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At least 757 records · Page 42

Small Fast Spectrum Reactor Designs Suitable for Direct Nuclear Thermal Propulsion

Advancement of U.S. scientific, security, and economic interests through a robust space exploration program requires high performance propulsion systems to support a variety of robotic and crewed missions beyond low Earth orbit. Past studies, in particular those in support of the Space Exploration Initiative (SEI), have shown nuclear thermal propulsion systems provide superior performance for high mass high propulsive delta-V missions. The recent NASA Design Reference Architecture (DRA) 5.0 Study re-examined mission, payload, and transportation system requirements for a human Mars landing mission in the post-2030 timeframe. Nuclear thermal propulsion was again identified as the preferred in-space transportation system. A common nuclear thermal propulsion stage with three 25,000-lbf thrust engines was used for all primary mission maneuvers. Moderately lower thrust engines may also have important roles. In particular, lower thrust engine designs demonstrating the critical technologies that are directly extensible to other thrust levels are attractive from a ground testing perspective. An extensive nuclear thermal rocket technology development effort was conducted from 1955-1973 under the Rover/NERVA Program. Both graphite and refractory metal alloy fuel types were pursued. Reactors and engines employing graphite based fuels were designed, built and ground tested. A number of fast spectrum reactor and engine designs employing refractory metal alloy fuel types were proposed and designed, but none were built. The Small Nuclear Rocket Engine (SNRE) was the last engine design studied by the Los Alamos National Laboratory during the program. At the time, this engine was a state-of-the-art graphite based fuel design incorporating lessons learned from the very successful technology development program. The SNRE was a nominal 16,000-lbf thrust engine originally intended for unmanned applications with relatively short engine operations and the engine and stage design were constrained to fit within the payload volume of the then planned space shuttle. The SNRE core design utilized hexagonal fuel elements and hexagonal structural support elements. The total number of elements can be varied to achieve engine designs of higher or lower thrust levels. Some variation in the ratio of fuel elements to structural elements is also possible. Options for SNRE-based engine designs in the 25,000-lbf thrust range were described in a recent (2010) Joint Propulsion Conference paper. The reported designs met or exceeded the performance characteristics baselined in the DRA 5.0 Study. Lower thrust SNRE-based designs were also described in a recent (2011) Joint Propulsion Conference paper. Recent activities have included parallel evaluation and design efforts on fast spectrum engines employing refractory metal alloy fuels. These efforts include evaluation of both heritage designs from the Argonne National Laboratory (ANL) and General Electric Company GE-710 Programs as well as more recent designs. Results are presented for a number of not-yet optimized fast spectrum engine options.

Schnitzler, Bruce G.↗

Wide Operating Temperature Range Electrolytes for High Voltage and High Specific Energy Li-Ion Cells

A number of electrolyte formulations that have been designed to operate over a wide temperature range have been investigated in conjunction with layered-layered metal oxide cathode materials developed at Argonne. In this study, we have evaluated a number of electrolytes in Li-ion cells consisting of Conoco Phillips A12 graphite anodes and Toda HE5050 Li(1.2)Ni(0.15)Co(0.10)Mn(0.55)O2 cathodes. The electrolytes studied consisted of LiPF6 in carbonate-based electrolytes that contain ester co-solvents with various solid electrolyte interphase (SEI) promoting additives, many of which have been demonstrated to perform well in 4V systems. More specifically, we have investigated the performance of a number of methyl butyrate (MB) containing electrolytes (i.e., LiPF6 in ethylene carbonate (EC) + ethyl methyl carbonate (EMC) + MB (20:20:60 v/v %) that contain various additives, including vinylene carbonate, lithium oxalate, and lithium bis(oxalato)borate (LiBOB). When these systems were evaluated at various rates at low temperatures, the methyl butyrate-based electrolytes resulted in improved rate capability compared to cells with all carbonate-based formulations. It was also ascertained that the slow cathode kinetics govern the generally poor rate capability at low temperature in contrast to traditionally used LiNi(0.80)Co(0.15)Al(0.05)O2-based systems, rather than being influenced strongly by the electrolyte type.

