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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Deformation and thermal histories of chondrules in the Chainpur (LL3.4) chondrite

The results of optical and TEM studies of chondrules in the Chainpur (LL3.4) chondrite are presented. Results were obtained, using a microprobe, from quantitative microchemical analyses for Mg, Fe, Si, and Ca for the chondrule olivine and pyroxene, showing that chondrules in the Chainpur chondrite experienced varied degrees of annealing and deformation. It is suggested that Chainpur may be an agglomerate of a breccia that experienced little overall deformation or heating during and after the final accumulation and compaction of its constituents.

Ruzicka, Alex↗
NASA NTRS1990

Origin and history of chondrite regolith, fragmental and impact-melt breccias from Spain

Six ordinary chondrite breccias from the Museo Nacional de Ciencias Naturales, Madrid (Spain), are described and classified as follows: the solar gas-rich regolith breccia Oviedo (H5); the premetamorphic fragmental breccias Cabezo de Mayo (type 6, L-LL), and Sevilla (LL4); the fragmental breccias Canellas (H4) and Gerona (H5); and the impact melt breccia, Madrid (L6). It is confirmed that chondrites with typical light-dark structures and petrographic properties typical of regolith breccias may (Oviedo) or may not (Canellas) be solar gas-rich. Cabezo de Mayo and Sevilla show convincing evidence that they were assembled prior to peak metamorphism and were equilibrated during subsequent reheating. Compositions of olivine and low-Ca pyroxene in host chondrite and breccia clasts in Cabezo de Mayo are transitional between groups L and LL. It is suggested, based on mineralogic and oxygen isotopic compositions of host and clasts, that the rock formed on the L parent body by mixing, prior to peak metamorphism. This was followed by partial equilibrium of two different materials: the indigenous L chondrite host and exotic LL melt rock clasts.

Casanova, I.↗
NASA NTRS1991

Preliminary results from the chemistry of micrometeoroid experiment (AO 187-1)

The purpose of experiment AO 187-1 was to expose high purity substrates of suitable cratering properties to obtain detailed crater statistics that may be converted into projectile masses and fluxes and to chemically characterize as many impactors as possible. The latter information would hopefully reveal distinct classes of natural and man-made particles in low-Earth orbit. It was found that crater that yield residues show that natural and man-made impactors may be differentiated and that diversity exists within each group. 'Chondritic' compositions dominate among natural particles, yet some craters contain unmelted fragments of minerals (Olivine and pyroxene).

Horz, Friedrich↗
NASA NTRS1991

Deimos: A featureless asteroid-like spectrum

High quality CCD spectra were obtained of Deimos from 0.5 to 1.0 micron at a spectral resolution of 15A at the time of the 1988 Mars opposition. The data acquisition and reduction methods allowed the quantitative prevention of scattered light from Mars contaminating the spectra. Solar analog stars BS560, BS2007, and BS8931 were observed the same night to allow removal of telluric absorptions. The ratio spectrum of Deimos has a red slope, increasing in reflectance by a factor of approx. 50 pct. over the one octave wavelength interval observed. Other than this slope, the spectrum is remarkably featureless. The absence of absorption bands in the spectrum of Deimos is in marked contrast with the spectra of Martian surface materials. No trace of the Fe(2+) charge transfer absorption band around 1 micron is observed, which rules out the presence of significant quantities of minerals such as the pyroxenes or olivine at the surface of Deimos. The featureless red spectrum of Deimos appears to be consistent with a surface composition of fine grained carbonaceous chondrite type material. An analysis is presented of the spectrum of Deimos which makes use of the Hapke scattering surface model.

