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NASA NTRS2012

Negative Ion Chemistry in the Coma of Comet 1P/Halley

Negative ions (anions) were identified in the coma of comet 1P/Halley from in-situ measurements performed by the Giotto spacecraft in 1986. These anions were detected with masses in the range 7-110 amu, but with insufficient mass resolution to permit unambiguous identification. We present details of a new chemical-hydrodynamic model for the coma of comet Halley that includes - for the first time - atomic and molecular anions, in addition to a comprehensive hydrocarbon chemistry. Anion number densities arc calculated as a function of radius in the coma, and compared with the Giotto results. Important anion production mechanisms arc found to include radiative electron attachment, polar photodissociation, dissociative electron attachment, and proton transfer. The polyyne anions C4H(-) and C6H(-) arc found to be likely candidates to explain the Giotto anion mass spectrum in the range 49-73 amu. Thc CN(-) anion probably makes a significant contribution to the mass spectrum at 26 amu. Larger carbon-chain anions such as C8H(1) can explain the peak near 100 amu provided there is a source of large carbon-chain-bearing molecules from the cometary nucleus.

Cordiner, M. A.↗
NASA NTRS2013

Review of Fluorescence-Based Velocimetry Techniques to Study High-Speed Compressible Flows

This paper reviews five laser-induced fluorescence-based velocimetry techniques that have been used to study high-speed compressible flows at NASA Langley Research Center. The techniques discussed in this paper include nitric oxide (NO) molecular tagging velocimetry (MTV), nitrogen dioxide photodissociation (NO2-to-NO) MTV, and NO and atomic oxygen (O-atom) Doppler-shift-based velocimetry. Measurements of both single-component and two-component velocity have been performed using these techniques. This paper details the specific application and experiment for which each technique has been used, the facility in which the experiment was performed, the experimental setup, sample results, and a discussion of the lessons learned from each experiment.

Bathel, Brett F.↗
NASA NTRS2012

The Extreme-ultraviolet Emission from Sun-grazing Comets

The Atmospheric Imaging Assembly (AIA) on the Solar Dynamics Observatory has observed two Sun-grazing comets as they passed through the solar atmosphere. Both passages resulted in a measurable enhancement of extreme-ultraviolet (EUV) radiance in several of the AIA bandpasses.We explain this EUV emission by considering the evolution of the cometary atmosphere as it interacts with the ambient solar atmosphere. Molecules in the comet rapidly sublimate as it approaches the Sun. They are then photodissociated by the solar radiation field to create atomic species. Subsequent ionization of these atoms produces a higher abundance of ions than normally present in the corona and results in EUV emission in the wavelength ranges of the AIA telescope passbands.

Comets↗
NASA NTRS2012

Extensive MRO CRISM Observations of 1.27 micron O2 Airglow in Mars Polar Night and Their Comparison to MRO MCS Temperature Profiles and LMD GCM Simulations

The Martian polar night distribution of 1.27 micron (0-0) band emission from O2 singlet delta [O2(1Delta(sub g))] is determined from an extensive set of Mars Reconnaissance Orbiter (MRO) Compact Reconnaissance Imaging Spectral Mapping (CRISM) limb scans observed over a wide range of Mars seasons, high latitudes, local times, and longitudes between 2009 and 2011. This polar nightglow reflects meridional transport and winter polar descent of atomic oxygen produced from CO2 photodissociation. A distinct peak in 1.27 micron nightglow appears prominently over 70-90NS latitudes at 40-60 km altitudes, as retrieved for over 100 vertical profiles of O2(1Delta(sub g)) 1.27 micron volume emission rates (VER). We also present the first detection of much (x80+/-20) weaker 1.58 micron (0-1) band emission from Mars O2(1Delta(sub g)). Co-located polar night CRISM O2(1Delta(sub g)) and Mars Climate Sounder (MCS) (McCleese et al., 2008) temperature profiles are compared to the same profiles as simulated by the Laboratoire de Météorologie Dynamique (LMD) general circulation/photochemical model (e.g., Lefèvre et al., 2004). Both standard and interactive aerosol LMD simulations (Madeleine et al., 2011a) underproduce CRISM O2(1Delta(sub g)) total emission rates by 40%, due to inadequate transport of atomic oxygen to the winter polar emission regions. Incorporation of interactive cloud radiative forcing on the global circulation leads to distinct but insufficient improvements in modeled polar O2(1Delta(sub g)) and temperatures. The observed and modeled anti-correlations between temperatures and 1.27 mm band VER reflect the temperature dependence of the rate coefficient for O2(1Delta(sub g)) formation, as provided in Roble (1995).

