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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Perovskite/Silicon Tandem Solar Cells: Insights and Outlooks

Organic-inorganic hybrid perovskites have been widely used in silicon-based tandem solar cells for their advantages of tunable bandgap, high light absorption coefficient, and high power conversion efficiency (PCE). However, the maximum PCE of perovskite/silicon tandem solar cells (PSTSCs) is still below the theoretical limit. This Review describes the PSTSCs' working principle and then summarizes the research progress in recent years, including a comparison of perovskite layers, interconnection layers, and silicon bottom cells. Then, the n-i-p PSTSCs and p-i-n PSTSCs are presented based on the PSCs' top cells, and the main factors affecting the efficiency of PSTSCs are discussed in detail. Finally, an outlook on the future development of PSTSCs is discussed.

electrical conductivity↗
NASA NTRSDate not supplied

Initial Testing the Exploration Extravehicular Mobility Unit (xEMU) in Lunar Environment Simulation at the Neutral Buoyancy Lab (NBL) in 2022

Understanding how to effectively train for Extravehicular Activities (EVAs) for Artemis missions is critical. Tasked by the new Extravehicular Activity and Human Surface Mobility Program(EHP), a team of stakeholders from engineering and flight operations worked together to test the Exploration Extravehicular Mobility (xEMU) in the Neutral Buoyancy Lab(NBL) simulating the lunar environment. The NBL is a pool in which astronauts are typically trained to complete simulated International Space Station (ISS) EVA tasks in a neutral weigh-out. The overall focus for this test series was evaluating how well the NBL could be used as an effective simulated environment for Artemis lunar EVAs. New NBL support hardware was manufactured to support this test series and update the interfaces to be more representative of xEMU hardware such as a new NBL Portable Life Support System(PLSS)mock-up and umbilical, lights and cameras, and display and control unit (DCU).To simulate the 1/6th-gravity (1/6-g) environment, extra weights were added around the suit to create an accurate center of gravity representation. The Partial Gravity Weigh-out Stand (PGWS) predicted where and how much weight would be required for the 1/6th-G simulation and predicted the center of gravity placement. After the weigh-out attempt was completed, the suited participant would complete a set of directed tasks such as kneeling, object pick-up, and walking to evaluate the weigh-out. To create the lunar environment, sand, boulders, and ramps were added to the pool floor. If time allowed after weigh-out was determined acceptable, the flight operations team would direct the suited participants to complete simulated Artemis EVA tasks using flight-like tools and tool cart. The team also evaluated turning out the overhead lights in the NBL for a portion of some of the test runs and using a solar simulator to create amore realistic lunar south pole lighting environment. The test series completed one unmanned test and nine manned tests. With four of the tests, dual xEMU suited operations were completed with subjects in both the small and large xEMU sizes. Overall, the NBL was able to create an acceptable lunar landscape and ability to have two subjects work side by side in pressurized xEMUs which currently cannot be achieved in other test environments. Achieving a stable 1/6th-G lunar weigh-out and clear, consistent dual suit communications was a challenge for this series. Future work is planned to continue to improve this simulation environment.

spacesuit↗
NASA NTRSDate not supplied

Initial Testing of the Exploration Extravehicular Mobility Unit (xEMU) in Lunar Environment Simulation at the Neutral Buoyancy Lab (NBL) in 2022

Understanding how to effectively train for Extravehicular Activities (EVAs) for Artemis missions is critical. Tasked by the new Extravehicular Activity and Human Surface Mobility Program(EHP), a team of stakeholders from engineering and flight operations worked together to test the Exploration Extravehicular Mobility (xEMU) in the Neutral Buoyancy Lab(NBL) simulating the lunar environment. The NBL is a pool in which astronauts are typically trained to complete simulated International Space Station (ISS) EVA tasks in a neutral weigh-out. The overall focus for this test series was evaluating how well the NBL could be used as an effective simulated environment for Artemis lunar EVAs. New NBL support hardware was manufactured to support this test series and update the interfaces to be more representative of xEMU hardware such as a new NBL Portable Life Support System(PLSS)mock-up and umbilical, lights and cameras, and display and control unit (DCU).To simulate the 1/6th-gravity (1/6-g) environment, extra weights were added around the suit to create an accurate center of gravity representation. The Partial Gravity Weigh-out Stand (PGWS) predicted where and how much weight would be required for the 1/6th-G simulation and predicted the center of gravity placement. After the weigh-out attempt was completed, the suited participant would complete a set of directed tasks such as kneeling, object pick-up, and walking to evaluate the weigh-out. To create the lunar environment, sand, boulders, and ramps were added to the pool floor. If time allowed after weigh-out was determined acceptable, the flight operations team would direct the suited participants to complete simulated Artemis EVA tasks using flight-like tools and tool cart. The team also evaluated turning out the overhead lights in the NBL for a portion of some of the test runs and using a solar simulator to create amore realistic lunar south pole lighting environment. The test series completed one unmanned test and nine manned tests. With four of the tests, dual xEMU suited operations were completed with subjects in both the small and large xEMU sizes. Overall, the NBL was able to create an acceptable lunar landscape and ability to have two subjects work side by side in pressurized xEMUs which currently cannot be achieved in other test environments. Achieving a stable 1/6th-G lunar weigh-out and clear, consistent dual suit communications was a challenge for this series. Future work is planned to continue to improve this simulation environment.

