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At least 757 records · Page 42

Detecting Methane From Leaking Pipelines and as Greenhouse Gas in the Atmosphere

Laser remote sensing measurements of trace gases from orbit can provide unprecedented information about important planetary science and answer critical questions about planetary atmospheres. Methane (CH4) is the second most important anthropogenically produced greenhouse gas. Though its atmospheric abundance is much less than that of CO2 (1.78 ppm vs. 380 ppm), it has much larger greenhouse heating potential. CH4 also contributes to pollution in the lower atmosphere through chemical reactions, leading to ozone production. Atmospheric CH4 concentrations have been increasing as a result of increased fossil fuel production, rice farming, livestock, and landfills. Natural sources of CH4 include wetlands, wild fires, and termites, and perhaps other unknown sources. Important sinks for CH4 include non-saturated soils and oxidation by hydroxyl radicals in the atmosphere. Remotely measuring CH4 and other biogenic molecules (such as ethane and formaldehyde) on Mars also has important implications on the existence of life on Mars. Measuring CH4 at very low (ppb) concentrations from orbit will dramatically improve the sensitivity and spatial resolution in the search for CH4 vents and sub-surface life on other planets. A capability has been developed using lasers and spectroscopic detection techniques for the remote measurements of trace gases in open paths. Detection of CH4, CO2, H2O, and CO in absorption cells and in open paths, both in the mid- IR and near-IR region, has been demonstrated using an Optical Parametric Amplifier laser transmitter developed at GSFC. With this transmitter, it would be possible to develop a remote sensing methane instrument. CH4 detection also has very important commercial applications. Pipeline leak detection from an aircraft or a helicopter can significantly reduce cost, response time, and pinpoint the location. The main advantage is the ability to rapidly detect CH4 leaks remotely. This is extremely important for the petrochemical industry. This capability can be used in manned or unmanned airborne platforms for the detection of leaks in pipelines and other areas of interest where a CH4 leak is suspected.

Riris, Haris↗

Radiative transfer in spherical shell atmospheres. I - Rayleigh scattering

The plane-parallel approximation and the more realistic spherical shell approximation for the radiance reflected from a planetary atmosphere are compared and are applied to the study of a planet the size of the earth with a homogeneous conservative Rayleigh scattering atmosphere extending to a height of 100 km. Inadequacies of the approximations are considered. Radiance versus height distributions for both single and multiple scattering are presented, as are results for the fractional radiance from altitudes in the atmosphere which contribute to the total unidirectional reflected radiance at the top of the atmosphere. The data can be used for remote sensing applications and planetary spectroscopy.

Adams, C. N.↗

Extendible probe for atmosphere sampling

Sampling probe is extended through small plug in heat shield by loaded bellows to sample planetary atmosphere for compositional analysis and total pressure during entry of space probe. Assembly prevents contamination of sample by gases from pyrotechnic device and serves as sealed plenum for atmospheric pressure sensor.

Jones, W. J.↗

Mass spectrometric measurements of atmospheric composition

The development of a magnetic sector field analyzer for continuous sampling and measurement of outer planetary atmospheres is discussed. Special features of the analyzer include a dynamic range of 10 to the minus 7th power, a mass range from 1 to 48 AMU, two ion sensitivities, a special scan time of 35 sec at 14 BPS, and the use of ion counting techniques for analysis.

Hoffman, J. H.↗

Ray propagation in oblate atmospheres

Phinney and Anderson's (1968) exact theory for the inversion of radio-occultation data for planetary atmospheres breaks down seriously when applied to occultations by oblate atmospheres because of departures from Bouguer's law. It has been proposed that this breakdown can be overcome by transforming the theory to a local spherical symmetry which osculates a ray's point of closest approach. The accuracy of this transformation procedure is assessed by evaluating the size of terms which are intrinsic to an oblate atmosphere and which are not eliminated by a local spherical approximation. The departures from Bouguer's law are analyzed, and it is shown that in the lowest-order deviation from that law, the plane of refraction is defined by the normal to the atmosphere at closest approach. In the next order, it is found that the oblateness of the atmosphere 'warps' the ray path out of a single plane, but the effect appears to be negligible for most purposes. It is concluded that there seems to be no source of serious error in making an approximation of local spherical symmetry with the refraction plane defined by the normal at closest approach.