Atmosphere↗
NASA NTRS2011

Emission Lines from the Gas Disk Around TW Hydra and the Origin of the Inner Hole

We compare line emission calculated from theoretical disk models with optical to submillimeter wavelength observational data of the gas disk surrounding TW Hya and infer the spatial distribution of mass in the gas disk. The model disk that best matches observations has a gas mass ranging from approx.10(exp −4) to 10(exp −5) M for 0.06AU < r < 3.5 AU and approx. 0.06M for 3.5AU < r < 200 AU. We find that the inner dust hole (r < 3.5 AU) in the disk must be depleted of gas by approx. 1-2 orders of magnitude compared with the extrapolated surface density distribution of the outer disk. Grain growth alone is therefore not a viable explanation for the dust hole. CO vibrational emission arises within r approx. 0.5 AU from thermal excitation of gas. [O i] 6300Å and 5577Å forbidden lines and OH mid-infrared emission are mainly due to prompt emission following UV photodissociation of OH and water at r < or approx. 0.1 AU and at r approx. 4 AU. [Ne ii] emission is consistent with an origin in X-ray heated neutral gas at r < or approx. 10 AU, and may not require the presence of a significant extreme-ultraviolet (hν > 13.6 eV) flux from TW Hya. H2 pure rotational line emission comes primarily from r approx. 1 to 30 AU. [Oi] 63microns, HCO+, and CO pure rotational lines all arise from the outer disk at r approx. 30-120 AU. We discuss planet formation and photoevaporation as causes for the decrease in surface density of gas and dust inside 4 AU. If a planet is present, our results suggest a planet mass approx. 4-7MJ situated at ∼3 AU. Using our photoevaporation models and the best surface density profile match to observations, we estimate a current photoevaporative mass loss rate of 4x10(exp −9M)/yr and a remaining disk lifetime of approx.5 million years.

Planet-Disk interactions↗
NASA NTRS2013

Herschel - PACS Survey Of Protoplanetary Disks In Taurus - Auriga Observations Of [O I] And [C Ii], And Far-Infrared Continuum

The Herschel Space Observatory was used to observe approx. 120 pre-main-sequence stars in Taurus as part of the GASPS Open Time Key project. Photodetector Array Camera and Spectrometer was used to measure the continuum as well as several gas tracers such as [O I] 63 micron, [O I] 145 micron, [C II] 158, micron OH, H2O, and CO. The strongest line seen is [O I] at 63 micron. We find a clear correlation between the strength of the [O I] 63 micron line and the 63 micron continuum for disk sources. In outflow sources, the line emission can be up to 20 times stronger than in disk sources, suggesting that the line emission is dominated by the outflow. The tight correlation seen for disk sources suggests that the emission arises from the inner disk (<50 AU) and lower surface layers of the disk where the gas and dust are coupled. The [O I] 63 micron is fainter in transitional stars than in normal Class II disks. Simple spectral energy distribution models indicate that the dust responsible for the continuum emission is colder in these disks, leading to weaker line emission. [C II] 158 micron emission is only detected in strong outflow sources. The observed line ratios of [O I] 63 micron to [O I] 145 micron are in the regime where we are insensitive to the gas-to-dust ratio, neither can we discriminate between shock or photodissociation region emission. We detect no Class III object in [O I] 63 micron and only three in continuum, at least one of which is a candidate debris disk.

