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At least 757 records · Page 42

A systems approach to the physiology of weightlessness

A general systems approach to conducting and analyzing research on the human adaptation to weightlessness is presented. The research is aimed at clarifying the role that each of the major components of the human system plays following the transition to and from space. The approach utilizes a variety of mathematical models in order to pose and test alternative hypotheses concerned with the adaptation process. Certain aspects of the problem of fluid and electrolyte shifts in weightlessnes are considered, and an integrated hypothesis based on numerical simulation studies and experimental data is presented.

White, Ronald J.↗

Multi-rate demodulator architecture

A unique digital multi-rate demodulator (MRD) architecture is presented for onboard satellite communications processing. The multi-rate feature enables the same demodulator hardware to process either one wideband channel (WBC), or process up to thirty-two independent narrowband channels (NBC) that are time division multiplexed (TDM). The MRD can process many quadrature modulation format such as offset quadrature phase shift keying (OQPSK). Possible applications include voice and data transmission for commercial or military users.

Sherry, Michael A.↗

Trade Study of Five In-Situ Propellant Production System for a Mars Sample Return Mission

One of the goals of NASA''s HEDS enterprise is to establish a long-term human presence on Mars at a fraction of the cost of employing today''s technology. The most direct method of reducing mission cost is to reduce the launch mass of the spacecraft. If the propellants for the return phase of the mission are produced on Mars, the total spacecraft mass could be reduced significantly. An interim goal is a Mars Sample Return (MSR) mission, which is proposed to demonstrate the feasibility of in-situ propellant production (ISPP). Five candidate ISPP systems for producing two fuels and oxygen from the Martian atmosphere are considered in this design trade-off study:(1) Zirconia cell with methanol synthesis, (2) Reverse water gas shift (RWGS) with water electrolysis and methanol synthesis, (3) Sabatier process for methane production with water electrolysis, (4) Sabatier process with water electrolysis and partial methane pyrolysis, and (5) Sabatier/RWGS combination with water electrolysis. These systems have been the subject of numerous previous analytical studies and laboratory demonstrations. In this investigation, the systems are objectively compared on the basis of thermochemical performance models using a commonly used chemical plant analysis software package. The realistic effects of incomplete chemical conversion and gas phase separator performance are included in these models. This study focuses on the chemical processing and product separation subsystems. The CO2 compression upstream of the chemical plane and the liquefaction/storage components are not included here.

Green, S. T.↗

The Molecular Ecology of Guerrero Negro: Justifying the Need for Environmental Genomics

The record of life on the only planet where it is known to exist is contained in the biogeochemical processes that organisms catalyze for their survival, in the compounds that they produce, and in their phylogenetic (evolutionary) relationships to each other. We manipulated sulfate and nutrient concentrations in intact microbial mats over periods of time up to a year. The objectives of the manipulations were: 1) characterize the diversity of process-associated functional genes; 2) understand environmental conditions leading to shifts in microbial guilds; 3) monitor/identify competitive responses of organisms sharing a metabolic niche. Characterization of functional genes associated with carbon (mcrA), nitrogen (nifH, nirK) and sulfur (dsrkB) cycling performed to date provided insight into the diversity and metabolic potential of the system; however, we only identified broad scale correlations between gene abundances and changes in mat physiology. For instance, increases in methane production by mats subjected to lowered sulfate and salinity concentrations were correlated with an observed increase in abundance of hydrogenotroph-like mcrA genes. However, due to low sequence similarity to any cultured isolates, phylogenetic associations only allow order level taxonomic commentary, preventing any associations being made on the cellular level. In each of the genes characterized from these experiments, a significant portion of sequences recovered show minimal phylogenetic affiliation to cultured organisms, preventing any understanding of inter-community dynamics and the functional capacities of these unknown organisms. Environmental genomics may provide insight into mat systems by allowing the correlation of functional genes with phylogenetic markers.