Li-ion Battery↗

The Effect of Electrolyte Additives upon the Lithium Kinetics of Li-Ion Cells Containing MCMB and LiNi(x)Co(1-x)O2 Electrodes and Exposed to High Temperatures

With the intent of improving the performance of lithium-ion cells at high temperatures, we have investigated the use of a number of electrolyte additives in experimental MCMB- Li(x)Ni(y)Co(1-y)O2 cells, which were exposed to temperatures as high as 80 C. In the present work, we have evaluated the use of a number of additives, namely vinylene carbonate (VC), dimethyl acetamide (DMAc), and mono-fluoroethylene carbonate (FEC), in an electrolyte solution anticipated to perform well at warm temperature (i.e., 1.0M LiPF6 in EC+EMC (50:50 v/v %). In addition, we have explored the use of novel electrolyte additives, namely lithium oxalate and lithium tetraborate. In addition to determining the capacity and power losses at various temperatures sustained as a result of high temperature cycling (cycling performed at 60 and 80 C), the three-electrode MCMB-Li(x)Ni(y)Co(1-y)O2 cells (lithium reference) enabled us to study the impact of high temperature storage upon the solid electrolyte interphase (SEI) film characteristics on carbon anodes (MCMB-based materials), metal oxide cathodes, and the subsequent impact upon electrode kinetics.

High Temperture Resilience↗

Success Factors in Human Space Programs - Why Did Apollo Succeed Better Than Later Programs?

The Apollo Program reached the moon, but the Constellation Program (CxP) that planned to return to the moon and go on to Mars was cancelled. Apollo is NASA's greatest achievement but its success is poorly understood. The usual explanation is that President Kennedy announced we were going to the moon, the scientific community and the public strongly supported it, and Congress provided the necessary funding. This is partially incorrect and does not actually explain Apollo's success. The scientific community and the public did not support Apollo. Like Apollo, Constellation was announced by a president and funded by Congress, with elements that continued on even after it was cancelled. Two other factors account for Apollo's success. Initially, the surprise event of Uri Gagarin's first human space flight created political distress and a strong desire for the government to dramatically demonstrate American space capability. Options were considered and Apollo was found to be most effective and technically feasible. Political necessity overrode both the lack of popular and scientific support and the extremely high cost and risk. Other NASA human space programs were either canceled, such as the Space Exploration Initiative (SEI), repeatedly threatened with cancellation, such as International Space Station (ISS), or terminated while still operational, such as the space shuttle and even Apollo itself. Large crash programs such as Apollo are initiated and continued if and only if urgent political necessity produces the necessary political will. They succeed if and only if they are technically feasible within the provided resources. Future human space missions will probably require gradual step-by-step development in a more normal environment.

Success factors↗

A Miniaturized Variable Pressure Scanning Electron Microscope (MVP-SEM) for the Surface of Mars: An Instrument for the Planetary Science Community

The Miniaturized Variable Pressure Scanning Electron Microscope(MVP-SEM) project, funded by the NASA Planetary Instrument Concepts for the Advancement of Solar System Observations (PICASSO) Research Opportunities in Space and Earth Science (ROSES), will build upon previous miniaturized SEM designs for lunar and International Space Station (ISS) applications and recent advancements in variable pressure SEM's to design and build a SEM to complete analyses of samples on the surface of Mars using the atmosphere as an imaging medium. By the end of the PICASSO work, a prototype of the primary proof-of-concept components (i.e., the electron gun, focusing optics and scanning system)will be assembled and preliminary testing in a Mars analog chamber at the Jet Propulsion Laboratory will be completed to partially fulfill Technology Readiness Level to 5 requirements for those components. The team plans to have Secondary Electron Imaging(SEI), Backscattered Electron (BSE) detection, and Energy Dispersive Spectroscopy (EDS) capabilities through the MVP-SEM.