GASPS Open Time Key project↗
NASA NTRS2014

The First Stars: A Low-Mass Formation Mode

We perform numerical simulations of the growth of a Population III stellar system under photodissociating feedback. We start from cosmological initial conditions at z = 100, self-consistently following the formation of a minihalo at z = 15 and the subsequent collapse of its central gas to high densities. The simulations resolve scales as small as approx. 1 AU, corresponding to gas densities of 10(exp 16)/cu cm. Using sink particles to represent the growing protostars, we evolve the stellar system for the next 5000 yr. We find that this emerging stellar group accretes at an unusually low rate compared with minihalos which form at earlier times (z = 20-30), or with lower baryonic angular momentum. The stars in this unusual system will likely reach masses ranging from <1Stellar Mass to approx. 5 Stellar Mass by the end of their main-sequence lifetimes, placing them in the mass range for which stars will undergo an asymptotic giant branch (AGB) phase. Based upon the simulation, we predict the rare existence of Population III stars that have survived to the present day and have been enriched by mass overflow from a previous AGB companion.

Low-Mass↗
NASA NTRS1961

Atmospheric Photochemistry

The upper atmosphere offers a vast photochemical laboratory free from solid surfaces, so all reactions take place in the gaseous phase. At 30 km altitude the pressure has fallen to about one-hundredth of that at ground level, and we shall, rather arbitrarily, regard the upper atmosphere as beginning at that height. By a little less than 100 km the pressure has fallen to 10(exp -3) mm Hg and is decreasing by a power of ten for every 15 km increase in altitude. Essentially we are concerned then with the photochemistry of a nitrogen-oxygen mixture under low-pressure conditions in which photo-ionization, as well as photodissociation, plays an important part. Account must also be taken of the presence of rare constituents, such as water vapour and its decomposition products, including particularly hydroxyl, oxides of carbon, methane and, strangely enough, sodium, lithium and calcium. Many curious and unfamiliar reactions occur in the upper atmosphere. Some of them are luminescent, causing the atmosphere to emit a dim light called the airglow. Others, between gaseous ions and neutral molecules, are almost a complete mystery at this time. Similar interesting phenomena must occur in other planetary atmospheres, and they might be predicted if sufficient chemical information were available.

Massey, Harrie↗
NASA NTRS2016

Chromophores from photolyzed ammonia reacting with acetylene: Application to Jupiters Great Red Spot

The high altitude of Jupiter's Great Red Spot (GRS) may enhance the upward flux of gaseous ammonia (NH3 ) into the high troposphere, where NH3 molecules can be photodissociated and initiate a chain of chemical reactions with downwelling acetylene molecules (C2H2 ). These reactions, experimentally studied earlier by (Ferris and Ishikawa [1987] Nature 326, 777-778) and (Ferris and Ishikawa [1988] J. Amer. Chem. Soc. 110, 4306-4312), produce chromophores that absorb in the visible and ultraviolet regions. In this work we photolyzed mixtures of NH3 and C2H2 using ultraviolet radiation with a wavelength of 214 nm and measured the spectral transmission of the deposited films in the visible region (400-740 nm). From these transmission data we estimated the imaginary indices of refraction. Assuming that ammonia grains at the top of the GRS clouds are coated with this material, we performed layered sphere and radiative transfer calculations to predict GRS reflection spectra. Comparison of those results with observed and previously unreported Cassini visible spectra and with true-color images of the GRS show that the unknown GRS chromophore is spectrally consistent with the coupled NH3-C2H2 photochemical products produced in our laboratory experiments. Using high-resolution mass spectrometry and infrared spectroscopy we infer that the chromophore-containing residue is composed of aliphatic azine, azo, and diazo compounds.

Jupiter↗
NASA NTRS2017

Ion Microprobe Measurements of Comet Dust and Implications for Models of Oxygen Isotope Heterogeneity in the Solar System