Grundy, W. M.↗
NASA NTRS1991

Remote compositional mapping of lunar titanium and surface maturity

Lunar ilmenite (FeTiO3) is a potential resource capable of providing oxygen for life support and spacecraft propellant for future lunar bases. Estimates of TiO2 content in mature mare soils can be made using an empirical relation between the 400/500 nm reflectance ratio and TiO2 wt percent. A TiO2 abundance map was constructed for the entire near-side lunar maria accurate to + or - 2 wt percent TiO2 using CCD images obtained at the Tumamoc Hill 0.5 m telescope in Tucson, employing bandpass filters centered at 400 and 560 nm. Highest TiO2 regions in the maria are located in western Mare Tranquillitatis. Greater contrast differences between regions on the lunar surface can be obtained using 400/730 nm ratio images. The relation might well be refined to accommodate this possibly more sensitive indicator of TiO2 content. Another potential lunar resource is solar wind-implanted He-3 which may be used as a fuel for fusion reactors. Relative soil maturity, as determined by agglutinate content, can be estimated from 950/560 nm ration images. Immature soils appear darker in this ratio since such soils contain abundant pyroxene grains which cause strong absorption centered near 950 nm due Fe(2+) crystal field transitions. A positive correlation exists between the amount of He-3 and TiO2 content in lunar soils, suggesting that regions high in TiO2 should also be high in He-3. Reflectance spectrophotometry in the region 320 to 870 nm was also obtained for several regions. Below about 340 nm, these spectra show variations in relative reflectance that are caused by as yet unassigned near-UV absorptions due to compositional differences.

Johnson, J. R.↗
NASA NTRS1991

Primary igneous rocks on Mars: Composition and distribution

The present knowledge of the crustal composition of Mars is synthesized and implications discussed for in-situ resource utilization. Sources of information include remote sensing observations, Viking XRF chemical measurements, and characteristics of the SNC meteorites (which most researchers now believe originated on Mars). There are a number of lines of evidence that abundant ferrous-iron rich igneous crustal rocks (and derivative soils) are available at or very near the current Martian surface at many locations on the planet. Most of these exposures show spectroscopic evidence for abundant pyroxene, consistent with basaltic compositions. The SNC meteorites, which have basaltic compositions, were also studied extensively. Interpretations of Mars crustal chemistry and mineralogy (petrology) based on these various sources are reviewed, and their consistencies and differences are discussed.

Singer, Robert B.↗
NASA NTRS1991

Impact of Mars sand on dust on the design of space suits and life support equipment: A technology assessment

Space suits and life support equipment will come in intimate contact with Martian soil as aerosols, wind blown particles and material thrown up by men and equipment on the Martian surface. For purposes of this discussion the soil is assumed to consist of a mixture of cominuted feldspar, pyroxene, olivine, quartz, titanomagnetite and other anhydrous and hydrous iron bearing oxides, clay minerals, scapolite and water soluble chlorides and sulfates. The soil may have photoactivated surfaces that acts as a strong oxidizer with behavior similar to hydrogen peroxide. The existing data about the Mars soil suggests that the dust and sand will require designs analogous to those uses on equipment exposed to salty air and blowing sand and dust. The major design challenges are in developing high performance radiators which can be cleaned after each EVA without degradation, designing seals that are readily cleaned and possibly in selecting materials which will not be degraded by any strong oxidants in the soil. The magnitude of the dust filtration challenge needs careful evaluation in terms of the trade off between fine-particle dust filters with low pressure drop that are either physically large and heavy, like filter baghouses require frequent replacement of filter elements, of low volume high pressure thus power consumption approaches, or washable filters. In the latter, filter elements are cleaned with water, as could the outsides of the space suits in the airlock.

Simonds, Charles H.↗
NASA NTRS1990

Disentangling nebular and asteroidal features of CO3 carbonaceous chondrite meteorites

Ten carbonaceous CO3 chondrites (including four chondrites from Antarctica and the Colony, Isna, Kainsaz, Lance , Ornans, and Warrenton chondrites) were analyzed with respect to mean compositions of olivines and low-Ca pyroxenes in order to distinguish the primary nebular features of these chondrites from the secondary (asteroidal or nebular) features. In three of the Antarctic chondrites, matrices and metal grains were analyzed in order to investigate the origin of mineralogical trends in the CO3 sequence. Based on these results, the CO3 chondrites were classified into subtypes 3.0-3.7. In the silicates of chondrites ALH A77307 and Colony, classified as type 3.0, metamorphic effects appear to be absent. Chemical and mineralogical studies suggest that the type 3.1 to 3.7 CO chondrites represent a metamorphic sequence that formed from material closely resembling type 3.0 CO chondrites by metamorphism in one or more planetesimals or asteroids, not by interactions between chondritic ingredients in the solar nebula.

