Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “RAMAN EFFECT”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

Theoretical study of collinear optical frequency comb generation under multi-wave, transient stimulated Raman scattering in crystals

Using mathematical modelling we have studied the conditions of low-threshold collinear optical frequency comb generation under transient (picosecond) stimulated Raman scattering (SRS) and parametric four-wave coupling of SRS components in crystals. It is shown that Raman-parametric generation of an octave-spanning optical frequency comb occurs most effectively under intermediate, transient SRS at a pump pulse duration exceeding the dephasing time by five-to-twenty times. We have found the optimal values of not only the laser pump pulse duration, but also of the Raman crystal lengths corresponding to highly efficient generation of an optical frequency comb from the second anti-Stokes to the fourth Stokes Raman components. For the KGd(WO{sub 4}){sub 2} (high dispersion) and Ba(NO{sub 3}){sub 2} (low dispersion) crystals pumped at a wavelength of 1.064 μm and a pulse duration five or more times greater than the dephasing time, the optimum length of the crystal was 0.3 and 0.6 cm, respectively, which is consistent with the condition of the most effective Stokes – anti-Stokes coupling ΔkL ≈ 15, where Δk is the wave detuning from phase matching of Stokes – anti-Stokes coupling, determined by the refractive index dispersion of the SRS medium. (nonlinear optical phenomena)

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Reduced graphene oxide and Ag wrapped TiO{sub 2} photocatalyst for enhanced visible light photocatalysis

A well-organised reduced graphene oxide (RGO) and silver (Ag) wrapped TiO{sub 2} nano-hybrid was successfully achieved through a facile and easy route. The inherent characteristics of the synthesized RGO-Ag/TiO{sub 2} were revealed through crystalline phase, morphology, chemical composition, Raman scattering, UV-visible absorption, and photoluminescence analyses. The adopted synthesis route significantly controlled the uniform formation of silver nanoparticles and contributed for the absorption of light in the visible spectrum through localized surface plasmon resonance effects. The wrapped RGO nanosheets triggered the electron mobility and promoted visible light shift towards red spectrum. The accomplishment of synergised effect of RGO and Ag well degraded Bisphenol A under visible light irradiation with a removal efficiency of 61.9%.

36 MATERIALS SCIENCE↗
DOE OSTI2013

Dependence of the efficiency of Raman scattering in silicon nanowire arrays on the excitation wavelength

The features of Raman scattering in layers of silicon nanowires from 50 to 350 nm in diameter, obtained by the chemical etching of crystalline silicon (c-Si) wafers with preliminarily deposited silver nanoparticles in fluoric acid solutions are studied. c-Si wafers with various crystallographic orientations and doping levels are used, which is conditioned by the different sizes and degrees of ordering of the formed nanostructures. It is found that the radiation of the Raman scattering of samples is depolarized, and its efficiency depends strongly on the excitation wavelength. Upon excitation by light with a wavelength of 1064 nm, the ratio of Raman-scattering intensities of silicon nanowire samples and c-Si is 2 to 5; as the wavelength decreases, this ratio increases for structures with larger silicon-nanowire diameters and higher degrees of ordering and decreases for less ordered structures. The results obtained are explained by the effect of partial light localization in silicon nanowire arrays.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Electrochemical synthesis and characterization of stable colloidal suspension of graphene using two-electrode cell system

The present work reports the synthesis and characterization of graphene via electrochemical exfoliation of graphite rod using two-electrode system assisted by Sodium Dodecyl Sulphate (SDS) as a surfactant. The electrochemical process was carried out with sequence of intercalation of SDS onto the graphite anode followed by exfoliation of the SDS-intercalated graphite electrode when the anode was treated as cathode. The effect of intercalation potential from 5 V to 9 V and concentration of the SDS surfactant of 0.1 M and 0.01 M were investigated. UV-vis Spectroscopic analysis indicated an increase in the graphene production with higher intercalation potential. Transmission Electron Microscopy (TEM) analysis showed a well-ordered hexagonal lattice of graphene image and indicated an angle of 60° between two zigzag directions within the honeycomb crystal lattice. Raman spectroscopy analysis shows the graphitic information effects after the exfoliation process.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Continued Evaluation of the Use of a Raman Spectrometer for H-Canyon Dissolver Monitoring

