturation. The persistent supersaturation in the former class of cirrus is consistent with the long time-scales (several hours or longer) for quenching of vapor in excess of saturation given the low ice concentrations and cold tropical tropopause temperatures. The low-concentration clouds are likely formed on a background population of insoluble particles with concentrations less than 100 L−1 (often less than 20 L−1), whereas the high ice concentration layers (with concentrations up to 10,000 L−1) can only be produced by homogeneous freezing of an abundant population of aqueous aerosols. These measurements, along with past high-altitude aircraft measurements, indicate that the low-concentration cirrus occur frequently in the tropical tropopause region, whereas the high-concentration cirrus occur infrequently. The predominance of the low-concentration clouds means cirrus near the tropical tropopause may typically allow entry of air into the stratosphere with as much as approx. 1.7 times the ice saturation mixing ratio.

dehydration↗

NASA NTRS1999

Predicting Decade-to-Century Climate Change: Prospects for Improving Models

Recent research has led to a greatly increased understanding of the uncertainties in today's climate models. In attempting to predict the climate of the 21st century, we must confront not only computer limitations on the affordable resolution of global models, but also a lack of physical realism in attempting to model key processes. Until we are able to incorporate adequate treatments of critical elements of the entire biogeophysical climate system, our models will remain subject to these uncertainties, and our scenarios of future climate change, both anthropogenic and natural, will not fully meet the requirements of either policymakers or the public. The areas of most-needed model improvements are thought to include air-sea exchanges, land surface processes, ice and snow physics, hydrologic cycle elements, and especially the role of aerosols and cloud-radiation interactions. Of these areas, cloud-radiation interactions are known to be responsible for much of the inter-model differences in sensitivity to greenhouse gases. Recently, we have diagnostically evaluated several current and proposed model cloud-radiation treatments against extensive field observations. Satellite remote sensing provides an indispensable component of the observational resources. Cloud-radiation parameterizations display a strong sensitivity to vertical resolution, and we find that vertical resolutions typically used in global models are far from convergence. We also find that newly developed advanced parameterization schemes with explicit cloud water budgets and interactive cloud radiative properties are potentially capable of matching observational data closely. However, it is difficult to evaluate the realism of model-produced fields of cloud extinction, cloud emittance, cloud liquid water content and effective cloud droplet radius until high-quality measurements of these quantities become more widely available. Thus, further progress will require a combination of theoretical and modeling research, together with intensified emphasis on both in situ and space-based remote sensing observations.

Somerville, Richard C. J.↗

NASA NTRS1994

H2O-H2SO4 system in Venus' clouds and OCS, CO, and H2SO4 profiles in Venus' troposphere