spacesuit↗
NASA NTRS2003

Advanced Rainbow Solar Photovoltaic Arrays

Photovoltaic arrays of the rainbow type, equipped with light-concentrator and spectral-beam-splitter optics, have been investigated in a continuing effort to develop lightweight, high-efficiency solar electric power sources. This investigation has contributed to a revival of the concept of the rainbow photovoltaic array, which originated in the 1950s but proved unrealistic at that time because the selection of solar photovoltaic cells was too limited. Advances in the art of photovoltaic cells since that time have rendered the concept more realistic, thereby prompting the present development effort. A rainbow photovoltaic array comprises side-by-side strings of series-connected photovoltaic cells. The cells in each string have the same bandgap, which differs from the bandgaps of the other strings. Hence, each string operates most efficiently in a unique wavelength band determined by its bandgap. To obtain maximum energy-conversion efficiency and to minimize the size and weight of the array for a given sunlight input aperture, the sunlight incident on the aperture is concentrated, then spectrally dispersed onto the photovoltaic array plane, whereon each string of cells is positioned to intercept the light in its wavelength band of most efficient operation. The number of cells in each string is chosen so that the output potentials of all the strings are the same; this makes it possible to connect the strings together in parallel to maximize the output current of the array. According to the original rainbow photovoltaic concept, the concentrated sunlight was to be split into multiple beams by use of an array of dichroic filters designed so that each beam would contain light in one of the desired wavelength bands. The concept has since been modified to provide for dispersion of the spectrum by use of adjacent prisms. A proposal for an advanced version calls for a unitary concentrator/ spectral-beam-splitter optic in the form of a parabolic curved Fresnel-like prism array with panels of photovoltaic cells on two sides (see figure). The surface supporting the solar cells can be adjusted in length or angle to accommodate the incident spectral pattern. An unoptimized prototype assembly containing ten adjacent prisms and three photovoltaic cells with different bandgaps (InGaP2, GaAs, and InGaAs) was constructed to demonstrate feasibility. The actual array will consist of a lightweight thin-film silicon layer of prisms curved into a parabolic shape. In an initial test under illumination of 1 sun at zero airmass, the energy-conversion efficiency of the assembly was found to be 20 percent. Further analysis of the data from this test led to a projected energy conversion efficiency as high as 41 percent for an array of 6 cells or strings (GaP, AlGaAs, InGaP2, GaAs, and two different InGaAs cells or strings).

Mardesich, Nick↗
DOE OSTI2024

Resolving electron and hole transport properties in semiconductor materials by constant light-induced magneto transport

The knowledge of minority and majority charge carrier properties enables controlling the performance of solar cells, transistors, detectors, sensors, and LEDs. Here, we developed the constant light induced magneto transport method which resolves electron and hole mobility, lifetime, diffusion coefficient and length, and quasi-Fermi level splitting. We demonstrate the implication of the constant light induced magneto transport for silicon and metal halide perovskite films. We resolve the transport properties of electrons and holes predicting the material’s effectiveness for solar cell application without making the full device. The accessibility of fourteen material parameters paves the way for in-depth exploration of causal mechanisms limiting the efficiency and functionality of material structures. To demonstrate broad applicability, we further characterized twelve materials with drift mobilities spanning from 10 –3 to 10 3 cm 2 V –1 s –1 and lifetimes varying between 10 –9 and 10 –3 seconds. The universality of our method its potential to advance optoelectronic devices in various technological fields.