The oxygen isotopic compositions of anhydrous minerals in carbonaceous chondrites reflect mixing between a O-16-rich and O-17, O18-rich reservoir. The UV photodissociation of CO (i.e. selfshielding) has been proposed as a mass-independent mechanism for producing these isotopically distinct reservoirs. Self-shielding models predict the composition for the CO gas reservoir to be O-16-rich, and that the accreting primordial dust was in isotopic equilibrium with the gaseous reservoir [1, 2]. Self-shielding also predicts that cometary water, presumed to represent the O-17, O-18-rich reservoir, should be enriched in O-17 and O-18, with compositions of 200 -1000per mille, and that the interaction with this O-17, O-18-rich H2O reservoir altered the compositions of the primordial dust toward planetary values. The bulk composition of the solar nebula, which may be an approximation to the 16O-rich gaseous reservoir, has been constrained by the Genesis results [3]. However, material representing the O-17, O-18-rich end-member is rare [4], and dust representing the original accreting primordial dust has been challenging to conclusively identify in current collections. Anhydrous dust from comets, which accreted in the distal cold regions of the nebula at temperatures below approximately 30K, may provide the best opportunity to measure the oxygen isotope composition of primordial dust. Chondritic porous interplanetary dust particles (CP-IDPs) have been suggested as having cometary origins [5]; however, until direct comparisons with dust from a known comet parent body were made, link between CP-IDPs and comets remained circumstantial. Oxygen isotope analyses of particles from comet 81P/Wild 2 collected by NASA's Stardust mission have revealed surprising similarities to minerals in carbonaceous chondrites which have been interpreted as evidence for large scale radial migration of dust components from the inner solar nebula to the accretion regions of Jupiter- family comets [6]. These studies have been largely focused on the coarse-grained terminal particles extracted from aerogel collectors; hypervelocity capture into aerogel resulted in fine-grained material that was melted and intimately mixed with the SiO2 capture medium. Hypervelocity impacts into Al foils surrounding the aerogel tiles produced impact craters that captured material from the impactor without significant oxygen contamination, allowing for analysis of both the coarse and fine-grained components of the Wild 2 dust. To date, no particles with definitive hydrated mineralogy have been observed in Stardust samples, though this may be a result of alteration due to hypervelocity capture. High-carbon hydrated CS-IDPs have been suggested as resulting from the aqueous alteration of CP-IDPs [7], and may retain evidence for interaction with O-17, O-18-enriched "cometary" water predicted by CO self-shielding. Here we present results of oxygen isotope measurements of twelve Stardust foil craters and four C-rich hydrated IDPs [8, 9], and discuss implications for models of oxygen isotope heterogeneity in the early solar system.

Snead, C. J.↗
NASA NTRS2018

Evidence for a Continuous Decline in Lower Stratospheric Ozone Offsetting Ozone Layer Recovery

Ozone forms in the Earth's atmosphere from the photodissociation of molecular oxygen, primarily in the tropical stratosphere. It is then transported to the extratropics by the Brewer-Dobson circulation (BDC), forming a protective "ozone layer" around the globe. Human emissions of halogen-containing ozone-depleting substances (hODSs) led to a decline in stratospheric ozone until they were banned by the Montreal Protocol, and since 1998 ozone in the upper stratosphere is rising again, likely the recovery from halogen-induced losses. Total column measurements of ozone between the Earth's surface and the top of the atmosphere indicate that the ozone layer has stopped declining across the globe, but no clear increase has been observed at latitudes between 60degS and 60degN outside the polar regions (60-90deg). Here we report evidence from multiple satellite measurements that ozone in the lower stratosphere between 60degS and 60degN has indeed continued to decline since 1998. We find that, even though upper stratospheric ozone is recovering, the continuing downward trend in the lower stratosphere prevails, resulting in a downward trend in stratospheric column ozone between 60degS and 60degN. We find that total column ozone between 60degS and 60degN appears not to have decreased only because of increases in tropospheric column ozone that compensate for the stratospheric decreases. The reasons for the continued reduction of lower stratospheric ozone are not clear; models do not reproduce these trends, and thus the causes now urgently need to be established.

Stratospheric Ozone↗
NASA NTRS2020

Possible Climate Histories of Venus Type Worlds

There are two well-known scenarios for Venus’ climate evolution. In one Venus had a long-lived magma ocean phase in its first 100Myr with a steam and CO2 dominated atmosphere. The faint young sun with its high XUV flux would cause photodissociation of the steam atmosphere and hydrodynamic escape would cause most of the hydrogen to escape & left-over oxygen would be absorbed by the magma ocean. Hence Venus would have started out hot and dry and the high D/H ratio measured by Pioneer Venus would be from this period of water loss. The other scenario is that Venus’ magma ocean lifetime would have been roughly the same length of time as Earth’s (~1Myr) and water would have condensed on its surface in its early history and had a short period of habitability before increasing solar insolation through time drove it into a runaway greenhouse. However, results from 2016 showed that if Venus remains in the slowly rotating climate dynamics regime (as seen in exoplanet related climate studies) its cloud albedo feedback would have kept it temperate for possibly billions of years. The only way to confirm which one of these scenarios occurred for Venus is to visit it and make the necessary measurements of noble and volatile gases. But exoplanet observations of young exo-Venus type worlds around young F,G,K dwarf stars may constrain which scenario is more probable for a population of such planets. We present a vision of Venus’ climate history that places it and its exoVenus cousins in an ‘Optimistic Venus Zone’ for ~3 billion years within the conventionally named ‘Venus Zone’ and hence encourage the exoplanet communit as possible habitable environments.