A coupled problem of diffusion and condensation is solved for the H2SO4-H2O system in Venus' cloud layer. The position of the lower cloud boundary and profiles of the H2O and H2SO4 vapor mixing ratios and of the H2O/H2SO4 ratio of sulfuric acid aerosol and its flux are calculated as functions of the column photochemical production rate of sulfuric acid, Phi(sub H2SO4). Variations of the lower cloud boundary are considered. Our basic model, which is constrained to yield f(sub H2O) (30 km) = 30 ppm (Pollack et al. 1993), predicts the position of the lower cloud boundary at 48.4 km coinciding with the mean Pioneer Venus value, the peak H2SO4 mixing ratio of 5.4 ppm, and the H2SO4 production rate Phi(sub H2SO4) = 2.2 x 10(exp 12)/sq cm/s. The sulfur to sulfuric acid mass flux ratio in the clouds is 1:27 in this model, and the mass loading ratio may be larger than this value if sulfur particles are smaller than those of sulfuric acid. The model suggests that the extinction coefficient of sulfuric acid particles with radius 3.7 micrometers (mode 3) is equal to 0.3/km in the middle cloud layer. The downward flux of CO is equal to 1.7 x 10(exp 12)/sq cm/s in this model. Our second model, which is constrained to yield f(sub H2O) = 10 ppm at the lower cloud boundary, close to the value measured by the Magellan radiooccultations, predicts the position of this boundary to be at 46.5 km, which agrees with the Magellan data; f(sub H2O) (30 km) = 90 ppm, close to the data of Moroz et al. (1983) at this altitude; Phi(sub H2SO4) = 6.4 x 10(exp 12)/sq cm/s; and Phi(sub co) = 4.2 x 10(exp 12)/sq cm/s. The S/H2SO4 flux mass ratio is 1:18, and the extinction coefficient of the mode 3 sulfuric acid particles is equal to 0.9 km in the middle cloud layer. A strong gradient of the H2SO4 vapor mixing ratio near the bottom of the cloud layer drives a large upward flux of H2SO4, which condenses and forms the excessive downward flux of liquid sulfuric acid, which is larger by a factor of 4-7 than the flux in the middle cloud layer. This is the mechanism of formation of the lower cloud layer. Variations of the lower cloud layer are discussed. Our modeling of the OCS and CO profiles in the lower atmosphere measured by Pollack et al. (1993) provides a reasonable explanation of these data and shows that the rate coefficient of the reaction SO3 + CO yields CO2 + SO2 is equal to 10(exp -11) exp(-(13,100 +/- 1000)/T) cc/s. The main channel of the reaction between SO3 and OCS is CO2 + (SO)2, and its rate coefficient is equal to 10(exp -11) exp(-(8900 +/- 500)/T) cc/s. In the conditions of Venus' lower atmosphere, (SO)2 is removed by the reaction (SO)2 + OCS yields CO + S2 + SO2. The model predicts an OCS mixing ratio of 28 ppm near the surface.

Krasnopolsky, V. A.↗

DOE OSTI2024

EPCAPE-PT-LANL Measurements: Aerodynamic Part Sizer

Coastal cities offer a unique environment for studying aerosol-cloud interactions and the effects of urban emissions on cloud properties. As part of the Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE), the Partitioning Thrust by Los Alamos National Laboratory (EPCAPE-PT-LANL) was conducted. Our campaign focused on measuring the optical and chemical properties of aerosols and their interactions within marine stratocumulus clouds in La Jolla, California. EPCAPE-PT-LANL enhances the primary goals of EPCAPE through innovative observations of vapor-phase transitions between aerosols and cloud droplets, the impact of black carbon on aerosol-cloud dynamics, and the effects of cloud processing on aerosol optical properties. Instrument: Aerodynamic particle sizer (TSI) Files data_10min_APS.csv Header: - List [0.54 to 19.81] middle of the size bin in microns: Data reports the concentration particles in this size bin per cubic centimeter, dN/dLog(dp). - CVI_Flag[bool]: A boolean flag indicating whether the Counterflow Virtual Impactor (CVI) was active (true) or inactive (false) during the measurement.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2021

Application of Radon Transform to Multi-Angle Measurements Made by the Research Scanning Polarimeter: A New Approach to Cloud Tomography. Part I: Theory and Tests on Simulated Data.

The Research Scanning Polarimeter (RSP) is an airborne along-track scanner measuring the polarized and total reflectances in 9 spectral channels. The RSP was a prototype for the Aerosol Polarimetry Sensor (APS) launched on-board the NASA Glory satellite. Currently the retrieval algorithms developed for the RSP are being adopted for the measurements of the space-borne polarimeters on the upcoming NASA’s Plankton, Aerosol, Cloud Ocean Ecosystem (PACE)satellite mission. The RSP’s uniquely high angular resolution coupled with the high frequency of measurements allows for characterization of liquid water cloud droplet sizes using the polarized rainbow structure. It also provides geometric constraints on the cumulus cloud’s 2D cross section yielding the cloud’s geometric shape estimates. In this study we further build on the latter technique to develop a new tomographic approach to retrieval of cloud internal structure from remote sensing measurements. While tomography in the strict definition is a technique based on active measurements yielding a tomogram (directional optical thickness as a function of angle and offset of the view ray), we developed a “semi-tomographic” approach in which tomogram of the cloud is estimated from passive observations instead of being measured directly. This tomogram is then converted into 2D spatial distribution of the extinction coefficient using inverse Radon transform (filtered back projection) which is the standard tomographic procedure used e.g., in medical CT scans. This algorithm is computationally inexpensive compared to techniques relying on highly-multi-dimensional least-square fitting; it does not require iterative 3D RT simulations. The resulting extinction distribution is defined up to an unknown constant factor, so we discuss the ways to calibrate it using additional independent measurements. In the next step we use the profile of the droplet size distribution parameters from the cloud’s side (derived by fitting the polarized rainbows) to convert the 2D extinction distribution into that of the droplet number concentration. We illustrate and validate the proposed technique using 3D-RT-simulatedRSP observations of a LES-generated Cu cloud. Quantitative comparisons between the retrieved and the original optical and microphysical parameters are presented.