14 SOLAR ENERGY↗
NASA NTRS1979

Tropospheric circulation and interplanetary magnetic sector boundaries followed by MeV proton streams

The MeV proton streams which Svestka et al. (1976) connected with certain sector boundary transits appear to select boundary transits associated with unusually active solar wind conditions. Changes in tropospheric circulation linked to the proton boundary transits were larger than those linked to other boundary transits observed during the same interval. This investigation of sector boundary transits also sheds light on the relationship between changes in solar wind velocity, density and magnetic field and terrestrial changes in the vorticity area index, geomagnetic activity, and cosmic ray flux at earth.

Wilcox, J. M.↗
NASA NTRS2005

High-temperature Solar Cell Development

The vast majority of space probes to date have relied upon photovoltaic power generation. If future missions designed to probe environments close to the sun (Figure 1) will be able to use such power generation, solar cells that can function at high temperatures, under high light intensity, and high radiation conditions must be developed. The significant problem is that solar cells lose performance at high temperatures.

Landis, Geoffrey A.↗
NASA NTRS2001

Neutron environments on the Martian surface

Radiation is a primary concern in the planning of a manned mission to Mars. Recent studies using NASA Langley Research Center's HZETRN space radiation transport code show that the low energy neutron fluence on the Martian surface is larger than previously expected. The upper atmosphere of Mars is exposed to a background radiation field made up of a large number of protons during a solar particle event and mixture of light and heavy ions caused by galactic cosmic rays at other times. In either case, these charged ions interact with the carbon and oxygen atoms of the Martian atmosphere through ionization and nuclear collisions producing secondary ions and neutrons which then interact with the atmospheric atoms in a similar manner. In the past, only these downward moving particles have been counted in evaluating the neutron energy spectrum on the surface. Recent enhancements in the HZETRN code allow for the additional evaluation of those neutrons created within the Martian regolith through the same types of nuclear reactions, which rise to the surface. New calculations using this improved HZETRN code show that these upward moving neutrons contribute significantly to the overall neutron spectrum for energies less than 10 MeV.

NASA Center LaRC↗
DOE OSTI2022

Pathway to Zero Energy Windows: Advancing Technologies and Market Adoption

As of 2021, buildings account for 39.1% of total U.S. primary energy use and 75% of total U.S. electricity use. Much of this energy is used to maintain a comfortable indoor environment. The building envelope consists of transparent and opaque elements that serve as a controllable barrier to help maintain the indoor environment regardless of external conditions. The envelope also allows the exchange of light and air, as well as other transfers with the external environment when it is beneficial for the building occupants. By leveraging desirable external environmental conditions (e.g., fresh air and natural light) and mitigating the influence of undesirable conditions (e.g., moisture, hot or cold temperatures, wind), the building envelope can reduce the need for space conditioning and electric light, and thus reduce energy use associated with lighting and heating, cooling, and ventilation equipment. In turn, high-performance building envelopes can reduce the substantial CO 2 emissions associated with energy use to satisfy heating, cooling, and lighting needs in buildings. The U.S. Department of Energy (DOE) Building Technologies Office's (BTO's) Emerging Technologies program supports R&D for technologies, systems, and software tools that can contribute to reductions in building energy use. Emerging Technologies funding is distributed competitively through solicitations (e.g., Funding Opportunity Announcements and National Lab Calls, which in general are open to applications from industry, academia, national laboratories, and other entities) and other mechanisms. This document focuses on R&D for windows and window system technologies and will provide guidance for BTO's investments in developing the next generation of high-performance, affordable, cost competitive windows, as well as integrated daylighting and shading technologies in partnership with industry and researchers. This document also addresses areas where DOE invests in software and design tools that translate sophisticated and complex physics into easy-to-use energy performance and optimization methods used by industry and other stakeholders for implementation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS2000

Connecting the Sun and the solar wind: source regions of the fast wind observed in interplanetary space

Highly sensitive radio occultation and white light measurements of path-integrated density have shown that the solar corona comprises three distinct morphological regions, streamer, quiet Sun, and polar coronal hole, which except for the streamer region, extend radially into interplanetary space from 1.15 R***s*** to at least 30 R***s***. The authors build on these results by comparing solar wind flow speeds observed at the same time as path-integrated density.

solar↗
DOE OSTI2022

Compositional texture engineering for highly stable wide-bandgap perovskite solar cells