Remote monitoring of dissolver activities in H-Canyon can help operators avoid delays associated with excessive levels of fuel fragments remaining after a run. SRNL has proposed that effective monitoring can be achieved by using a Raman spectrometer to measure NO 2 concentrations in the offgas stream sampled from the facility stack. Prior work (SRNL-STI-2021-00451) measuring the offgas from one dissolution batch of High Flux Isotope Reactor (HFIR) fuel suggested a relationship between %NO 2 levels and fragment height. Herein, we report the results of monitoring and analysis of the dissolution of four batches of Material Test Reactor (MTR) fuel. A rigorous quantitative relationship between %NO 2 measurements and fragment heights could not be established, due to high uncertainties associated with both measurements. Uncertainties with gas measurements are associated with the %NO 2 levels in the offgas being close to the detection limit for the analyzer. Alternative gas measurement strategies are discussed which could improve sensitivity and reduce uncertainty. Limitations to the precision of the probe measurements are also discussed. It is also noted that the offgas is an average of the products from simultaneous dissolution of elements in multiple wells. Detection of a high fragment height level in an individual well may be hindered by low levels in other wells.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2011

Stimulated Raman back-scattering of a laser in a magnetized plasma channel

A Gaussian laser beam, propagating as an eigenmode through a low density plasma channel in the presence of an axial magnetic field, undergoes stimulated Raman back scattering, producing an upper hybrid wave and a radially localized electromagnetic sideband wave. The channel may be self created by the laser due to ponderomotive force or by a pre-pulse. The radial width of sideband is {approx_equal}a and Langmuir wave of extent b{approx_equal}(a{lambda}{sub D}){sup 1/2}<<a. The nonlocal effect arising, due to self generated magnetic field, modifies the electron response to these Eigen modes, reduces the region of nonlocal interaction and hence the growth rate. The growth rate decreases with the pump wave amplitude and it maximum for back scattering. A nonlocal theory of stimulated Raman back-scattering of a laser, propagating through a plasma channel in the presence of an axial magnetic field, is developed. The laser excites a forward propagating upper hybrid mode, that is strongly localized radially, and a backward propagating electromagnetic wave-sideband. The growth rate significantly decreases with the magnetic field.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2019

In Situ Monitoring and Kinetic Analysis of the Extraction of Nitric Acid by Tributyl Phosphate in n-Dodecane using Raman Spectroscopy

Understanding the fundamental rates of transfer and complex formation is crucial in maintaining optimal efficiency and effectivity in solvent extraction. Methodologies to effectively analyze solvent extraction systems are lacking in that they are commonly off-line. Thus, a method to effectively investigate solvent extraction systems in a Lewis cell using in situ Raman spectroscopy paired with chemometric modelling has been developed to allow for on-line analysis and monitoring. Kinetic parameters of interfacial mass transfer for the extraction of nitric acid by tributyl phosphate, a process crucial to used nuclear fuel reprocessing, were measured in by spectroscopic monitoring of both phases simultaneously in a two-phase solvent extraction system. Resulting concentration data, derived from a chemometric model using Raman spectra as the base set, allowed for the calculation of kinetic parameters in the system when paired with extraction time. The forward and reverse interfacial mass transfer coefficients, kf and kr, were determined for solutions that were process relevant and of pro-cess interest, where kf was calculated as 5.3 (± 0.3) × 10-3 cm min 1 and kr was calculated as 2.9 (± 0.2) × 10-2 cm min-1. The information obtained regarding solvent extraction parameters and transfer can be applied in the further study of systems of higher complexity involving complex formation and their transfer across a liquid:liquid interface.

extraction, interfacial transport, Lewis Cell, Liq↗
DOE OSTI2016

Simulation of stimulated Brillouin scattering and stimulated Raman scattering in shock ignition

