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At least 757 records · Page 42

Integrated Process Optimization for Biochemical Conversion

This research is motivated by the challenges faced during biomass processing in bioenergy plants. It has been observed that variations in biomass characteristics, such as moisture, ash, and carbohydrate contents cause variations in feeding of the system which led to underutilization of equipment and the reactor. The objective of this research is to ensure a continuous flow of biomass to the reactor in plants that use the biochemical conversion process to generate liquid fuels. The overall goal is to lower the cost of producing biofuels, which could lead to improving US’s energy independency and growing US’s rural economy. The research team developed analytical models, such as discrete element method (DEM) models and mathematical models. The DEM models are unit-level models that explicitly capture biomass characteristics and quantify the impacts of biomass characteristics on bulk material properties and the performance of specific equipment. The mathematical models are system-level models that capture the impacts of system infeed rate, equipment processing rate, storage location and capacity, and biomass characteristics on system throughput. The functional relations predicting the bulk material properties from DEM models are incorporated to the mathematical models. The models developed were validated and evaluated using data collected at Idaho National Laboratory’s biomass processing facility. Via these models, we identified process control strategies that ensure a continuous flow of biomass to the reactor, while meeting the requirements of biochemical conversion process. Our analysis indicates that sequencing of biomass bales based on moisture level, and carbohydrate contents could have a positive impact on reducing processing time and inventory level and increasing throughput rate. Short bale sequences that repeat frequently, seem to have the greatest impact on improving system’s performance. Based on our experiments, the total annual system operating costs reduced by 20-30%, and the maximum inventory level reduced by 3 to 4 times. The operating costs include the annual equipment amortization cost and processing cost. The implementation of the models developed requires the use of standardized bale format, Radio Frequency Identification technology, sensing and real time monitoring of material attributes, automated material handling equipment, and automated process control. The scope of the model proposed can be extended to include the whole supply chain. The supply chain models help identify how many bales of different biomass feedstock to purchase given biomass availability in the region, biomass price and quality, and the biomass processing capabilities of the biorefinery. Thus, the outcomes of supply chain models can be used to inform the design of long-term contracts among farmers and the biorefinery.

09 BIOMASS FUELS↗

Segmented Gamma Scanner for Radioactive Waste Assessment: A User Guide

Radioactive waste assessment is important for ensuring nuclear material security at various types of facilities, such as enrichment, fuel fabrication, and reprocessing plants. The waste generated at such nuclear facilities is stored in standard containers and is required to be characterized for material-accounting purposes. The segmented gamma scanner system is a popular, nondestructive analysis measurement system used for characterizing nuclear material, including radioactive waste. This document provides guidance on how to achieve effective performance from a segmented gamma scanner system for accurately quantifying fission products, activation products, and transuranic wastes.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

National Energy Water Treatment & Speciation (NEWTS): A Water & Critical Mineral Database and Dashboard

The scarcity of water resources, the need for beneficial water reuse, and the challenges of wastewater treatment are becoming increasingly pressing in economic, social, and environmental domains. Addressing these concerns requires effective treatment strategies to manage wastewater streams and tackle environmental and economic issues. Furthermore, the recovery of critical minerals from the waste streams associated with energy production holds the promise of offsetting treatment costs and securing local sources of valuable minerals. However, relevant data on these waste streams are dispersed and challenging to locate. The process of ingesting such data into modeling software often involves multiple steps, requiring data restructuring to meet software-input requirements. The non-standardized reporting of water data makes data aggregation and reformatting a time-consuming process. Additionally, essential attributes necessary for modeling water treatment and mineral scale formation are frequently missing. Moreover, data gaps vary depending on the region of interest. Consequently, there is a pressing need for high-quality energy-water composition data that can be easily imported into water chemistry modeling software. To address this need, the National Energy Technology Laboratory has created the National Energy Water Treatment and Speciation (NEWTS) Database and Dashboard—a free online tool catering to community leaders and water researchers. NEWTS facilitates a comprehensive understanding of the composition of energy-related wastewater streams in the United States. The datasets provide detailed concentrations and speciation of major and minor aqueous compounds in energy-related wastewater streams, including power plant leachate, acid mine drainage, brackish water, and oil and gas produced water across the United States. Many of the aqueous species are critical minerals (Li, REEs) in high demand to modernize the world’s energy infrastructure. Many of the datasets also contain volumetric flow-rates needed to model the treatment and reuse scenarios in advanced aqueous chemistry software programs. The NEWTS Database and Dashboard offer public access to hitherto challenging-to-access datasets, presented in a standardized format that is tailored for easy input into aqueous chemistry modeling software. By performing the work needed to transform dispersed, disparate data sources into unified, model-ready datasets, NEWTS serves as an essential resource in advancing water treatment research and sustainable water resource management.

produced water management↗

Package Testing Program Process for Validation and Verification of Software

The purpose of this document is to define the process for validation and verification (V&V) of software used to test the thermal data acquisition equipment in the Oak Ridge National Laboratory (ORNL) Package Testing Program (PTP) as part of the testing configuration(s). This process adheres to all applicable ORNL Standards Based Management System requirements and correlates with the PTP Quality Management System and the Software Quality Assurance Plan.