Smith, Jason M.↗

Connecting the Dots: An Assessment of Cyber-risks in Networked Building and Municipal Infrastructure Systems

The buildings and city streets we walk down are changing. Driven by various data-driven use cases, there is increased interest in networking and integrating lighting and other building systems (e.g., heating, ventilation, and air conditioning (HVAC), security, scheduling) that were previously not internet-facing, and equipping them with sensors that collect information about their environment and the people that inhabit it. These data-enabled systems can potentially deliver improved occupant and resident experiences and help meet the U.S. Department of Energy (DOE) national energy and carbon reduction goals. Deploying connected devices new to being networked, however, is not without its challenges. This paper explores tools available to system designers and integrators that facilitate a cybersecurity landscape assessment – or more specifically the identification of threats, vulnerabilities, and adversarial behaviors that could be used against these networked systems. These assessments can help stakeholders shift security prioritization proactively toward the beginning of the development process.

cyber-risk assesment, adversarial behavior, MITRE ↗

Mars 2020 Entry, Descent, and Landing as Observed by Radio Science Techniques at UHF and X-band Frequencies

On February 18, 2021, NASA’s Mars 2020 Rover “Perseverance” conducted the Entry, Descent, and Landing (EDL) sequence to land safely on the surface of Mars at Jezero Crater. Due to the criticality of the EDL sequence, redundant telecommunications strategies were utilized to observe the event. The rover transmitted an X-band (8.4 GHz) signal encoded with Multiple Frequency Shift Keying tones direct-to-Earth and a UHF (401.5 MHz) signal with 8 kbps encoded telemetry to orbiters, which relayed the signal back to Earth at X-band. NASA’s Deep Space Network complexes at Goldstone, California and Madrid, Spain received the direct-to-Earth X-band signal. Two of the largest steerable radio telescopes in the world, the 100-meter Green Bank Telescope in West Virginia and the Effelsberg 100-meter Radio Telescope in Germany also received the UHF carrier signal on Earth. During the EDL event, full spectrum recordings of the UHF and X-band signals were captured at these observatories using open-loop receivers. Real-time and post-processing signal analysis to determine power level, received frequency, and Doppler shift allowed determination of the spacecraft’s health and safety state during critical sequences, including event detection such as atmospheric entry, plasma blackouts, and parachute deployment. Simultaneous observations of the UHF and X-band radio links allow for redundancy in the event of a fault and greatly improve confidence in Doppler event detection.

Gladden, Roy↗

Aerogel with Unparalleled Performance and Cost-Effectiveness for All Insulation Needs (CRADA Final Report)

Westwood Aerogel investigated the reproducible production of an ambiently or electromagnetic spectrum assisted drying of extremely porous aerogel materials. Traditional aerogel processing is limited by low throughput and scalability due to supercritical drying. Westwood Aerogel’s advanced manufacturing process enables commercialization and deployment at scale, making aerogel materials more accessible to a range of industries and applications. We focused on shifting from the lab scale environment to manufacturing prototypes. The initial manufacturing model is based on the float glass process, which is the industry standard for glass window production, and the paper drying process. By incorporating an ambient drying process a continuous line model can be used from start to finish. The project team worked to develop a continuous manufacturing system to scale-up and reduce costs while maintaining the lightweight and insulative properties of aerospace-grade aerogel. While aerogels are extremely insulative, lightweight, and thin materials (making them ideal insulators across application spaces), high costs and stagnant innovation have hampered their wider adoption. Traditional manufacturing of aerogel requires supercritical extraction of pore fluid to obtain highly insulating materials, which is an energy intensive batch process and limits aerogel production output. Westwood Aerogel’s proprietary ambient drying process enables the continuous production of highly insulative aerogel materials without the use of supercritical extraction.

36 MATERIALS SCIENCE↗

MAGNETOROTATIONALLY DRIVEN SUPERNOVAE AS THE ORIGIN OF EARLY GALAXY r-PROCESS ELEMENTS?

We examine magnetorotationally driven supernovae as sources of r-process elements in the early Galaxy. On the basis of thermodynamic histories of tracer particles from a three-dimensional magnetohydrodynamical core-collapse supernova model with approximated neutrino transport, we perform nucleosynthesis calculations with and without considering the effects of neutrino absorption reactions on the electron fraction (Y{sub e} ) during post-processing. We find that the peak distribution of Y{sub e} in the ejecta is shifted from {approx}0.15 to {approx}0.17 and broadened toward higher Y{sub e} due to neutrino absorption. Nevertheless, in both cases, the second and third peaks of the solar r-process element distribution can be reproduced well. The rare progenitor configuration that was used here, characterized by a high rotation rate and a large magnetic field necessary for the formation of bipolar jets, could naturally provide a site for the strong r-process in agreement with observations of the early Galactic chemical evolution.