Way, M. J.↗
NASA NTRS2020

A Coupled Analysis of Atmospheric Mass Loss and Tidal Evolution in XUV Irradiated Exoplanets: The TRAPPIST-1 Case Study

Exoplanets residing close to their stars can experience evolution of both their physical structures and their orbits due to the influence of their host stars. In this work, we present a coupled analysis of dynamical tidal dissipation and atmospheric mass loss for exoplanets in X-ray and ultraviolet (XUV) irradiated environments. As our primary application, we use this model to study the TRAPPIST-1 system and place constraints on the interior structure and orbital evolution of the planets. We start by reporting on an ultraviolet continuum flux measurement (centered around ∼1900 Å) for the star TRAPPIST-1, based on 300 ks of Neil Gehrels Swift Observatory data, and which enables an estimate of the XUV-driven thermal escape arising from XUV photodissociation for each planet. We find that the X-ray flaring luminosity, measured from our X-ray detections, of TRAPPIST-1 is 5.6 × 10(exp −4) L(*), while the full flux including non-flaring periods is 6.1 × 10(exp −5) L*, when L(*) is TRAPPIST-1ʼs bolometric luminosity. We then construct a model that includes both atmospheric mass loss and tidal evolution and requires the planets to attain their present-day orbital elements during this coupled evolution. We use this model to constrain the ratio Q' = 3Q/2k2 for each planet. Finally, we use additional numerical models implemented with the Virtual Planet Simulator VPLanet to study ocean retention for these planets using our derived system parameters.

Juliette Becker↗
NASA NTRSDate not supplied

Bulk Oxygen Isotopic Compositions of Anhydrous Interplanetary Dust Particles: Indication of an 16O-Poor Reservoir In The Outer Solar System

The oxygen isotopic ratios of ancient solar system materials reflect the isotopically distinct reservoirs in which they formed or were altered. These compositions are generally explained by mixing of material derived from an 16O-rich reservoir and material from an 16O-poor reservoir thought to be isotopically heavy H2O. Evidence of this 16O-poor reservoir is scarce and includes cosmic symplectite (COS), probable silicates in an interplanetary dust particle (IDP), and sulfates in a cometary xenolith. These materials have 17O and 18O enrichments between ~150–200 ‰, which agree with predictions for self-shielding and photodissociation of CO. The ‘cometary’ 16O-poor materials indicate alteration or formation in the outer solar system. The bulk O isotopic compositions of IDPs thought to have cometary origins may also harbor evidence of this primordial 16O-poor reservoir. Here we report the bulk O compositions of anhydrous IDPs and discuss the nebular reservoirs from which they derived

A N Nguyen↗
NASA NTRS2022

Deuterium Isotope Fractionation of Polycyclic Aromatic Hydrocarbons in Meteorites as an Indicator of Interstellar/Protosolar Processing History

The stable isotope composition of soluble and insoluble organic compounds in carbonaceous chondrites can be used to determine the provenance of organic molecules in space. Deuterium enrichment in meteoritic organics could be a residual signal of synthetic reactions occurring in the cold interstellar medium or an indicator of hydrothermal parent-body reactions. δD values have been measured in grains and bulk samples for a wide range of meteorites; however, these reservoirs are highly variable and may have experienced fractionation during thermal and/or aqueous alteration. Among the plethora of organic compounds in meteorites are polycyclic aromatic hydrocarbons (PAHs), which are stable and abundant in carbonaceous chondrites, and their δD ratio may preserve evidence about their formation environment as well as the influence of parent-body processes. This study tests hypotheses about the potential links between PAHs-deuteration concentrations and their formation conditions by examining the δD ratio of PAHs in three CM carbonaceous chondrites representing an aqueous alteration gradient. We use deuterium enrichments in soluble 2–5-ring PAHs as an indicator of either photon-driven deuteration due to unimolecular photodissociation in warm regions of space, gas-phase ion–molecule reactions in cold interstellar regions of space, or UV photolysis in ices. We also test hypothesized reaction pathways during parent-body processing that differ between partially and fully aromatized PAHs. New methodological approaches were developed to extract small, volatile PAHs without fractionation. Our results suggest that meteoritic PAHs could have formed through reactions in cold regions, with possible overprinting of deuterium enrichment during aqueous parent-body alteration, but the data could not rule out PAH alteration in icy mantles as well.

