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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Shock compression of a low-density carbon foam

Porous polymer foams are found in numerous applications where they may be subjected to dynamic compression. The shockwave properties of polymer foams have several features that make shock Hugoniot measurements and interpretation challenging. Here, we present a comparison of dynamic X-ray phase contrast imaging and traditional optical velocimetry approaches to measuring the shocked states for a low-density carbon foam. Overall, dynamic X-ray phase contrast imaging was found to reduce errors associated with the measured Hugoniot states. In this study, the foam exhibits anomalous compression as expected due to its high initial porosity arising from shock heating.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Assessing mechanical response of CO 2 storage into a depleted carbonate reef using a site-scale geomechanical model calibrated with field tests and InSAR monitoring data

Geomechanical risks of injection have raised concerns regarding secure CO 2 storage. In this work, a combined monitoring and modeling approach is used to assess the stress changes and surface uplift associated with CO 2 injection into a depleted carbonate reef of the Michigan basin. A site-scale geomechanical model is built by assigning mechanical properties of formations using well-log and experimental data. Gravity load is applied to the model to estimate the vertical component of stress as well as different lateral boundary displacement scenarios to estimate horizontal stresses. We used a poroelastic pressure-dependent model (instead of a linear elastic mechanical earth model) to calibrate initial stresses using hydraulic fracture test data measured at depleted reservoir status. Multi-phase fluid flow-geomechanical simulations are performed to estimate the poroelastic response during (1) primary depletion (2) field-scale CO 2 injection phase (3) a hypothetical forecast scenario in which well bottom hole pressure (BHP) reach 45000 KPa. The predicted surface uplift is less than 1 mm at the end of the field-scale CO 2 injection phase which is in good agreement with Interferometric Synthetic Aperture Radar (InSAR) uplift measurement. Although the InSAR data shows an insignificant uplift, hydromechanical modeling of injection shows that CO 2 injection still causes reservoir deformation emphasizing the role of carbonate overburden and reservoir formation mechanical properties and limited size of reef on diminishing the surface deformation. Modeling indicates poroelastic response of caprock matters to estimate uplift. The lower permeability of the top two layers provides additional barrier to large uplift. Also, history of subsidence due to production should be accounted to predict uplift due to a follow up injection correctly. This report shows the significance of combining a calibrated geomechanical model with field measured stresses and monitoring data to be used as a tool to ensure the safety of CO 2 storage.

42 ENGINEERING↗
DOE OSTI2025

Fused-ring isomerism modulates molecular packing and device performance in non-halogenated organic solar cells

Subtle changes in molecular backbone geometry impact intermolecular interactions and performance of organic solar cells. Here, three isomeric small-molecule acceptors (NaO1, NaO2, and NaO3) are investigated to reveal how different fused-ring configurations control molecular packing, electronic coupling, and film formation. Structural and spectroscopic analyses show that the linearly fused NaO1 forms a compact three-dimensional packing network with large and balanced electronic couplings (>24 meV) across multiple directions, while the more curved analogues exhibit excessive crystallization and phase segregation. In-situ optical measurements demonstrate that NaO1 promotes fast and continuous structural evolution during film formation, resulting in smooth morphology and homogeneous phase distribution. These structural and dynamic advantages facilitate efficient charge generation and transport, accompanied by reduced non-radiative energy loss, ultimately achieving an efficiency of 20.07% for non-halogenated ternary devices. Our findings highlight how fused-ring isomerism decisively governs structure–packing–performance relationships in organic solar cells.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Inherent stochasticity during insulator–metal transition in VO 2

Vanadium dioxide (VO 2 ), which exhibits a near-room-temperature insulator–metal transition, has great potential in applications of neuromorphic computing devices. Although its volatile switching property, which could emulate neuron spiking, has been studied widely, nanoscale studies of the structural stochasticity across the phase transition are still lacking. In this study, using in situ transmission electron microscopy and ex situ resistive switching measurement, we successfully characterized the structural phase transition between monoclinic and rutile VO 2 at local areas in planar VO 2 /TiO 2 device configuration under external biasing. After each resistive switching, different VO 2 monoclinic crystal orientations are observed, forming different equilibrium states. We have evaluated a statistical cycle-to-cycle variation, demonstrated a stochastic nature of the volatile resistive switching, and presented an approach to study in-plane structural anisotropy. Furthermore, our microscopic studies move a big step forward toward understanding the volatile switching mechanisms and the related applications of VO 2 as the key material of neuromorphic computing.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Continuous variable quantum secret sharing