79 ASTRONOMY AND ASTROPHYSICS↗

Steady-state simulation and optimization of an integrated gasification combined cycle power plant with CO2 capture

Integrated gasification combined cycle (IGCC) plants are a promising technology option for power generation with carbon dioxide (CO2) capture in view of their efficiency and environmental advantages over conventional coal utilization technologies. This paper presents a three-phase, top-down, optimization-based approach for designing an IGCC plant with precombustion CO2 capture in a process simulator environment. In the first design phase, important global design decisions are made on the basis of plant-wide optimization studies with the aim of increasing IGCC thermal efficiency and thereby making better use of coal resources and reducing CO2 emissions. For the design of an IGCC plant with 90% CO2 capture, the optimal combination of the extent of carbon monoxide (CO) conversion in the water-gas shift (WGS) reactors and the extent of CO2 capture in the SELEXOL process, using dimethylether of polyethylene glycol as the solvent, is determined in the first phase. In the second design phase, the impact of local design decisions is explored considering the optimum values of the decision variables from the first phase as additional constraints. Two decisions are made focusing on the SELEXOL and Claus unit. In the third design phase, the operating conditions are optimized considering the optimum values of the decision variables from the first and second phases as additional constraints. The operational flexibility of the plant must be taken into account before taking final design decisions. Two studies on the operational flexibility of the WGS reactors and one study focusing on the operational flexibility of the sour water stripper (SWS) are presented. At the end of the first iteration, after executing all the phases once, the net plant efficiency (HHV basis) increases to 34.1% compared to 32.5% in a previously published study (DOE/NETL-2007/1281; National Energy Technology Laboratory, 2007). The study shows that the three-phase, top-down design approach presented is very useful and effective in a process simulator environment for improving efficiency and flexibility of IGCC power plants with CO2 capture. In addition, the study identifies a number of key design variables that has strong impact on the efficiency of an IGCC plant with CO2 capture.

01 COAL, LIGNITE, AND PEAT↗

To What Extent Will Decarbonization Deepen the Conversation Between Industry and the Grid?

Decarbonization - the transition away from un-mitigated fossil fuel combustion throughout the economy - requires big changes from both power and process systems. On the power system side, those changes are expected to include large increases in variable generation, e.g., from wind and solar, which has near-zero marginal costs and at large shares can produce infrequent but consequential energy droughts. On the process systems side, industries are investigating their options for direct and indirect electrification, the latter exemplified by replacing fossil fuel inputs with zero-carbon, energy-carrying chemicals like hydrogen and ammonia produced via electrochemical processes. The economic features of these changes within the larger context of power and process systems suggest that their realization could be accompanied by a paradigm shift in how industrial facilities interact with the grid. For example, the dominant type of demand participation in power markets could change from today's focus on load reductions at peak times to a new focus on shifting electricity use, enabled in part by large-scale product storage, to take advantage of renewable energy that would otherwise be curtailed and to avoid consumption during high-price energy droughts. This talk will describe these and other possible design and operational approaches from grid and industrial economic perspectives, culminating in an enumeration of open problems that lie at the interface of today and tomorrow's power and process systems.

co-design↗

Enhanced exchange bias effect in size modulated Sm{sub 0.5}Ca{sub 0.5}MnO{sub 3} phase separated manganite

The effect of grain size modulation on exchange bias effect in CE-type antiferromagnetic Sm{sub 0.5}Ca{sub 0.5}MnO{sub 3} phase separated manganite is reported here. With the reduction of particle size, ferromagnetic clusters are found to form in the charge ordered antiferromagnetic matrix and gradually become larger. The horizontal and vertical shifts of the magnetic hysteresis loops in the field cooled magnetization process clearly indicate the size dependent exchange bias effect and it can be tuned with the reduction of particle sizes. The values of exchange bias parameter, i.e., exchange bias field (H{sub E}), coercivity (H{sub C}), remanence asymmetry (M{sub E}), and magnetic coercivity (M{sub C}) are found to depend strongly on the particle size. The variations of H{sub E} follow non-monotonic dependencies with reduction in particle size and show maximum (1205 Oe) at particle size of 150 nm at T = 5 K, which can be ascribed due to the changes in uncompensated surface spins. The values of H{sub E} and M{sub E} are found to decrease exponentially with increasing temperature below the spin- or cluster-glass like freezing temperature. The spin relaxation model has been employed for analysis of large magnetic training effect. The linear relationship between H{sub E} and M{sub E} further confirms the role of uncompensated surface spins. In view of spintronics application of manganites, the present observation of large exchange bias shift in this half-doped manganite may have great technological importance.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Observation of site-selective chemical bond changes via ultrafast chemical shifts