clouds↗

DOE OSTI2020

AATTENUATION—The Atmospheric Attenuation Model for CSP Tower Plants: A Look-Up Table for Operational Implementation

Attenuation of solar radiation between the receiver and the heliostat field in concentrated solar power (CSP) tower plants can reduce the overall system performance significantly. The attenuation varies strongly with time and the average attenuation at different sites might also vary strongly from each other. If no site specific attenuation data is available, the optimal plant design cannot be determined and rough estimations of the attenuation effect are required leading to high uncertainties of yield analysis calculations. The attenuation is caused mainly by water vapor content and aerosol particles in the lower atmospheric layer above ground. Although several on-site measurement systems have been developed during recent years, attenuation data sets are usually not available to be included during the plant project development. An Atmospheric Attenuation (AATTENUATION) model to derive the atmospheric transmittance between a heliostat and receiver on the basis of common direct normal irradiance (DNI), temperature, relative humidity, and barometric pressure measurements was developed and validated by the authors earlier. The model allows the accurate estimation of attenuation for sites with low attenuation and gives an estimation of the attenuation for less clear sites. However, the site-dependent coefficients of the AATTENUATION model had to be developed individually for each site of interest, which required time-consuming radiative transfer simulations, considering the exact location and altitude, as well as the pre-dominant aerosol type at the location. This strongly limited the application of the model despite its typically available input data. In this manuscript, a look-up table (LUT) is presented which enables the application of the AATTENUATION model at the site of interest without the necessity to perform the according complex radiative transfer calculations for each site individually. This enables the application of the AATTENUATION model for virtually all resource assessments for tower plants and in an operational mode in real time within plant monitoring systems around the world. The LUT also facilitates the generation of solar attenuation maps on the basis of long-term meteorological data sets which can be considered during resource assessment for CSP tower plant projects. The LUTs are provided together with this manuscript as supplementary files. The LUT for the AATTENUATION model was developed for a solar zenith angle (SZA) grid of 1°, an altitude grid of 100 m, 7 different standard aerosol types and the standard AFGL atmospheres for mid-latitudes and the tropics. The LUT was tested against the original version of the AATTENUATION model at 4 sites in Morocco and Spain, and it was found that the additional uncertainty introduced by the application of the LUT is negligible. With the information of latitude, longitude, altitude above mean sea level, DNI, relative humidity (RH), ambient temperature (Tair), and barometric pressure (bp), the attenuation can be now derived easily for each site of interest.

14 SOLAR ENERGY↗

NASA NTRS1992

Aureole lidar: Design, operation, and comparison with in-situ measurements

In 1986, H. Berber and Hooper examined the signals that could be detected by an airborne lidar flying above the marine boundary layer (MBL). One signal (aureole) formed from laser light returned to the receiver after a reflect off the ocean and forward scatter off the aerosol particles appeared to be both detectable and related to the optical depth of the MBL. Now, research has been directed towards developing a practical instrument to measure the aureole and finding an algorithm to use the information. Unlike the lidar backscatter which typically requires a telescope with a narrow field of view (0.5 mrad), the aureole signal occurs over a wide field of view (50 mrad). To accommodate the totally different needs, a standard commercial Cassegrainian telescope was modified to yield a telescope with two focal planes. The secondary mirror was replaced by a lens, whose front surface was half silvered and curved to match the replaced mirror. Light reflecting off the lens focused behind the primary mirror. The back lens surface was curved to allow unreflected light to focus at the natural focus of the primary mirror. This focal plane which is behind the lens has a wide field of view. To calculate an extinction profile, the aureole optical depth estimate is combined with the lidar backscatter profile.

