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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Low temperature lithium production

A method and electrolysis cell for producing lithium metal at a low temperature. The method includes combining (i) phenyl trihaloalkyl sulfone and (ii) an organic cation bis(trihaloalkylsulfonyl)imide or organic cation bis(trihalosulfonyl)imidic acid in a weight ratio of (i) to (ii) about 10:90 to about 60:40 to provide a non-aqueous electrolyte composition. A lithium compound selected from the group consisting of LiOH, Li 2 O and Li 2 CO 3 is dissolved in the electrolyte composition to provide a soluble lithium ion species in the electrolyte composition. Power is applied to the electrolyte composition to form lithium metal on a cathode of an electrolysis cell. The lithium metal is separated from the cathode has a purity of at least about 95 wt. %.

36 MATERIALS SCIENCE↗
NASA NTRS2015

The Gravity Field of Mars From MGS, Mars Odyssey, and MRO Radio Science

The Mars Global Surveyor (MGS), Mars Odyssey (ODY), and Mars Reconnaissance Orbiter (MRO) missions have enabled NASA to conduct reconnaissance and exploration of Mars from orbit for sixteen consecutive years. These radio systems on these spacecraft enabled radio science in orbit around Mars to improve the knowledge of the static structure of the Martian gravitational field. The continuity of the radio tracking data, which cover more than a solar cycle, also provides useful information to characterize the temporal variability of the gravity field, relevant to the planet's internal dynamics and the structure and dynamics of the atmosphere [1]. MGS operated for more than 7 years, between 1999 and 2006, in a frozen sun-synchronous, near-circular, polar orbit with the periapsis at approximately 370 km altitude. ODY and MRO have been orbiting Mars in two separate sun-synchronous orbits at different local times and altitudes. ODY began its mapping phase in 2002 with the periapis at approximately 390 km altitude and 4-5pm Local Solar Time (LST), whereas the MRO science mission started in November 2006 with the periapis at approximately 255 km altitude and 3pm LST. The 16 years of radio tracking data provide useful information on the atmospheric density in the Martian upper atmosphere. We used ODY and MRO radio data to recover the long-term periodicity of the major atmospheric constituents -- CO2, O, and He -- at the orbit altitudes of these two spacecraft [2]. The improved atmospheric model provides a better prediction of the annual and semi-annual variability of the dominant species. Therefore, the inclusion of the recovered model leads to improved orbit determination and an improved gravity field model of Mars with MGS, ODY, and MRO radio tracking data.

Mars↗
DOE OSTI2022

Search for the NΔ resonance in the 𝛾𝑑 → 𝑑𝜋 +𝜋 − reaction

A dibaryon which is an object with baryon number B = 2 has been studied for a long time. Dyson and Xuong classified non-strangeness dibaryon states based on SU(6) symmetries in 1960?s. In the framework, the deuteron is classified as one of the sextet states of dibaryons. Although dibaryon have been an interesting subject of research for a long time, most of the experimental studies up to the early 2000?s were unsuccessful. The CELCIUS/WASA collaboration reported this state via the double-pionic fusion reaction (?= ! 3c0c0) in 2009. Thereafter, the WASA-at-COSY collaboration revealed properties of the isoscaler resonance state via the ?= ! 3c0c0 reaction in 2011. The dibaryon resonance state with isospin ? = 0 and spin ( = 3 thought to be a ?03 which was predicted by Dyson and Xuong at 2.35 GeV?22 with a configuration of ??. The reported mass and width of that state were 2?37 GeV?22 and 0?07 GeV?22, espectively. The mass was ?0?08 GeV?22 smaller than that of 2?, the width was narrower than that of single ?. This surprising result made dibaryon study come back into the limelight. ?12 is one of the dibaryon states classified by Dyson and Xuong with isospin ? = 1, spin ( = 2. This state can be regarded as an s-wave #? resonance. ?12 is an interesting state from the point of view of the possibilities of existence as an internal structure of ?03 and contribution to many-body effects in nuclei. Though there were some experimental clues and theoretical studies of this state, it was unclear whether the obtained experimental results represented a real resonance or not due to the difficulty of separation from kinematical effects. Very recently, the FOREST group at Tohoku University reported a photoproduced isovector dibaryon state at mass of 2.14 GeV?22 in the 3c0 invariant mass spectra of the W3 ! 3c0c0 reaction. The most probable ?% configuration was 2¸ although they didn?t exclude the possibility of ?% = 1¸ or 3?. They separated the dibaryon production process from conventional pion production process for the first time using angular distribution of deuteron. We investigated the W3 ! 3c¸c? reaction for study of a possible #? dibaryon state using a deuterium target at the Research Center for Electron Photon Science, Tohoku University, Japan. In the experiment, ?3 ? 1012 tagged photon beam at energies ranging from 0.8 to 1.1 GeV was impinged to the liquid deuterium target (?520 mg?cm2) and the charged particles in the final state: deuteron, c¸, and c?, were detected by a magnetic spectrometer with a large solid angle named NKS2. NKS2 had capabilities of reconstructing momentum of charged particles, multi-track analysis, and ??c separation. We performed two different analyses named 2-track analysis and 3-track analysis. The 2-track (3-track) analysis was for events in which two (three) particles of 3c¸c? in the final state, including deuteron, were detected by NKS2. In the 3-track and 2-track analysis, ?2000? ?15000 events were identified as the W3 ! 3c¸c? reaction events, respectively. The 2-track analysis with higher statistics was mainly used to derive the cross sections, and the 3-track analysis was used to check the consistency of the 2-track analysis. In this thesis, we have shown the total cross section, the differential cross sections of the W3 ! 3c¸c? reaction in the region of jC j ¡ 0?15 GeV2. This is the world?s first measurement of this reaction in this energy region. Dibaryon resonance structures were observed below the #? threshold in the differential cross section of the invariant mass of 3c?. The mass and width of the structure were consistent with these of ?12 measured by the W3 ! 3c0c0 reaction. The mechanism of the production process was discussed based on the angular distribution of emitted deuteron.