The concomitant motion of electrons and nuclei on the femtosecond time scale marks the fate of chemical and biological processes. Here we demonstrate the ability to initiate and track the ultrafast electron rearrangement and chemical bond breaking site-specifically in real time for the carbon monoxide diatomic molecule. We employ a local resonant x-ray pump at the oxygen atom and probe the chemical shifts of the carbon core-electron binding energy. We observe charge redistribution accompanying core-excitation followed by Auger decay, eventually leading to dissociation and hole trapping at one site of the molecule. The presented technique is general in nature with sensitivity to chemical environment changes including transient electronic excited state dynamics. This work provides a route to investigate energy and charge transport processes in more complex systems by tracking selective chemical bond changes on their natural timescale.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Practical Operational Readiness Gambits: Operations Training Simulations for the Curiosity Rover

The Mars Science Laboratory team had been puttingin effort to make a Training Venue to allow for parallel shadowtactical operations for trainees to actively work alongside theprime tactical operations personnel without affecting operations,since staffing constraints and shortened operations timelineswere straining the tactical process in supporting operationstrainees in the traditional way. The COVID- 19 Pandemic presentedfurther challenges in continuing on-console training forMSL operations trainees. The MSL operations team switched tofully remote operations, thus hampering the direct mentorshipa trainee would normally receive while on site at JPL. TheMars 2020 training team had developed a concept for roveroperations training simulations based on Johnson Space Center’sextensive simulations training program for astronauts andflight controllers. The MSL team borrowed this idea, and implementedthese training simulations which are called PracticalOperational Readiness Gambits (PORGs). The PORGs so farhave focused on the Science Planner and Rover Planner roles,which are two crucial roles in tactical operations that engagein key interactions throughout a shift. PORGs are based onactual sol scenarios that have occurred on Mars and follow thetactical operations process and timeline as closely as possible.However, unlike an operations shift, PORGs can slow down orpause to allow for more mentoring time. PORGs can focus onparticular skills to test the trainees on their understanding ofa concept. PORGs increase in complexity with each scenario toease the trainees into more typical tactical operations workloads.As more trainees join the MSL operations team, more roles arebeing incorporated into PORGs. There are plans to incorporatecertified operations personnel into PORGs to practice anomalyresponse situations. PORGs have become an essential part of theMSL operations training program and will continue even afterthe return to on-site operations at JPL.

Gajeway, Jocelyn↗

Looking Beyond Energy Efficiency: An Applied Review of Water Desalination Technologies and an Introduction to Capillary-Driven Desalination

Most notable emerging water desalination technologies and related publications, as examined by the authors, investigate opportunities to increase energy efficiency of the process. In this paper, the authors reason that improving energy efficiency is only one route to produce more cost-effective potable water with fewer emissions. In fact, the grade of energy that is used to desalinate water plays an equally important role in its economic viability and overall emission reduction. This paper provides a critical review of desalination strategies with emphasis on means of using low-grade energy rather than solely focusing on reaching the thermodynamic energy limit. Herein, it is argued that large-scale commercial desalination technologies have by-and-large reached their engineering potential. They are now mostly limited by the fundamental process design rather than process optimization, which has very limited room for improvement without foundational change to the process itself. The conventional approach toward more energy efficient water desalination is to shift from thermal technologies to reverse osmosis (RO). However, RO suffers from three fundamental issues: (1) it is very sensitive to high-salinity water, (2) it is not suitable for zero liquid discharge and is therefore environmentally challenging, and (3) it is not compatible with low-grade energy. From extensive research and review of existing commercial and lab-scale technologies, the authors propose that a fundamental shift is needed to make water desalination more affordable and economical. Future directions may include novel ideas such as taking advantage of energy localization, surficial/interfacial evaporation, and capillary action. Here, some emerging technologies are discussed along with the viability of incorporating low-grade energy and its economic consequences. Finally, a new process is discussed and characterized for water desalination driven by capillary action. The latter has great significance for using low-grade energy and its substantial potential to generate salinity/blue energy.