Mars↗

Advancing Torpor Inducing Transfer Habitats for Human Stasis to Mars: II - Phase

SpaceWorks Enterprises, Inc. (SEI) has conducted an evaluation of an advanced habitat system designed to transportcrews between the Earth and Mars. This new and innovative habitat concept is capable of placing crew members ininactive, torpor states during transit phases of a deep space mission. This substantially reduces the mass and size ofthe habitat, which ultimately leads to significant reductions in the overall architecture size.Our approach for achieving this is based on extending the current and evolving medical practice of TherapeuticHypothermia (TH) - a proven and effective treatment for various traumatic injuries. TH is a medical treatment thatlowers a patient's body temperature by just 5 to 10 degrees Fahrenheit causing human metabolic rate to decreasesignificantly and the body to enter an unconscious state. This method avoids the intractable challenges often associatedwith cell metabolic cessation through cryogenic freezing and other highly speculative approaches.The initial results obtained from the research and analysis conducted in the Phase I effort warranted further study ofthis concept and technology. The specific objectives of the continued work include:1. Addressing critical medical aspects and risks for inducing torpor via Therapeutic Hypothermia and theapproach for providing nutrition and hydration for the crew during torpor. 2. Focusing on mitigation aspects and technology potential for solving key human spaceflight challenges. 3. Addressing critical engineering aspects of the design that may impact the initial performance and cost resultsobtained in Phase I. 4. Examining the broader extensibility and enabling capabilities of this concept through applicability toadditional exploration missions beyond Mars. 5. Establishing a technology development roadmap, addressing both medical and engineering aspects, thatindicate a logical and scientifically achievable path forward for maturation of this technology.

Stasis↗

Final Mission and Navigation Design for the 2016 Mars InSight Mission

NASA’s Interior Exploration using Seismic Investigations, Geodesy, and Heat Transport (InSight) mission was scheduled to launch the next lander to Mars in March 2016 arriving to the Red Planet in the fall. Derived from the Phoenix mission which successfully landed on Mars in May 2008, the InSight Entry, Descent, and Landing system will place a lander in the Elysium Planitia region. This paper specifies the mission and navigation requirements set by the Project and how the final mission and navigation design satisfies those requirements. Background information affecting navigation including spacecraft modeling and the physical environment which influences the spacecraft motion are included. (Note from the author: The InSight launch in 2016 was suspended due to critical issues with the Seismic Experiment for Interior Structure (SEIS) instrument that could not be fixed prior to the planned launch period. This paper represents the state of the design for the 2016 mission. No attempt has been made to reflect the latest developments).

Abilleira, Fernando↗

Seasonal Variations of Seismic Activity on Mars?

We analyze the sequence of seismic events of different types as recorded by the SEIS instrument of the InSight mission. After several weeks without any detection, event counts started to increase at the end of May 2019. The majority of recorded events belongs to the class of 2.4 Hz events, which prominently excite a continuously observed natural resonance frequency. Comparison with expected event counts from a constant-rate Poisson process shows a repeated, step wise increase of the event rate with time. At the same time, event amplitudes, and hence magnitudes, are found to increase as well.

Knapmeyer, M.↗

Preparation and Execution of the InSight Instrument Deployment Phase

The NASA InSight lander arrived at Mars on November 26, 2018 on a unique science mission to study the interior of the red planet. InSight’s instrument suite is investigating the geophysical characteristics of Mars, providing a glimpse into the formation and evolution of the planet and other similar Earth-like terrestrial bodies. Upon landing, the mission entered the Instrument Deployment Phase (IDP) to survey, deploy, and install the SEIS, WTS, and HP3 elements onto the Martian surface.