Toyama, Yuichi↗
NASA NTRS2015

FINESSE: Field Investigations to Enable Solar System Science and Exploration

The FINESSE (Field Investigations to Enable Solar System Science and Exploration) team is focused on a science and exploration field-based research program aimed at generating strategic knowledge in preparation for the human and robotic exploration of the Moon, near-Earth asteroids (NEAs) and Phobos and Deimos. We follow the philosophy that "science enables exploration and exploration enables science." 1) FINESSE Science: Understand the effects of volcanism and impacts as dominant planetary processes on the Moon, NEAs, and Phobos & Deimos. 2) FINESSE Exploration: Understand which exploration concepts of operations (ConOps) and capabilities enable and enhance scientific return. To accomplish these objectives, we are conducting an integrated research program focused on scientifically-driven field exploration at Craters of the Moon National Monument and Preserve in Idaho and at the West Clearwater Lake Impact Structure in northern Canada. Field deployments aimed at reconnaissance geology and data acquisition were conducted in 2014 at Craters of the Moon National Monument and Preserve. Targets for data acquisition included selected sites at Kings Bowl eruptive fissure, lava field and blowout crater, Inferno Chasm vent and outflow channel, North Crater lava flow and Highway lava flow. Field investigation included (1) differential GPS (dGPS) measurements of lava flows, channels (and ejecta block at Kings Bowl); (2) LiDAR imaging of lava flow margins, surfaces and other selected features; (3) digital photographic documentation; (4) sampling for geochemical and petrographic analysis; (5) UAV aerial imagery of Kings Bowl and Inferno Chasm features; and (6) geologic assessment of targets and potential new targets. Over the course of the 5-week field FINESSE campaign to the West Clearwater Impact Structure (WCIS) in 2014, the team focused on several WCIS research topics, including impactites, central uplift formation, the impact-generated hydrothermal system, multichronometer dating of impact products, and using WCIS as an analog test site for crew studies of sampling protocols. The FINESSE team visited and mapped all of the major islands within West Clearwater Lake. Excellent cliff exposures around the coasts of many of the islands allowed a general stratigraphy of impactites to be defined. Notable differences to previous work includes the discovery of a monomict lithic breccia and a medium to coarse grained impact melt rock. In addition, ample rock samples were returned from West Clearwater for geochronology study. Geochronology work centers around laboratory analyses of these samples (and samples collected in the future or obtained from archives housed at the Canadian Geological Survey). Samples returned from the FINESSE field season have been evaluated for suitability for geochronologic analysis, and selected samples have been crushed for mineral separation and/or sawed for the preparation of polished petrologic thin sections. Heavy minerals (e.g., zircon, titanite, and apatite) will be separated from the crushed material for (U-Th)/He geochronology. The sections will be used for laser ablation 40Ar/39Ar research after neutron irradiation. This presentation will highlight the exciting science and exploration work conducted by FINESSE, as well as future plans for continued research.