Ahmadvand, Seyedsaeid (ORCID:000000017888262X)↗

Determining Aliasing in Isolated Signal Conditioning Modules

The basic concept of aliasing is this: Converting analog data into digital data requires sampling the signal at a specific rate, known as the sampling frequency. The result of this conversion process is a new function, which is a sequence of digital samples. This new function has a frequency spectrum, which contains all the frequency components of the original signal. The Fourier transform mathematics of this process show that the frequency spectrum of the sequence of digital samples consists of the original signal s frequency spectrum plus the spectrum shifted by all the harmonics of the sampling frequency. If the original analog signal is sampled in the conversion process at a minimum of twice the highest frequency component contained in the analog signal, and if the reconstruction process is limited to the highest frequency of the original signal, then the reconstructed signal accurately duplicates the original analog signal. It is this process that can give birth to aliasing.

Source record↗

Ocean cavity regime shift reversed West Antarctic grounding line retreat in the late Holocene

Recent geologic and modeled evidence suggests that the grounding line of the Siple Coast of the West Antarctic Ice Sheet (WAIS) retreated hundreds of kilometers beyond its present position in the middle to late Holocene and readvanced within the past 1.7 ka. This grounding line reversal has been attributed to both changing rates of isostatic rebound and regional climate change. Here, we test these two hypotheses using a proxy-informed ensemble of ice sheet model simulations with varying ocean thermal forcing, global glacioisostatic adjustment (GIA) model simulations, and coupled ice sheet-GIA simulations that consider the interactions between these processes. Our results indicate that a warm to cold ocean cavity regime shift is the most likely cause of this grounding line reversal, but that GIA influences the rate of ice sheet response to oceanic changes. This implies that the grounding line here is sensitive to future changes in sub-ice shelf ocean circulation.

58 GEOSCIENCES↗

Renewable hydrogen production via thermochemical/electrochemical coupling

A coupled electrochemical/thermochemical cycle was investigated to produce hydrogen from renewable resources. Like a conventional thermochemical cycle, this cycle leverages chemical energy stored in a thermochemical working material that is reduced thermally by solar energy. However, in this concept, the stored chemical energy only needs to be partially, but not fully, capable of splitting steam to produce hydrogen. To complete the process, a proton-conducting membrane is driven to separate hydrogen as it is produced, thus shifting the thermodynamics toward further hydrogen production. This novel coupled-cycle concept provides several benefits. First, the required oxidation enthalpy of the reversible thermochemical material is reduced, enabling the process to occur at lower temperatures. Second, removing the requirement for spontaneous steam-splitting widens the scope of materials compositions, allowing for less expensive/more abundant elements to be used. Lastly, thermodynamics calculations suggest that this concept can potentially reach higher efficiencies than photovoltaic-to-electrolysis hydrogen production methods. This Exploratory Express LDRD involved assessing the practical feasibility of the proposed coupled cycle. A test stand was designed and constructed and proton-conducting membranes were synthesized. While the full proof of concept was not achieved, the individual components of the experiment were validated and new capabilities that can be leveraged by a variety of programs were developed.

08 HYDROGEN↗

Magnetoelastic Effects in Doubly Clamped Electroplated $\mathrm{Co_{77}Fe_{23}}$ Microbeam Resonators

Magnetostrictive $\mathrm{Co_{77}Fe_{23}}$ films are fully suspended to produce free-standing, clamped-clamped, microbeam resonators. A negative or positive shift in the resonant frequency is observed for magnetic fields applied parallel or perpendicular to the length of the beam, respectively, confirming the magnetoelastic nature of the shift. Notably, the resonance shifts linearly with higher-bias fields oriented perpendicular to the beam’s length. Domain imaging elucidates the distinction in the reversal processes along the easy and hard axes. Finally, these results suggest that through modification of the magnetic anisotropy, the frequency shift and angular dependence can be tuned, producing highly magnetic-field-sensitive resonators.

47 OTHER INSTRUMENTATION↗