97 MATHEMATICS AND COMPUTING↗

Evaluation of Cease Fire CFP 640 for Use in Gloveboxes (Final Report)

A Los Alamos National Laboratory (LANL) task group was established to discuss and evaluate a candidate fire suppression system (FSS) for gloveboxes (GB) and dropboxes (DB, for brevity, this report will simply refer to gloveboxes). Suitability criteria include compliance, compatibility, and capability. LANL contracted with New Mexico Tech (NMT) to quantitatively evaluate the perfor mance of one of those systems including its ability to extinguish GB fires, limit over-pressurization of the GB, etc. Additionally, the results of these experiments provide data points that could be used when fire hazard evaluations (FHEs) are conducted for determining when to require a fire suppres sion system installation within a GB (as required by NFPA 801, Standard for Facilities Handling Radioactive Materials, DOE Standard 1066-2012 Fire Protection, and AGS-G010-2011 Standard of Practice for Glovebox Fire Protection).

42 ENGINEERING↗

Evaluation of Data Lake Design for the Accelerator Control System

In this modern world, the user expects faster processing and real-time response to operate accelerator control devices. The existing framework with its infrastructure does not have the ability to satisfy these future needs. Therefore, modernization is required to reach industry standards and develop a modular framework that can provide flexibility and dynamic scalability. The data lake architecture, comprising three layers, ingestion, processing, and data consumption, provides flexibility and scalability to meet current and future demands for the accelerator control system.

Jaikar, Amol [Fermilab]↗

Probabilistic Data Association for Orbital-Element Estimation Using Multistage Expectation–Maximization

Tracking space objects is important for managing space traffic and predicting collisions, but is difficult in part due to data association and orbit model uncertainty. Expectation–maximization (EM) is a commonly used tracking method that has not been widely considered for tracking space objects. The technique consists of iteratively computing data association probabilities with a set of current element estimates, and updating estimates of the elements by solving a nonlinear weighted least-squares regression problem where the weights are the data association probabilities. In this paper, we demonstrate the use of EM for probabilistic data association and orbital-element estimation by applying the technique to simulated data from two angles-only tracking scenarios. In both scenarios, EM provides correct data associations and accurate maximum likelihood estimates of orbital elements. One scenario considers tracking a single object in clutter and quantifies the improvement of the orbital-element estimates and data associations as the detection probability increases. However, standard application of EM requires knowing the number of objects or may fail when a large number of objects are present. To address these issues, this paper employs a multistage version of EM that is applicable when there are a large and possibly unknown number of objects.

97 MATHEMATICS AND COMPUTING↗

The first measurement of the muon anomalous magnetic moment from the Fermilab Muon g-2 collaboration

This paper will cover the physics and methods behind Fermilab’s Muon g-2 Experiment, along with the long-awaited results from Run-1. The experiment was undertaken to resolve the tension between the Standard Model and the previous measurement taken at Brookhaven National Laboratory. The measured value of the muon magnetic anomaly is a µ (FNAL) = 116592040(54) × 10 -11 . This result is in good agreement with Brookhaven’s previous measurement. The new world average, a µ (Exp) = 116592061(41) × 10 -11 , shows a difference from the theoretical value of the Standard Model (SM), a µ (SM) = 116591810(43) × 10 -11 , of 4.2 standard deviations, strongly hinting at physics beyond the Standard Model. The experiment requires the simultaneous measurement of the muon precession frequency, the magnetic field, and the muons’ distribution in the field. All three of these measurements will be discussed in context, along with the main systematic corrections and uncertainties.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Chronic Cardiotoxicity Assays Using Human Induced Pluripotent Stem Cell-Derived Cardiomyocytes (hiPSC-CMs)