The development of highly stable and efficient wide-bandgap (WBG) perovskite solar cells (PSCs) based on bromine-iodine (Br–I) mixed-halide perovskite (with Br greater than 20%) is critical to create tandem solar cells. However, issues with Br–I phase segregation under solar cell operational conditions (such as light and heat) limit the device voltage and operational stability. This challenge is often exacerbated by the ready defect formation associated with the rapid crystallization of Br-rich perovskite chemistry with antisolvent processes. We combined the rapid Br crystallization with a gentle gas-quench method to prepare highly textured columnar 1.75–electron volt Br–I mixed WBG perovskite films with reduced defect density. Here, with this approach, we obtained 1.75–electron volt WBG PSCs with greater than 20% power conversion efficiency, approximately 1.33-volt open-circuit voltage (V oc ), and excellent operational stability (less than 5% degradation over 1100 hours of operation under 1.2 sun at 65°C). When further integrated with 1.25–electron volt narrow-bandgap PSC, we obtained a 27.1% efficient, all-perovskite, two-terminal tandem device with a high V oc of 2.2 volts.

14 SOLAR ENERGY↗
DOE OSTI2023

Data and scripts associated with "Coupled primary production and respiration in a large river contrasts with smaller rivers and streams."

This data package is associated with the publication "Coupled primary production and respiration in a large river contrasts with smaller rivers and streams." in review at Limnology and Oceanography (Roley et al. 2023). This study focuses on understanding ecosystem metabolism for the Hanford Reach of the Columbia River in Washington state, a free-flowing stretch with a substantial discharge. Large rivers have been overlooked compared to small and medium rivers due to the challenges associated with measurements. Our study presents novel ways to address these challenges and highlights that metabolism patterns in large rivers differ from those observed in small-medium rivers and requires the application of knowledge and tools beyond those implemented for smaller rivers.This data package includes the data and R scripts for the analyses described in Roley et al. 2023. It includes dissolved oxygen and temperature data from a dissolved oxygen HOBO sensor, light data collected from the National Solar Radiation Database (https://nsrdb.nrel.gov/) and hydrologic variables estimated from the MASS-1 model (Niehus et al.; 2014). It also includes metabolism estimates (gross primary production, ecosystem respiration, and net ecosystem production) estimated via streamMetabolizer (Appling et al.; 2018). All analyses in the paper can be replicated with these data and scripts.The data package is comprised of one main data folder. The folder includes (1) file-level metadata (flmd); (2) a data dictionary (dd) for each data file; (3) data files; and (4) R scripts for metabolism estimates and data analysis. All files are .R, .csv, or .pdf.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

A Dive into Underwater Solar Cells

Our oceans are vast, mostly unexplored and difficult to monitor. Large-scale implementation of a fully autonomous 'Internet of Underwater Things' would transform how we collect and share data from this domain; however, deployment is prohibited by the lack of persistent power sources. In principle, underwater solar-energy generation can complement the use of batteries and provide a solution, although dedicated research is needed since traditional silicon solar cells do not perform well underwater due to water's strong absorption of near-infrared light. In this Perspective we present examples of solar-powered underwater applications and discuss which types of solar-harvesting materials could be appropriate, including GaInP variants, CdTe, organic semiconductors, and perovskite semiconductors. We also discuss challenges that need to be addressed, such as the development of effective antifouling coatings and new certification standards given that underwater conditions are starkly different from those in terrestrial environments.

antifouling coatings↗
NASA NTRS2006

Polyimides From a-BPDA and Aromatic Diamines

Polymers having low color and a favorable combination of other properties, including high glass-transition temperature (Tg) and high mechanical properties (strength, tensile modulus, and toughness) will find use in a variety of terrestrial and space applications. Some of the space applications will be in thin films used as membranes on antennas, solar concentrators, coatings on second-surface mirrors, solar sails, sunshades, thermal and optical coatings, and multi-layer thermal insulation blankets. Depending upon the application, the film will be required to exhibit a unique combination of such properties as resistance to degradation by ultraviolet light, visible light, and electrons; low color and/or low solar absorptivity; resistance to tearing and/or wrinkling during packaging and deployment; and high mechanical properties (e.g. high strength, stiffness, and toughness).

Hergenrother, Paul M.↗
NASA NTRS2003

On the Nature of the Eclipsing Bright X-ray Source in the Circinus Galaxy Field

The X-ray spectrum and light curve of the bright source CG X-1 in the field of the Circinus galaxy are re-examined. Previous analyses have concluded that the source is an accreting black hole of about 50 solar masses although it was noted that the light curve resembles that of an AM Her-type system. Here we show that the light curve and orbital dynamics constrain the mass of the compact object to less than 30 solar masses and the mass of the companion to less than 1 solar mass. Combining the mass constraints with the observed X-ray flux, we show that an accreting object must either radiate anisotropically or strongly violate the Eddington limit. If the emission is beamed, then the companion star, which intercepts this flux during eclipse, will be driven out of thermal equilibrium and evaporate within approx. 103 yr. We find, therefore, that the observations are most consistent with the interpretation of CG X-1 as a bright, long-period, AM Her system in the Milky Way.