Continuous variable quantum secret sharing (CV-QSS) technologies are described that use laser sources and homodyne detectors. Here, a Gaussian-modulated coherent state (GMCS) prepared by one device passes through secure stations of other devices sequentially on its way to a trusted device, and each of the other devices coherently adds a locally prepared, independent GMCS to the group of propagating GMCSs. Finally, the trusted device measures both the amplitude and the phase quadratures of the received group of coherent GMCSs using double homodyne detectors. The trusted device suitably uses the measurement results to establish a secure key for encoding secret messages to be broadcast to the other devices. The devices cooperatively estimate, based on signals corresponding to their respective Gaussian modulations, the trusted device's secure key, so that the cooperative devices can decode the broadcast secret messages with the secure key.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2023

Brewster angle-cavity ringdown spectroscopy for low temperature plasma measurements in multiphases

Here we report on the development of a Brewster angle-cavity ringdown spectroscopy (BA-CRDS) system for low temperature plasma diagnostics. The system can measure gas species in solutions, with a detection limit (minimum detectable absorbance) of 9.1 × 10 -5 , which is equivalent to a detection limit of 0.04 parts per billion for measuring OH radicals in water at 308 nm. With higher reflectivity ringdown mirrors and improved design of a Brewster angle cell, the detection limit can potentially be up to 10 -6 or lower. In this exploratory study, the absorption cross sections of HgBr 2 and H 2 O 2 in the aqueous phase at 256 nm are measured to be (1.8 ± 0.1) × 10 -18 cm 2 and (5.2 ± 0.5) × 10 -20 cm 2 , respectively. Furthermore, temporal profiles of absorbance from distilled water, HgBr 2 , and H 2 O 2 solutions when interacting with a helium atmospheric plasma jet are individually characterized at different plasma powers, gas flow rates, and/or solute concentrations. The observed linear temporal profiles of absorbance from the plasma-interacted water suggest formation of H 2 O 2 from plasma-generated OH radicals, while the nonlinear temporal profiles from the plasma-treated HgBr 2 solutions reveal possible removal of HgBr 2 by OH radicals. Our results demonstrate that the new BA-CRDS system is a powerful tool for quantification of reactive plasma species in multiphases or other complex settings.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Instantaneous Three-Dimensional Temperature Measurements via Ultrafast Laser Spectroscopy with Structured Light

Detonations and flames are characterized by three-dimensional (3D) temperature fields, yet state-of- the-art temperature measurement techniques yield information at a point or along a line. The goal of the research documented here was to combine ultrafast laser spectroscopy and structured illumination to deliver an unprecedented measurement capability—three-dimensional, instantaneous temperature measurements in a gas-phase volume. To achieve this objective, different parts of the proposed technique were developed and tested independently. Structured illumination was used to image particulate matter (soot) in a turbulent flame at multiple planes using a single laser pulse and a single camera. Emission spectroscopy with structured detection was demonstrated for emission- based measurements of explosives with enhance dimensionality. Finally, an instrument for multi- planar laser-based temperature measurement technique was developed. Structured illumination techniques will continue to be developed for multi-dimensional and multi-parameter measurements. These new measurement capabilities will be important for heat transfer and fluid dynamic research areas.