Phobos & Deimos↗
DOE OSTI2025

Developing Fluorescence-Based Sensors to Support Rare Earth Element Separation

Rare earth elements (REEs) are essential to most renewable energy technologies. Unfortunately, as we transition to sustainable energy production, the demand for REEs is rapidly growing well beyond current rates of production. As a result, novel means of efficient, scalable, and easily adaptable methods for processing primary and recycle feedstocks are needed. Development and integration of sensors for highly selective in-line monitoring can support more efficient design and testing of such novel separation processes, as well as more cost-effective deployment of those separation flowsheets. Work here will explore the application of fluorescence spectroscopy, a highly sensitive and selective technique, to quantify multiple lanthanides in complex mixtures including known interferents or quenching agents. Results include identification of the optimal excitation wavelength and the limit of detection of various rare earth elements as well as the performance of data-science-based quantification approaches in streams where “unknowns” are present. Overall, the data science tools in conjunction with optical sensor data were able to quantify analytes in the presence of other lanthanides which can be anticipated in the actual industrial stream. Here we include characterization of lanthanides in a microfluidic device similar to those used in new process development. This study demonstrates the capability of utilizing fluorescence spectroscopy to quantify analytes in a complicated solution matrix, suggesting this is a successful approach for in-line monitoring to optimize the separation efficiency in an industrial stream.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Publication and Impact of Preprints Included in the First 100 Editions of the CDC COVID-19 Science Update: Content Analysis

Preprints are publicly available manuscripts posted to various servers that have not been peer reviewed. Although preprints have existed since 1961, they have gained increased popularity during the COVID-19 pandemic due to the need for immediate, relevant information. The aim of this study is to evaluate the publication rate and impact of preprints included in the Centers for Disease Control and Prevention (CDC) COVID-19 Science Update and assess the performance of the COVID-19 Science Update team in selecting impactful preprints. All preprints in the first 100 editions (April 1, 2020, to July 30, 2021) of the Science Update were included in the study. Preprints that were not published were categorized as “unpublished preprints.” Preprints that were subsequently published exist in 2 versions (in a peer-reviewed journal and on the original preprint server), which were analyzed separately and referred to as “peer-reviewed preprint” and “original preprint,” respectively. Time to publish was the time interval between the date on which a preprint was first posted and the date on which it was first available as a peer-reviewed article. Impact was quantified by Altmetric Attention Score and citation count for all available manuscripts on August 6, 2021. Preprints were analyzed by publication status, publication rate, preprint server, and time to publication. Of the 275 preprints included in the CDC COVID-19 Science Update during the study period, most came from three servers: medRxiv (n=201, 73.1%), bioRxiv (n=41, 14.9%), and SSRN (n=25, 9.1%), with 8 (2.9%) coming from other sources. Additionally, 152 (55.3%) were eventually published. The median time to publish was 2.3 (IQR 1.4-3.7). When preprints posted in the last 2.3 months were excluded (to account for the time to publish), the publication rate was 67.8%. Moreover, 76 journals published at least one preprint from the CDC COVID-19 Science Update, and 18 journals published at least three. The median Altmetric Attention Score for unpublished preprints (n=123, 44.7%) was 146 (IQR 22-552) with a median citation count of 2 (IQR 0-8); for original preprints (n=152, 55.2%), these values were 212 (IQR 22-1164) and 14 (IQR 2-40), respectively; for peer-review preprints, these values were 265 (IQR 29-1896) and 19 (IQR 3-101), respectively. Prior studies of COVID-19 preprints found publication rates between 5.4% and 21.1%. Preprints included in the CDC COVID-19 Science Update were published at a higher rate than overall COVID-19 preprints, and those that were ultimately published were published within months and received higher attention scores than unpublished preprints. These findings indicate that the Science Update process for selecting preprints had a high fidelity in terms of their likelihood to be published and their impact. The incorporation of high-quality preprints into the CDC COVID-19 Science Update improves this activity’s capacity to inform meaningful public health decision-making.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS2008

The Telesupervised Adaptive Ocean Sensor Fleet (TAOSF) Architecture: Coordination of Multiple Oceanic Robot Boats