Cardiomyocytes (CMs) differentiated from human induced pluripotent stem cells (hiPSCs) are increasingly used in cardiac safety assessment, disease modeling and regenerative medicine. A vast majority of cardiotoxicity studies in the past have tested acute effects of compounds and drugs; however, these studies lack information on the morphological or physiological responses that may occur after prolonged exposure to a cardiotoxic compound. In this review, we focus on recent advances in chronic cardiotoxicity assays using hiPSC-CMs. We summarize recently published literature on hiPSC-CMs assays applied to chronic cardiotoxicity induced by anticancer agents, as well as non-cancer classes of drugs, including antibiotics, anti-hepatitis C virus (HCV) and antidiabetic drugs. We then review publications on the implementation of hiPSC-CMs-based assays to investigate the effects of non-pharmaceutical cardiotoxicants, such as environmental chemicals or chronic alcohol consumption. We also highlight studies demonstrating the chronic effects of smoking and implementation of hiPSC-CMs to perform genomic screens and metabolomics-based biomarker assay development. The acceptance and wide implementation of hiPSC-CMs-based assays for chronic cardiotoxicity assessment will require multi-site standardization of assay protocols, chronic cardiac maturity marker reproducibility, time points optimization, minimal cellular variation (commercial vs. lab reprogrammed), stringent and matched controls and close clinical setting resemblance. A comprehensive investigation of long-term repeated exposure-induced effects on both the structure and function of cardiomyocytes can provide mechanistic insights and recapitulate drug and environmental cardiotoxicity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Developing Practical Models of Complex Salts for Molten Salt Reactors

Molten salt reactors (MSRs) utilize salts as coolant or as the fuel and coolant together with fissile isotopes dissolved in the salt. It is necessary to therefore understand the behavior of the salts to effectively design, operate, and regulate such reactors, and thus there is a need for thermodynamic models for the salt systems. Molten salts, however, are difficult to represent as they exhibit short-range order that is dependent on both composition and temperature. A widely useful approach is the modified quasichemical model in the quadruplet approximation that provides for consideration of first- and second-nearest-neighbor coordination and interactions. Its use in the CALPHAD approach to system modeling requires fitting parameters using standard thermodynamic data such as phase equilibria, heat capacity, and others. A shortcoming of the model is its inability to directly vary coordination numbers with composition or temperature. Another issue is the difficulty in fitting model parameters using regression methods without already having very good initial values. The proposed paper will discuss these issues and note some practical methods for the effective generation of useful models.

Besmann, Theodore M. (ORCID:0000000155980550)↗

A Biochar Classification System and Associated Test Methods

In this chapter, a biochar classification system related to its use as soil amendment is proposed. This document builds upon previous work: “Standardized product definition and product testing guidelines for biochar that is used in soil” (IBI, 2015) (aka IBI Biochar Standards) and “Guidelines for biochar production for a sustainable production of biochar: European Biochar Certificate” (EBC, 2012-2022) (aka EBC Biochar Standards). It should be noted that the EBC guidelines constitute the basis for biochar certification through the independent government accredited inspection agency, Bio.Inspecta AG. The present document constrains its scope to materials with properties that satisfy the criteria for biochar as defined by either the IBI Biochar Standards or the EBC Standards (Annex I), as required by the current methodologies developed for accounting carbon credits associated with the biochar use in the voluntary market (e.g., Verra, Puro.Earth). The classification system envisions enabling stakeholders and commercial entities to (i) identify the most suitable biochar to fulfil the requirements for a particular soil and/or land-use, (ii) distinguish the application of biochar for specific niches (e.g., soilless agriculture), and (iii) assess the climate-impact value based on biochar properties, production efficiency, and alternative feedstock uses. It is based on the best current knowledge and will need to be improved as new data and knowledge become available in the scientific literature.

biochar, climate change impacts, soil amendment, c↗

Metrics for Intercomparison of Remapping Algorithms (MIRA) protocol applied to Earth system models

Abstract. Strongly coupled nonlinear phenomena such as those described by Earth system models (ESMs) are composed of multiple component models with independent mesh topologies and scalable numerical solvers. A common operation in ESMs is to remap or interpolate component solution fields defined on their computational mesh to another mesh with a different combinatorial structure and decomposition, e.g., from the atmosphere to the ocean, during the temporal integration of the coupled system. Several remapping schemes are currently in use or available for ESMs. However, a unified approach to compare the properties of these different schemes has not been attempted previously. We present a rigorous methodology for the evaluation and intercomparison of remapping methods through an independently implemented suite of metrics that measure the ability of a method to adhere to constraints such as grid independence, monotonicity, global conservation, and local extrema or feature preservation. A comprehensive set of numerical evaluations is conducted based on a progression of scalar fields from idealized and smooth to more general climate data with strong discontinuities and strict bounds. We examine four remapping algorithms with distinct design approaches, namely ESMF Regrid (Hill et al., 2004), TempestRemap (Ullrich and Taylor, 2015), generalized moving least squares (GMLS) (Trask and Kuberry, 2020) with post-processing filters, and WLS-ENOR (Li et al., 2020). By repeated iterative application of the high-order remapping methods to the test fields, we verify the accuracy of each scheme in terms of their observed convergence order for smooth data and determine the bounded error propagation using challenging, realistic field data on both uniform and regionally refined mesh cases. In addition to retaining high-order accuracy under idealized conditions, the methods also demonstrate robust remapping performance when dealing with non-smooth data. There is a failure to maintain monotonicity in the traditional L2-minimization approaches used in ESMF and TempestRemap, in contrast to stable recovery through nonlinear filters used in both meshless GMLS and hybrid mesh-based WLS-ENOR schemes. Local feature preservation analysis indicates that high-order methods perform better than low-order dissipative schemes for all test cases. The behavior of these remappers remains consistent when applied on regionally refined meshes, indicating mesh-invariant implementations. The MIRA intercomparison protocol proposed in this paper and the detailed comparison of the four algorithms demonstrate that the new schemes, namely GMLS and WLS-ENOR, are competitive compared to standard conservative minimization methods requiring computation of mesh intersections. The work presented in this paper provides a foundation that can be extended to include complex field definitions, realistic mesh topologies, and spectral element discretizations, thereby allowing for a more complete analysis of production-ready remapping packages.