Imken, Travis↗

Instrumentation for Exploring Mars with High Science Return Small Payload Missions

The Mars Exploration Directorate at the JPL is sponsoring a study to examine technical feasibility of developing small spacecraft missions (SSc) capable of low-cost compelling science. Low cost small spacecraft missions can enable unique mission concepts with higher than normal mission risk. This increase in risk can create opportunities for low-cost, compelling science missions in regions that may be otherwise unexplored, provide opportunities for constellations, networks scouts, and fundamentally new measurements. Potential science instruments for MEPAG high-priority investigations suited to small spacecraft mass, volume, power, and cost constraints include compact versions of a camera (MSL EECam), Meteorology (MEDA-ATS or FMI wind, barometry, T, and P), Seismometer (INSIGHT SEIS), Atmosphere and trace Gases (MSL Tunable Laser Spectrometer), Dust (ExoMars MicroMED) analyzers, and fluxgate magnetometers (INSIGHT Mag). Two examples of low cost mission concepts are LOKI (Localizing Organic Key Ingredients), an areostationary SmallSat orbital constellation designed to measure trace gases, and TH2OR, a time-domain EM sound capable of water detection to a depth of many kilometers which would be landed via a small high impact energy device (SHIELD).

Anderson, R.↗

The Promise of Alloy Anodes for Solid-State Batteries

Solid-state batteries are anext-generation technology that could featureimproved safety and energy density, but reliably integrating high-capacity electrode materials to enable high energy while retaining stablelong-termcycling remains a challenge. Anode materials that alloy with lithium, such as silicon, tin, and aluminum,offer high capacity that canyield high-energy battery cells. The use of alloy anodes in solid-state batteries potentially offers major mechanistic benefits compared to other anode contendersand battery systems, such as lithium metal in solid-state architectures or alloys in liquid-electrolyte batteries. This perspective discusseskey advantagesof alloy anode materials for solid-state batteries, including the avoidance of the short circuiting observed with lithium metal and the chemo-mechanical stabilization of the solid-electrolyte interphase (SEI). We further discuss open research questions and challenges in engineering alloy-anode-based solid-state batteries, with the goal of advancing our understanding and control of alloy anode materialswithin solid-state architectures toward commercial application.

John A Lewis↗

Results from InSight Robotic Arm Activities

The InSight lander carried an Instrument Deployment System (IDS) that included an Instrument Deployment Arm (IDA), scoop, five finger “claw” grapple, forearm-mounted Instrument Deployment Camera (IDC) requiring arm motion to image a target, and landermounted Instrument Context Camera (ICC), designed to image the workspace, and to place the instruments onto the surface. As originally proposed, the IDS included a previously built arm and flight spare black and white cameras and had no science objectives or requirements, or expectation to be used after instrument deployment (90 sols). During project development the detectors were upgraded to color, and it was recognized that the arm could be used to carry out a wide variety of activities that would enable both geology and physical properties investigations. During surface operations for two martian years, the IDA was used during major campaigns to image the surface around the lander, to deploy the instruments, to assist the mole in penetrating beneath the surface, to bury a portion of the seismometer tether, to clean dust from the solar arrays to increase power, and to conduct a surface geology investigation including soil mechanics and physical properties experiments. No other surface mission has engaged in such a sustained and varied campaign of arm and scoop activities directed at such a diverse suite of objectives. Images close to the surface and continuous meteorology measurements provided important constraints on the threshold friction wind speed needed to initiate aeolian saltation and surface creep. The IDA was used extensively for almost 22 months to assist the mole in penetrating into the subsurface. Soil was scraped into piles and dumped onto the seismometer tether six times in an attempt to bury the tether and ∼ 30% was entrained in the wind and dispersed downwind 1-2 m, darkening the surface. Seven solar array cleaning experiments were conducted by dumping scoops of soil from 35 cm above the lander deck during periods of high wind that dispersed the sand onto the panels that kicked dust off of the panels into suspension in the atmosphere, thereby increasing the power by ∼15% during this period. Final IDA activities included an indentation experiment that used the IDA scoop to push on the ground to measure the plastic deformation of the soil that complemented soil mechanics measurements from scoop interactions with the surface, and two experiments in which SEIS measured the tilt from the arm pressing on the ground to derive near surface elastic properties.