Weisskopf, M. C.↗
DOE OSTI2024

Enhanced Interfacial Electron Transfer in Photocatalyst-Natural Enzyme Coupled Artificial Photosynthesis System: Tuning Strategies and Molecular Simulations

Laccase is capable of catalyzing a vast array of reactions, but its low redox potential limits its potential applications. The use of photocatalytic materials offers a solution to this problem by converting absorbed visible light into electrons to facilitate enzyme catalysis. Herein, MIL-53(Fe) and NH 2 -MIL-53(Fe) serve as both light absorbers and enzyme immobilization carriers, and laccase is employed for solar-driven chemical conversion. Electron spin resonance spectroscopy results confirm that visible light irradiation causes rapid transfer of photogenerated electrons from MOF excitation to T1 Cu(II) of laccase, significantly increasing the degradation rate constant of tetracycline (TC) from 0.0062 to 0.0127 min -1 . Conversely, there is only minimal or no electron transfer between MOF and laccase in the physical mixture state. Theoretical calculations demonstrate that the immobilization of laccase's active site and its covalent binding to the metal-organic framework surface augment the coupled system's activity, reducing the active site accessible from 27.8 to 18.1 Å. In conclusion, the constructed photo-enzyme coupled system successfully combines enzyme catalysis’ selectivity with photocatalysis's high reactivity, providing a promising solution for solar energy use.

36 MATERIALS SCIENCE↗
NASA NTRS2020

Satellite Beach Energy - Restructuring the Energy Balance in Satellite Beach, Florida, by Quantifying Solar Energy Production Potential using NASA POWER Data Products and LiDAR

The City of Satellite Beach, Florida, has committed to supplying 100% of its energy use from renewable energy, primarily solar, by the year 2050. The team created a methodology for estimating rooftop solar power potential using a high-resolution Light Detection and Ranging (LiDAR) dataset and the NASA Prediction of Worldwide Energy Resources (POWER) dataset to assist Satellite Beach in reaching their solar renewable energy goals. The POWER dataset provides information on direct and diffuse solar irradiation on horizontal surfaces, surface albedo, and effects of local meteorology, such as clouds. The team integrated the solar irradiance data with the LiDAR data to model slope, aspect, and shadowing in the 7 km2 study area to find suitable roof segments for solar panel installation and estimate the solar potential of each segment. This process was supplemented by an analysis of land surface temperature and urban greenness measured through the Normalized Difference Vegetation Index (NDVI) from Landsat 8 Operational Land Imager and Thermal Infrared Sensor (OLI/TIRS) observations. These metrics serve to target areas for cooling initiatives aimed at reducing Satellite Beach’s overall energy consumption. The team found the total rooftop solar potential throughout the city to be 221,919,330KWh per year with an average annual rooftop photovoltaic, or PV, potential of 55,647KWh per building. As such, the average building could generate over five times the annual energy needs for an average household if PV panels were installed on all viable areas of its roof.

Spencer Nelson↗
NASA NTRS1996

1985 Voyager 2 Radio Ranging Measurements of Coronal Density: Asymmetry in the Radial Profiles Explained

An asymmetry in the radial variation of electron density above the cast and west limbs of the Sun was inferred from centimeter wavelength ranging measurements conducted by Voyager 2 during its 1985 solar conjunction. The Voyager 2 ranging measurements, which took place in the heliocentric distance range of 7-40 solar radius, have been compared with the white-light coronagraph measurements of the underlying corona collected by the Mark 3 K-coronameter located at the Mauna Loa Solar Observatory. It is shown that the disparity in radial profiles is not real but is instead caused by longitudinal variations stemming from the probing of significantly different source regions its revealed in the white-light measurements. These results improve our understanding of the probing abilities of ranging measurements and their relationship to white-light measurements. They reinforce the notion that the high-precision and high-sensitivity features of ranging measurements are more fully exploited in the investigation of density variations across the ubiquitous low-contrast raylike structures that permit the corona, rather than in determining radial density profiles.

Woo, Richard↗