58 GEOSCIENCES↗

Tool simplifies machining of pipe ends for precision welding

Single tool prepares a pipe end for precision welding by simultaneously performing internal machining, end facing, and bevel cutting to specification standards. The machining operation requires only one milling adjustment, can be performed quickly, and produces the high quality pipe-end configurations required to ensure precision-welded joints.

Matus, S. T.↗

Apollo 11 impact on the occupational medicine program, NASA Manned Spacecraft Center

Requirements and development of standards for occupational medicine support of personnel in the Lunar Receiving Laboratory (LRL) are outlined. Considered are proper personnel performance and exclusion of people prone to develop a serious illness within the quarantine area. Occupational medicine report for the LRL consists of examination procedures covering laboratory work, periodic examinations, immunizations, health maintenance, preventive practices, medical standards, and waiver authority.

Wright, P. E.↗

Correlation and registration of ERTS multispectral imagery

Examples of automatic digital processing demonstrate the feasibility of registering one ERTS multispectral scanner (MSS) image with another obtained on a subsequent orbit, and automatic matching, correlation, and registration of MSS imagery with aerial photography (multisensor correlation) is demonstrated. Excellent correlation was obtained with patch sizes exceeding 16 pixels square. Qualities which lead to effective control point selection are distinctive features, good contrast, and constant feature characteristics. Results of the study indicate that more than 300 degrees of freedom are required to register two standard ERTS-1 MSS frames covering 100 by 100 nautical miles to an accuracy of 0.6 pixel mean radial displacement error. An automatic strip processing technique demonstrates 600 to 1200 degrees of freedom over a quater frame of ERTS imagery. Registration accuracies in the range of 0.3 pixel to 0.5 pixel mean radial error were confirmed by independent error analysis. Accuracies in the range of 0.5 pixel to 1.4 pixel mean radial error were demonstrated by semi-automatic registration over small geographic areas.

Bonrud, L. O.↗

Demonstration of optical navigation measurements on Mariner 10

An experiment was performed on the Mariner 10 Venus/Mercury mission to assess the performance of the onboard television cameras and ground-based software used in the optical navigation measurement system. The elements of the system, calibration, and distortion are considered. The navigation technique requires detection of stars in the same field of view as the target body. The star detection capability is discussed with reference to required threshold, calibration factors, standard conditions, camera sensitivity, response uniformity, and the effect of image smearing. Tests conducted during the Mariner 10 encounters with Mercury demonstrated that a large bright planet can be imaged simultaneously with faint stars to provide accurate navigation data. Improvements are suggested in the system for the Mariner Jupiter/Saturn 1977 and later missions.

Stanton, R. H.↗

Investigation of field induced trapping on floating gates

The development of a technology for building electrically alterable read only memories (EAROMs) or reprogrammable read only memories (RPROMs) using a single level metal gate p channel MOS process with all conventional processing steps is outlined. Nonvolatile storage of data is achieved by the use of charged floating gate electrodes. The floating gates are charged by avalanche injection of hot electrodes through gate oxide, and discharged by avalanche injection of hot holes through gate oxide. Three extra diffusion and patterning steps are all that is required to convert a standard p channel MOS process into a nonvolatile memory process. For identification, this nonvolatile memory technology was given the descriptive acronym DIFMOS which stands for Dual Injector, Floating gate MOS.

Gosney, W. M.↗

Bisphenol A polycarbonate as a reference material

Test methods require reference materials to standardize and maintain quality control. Various materials have been evaluated as possible reference materials, including a sample of bisphenol A polycarbonate without additives. Screening tests for relative toxicity under various experimental conditions were performed using male mice exposed to pyrolysis effluents over a 200-800 C temperature range. It was found that the bisphenol A polycarbonate served as a suitable reference material as it is available in large quantities, and does not significantly change with time.

Hilado, C. J.↗