Mars↗

Lithium Metal Electrode — Understanding Its Unique Characteristics and Functions

Lithium metal electrode (LME) is attractive for the next generation of commercial high-energy rechargeable lithium battery (RLB) design and development. As a light element with a very reducing electrochemical potential, Li metal certainly has the unique characteristics that also present challenges for its application in RLBs. To overcome technical barriers with LME such as the dendrite formation that causes uneven current distributions, excessive SEI formation that consumes Li inventory, and formation of inactive Li metal in granular forms that induces safety hazards, more fundamental understanding of the unique characteristics of LME and its impact on functions in performance in RLBs is critical. Here, we present some recent work based on temporally-correlated reactive molecular dynamics simulations to understand the Li deposition and the associated nucleation and growth process on the LME or graphitic electrode surfaces. Such a study provides some intriguing perspectives on how Li reacts with electrolytes on LME and conventional graphitic electrodes in the RLB operation. Such an insight could help improving our strategy to deal with LME problems and provide functional improvements for LME’s application in RLBs. This presentation is dedicated to Professor Robert Huggins for his life-long teaching of the fundamentals on solid state ionics and its implications in understanding the electrochemical behavior of Li in RLB applications.

25 ENERGY STORAGE↗

Co-solvents with high coulombic efficiency in propylene carbonate based electrolytes

A homologous series of cyclic carbonate or propylene carbonate (PC) analog solvents with increasing length of linear alkyl substitutes were synthesized and used as co-solvents with PC for graphite based lithium ion half cells. A graphite anode reaches a capacity around 310 mAh/g in PC and its analog co-solvents with 99.95% Coulombic efficiency. Cyclic carbonate co-solvents with longer alkyl chains are able to prevent exfoliation of graphite when used as co-solvents with PC. The cyclic carbonate co-solvents of PC compete for solvation of Li ion with PC solvent, delaying PC co-intercalation. Reduction products of PC on graphite surfaces via single-electron path form a stable Solid Electrolyte Interphase (SEI), which allows the reversible cycling of graphite.

25 ENERGY STORAGE↗

Mechanism of Solid Electrolyte Interphase Formation on Lithium Anodes Studied by Molecular Dynamics Simulations

We investigated the initial formation of the SEI on lithium-metal anodes in presence of several electrolyte compositions using ReaxFF, in absence of a bias potential. We observed the formation of well-defined regions with different density and oxidation states of Li. Dissolution of Li metal atoms results in an uneven distribution of Li in the liquid phase. The electrolyte decomposition mechanism was studied for various electrolyte mixtures. Overall, the reaction mechanisms observed with ReaxFF are in good agreement with previous reports using DFT. However, we found some discrepancies in specific predictions by the ReaxFF that should be addressed in future work.

25 ENERGY STORAGE↗

Solvent-Free and Non-Sintered 500 Wh/kg All Solid-State Battery

Navitas teamed up with UMD and ORNL to establish a reliable scientific research team. The project addressed processing limitations of state-of-the-art solid electrolytes by extending solvent-free electrode fabrication technology to the scalable production of cathode/solid electrolyte laminates. The innovation started with a solid-state sulfide electrolyte (LiPS) with Cl stabilization able to meet the keystone conductivity challenge in a film of practical thickness (μ 50 µm). The electrolyte was based on a composite of PTFE, and stabilized LiPSCl. With optimization, the ionic conductivity reached 3.3 ×10 -3 S/cm. The solid electrolyte with as low as 0.4% binder allowed long term cycling (> 500 cycles) of Li/SSE/Li cell at > 4 mA/cm 2 with the utilization of Li > 80%. The Li and SSE interfaces were successfully protected with LiF-rich SEI layer. NCM811cathode active materials were coated with a thin layer of Al 2 O 3 (5 nm). The free standing cathode film was fabricated through dry-process with Al2O3-coated NCM811, LiPSCl, active carbon, and small amount PTFE. The all-solid-state batteries were laminated with free standing surface coated NCM811 cathode film, free standing LiPSCl SSE film, and surface protected Li anode together in a single lamination step, and demonstrated high specific capacity (> 200 mAh/g) with coulombic efficiency > 99.5%. The all-solid-state batteries through solvent-free and no-sintering process are promising for large format cell with 500 Wh/Kg specific energy density.

25 ENERGY STORAGE↗