42 ENGINEERING↗
DOE OSTI2024

Controllable strain-driven topological phase transition and dominant surface-state transport in HfTe5

Abstract The fine-tuning of topologically protected states in quantum materials holds great promise for novel electronic devices. However, there are limited methods that allow for the controlled and efficient modulation of the crystal lattice while simultaneously monitoring the changes in the electronic structure within a single sample. Here, we apply significant and controllable strain to high-quality HfTe 5 samples and perform electrical transport measurements to reveal the topological phase transition from a weak topological insulator phase to a strong topological insulator phase. After applying high strain to HfTe 5 and converting it into a strong topological insulator, we found that the resistivity of the sample increased by 190,500% and that the electronic transport was dominated by the topological surface states at cryogenic temperatures. Our results demonstrate the suitability of HfTe 5 as a material for engineering topological properties, with the potential to generalize this approach to study topological phase transitions in van der Waals materials and heterostructures.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Electric field dynamics in an atmospheric pressure helium plasma jet impinging on a substrate

Time and spatially resolved electric field measurements by Stark polarization spectroscopy in a nanosecond pulsed atmospheric pressure helium jet operating in ambient air and impinging on a conductive indium tin oxide (ITO) coated glass slide are reported. An automatic fitting procedure of the Stark shifted spectra taking into consideration constraints regarding Stark components positions and intensities as well as molecular nitrogen emission subtraction was implemented. This allowed electric field vector components measurements both in the gas phase and at the interface when the jet impinges on the substrate and during the development of a surface ionization wave. The obtained results show an increase of the axial electric field in the jet effluent in the gas phase with a peak magnitude from 12 to 18 kVcm -1 before the ionization wave impinges on the substrate. A steep electric field enhancement to a peak value of about 24 kVcm -1 was observed when the ionization wave impinges on the surface. A peak radial electric field of about 27 kVcm -1 was measured off-axis in the surface ionization wave. These results are consistent with previously reported modelling predictions. While Stark polarization spectroscopy is limited to electric field measurement from regions with emission, we illustrate that the capability to measure near surface electric fields in helium makes it a valuable complementary technique for the electric field-induced second harmonic (E-FISH) technique.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Proof-of-concept Talbot–Lau x-ray interferometry with a high-intensity, high-repetition-rate, laser-driven K-alpha source

Talbot–Lau x-ray interferometry is a grating-based phase-contrast technique, which enables measurement of refractive index changes in matter with micrometric spatial resolution. The technique has been established using a variety of hard x-ray sources, including synchrotron, free-electron lasers, and x-ray tubes, and could be used in the optical range for low-density plasmas. The tremendous development of table-top high-power lasers makes the use of high-intensity, laser-driven K-alpha sources appealing for Talbot–Lau interferometer applications in both high-energy-density plasma experiments and biological imaging. To this end, we present the first, to the best of our knowledge, feasibility study of Talbot–Lau phase-contrast imaging using a high-repetition-rate laser of moderate energy (100 mJ at a repetition rate of 10 Hz) to irradiate a copper backlighter foil. The results from up to 900 laser pulses were integrated to form interferometric images. A constant fringe contrast of 20% is demonstrated over 100 accumulations, while the signal-to-noise ratio continued to increase with the number of shots. Phase retrieval is demonstrated without prior ex-situ phase stepping. Instead, correlation matrices are used to compensate for the displacement between reference acquisition and the probing of a PMMA target rod. The steps for improved measurements with more energetic laser systems are discussed. The final results are in good agreement with the theoretically predicted outcomes, demonstrating the applicability of this diagnostic to a range of laser facilities for use across several disciplines.

Bouffetier, V. (ORCID:0000000160791260)↗
DOE OSTI2024

MHD stability trends and improved performance of LHD inward-shifted configurations: The role of the neutral beam current drive and thermal plasma density