Hooper, William P.↗

NASA NTRS2005

Review of HxPyOz-Catalyzed H + OH Recombination in Scramjet Nozzle Expansions; and Possible Phosphoric Acid Enhancement of Scramjet Flameholding, from Extinction of H3PO4 + H2 - Air Counterflow Diffusion Flames

Recent detailed articles by Twarowski indicate that small quantities of phosphorus oxides and acids in the fuel-rich combustion products of H2 + phosphine (PH3) + air should significantly catalyze H, OH and O recombination kinetics during high-speed nozzle expansions -- to reform H2O, release heat, and approach equilibrium more rapidly and closely than uncatalyzed kinetics. This paper is an initial feasibility study to determine (a) if addition of phosphoric acid vapor (H3PO4) to a H2 fuel jet -- which is much safer than using PH3 -- will allow combustion in a high-speed scramjet engine test without adverse effects on localized flameholding, and (b) if phosphorus-containing exhaust emissions are environmentally acceptable. A well-characterized axisymmetric straight-tube opposed jet burner (OJB) tool is used to evaluate H3PO4 addition effects on the air velocity extinction limit (flame strength) of a H2 versus air counterflow diffusion flame. Addition of nitric oxide (NO), also believed to promote catalytic H-atom recombination, was evaluated for comparison. Two to five mass percent H3PO4 in the H2 jet increased flame strength 4.2%, whereas airside addition decreased it 1%. Adding 5% NO to the H2 caused a 2% decrease. Products of H-atom attack on H3PO4 produced an intense green chemiluminescence near the stagnation point. The resultant exothermic production of phosphorus oxides and acids, with accelerated H-atom recombination, released sufficient heat near the stagnation point to increase flame strength. In conclusion, the addition of H3PO4 vapor (or more reactive P sources) to hydrogen in scramjet engine tests may positively affect flameholding stability in the combustor and thrust production during supersonic expansion -- a possible dual benefit with system design / performance implications. Finally, a preliminary assessment of possible environmental effects indicates that scramjet exhaust emissions should consist of phosphoric acid aerosol, with gradual conversion to phosphate aerosol. This is compared to various natural abundances and sources.

Pellett, Gerald↗

NASA NTRS2014

An Experimental and Computational Study on Soot Formation in a Coflow Jet Flame Under Microgravity and Normal Gravity

Upon the completion of the Structure and Liftoff in Combustion Experiment (SLICE) in March 2012, a comprehensive and unique set of microgravity coflow diffusion flame data was obtained. This data covers a range of conditions from weak flames near extinction to strong, highly sooting flames, and enabled the study of gravitational effects on phenomena such as liftoff, blowout and soot formation. The microgravity experiment was carried out in the Microgravity Science Glovebox (MSG) on board the International Space Station (ISS), while the normal gravity experiment was performed at Yale utilizing a copy of the flight hardware. Computational simulations of microgravity and normal gravity flames were also carried out to facilitate understanding of the experimental observations. This paper focuses on the different sooting behaviors of CH4 coflow jet flames in microgravity and normal gravity. The unique set of data serves as an excellent test case for developing more accurate computational models.Experimentally, the flame shape and size, lift-off height, and soot temperature were determined from line-of-sight flame emission images taken with a color digital camera. Soot volume fraction was determined by performing an absolute light calibration using the incandescence from a flame-heated thermocouple. Computationally, the MC-Smooth vorticity-velocity formulation was employed to describe the chemically reacting flow, and the soot evolution was modeled by the sectional aerosol equations. The governing equations and boundary conditions were discretized on an axisymmetric computational domain by finite differences, and the resulting system of fully coupled, highly nonlinear equations was solved by a damped, modified Newtons method. The microgravity sooting flames were found to have lower soot temperatures and higher volume fraction than their normal gravity counterparts. The soot distribution tends to shift from the centerline of the flame to the wings from normal gravity to microgravity.