We study stimulated Brillouin scattering (SBS) and stimulated Raman scattering (SRS) in shock ignition by comparing fluid and particle-in-cell (PIC) simulations. Under typical parameters for the OMEGA experiments [Theobald et al., Phys. Plasmas 19, 102706 (2012)], a series of 1D fluid simulations with laser intensities ranging between 2 × 10{sup 15} and 2 × 10{sup 16 }W/cm{sup 2} finds that SBS is the dominant instability, which increases significantly with the incident intensity. Strong pump depletion caused by SBS and SRS limits the transmitted intensity at the 0.17n{sub c} to be less than 3.5 × 10{sup 15 }W/cm{sup 2}. The PIC simulations show similar physics but with higher saturation levels for SBS and SRS convective modes and stronger pump depletion due to higher seed levels for the electromagnetic fields in PIC codes. Plasma flow profiles are found to be important in proper modeling of SBS and limiting its reflectivity in both the fluid and PIC simulations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2015

Non‐invasive imaging of cellulose microfibril orientation within plant cell walls by polarized Raman microspectroscopy

ABSTRACT Cellulose microfibrils represent the major scaffold of plant cell walls. Different packing and orientation of the microfibrils at the microscopic scale determines the macroscopic properties of cell walls and thus affect their functions with a profound effect on plant survival. We developed a polarized Raman microspectroscopic method to determine cellulose microfibril orientation within rice plant cell walls. Employing an array of point measurements as well as area imaging and subsequent Matlab‐assisted data processing, we were able to characterize the distribution of cellulose microfibril orientation in terms of director angle and anisotropy magnitude. Using this approach we detected differences between wild type rice plants and the rice brittle culm mutant, which shows a more disordered cellulose microfibril arrangement, and differences between different tissues of a wild type rice plant. This novel non‐invasive Raman imaging approach allows for quantitative assessment of cellulose fiber orientation in cell walls of herbaceous plants, an important advancement in cell wall characterization. Biotechnol. Bioeng. 2016;113: 82–90. © 2015 Wiley Periodicals, Inc.

Sun, Lan↗
DOE OSTI2017

Infrared and multi-wavelength Raman spectroscopy of regio-regular P3HT and its deutero derivatives

The recently synthesized regio–regular poly(3–hexylthiophene–2,5–diyl) selectively deuterated on the main chain backbone and/or on the hexyl side chain have given the opportunity to record their infrared (IR) and Raman spectra, and to carry out a spectroscopic study supported by density functional theory calculations. The Effective Conjugation Coordinate associated with the collective C=C stretching mode, with Raman scattering and IR absorption near 1,450 cm –1 , is used as a probe of the electronic structure and the molecular conformation of the chain backbone. With the help of the data collected from the deuterated species, the vibrational assignment for the structurally relevant 1,600–1,300 cm –1 region has been clarified. The excitation–dependent wavenumbers and intensities of the C=C stretching Raman modes are discussed. Raman spectra excited in–resonance or off–resonance show the existence of a multimodal distribution of effective conjugation lengths that are ascribed to a phase hairy–A with a practically flat backbone chain, a phase hairy–B where the conformation of the backbone is slightly distorted, and an amorphous phase. As a result, IR spectra provide additional information on the Effective Conjugation Coordinate.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Formation of carbon quantum dots and nanodiamonds in laser ablation of a carbon film

We have experimentally shown that nanosecond near-IR pulsed laser ablation of a thin amorphous carbon film produces carbon quantum dots with a graphite structure and nanodiamonds with a characteristic size of 20 – 500 nm on the substrate surface. The formation of these nanostructures is confirmed by electron microscopic images, luminescence spectra and Raman spectra. The mechanisms explaining the observed effects are proposed. (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2018

Simultaneous optical fibre strain and temperature measurements in a hybrid distributed sensor based on Rayleigh and Raman scattering