The aim of the present study is to analyze the effect of the neutral beam current drive (NBCD), thermal plasma density, and NBI operational regime on the stability of pressure gradient-driven modes (PGDM) and Alfvén eigenmodes (AE) in LHD inward-shifted configurations. The stabilization of n/m = 1/2 PGDM (n toroidal mode and m poloidal mode) is observed in the discharge 167 800 during the co-NBCD phase. The iota profile evolution measured by motional stark effect diagnostic may indicate the iota profile up-shift caused by the co-NBCD can induce a non-resonant transition of the rational surface 1/2 before the mode stabilization. The evolution of the iota profile and continuum gaps in the discharge 167 805 during the ctr-NBCD phase leads to the stabilization of the AE, caused by the narrowing of the continuum gap as the iota profile down-shift. Opposite stability trends are identified for PGDM and AE stability with respect to the thermal plasma density. A larger thermal plasma density (larger thermal β) further enhances PGDM although the continuum gaps are narrower leading to configurations with stable AEs. The linear stability of AEs is analyzed using the gyro-fluid FAR3d code to reproduce the AE stability trends observed in the experiments with respect to the NBCD and thermal plasma density. The analysis of hypothetical scenarios dedicated to study different NBI operational regimes with respect to EP energy, and β and radial density profiles indicate off-axis NBI operation shows a higher EP β threshold to destabilize AEs compared to on-axis configuration. This is explained by the presence of a TAE gap in the inner plasma region, easily destabilized by an on-axis NBI injection. The control of the NBCD and thermal plasma in the discharge 167 800 shows a transitory stabilization of PGDM and AEs, as well as an improved discharge performance identified by an increment of the neutron fluxes.

Varela, Jacobo↗
DOE OSTI2025

Calculation of rf-induced temporal jitter in ultrafast electron diffraction

A significant contribution to the temporal resolution of an ultrafast electron diffraction (UED) instrument is arrival time jitter caused by amplitude and phase variation of radio-frequency (rf) cavities. In this paper, we present a semianalytical approach for calculating rf-induced temporal jitter from klystron and rf cavity parameters. Our approach allows fast estimation of temporal jitter for MeV-UED beamlines and can serve as a virtual timing tool when shot-to-shot measurements of rf amplitude and phase jitters are available. A simulation study for the SLAC MeV-UED instrument is presented, and the temporal resolution of several beamline configurations is compared.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

Fast response High Altitude Laser Optical Sensor (HALOS) for atmospheric water and temperature measurements

Advanced instrumentation and sensing methods are the key factor in the determination of many climate science research problems. In this Phase I STTR a laser-based diagnostic system for atmospheric temperature and water concentrations measurements was developed, this system, HALOS – High Altitude Laser Optical Sensor, employs a mid-infrared (MIR) quantum cascade laser (QCL) of the distributed feedback variety (DFB) powered by a 100 kHz rep rate ramp modulated current profile which enables spectral profiling. Measurements made during Phase I showed that HALOS can surpass the available hygrometers refresh rates while offering superior accuracy (<4%) from the low Frost Point (Tfrost) of -110°C to dew points (Tdew) at 35°C while being able to encompass sub ppm concentration at altitude and supersaturated conditions at ground level. Readings from HALOS include temperature sensitivity on the order of 0.2°C and absolute humidity sensitivity (AH) on the order of 0.010 μmol/m 3 (0.18 mg/m 3 ) at a data output rate exceeding 1 kHz. HALOS can be easily integrable in existing Department of Energy (DOE) or National Oceanic and Atmospheric Administration (NOAA) conventional or remote operated aircraft having either a fixed or rotary wing.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

A review of ptychographic techniques for ultrashort pulse measurement

The measurement of optical ultrafast laser pulses is done indirectly because the required bandwidth to measure these pulses exceeds the bandwidth of current electronics. As a result, this measurement problem is often posed as a 1-D phase retrieval problem, which is fraught with ambiguities. The phase retrieval method known as ptychography solves this problem by making it possible to measure ultrafast pulses in either the time domain or the frequency domain. One well known algorithm is the principal components generalized projections algorithm (PCGPA) for extracting pulses from Frequency-Resolved Optical Gating (FROG) measurements. In this work, we discuss the development of the PCPGA and introduce new developments including an operator formalism that allows for the convenient addition of external constraints and the development of more robust algorithms. A close cousin, the ptychographic iterative engine will also be covered and compared to the PCGPA. Additional developments using other algorithmic strategies will also be discussed along with new developments combining optics and high-speed electronics to achieve megahertz measurement rates.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

Combustion synthesis of Eu 2 O 3 nanomaterials with tunable phase composition and morphology