Earth science research must bridge the gap between the atmosphere and the ocean to foster understanding of Earth s climate and ecology. Ocean sensing is typically done with satellites, buoys, and crewed research ships. The limitations of these systems include the fact that satellites are often blocked by cloud cover, and buoys and ships have spatial coverage limitations. This paper describes a multi-robot science exploration software architecture and system called the Telesupervised Adaptive Ocean Sensor Fleet (TAOSF). TAOSF supervises and coordinates a group of robotic boats, the OASIS platforms, to enable in-situ study of phenomena in the ocean/atmosphere interface, as well as on the ocean surface and sub-surface. The OASIS platforms are extended deployment autonomous ocean surface vehicles, whose development is funded separately by the National Oceanic and Atmospheric Administration (NOAA). TAOSF allows a human operator to effectively supervise and coordinate multiple robotic assets using a sliding autonomy control architecture, where the operating mode of the vessels ranges from autonomous control to teleoperated human control. TAOSF increases data-gathering effectiveness and science return while reducing demands on scientists for robotic asset tasking, control, and monitoring. The first field application chosen for TAOSF is the characterization of Harmful Algal Blooms (HABs). We discuss the overall TAOSF architecture, describe field tests conducted under controlled conditions using rhodamine dye as a HAB simulant, present initial results from these tests, and outline the next steps in the development of TAOSF.

sensor web↗
DOE OSTI2023

Sequential Deposition of Multicomponent Bulk Heterojunctions Increases Efficiency of Organic Solar Cells

Constructing tandem and multi-blend organic solar cells (OSCs) is an effective way to overcome the absorption limitations of conventional single-junction devices. However, these methods inevitably require tedious multilayer deposition or complicated morphology-optimization procedures. Herein, sequential deposition is utilized as an effective and simple method to fabricate multicomponent OSCs with a double-bulk heterojunction (BHJ) structure of the active layer to further improve photovoltaic performance. Two efficient donor-acceptor pairs, D18-Cl:BTP-eC9 and PM6:L8-BO, are sequentially deposited to form the D18-Cl:BTP-eC9/PM6:L8-BO double-BHJ active layer. In these double-BHJ OSCs, light absorption is significantly improved, and optimal morphology is also retained without requiring a more complicated morphology optimization involved in quaternary blends. Compared to the quaternary blend devices, energy loss (E loss ) is also reduced by rationally matching each donor with an appropriate acceptor. Consequently, the power conversion efficiency (PCE) is improved from 18.25% for D18-Cl:BTP-eC9 and 18.69% for PM6:L8-BO based binary blend OSCs to 19.61% for the double-BHJ OSCs. In contrast, a D18-Cl:PM6:L8-BO:BTP-eC9 quaternary blend of OSCs exhibited a dramatically reduced PCE of 15.83%. Finally, these results demonstrate that a double-BHJ strategy, with a relatively simple processing procedure, can potentially enhance the device performance of OSCs and lead to more widespread use.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Electrostatic limits on charge selectivity in ultrahigh charge density polymer membranes

Ion-exchange membranes (IEMs) with ultrahigh charge densities offer the promise of enhanced ion transport for electrochemical technologies, yet the fundamental limits of this membrane design strategy are not yet understood. In this work, we present a systematic study of bis(1-vinyl-3-imidazolium) cross-linked polymer membranes with fixed charge contents ranging from 6 to 9 mol/L[dry polymer], synthesized to isolate the effects of charge density at constant membrane water content. While ionic conductivity increases monotonically with increasing charge density, a sharp decline in charge selectivity is observed for the most densely charged membranes, defying conventional expectations. Structural, thermal, and mechanical analyses reveal a critical onset of network disruption and anomalous ion partitioning behavior in these densely charged membranes. With proper consideration of cross-linker geometry, these results are interpreted using Manning's counter-ion condensation theory, which suggests that closely packed charged cross-linkers amplify inter-chain electrostatic interactions and trigger excess counter-ion condensation. Our findings suggest that, beyond a threshold spacing between fixed charges, increased functionalization may harm rather than help charge selectivity of IEMs.

36 MATERIALS SCIENCE↗
DOE OSTI2025

High-precision Measurement of the 16 O($n, n'γ$) Cross Section using $γ$-ray Detection in Liquid Scintillators with H 2 O and BeO Targets

The 16 O($n, n'γ$) reaction was measured at the Los Alamos Neutron Science Center white neutron source using γ-ray detection in liquid scintillators present in the upper hemisphere of the Correlated Gamma-Neutron Array for sCattering (CoGNAC). Separate measurements of this reaction were performed using H 2 O and BeO targets in successive years. The unique high energies of γ rays emitted from the 16 O($n, n'γ$) reaction facilitated a clean selection of this reaction from threshold to 9.8 MeV incident neutron energy without the need for precise measurements of the γ-ray energy or the scattered neutrons. The precise time resolution of the liquid scintillator detectors was then exploited to obtain high-resolution incident neutron energy measurements, and good agreement was obtained between the H 2 O and BeO results reported here. The dominant literature data sets for this reaction have systematic differences between them, but the present results improve upon the neutron energy resolution of earlier measurements and show important discrepancies in recent data. Finally, tentative data are also shown up to 20 MeV incident neutron energy but are potentially subject to improved understanding of the relative γ-ray and α decay branches from 16 O excited states.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2022