Scott, Edward R. D.↗
NASA NTRS1989

Mineralogical and chemical properties of the lunar regolith

The composition of lunar regolith and its attendant properties are discussed. Tables are provided listing lunar minerals, the abundance of plagioclase feldspar, pyroxene, olivine, and ilmenite in lunar materials, typical compositions of common lunar minerals, and cumulative grain-size distribution for a large number of lunar soils. Also provided are charts on the chemistry of breccias, the chemistry of lunar glass, and the comparative chemistry of surface soils for the Apollo sites. Lunar agglutinates, constructional particles made of lithic, mineral, and glass fragments welded together by a glassy matrix containing extremely fine-grained metallic iron and formed by micrometeoric impacts at the lunar surface, are discussed. Crystalline, igneous rock fragments, breccias, and lunar glass are examined. Volatiles implanted in lunar materials and regolith maturity are also addressed.

Mckay, David S.↗
NASA NTRS1991

The mineralogy of ordinary chondrites and implications for asteroid spectrophotometry

Published data from bulk chemical analyses of 94 ordinary chondrites are compiled in a table of normative mineralogy and discussed in detail. Significant variations in olivine, pyroxene, and metal abundance ratios are found within each chondrite class and attributed to redox processes superimposed on initial differences in metal/silicate ratios. The use of the diagrams constructed here to predict the mineralogic characteristics of asteroids on the basis of spectrophotometric observations is suggested.

Mcsween, Harry Y., Jr.↗
NASA NTRS1991

Sm-Nd and Rb-Sr isotopic systematics of ureilites

The present evaluation of Sm-Nd and Rb-Sr isotopic data for seven ureilites establishes their divisions into three groups on the bases of Sm-Nd isotopic systematics. The first group of ureilites is made up of whole-rock samples whose highly depleted assemblages indicate Sm-Nd model ages consistent with 4.55 Ga. The second group of whole-rock samples of Kenna, Novo Urei, and ALHA77257 are heterogeneous mixtures of an unidentified light REE-enriched component and a light REE-depleted olivine-pyroxene assemblage. In the third group, LEW85440 neither has a model Sm-Nd age of 4.55 Ga nor plots of the 3.74 Ga isochron of the Kenna group; it might have had an evolution similar to the Kenna group, but involving different times and/or isotopic compositions.

Goodrich, Cyrena Anne↗
NASA NTRS1991

Pristine moon rocks - Apollo 17 anorthosites

New chemical analyses and petrographic descriptions for 10 previously unanalyzed Apollo 17 rock samples are provided. Attention is focused on several that appear to be pristine. All samples were analyzed in INAA using a procedure based on that of Kallemeyn et al. (1989). One sample was found to be unambiguously pristine, and is the first pristine ferroan-anorthositic suite (FAS) sample from Apollo 17. It exhibits extremely low-mg(asterisk) mafic silicates, coupled with relatively sodic plagioclase. It has an unusually high augite/low-Ca pyroxene ratio and contains incompatible trace elements at levels unprecedentedly high compared to FAS anorthosites from the Apollo 14, 15, 16 sites. It is inferred that 74114.5, and Apollo 17 anorthosites in general, formed at a relatively late stage in the evolution of the primordial magmasphere.

Warren, P. H.↗
NASA NTRS1991

Evolved hypabyssal rocks from Station 7, Apennine Front, Apollo 15

Three 4-10-mm coarse fines cataclasized particles from Station 7 on the Apennine Front, Apollo 15, have mineral phases and compositions similar to those in the quartz monzodiorites in 15405, from Station 6a. The chemical analyses of the Station 7 particles have lower trace-element abundances and flatter rare earth element patterns, and there is considerable disagreement among and between mineral norms and modes. The zoning of pyroxenes and the nature of their exsolution strongly suggest a common origin of the three particles and 15405 quartz monzodiorites in a hypabyssal environment. The differences then are a result of short-range differences in igneous modes considerably exaggereted by unrepresentative sampling of coarse rocks in small fragments. The parent hypabyssal rocks crystallized (4.35 Ga ago?) by fractionation of a poorly defined KREEP basalt magma, before the residual liquid reached any field of immiscibility. An impact event, possibly that forming Aristillus, ejected the upper levels of the bypabyssal intrusion, some of the ejecta spraying the Apennine Front.