microgravity↗

NASA NTRS2021

Polarimetric calibration of the Multi-Angle Imager for Aerosols (MAIA)

NASA’s Multi-Angle Imager for Aerosols (MAIA) mission, under development at the Jet Propulsion Laboratory, is designed to study the adverse health effects of different types of particulate air pollution. Planned for launch in 2023 for a 3-year mission, the MAIA satellite instrument will focus on a selected set of metropolitan target areas, where air quality monitors and health data are available. Aerosol concentration and speciation are inferred from multi-angle measurements of backscattered sunlight in 14 spectral bands from 350-2200 nm, with bands near 442, 645 and 1040 nm measuring the degree (DoLP) and angle of linear polarization (AoLP) in addition to radiance. The pushbroom camera has a ~240-km cross-track field of view with a nadir resolution of ~200 m, and is mounted onto a biaxial gimbal to provide along-track view angles within ±60°, to extend the field of regard to ±48°, and to view the instrument’s onboard calibrator (OBC) and dark target. The OBC consists of a sunlit transmissive diffuser, followed by 12 polarizers at different orientations. MAIA’s polarimetry is implemented using miniature wire grid polarizers on the focal plane array, and dual photoelastic modulators (PEMs) and achromatic quarter-wave plates to rapidly rotate the polarization. The resulting ~26-Hz intensity modulation encodes the linearly polarized and total radiance in each pixel, leaving the DoLP and AoLP insensitive to gain calibration. We report on the polarimetric calibration of the MAIA camera using a vacuum-compatible polarization state generator, consisting of a 1600W Xenon lamp, 12-inch integrating sphere, and rotating high-extinction polarizer. Mueller-matrix-based calibration coefficients for each detector pixel are derived from measurements at multiple polarizer angles, and are used to correct the measurements for instrumental polarization aberrations. Prior to flight, the calibrated MAIA camera is panned across the OBC to characterize its output, using uniform illumination with an irradiance similar to the Sun.

Werne, Thomas↗

NASA NTRSDate not supplied

Look-up Table for Lidar and Polarimeter Liquid Water Cloud Studies

- Combined lidar and polarimeter retrievals of aerosol, cloud and ocean microphysical properties involve single scattering cloud calculations that are time consuming. - We create a look-up table to speed up calculations for water droplets in the atmosphere. The gained increase in computational efficiency is up to 10^(4). - In our new Lorenz-Mie look-up table we tabulate the light scattering by an ensemble of homogeneous isotropic spheres at wavelengths starting from 0.35 µm. - The look-up table covers liquid water cloud particles with radii in the range of 0.001—500 µm. - The covered complex refractive indices range from 1.25 to 1.36 for the real part and from 0 to 0.001 for the imaginary part. - Using look-up table, we can precisely compute inherent optical properties for the particle size distributions ranging up to 100 µm for the effective radius and up to 0.6 for the effective variance. - We test wavelengths from 0.35 to 2.3 µm and find that the P12 element of the normalized scattering matrix is precise to within 1% for 96.7% of cases; the absorption and backscatter coefficients, and lidar ratio are precise to within 1% for 99% of cases; the P11 , P33 and P34 elements of the normalized scattering matrix, the asymmetry parameter, the extinction and scattering coefficients are precise to within 1% for all cases. - We provide an example of using the look-up table with in situ measurements to determine agreement with remote sensing. - The look-up table along with examples of its use soon will be freely available at https://science.larc.nasa.gov/polarimetry

Eduard Chemyakin↗