H V Graham↗
NASA NTRSDate not supplied

New Features of the NEQAIR Radiation Code

The longest-lived code for predicting shock layer radiation, NEQAIR, is now in its 5th decade of service. Substantial changes to the code have been made over the previous decade, the most recent report of which was at the 5th Workshop on Radiation in High Temperature Gases in 2014, for the version referred to as NEQAIR14. This paper will review some of the improvements made to the NEQAIR code since then, which is now at v15.2. Some of these features are discussed briefly below. NEQAIR15 and subsequent versions have enabled parallel evaluation of multiple lines of sight. This is accomplished by utilizing the HDF5 file format and placing multiple lines into a single file, LOS.h5, which is used for both input and output. This approach enables straightforward parallel execution both over the number of lines of sight and the number of points per line. For large problems, runtime reduces linearly with the number of nodes deployed since each line is processed independently by a subset of MPI ranks. Three applications of the multi-line solver are discussed. The first has to do with performing loosely coupled radiation-flowfield solutions. In this case the computed absorption and emission coefficients are used to evaluate the total energy absorbed or emitted at each point, allowing evaluation of the volumetric source term in the flowfield. The second computation is for obtaining heat flux from nonuniform flows, which require integration over spherical co-ordinates. These are of particular interest for evaluating radiation on the vehicle backshell. This 3D option improves the angular integration scheme and allows adaptive line selection that together reduce the number of lines required by about an order of magnitude. The final application is for remote observation, which is essentially the 3D integration problem over a small solid angle. For all three of these computations, data can be stored in the HDF5 file which allows a NEQAIR run to be restarted when it times out, or to add atmospheric absorption or instrument scan functions. An additional level of parallelism is enabled in NEQAIR15.2 using GPU routines. The GPU parallelism has realized up to 8x speed-up when running on a single core but diminishes as CPU parallelism is increased. For running multi-line simulations, it may be easier to reserve a large number of CPU nodes than to obtain the number of GPU nodes required for similar performance. A GUI, known as NEQTPY, allows for reading and creating input files, running NEQAIR, and displaying results. A significant feature of NEQTPY is the ability to perform spectral fits to data. The fits can operate on a single line spectrum (radiance vs. wavelength) or a 3D input file with multiple columns of data. Other new features include improved constants, additional species, more detailed non-Boltzmann modelling, advanced user controls, the ability to read and calculate spectra from HITRAN datafiles, photodissociation and photoionization cross-sections. A “fast” automatic grid option may reduce the size and time of spectral calculations while still maintaining good accuracy for total heat flux.

Brett A Cruden↗
NASA NTRS2015

Stratospheric Temperatures and Water Loss From Moist Greenhouse Atmospheres of Earth-Like Planets

A radiative-convective climate model is used to calculate stratospheric temperatures and water vapor concentrations for ozone-free atmospheres warmer than that of modern Earth. Cold, dry stratospheres are predicted at low surface temperatures, in agreement with recent 3D calculations. However, at surface temperatures above 350 K, the stratosphere warms and water vapor becomes a major upper atmospheric constituent, allowing water to be lost by photodissociation and hydrogen escape. Hence, a moist greenhouse explanation for loss of water from Venus, or some exoplanet receiving a comparable amount of stellar radiation, remains a viable hypothesis. Temperatures in the upper parts of such atmospheres are well below those estimated for a gray atmosphere, and this factor should be taken into account when performing inverse climate calculations to determine habitable zone boundaries using 1D models.

Astrobiology↗