Ryder, G.↗
NASA NTRS1991

Clays on Mars: Review of chemical and mineralogical evidence

Mafic igneous bedrock is inferred for Mars, based on spectrophotometric evidence for pyroxene (principally in optically dark areas of the globe) and the pyroxenite-peridotite petrology of shergottite nakhlite chassignite (SNC) meteorites. Visible and infrared spectra of reddish-brown surface fines (which dominate Martian bright areas) indicate ferric iron and compare favorably (though not uniquely) with spectra of palagonitic soils. Laboratory studies of SNC's and Viking Lander results support a model for Martian soil based on chemical weathering of mafic rocks to produce layer structured silicates (clay minerals), salts, and iron oxides.

Banin, Amos↗
NASA NTRS1992

Preliminary analysis of LDEF instrument A0187-1: Chemistry of Micrometeoroids Experiment

The Chemistry of Micrometeoroids Experiment (CME) exposed approximately 0.8 sq. m of gold on the Long Duration Exposure Facility's (LDEF's) trailing edge (location A03) and approximately 1.1 sq. m of aluminum in the forward-facing A11 location. The most significant results to date relate to the discovery of unmelted pyroxene and olivine fragments associated with natural cosmic dust impacts. The latter are sufficiently large for detailed phase studies, and they serve to demonstrate that recovery of unmelted dust fragments is a realistic prospect for further dust experiments that will employ more advanced collector media. We also discovered that man-made debris impacts occur on the LDEF's trailing edge with substantially higher frequency than expected, suggesting that orbital debris in highly elliptical orbits may have been somewhat underestimated.

Hoerz, Friedrich↗
NASA NTRS1992

A new angle on lunar ferroan-suite differentiation

Small fragments of rock found among soil particles in sample 67513 from Station 11 on the southern rim of North Ray Crater at Apollo 16 yield information regarding the mafic, ferroan rocks from which they drive. We have identified a set of particles that have distinctive trace element geochemistry and whose bulk and mineral compositions indicate a genetic relationship to one another. These include polymict as well as monomict lithologies. Igneous members range from fragments with abundant anorthite to some with abundant exsolved pigeonite and augite. Consideration of this set of rock fragments, combined with mafic ferroan clasts from large breccias and from lunar-highlands meteorites suggests that there may be separate differentiation trends within the ferroan suite which are subparallel and which are less steem in Fe-Mg vs. An fractionation that the vertical trend obtained when the entire ferroan suite is taken together. This may result from a complex magma system with isolated reservoirs or separate, independently evolving magmas. Mineral compositional and textural variations are consistent with a model set forth by Longhi and Boudreau wherein the anorthite-rich samples reflect adcumulus growth with mafic crystals forming only from trapped liquid, and the more mafic samples by anorthite and pyroxene orthocumulate development.

Jolliff, B. L.↗
NASA NTRS1992

A liquidus phase diagram for the groundmass of EETA 79001A (Eg), a primitive Shergottite composition

Shergottites are members of the SNC meteorite suite, which may be samples of Mars. If so, the shergottite in our collection that most likely represents primitive liquid from the Martian mantle is EETA 79001. EETA 79001 has the Nd isotopic signature of a long-term depleted mantle, a relatively high Mg number, and a slightly olivine-normative composition. The authors have performed experiments on the composition of EETA 79001 for traces of Eg. Other topics discussed include: comparison of calculated phase equilibria; nature of the olivine-pyroxene boundary; and interstitial liquids.

Jones, J. H.↗
NASA NTRS1991

Mineral compositions in pristine lunar highland rocks and the diversity of highland magmatism

High precision electron microprobe analyses of olivine and pyroxene in pristine lunar highland rocks confirm the dichotomy between ferroan anorthosites and the Mg-suite. Ferroan-anorthosites plot as coherent trends, consistent with formation in a complex global magma system. Lack of coherent compositional trends in the Mg-suite rocks indicates derivation from numerous magmas.

Bersch, Michael G.↗