A new type of sensor for simultaneous measurements of strain and temperature changes in an optical fibre is proposed. Its operation builds on the use of Raman optical time-domain reflectometry and wavelength-tunable quasi-monochromatic Rayleigh reflectometry implemented using a microelectromechanical filter (MEMS). The sensor configuration includes independent Raman and Rayleigh scattering channels. Our experiments have demonstrated that, at a sensing fibre length near 8 km, spatial resolution of 1 – 2 m, and measurement time of 10 min, the noise level (standard deviation) is 1.1 μϵ (μm m{sup −1}) for the measured tension change (at small temperature deviations) and 0.04 °C for the measured temperature change, which allows for effective sensing of mechanical and temperature influences with improved accuracy. (fibre-optic sensors)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

SU-E-T-771: Two Dimensional Raman Mapping of Carbon Bonds of Radiochromic Films: An Approach to Micro-Dosimetry

Purpose: To study a feasibility of micro-dosimetry with high dose-sensitivity and resolution using two-dimensional Raman mapping on the basis of carbon bonds concentration of radiochromic films Methods: Unlaminated EBT3 films with the purpose of maximal Raman data acquisition were irradiated by 6 MV beam from 5 MU to 1000 MU at the reference condition. Each film was irradiated with shielding material of lead blocking on the half of film as well as the jaw open in half for distinct dose contrast. Raman peaks of 2070 cm-1, 2095 cm-1, and 2115 cm-1 were major subjects to study, which are assumed to be the spectroscopy of carbon triple bonds of monomers, carbon double bonds of polymers, and carbon triple bonds of polymers, respectively. Laser exposure for Raman spectroscopy generated peak’s trend due to polymerization by laser output and this trend was utilized to find out basic peaks related to polymerization process. The relative dose contrast in each one film was detected by Raman spectroscopy with the aid of an auto-scanning stage, comparing the dose contrast between non-irradiated area and irradiated area. Raman spatial resolution was enhanced up to 20 micrometers, assuming the spatial uniformity of radio¬active rod-shaped LiPCDA crystals. An optical scanner with 9600 dpi was used to scan the red-channel intensity to read the dose contrast for 5 MU delivered film. Results: The peak intensity for Raman wavenumber of 2070 cm-1 was used for mapping since it reflected the different peak intensities based on polymerization degree by irradiation. Dose contrast from 1000MU to 5 MU was distinguished by Raman mapping analysis, whereas optical intensity of red-channel didn’t show any difference. Conclusion: In consideration of laser effect, the quantitative analysis based on raw data of Raman mapping could provide more statistically reliable dosimetry than point measurements.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2014

Effects of diethanolamine on sol–gel–processed Cu{sub 2}ZnSnS{sub 4} photovoltaic absorber thin films

Highlights: • DEA content significantly affected the crystal structure and the phase purity. • The films’ crystallite sizes increased with increasing DEA content. • Two different impurity levels were found for each film via R-T characteristics. • Under different illuminations, the n-Si/CZTS exhibited good photo-response. • The light on/off current ratios confirmed the photo-sensitivity of the junction. - Abstract: As a promising solar absorber, the Cu{sub 2}ZnSnS{sub 4} compound has been popular recently for the production of green and economical thin-film solar cells owing to the abundancy and non-toxicity of all the constituents. In this study, we have produced Cu{sub 2}ZnSnS{sub 4} films via the sol–gel technique. As a stabilizer, the effects of the diethanolamine on the properties of the films were investigated. The amount of diethanolamine significantly affected the crystal structure, crystallite sizes and phase purity of the films. X-ray diffraction and Raman spectroscopy analyses confirmed the formation of phase-pure CZTS films. It was found that the film produced by using 2 ml of diethanolamine in sol exhibited pure CZTS phase, compact and dense morphology and enhanced photo-sensitivity. Light on/off current ratio of the n-Si/Cu{sub 2}ZnSnS{sub 4} junction was found to be 47 under 100 mW/cm{sup 2} of illumination. Electrical activation energies of the films were investigated and the variations were attributed to delocalized phonon states generating from the presence of other phases and lattice defects.