Combustion reactions in europium nitrate – acetylacetone – 2-methoxyethanol solutions and gels were investigated to produce europium (III) oxide (Eu 2 O 3 ) nanocrystalline materials and thin films. Thermal analyses of solutions indicated that the 2-methoxyethanol solvent also acts as a fuel in the absence of acetylacetone. Adding acetylacetone increases the overall heat of the reaction. Thermal analysis results revealed that the slow oxidation of unburned hydrocarbon residues follows the primary combustion reaction. Time-temperature profile measurements of the bulk combustion synthesis process in air and nitrogen atmospheres enabled the extraction of the maximum reaction temperature and the heating and cooling rates in the combustion zone. Several direct correlations exist between measured combustion parameters and the phase composition of the products. Combustion in air results in mixed-phase cubic and monoclinic nanocrystalline Eu 2 O 3 . Increasing the acetylacetone concentration in solutions increases the synthesis temperature and decreases the quantity of cubic Eu 2 O 3 . Here, the reaction of solutions in a nitrogen atmosphere or diluted with Eu 2 O 3 provides control of the product phase composition and reduces the quantity of the monoclinic phase. Transmission electron microscopy imaging shows that the Eu 2 O 3 end products are highly porous aggregates of nanocrystalline particles. Electrospraying of reactive solutions onto different substrates followed by short annealing makes the preparation of Eu 2 O 3 materials with diverse morphologies possible.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Giant Magnetostriction in Ferrimagnetic SmFe 5 As 3

Magnetostrictive materials are of interest not only from a fundamental perspective but also for their potential applications, spanning spintronics to energy harvesting. A new magnetostrictive material—SmFe 5 As 3 —reveals a complex interplay between magnetostriction, magnetic properties, and the crystal structure behavior. The ground state of SmFe 5 As 3 is ferrimagnetic, as evidenced by magnetic susceptibility data, band-structure calculations, and XANES measurements. At T m1 = 28 ± 4 K, part of the Fe sublattice reorients, transitioning into a ferromagnetic state. This is followed by an entrance into the paramagnetic state at T m2 = 76 ± 4 K. The effects observed in the magnetic measurements are accompanied by structural phase transitions. All three phases—below T m1 , between T m1 and T m2 , and above T m2 —are described by the same structural motif of the UCr 5 P 3 type (monoclinic space group P2 1 /m), differing only in the degree of deformation of the Fe–As framework. The new material exhibits giant magnetostriction of 2500 x 10 -6 . Dilatometry measurements on a SmFe 5 As 3 single crystal indicate strongly diverse behavior, exhibiting not only negative, but also zero, as well as positive thermo-elastic effects.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Mott localization in the van der Waals crystal CrI 3 : A GGA+DMFT study

Using the generalized gradient approximation plus dynamical mean-field theory (GGA+DMFT) we confirm the importance of multi-orbital dynamical correlations in determining the paramagnetic insulating state of CrI 3 . Furthermore, while the ferromagnetic phase reveals weak electronic correlation effects due to strong spin-orbital polarization, the Mott insulating state of paramagnetic CrI 3 crystal is shown to be driven by the interplay between orbital-dependent one-electron lineshape and multi-orbital electronic interactions. To probe the paramagnetic Mott insulating state we performed x-ray absorption spectroscopy (XAS) measurements for the two structural phases of CrI 3 . Our study is relevant to understanding the orbital-selective electronic structure reconstruction of Mott insulators and should be applicable to other van der Waals bonded materials from bulk to the ultrathin limit.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Magnetic field induced phase transition in spinel GeNi 2 O 4

Cubic spinel GeNi 2 O 4 exhibits intriguing magnetic properties with two successive antiferromagnetic phase transitions (T N1 ≈ 12.1 and T N2 ≈ 11.4 K) with the absence of any structural transition. We have performed detailed heat capacity and magnetic measurements in different crystallographic orientations. A new magnetic phase in presence of magnetic field (H ≥ 4 T) along the [111] direction is revealed, which is not observed when the magnetic field is applied along the [100] and [110] directions. High field neutron powder diffraction measurements confirm such a change in magnetic phase, which could be ascribed to a spin reorientation in the presence of magnetic field. In conclusion, a strong magnetic anisotropy and competing magnetic interactions play a crucial role on the complex magnetic behavior in this cubic system.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