Machine learning predictions for local electronic properties of disordered correlated electron systems

We present a scalable machine learning (ML) model to predict local electronic properties such as on-site electron number and double occupation for disordered correlated electron systems. Our approach is based on the locality principle, or the nearsightedness nature, of many-electron systems, which means local electronic properties depend mainly on the immediate environment. A ML model is developed to encode this complex dependence of local quantities on the neighborhood. We demonstrate our approach using the square-lattice Anderson-Hubbard model, which is a paradigmatic system for studying the interplay between Mott transition and Anderson localization. We develop a lattice descriptor based on the group-theoretical method to represent the on-site random potentials within a finite region. The resultant feature variables are used as input to a multilayer fully connected neural network, which is trained from data sets of variational Monte Carlo (VMC) simulations on small systems. We show that the ML predictions agree reasonably well with the VMC data. Our work underscores the promising potential of ML methods for multiscale modeling of correlated electron systems.

36 MATERIALS SCIENCE↗
DOE OSTI2021

NNSA Light Source Enhancements: Coupling a High Energy Laser Driver to an XFEL

NNSA has an unmet capability gap to predict how changes in material microstructure, due to aging and new manufacturing practices, can affect performance at extremes. This capability gap is the basis for the Dynamic Mesoscale Material Science Capability (DMMSC) CD-0 that was signed in 2015 [1]. Because of the delay to the MaRIE facility approach, the Tri-Lab in March 2020 proposed separate complementary investments at the APS and LCLS to address portions of the DMMSC mission need [2].

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Spectroscopic Investigations of Molecular Symmetry Breakdown

This project addressed precise measurements of the spectra of molecules to address fundamental questions in chemical physics in the realm of nuclear spin symmetries and their breakdown in molecules, and parity non-conservation caused by the weak nuclear force. Nuclear spin symmetry is intimately connected to parity in symmetrical molecules and plays a central role in the physical and chemical properties of symmetric molecules, their collisional relaxation, and the establishment of thermodynamic equilibrium in an ensemble. Such effects are present in every molecular system or process, but their small size means they are often only directly observable under special conditions. However, their measurement is of fundamental, and often practical importance, and strongly relates to the themes of coherence in light and matter in the recent Basic Energy Sciences Advisory Committee (BESAC) report “Challenges at the Frontiers of Matter and Energy: Transformative Opportunities for Discovery Science”. We begin by addressing lifetime broadening of spectroscopic lines caused by self-collisions in acetylene, where efficient resonant rotational energy transfer between a pair of molecules separated in energy by rotational quantum number ΔJ = ± 2, can result in a different pressure broadening for ortho- and para- nuclear spin state molecules. This work was prompted by a controversial report [Iwakuni et al. Phys. Rev Letts. 117 (2016) 143902] of the observation of such an effect in the v 1 +v 3 combination band transition of acetylene discussed in the original proposal. After delays caused by the COVID-19 pandemic, we have completed these measurements and a paper was published in the Journal of Chemical Physics describing the work. The measurements pointed out that the use of an approximate model in the analysis of the original work was the cause of the erroneous conclusion that ortho and para acetylene molecules had substantially different collisional lifetime broadening. In the process, much improved broadening measurements have been made that will permit more reliable modeling of the effects in the future. Subsequently, we have completed a new set of measurements of self- and nitrogen-collisional broadening at a series of low and intermediate temperatures to characterize the temperature dependence of the effects in the molecule. This work is currently being analyzed and will be the subject of a paper to be published in the relatively near future. In addition, some very preliminary measurements of CH 4 as described in the proposal, have been completed. If facilities and time permit, these will continue as an undergraduate research project.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS1981

Simultaneous in-flight calibrations of the Galileo science platform and attitude control subsystems

This paper presents a design metholodology and simulation study results for a combined star scanner-gyro-scan platform in-flight calibration for the dual spin Galileo spacecraft. The design process involves three separate parts: the construction of an error model, development of the calibration model, and the selection of the appropriate estimation technique. The major innovative contribution lies in the development of the first two parts which are unique to the Galileo design. A unified procedure has been developed to allow simultaneous calibration of the three subsystems. However, provisions are also made in the software to calibrate each subsystem separately when the necessary a priori information is available.

Lai, J. Y.↗