36 MATERIALS SCIENCE↗
DOE OSTI2013

Magneto-optical studies of ensembles of semimagnetic self-organized Cd(Mn)Se/Zn(Mn)Se Quantum Dots

Ensembles of Cd(Mn)Se/ZnSe and CdSe/Zn(Mn)Se semimagnetic self-organized quantum dots with different Mn content have been studied by photoluminescence and resonant Raman scattering under strong magnetic fields in Faraday and Voigt geometries and with spectral and polarization selective excitation. Electron spin-flip Raman scattering has been observed in Voigt geometry in the structures with large Mn content. Narrow exciton peaks completely σ{sup −}σ{sup +} polarized have been observed under selective excitation in Faraday geometry in the structures with medium and small Mn content. A number of specific effects manifested themselves in the structures with a smallest Mn content where no Zeeman shift of the photoluminescence bands was observed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Structural, Electrical, and Optical Properties of Single-Walled Carbon Nanotubes Synthesized through Floating Catalyst Chemical Vapor Deposition

Single-walled carbon nanotube (SWCNT) thin films were synthesized by using a floating catalyst chemical vapor deposition (FCCVD) method with a low flow rate (200 sccm) of mixed gases (Ar and H 2 ). SWCNT thin films with different thicknesses can be prepared by controlling the collection time of the SWCNTs on membrane filters. Transmission electron microscopy (TEM) showed that the SWCNTs formed bundles and that they had an average diameter of 1.46 nm. The Raman spectra of the SWCNT films suggested that the synthesized SWCNTs were very well crystallized. Although the electrical properties of SWCNTs have been widely studied so far, the Hall effect of SWCNTs has not been fully studied to explore the electrical characteristics of SWCNT thin films. In this research, Hall effect measurements have been performed to investigate the important electrical characteristics of SWCNTs, such as their carrier mobility, carrier density, Hall coefficient, conductivity, and sheet resistance. The samples with transmittance between 95 and 43% showed a high carrier density of 10 21– 10 23 cm –3 . The SWCNTs were also treated using Brønsted acids (HCl, HNO 3 , H 2 SO 4 ) to enhance their electrical properties. After the acid treatments, the samples maintained their p-type nature. The carrier mobility and conductivity increased, and the sheet resistance decreased for all treated samples. The highest mobility of 1.5 cm 2 /Vs was obtained with the sulfuric acid treatment at 80 °C, while the highest conductivity (30,720 S/m) and lowest sheet resistance (43 ohm/square) were achieved with the nitric acid treatment at room temperature. Different functional groups were identified in our synthesized SWCNTs before and after the acid treatments using Fourier-Transform Infrared Spectroscopy (FTIR).

36 MATERIALS SCIENCE↗
DOE OSTI2015

Relativistic Eulerian Vlasov simulations of the amplification of seed pulses by Brillouin backscattering in plasmas

We apply an Eulerian Vlasov code to study the amplification by Brillouin scattering of a short seed laser pulse by a long pump laser pulse in an underdense plasma. The stimulated Brillouin backscattering interaction is the coupling of the pump and seed electromagnetic waves propagating in opposite directions, and the ion plasma wave. The code solves the one-dimensional relativistic Vlasov-Maxwell set of equations. Large amplitude ion waves are generated. In the simulations we present, the density plateau of the plasma is n{sub e}=0.3 n{sub c} (n{sub c} is the critical density), which excludes spurious stimulated Raman scattering amplification (which can occur only if n{sub e}<n{sub c}/4). We also varied the duration and/or amplitude of the short input seed pulse to study how these influence its subsequent behaviour. An initially broad pulse grows more rapidly than an initially narrow pulse. Furthermore, for an initially broader seed pulse, towards the end of the simulation, it is seen to become narrower and to gradually detach from the trailing signal. On the contrary, initially very narrow seed pulses are seen to broaden. The absence of noise in the Vlasov simulations allows to simulate long plasma amplifier lengths, and to follow the evolution of the system with a fully kinetic description and with an accurate representation of the phase-space structures of distribution function.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