Hubbard, W. B.↗

Dual-Band Optical Bench for Terahertz Radiometer for Outer Planet Atmospheres (TROPA)

We have developed a wide-band dual frequency spectrometer for use in deep space planetary atmospheric spectroscopy. The instrument uses a dual-band architecture, both to be able to observe spectral lines from a wide range of atmospheric species, and to allow a higher precision retrieval of temperature/pressure/partial pressure and wind profiles. This dual-band approach requires a new design for the optical bench to couple both frequencies into their respective receivers.

submillitmeter↗

Neutral upper atmospheres of Venus and Mars

Results obtained over the last 21 years from satellite measurements of the neutral upper atmospheres of Venus and Mars are discussed. Particular attention is given to the chemistry of the neutral upper atmospheres of the two planets, the exospheric temperatures, and the sensitivity of their atmospheric temperatures to solar activity. Various theoretical models used to interpret the planetary atmospheric data are discussed.

Keating, G. M.↗

The solar spectrum

The UV-IR solar spectrum is presented and discussed with a view to the comparative value of the data and their application in atomic or molecular spectroscopy and in solar, atmospheric, planetary, cometary, or stellar physics. Attention is given to intensity spectra, terrestrial atmospheric spectra, the 296-1300 nm Solar Flux Atlas of Kurucz et al. (1984), and line identifications.

Kurucz, Robert L.↗

Modeling Clouds in Brown Dwarf and Exoplanet Giant Planet Atmospheres

Clouds and hazes are commonplace in the atmospheres of solar system planets and are likely ubiquitous in the atmospheres of extrasolar planets as well. Clouds affect every aspect of a planetary atmosphere, from the transport of radiation, to atmospheric chemistry, to dynamics and they influence - if not control - aspects such as surface temperature and habitability. In my presentations I aim to provide an introduction to the role and properties of clouds in exoplanetary atmospheres and will discuss the lessons learned from the past two decades of studying clouds in brown dwarf atmospheres. I will consider the role clouds play in influencing the spectra of extrasolar giant planets and will discuss the relative simple approaches that have been taken so far to model exoplanet clouds. I will also review how the scattering and extinction efficiencies of cloud particles may be approximated in certain limiting cases of small and large particles in order to facilitate physical understanding and will discuss the need for optimized cloud models that can be applied to exoplanet transmission spectra. Finally I will discuss the various sources of aerosol opacity, including photochemistry, disequilibrium chemistry, and equilibrium condensation.

Marley, Mark S.↗

Aerocapture and aeroassisted orbital transfer - A high performance leverage space technology

Single pass aerocapture and aeroassisted orbital transfer designs are discussed for modifying spacecraft orbits using planetary atmospheres. Aerodynamic drag can be used to shift a hyperbolic flyby trajectory to a planetary orbit by having the spacecraft altering its in-plane L/D ratio to maintain constant drag until the desired velocity is attained. The spacecraft would then move out of the atmosphere, sometimes with a small propulsive assist. Sample missions to Uranus, Jupiter, and Titan are mentioned, with mission scenarios commencing with a Shuttle launch. Biconic-shaped spacecraft are cited as having the best L/D for insertion accuracy, a low hypersonic ballistic coefficient, and volumeric efficiency. Aeroassisted orbital transfer involves atmospheric braking in order to shed velocity on a return trip from higher orbits. No decision has yet been made as to the spacecraft shape, but calculations indicate that aeroassist braking before return to LEO for rendezvous with the Shuttle has the potential for the lowest cost/mass to GEO of any delivery system currently under consideration.

Cruz, M. I.↗

Photoselective isotope fractionation dynamics of N 2 with cosmo and atmospheric chemistry perspectives

Stable isotope ratio measurements provide valuable insights into a broad range of natural processes, from planetary atmospheres and climate to interstellar chemistry. Nitrogen, which has two stable isotopes, exhibits varying isotope ratios across the solar system. To model these observations, the isotope fraction as a function of energy is essential. At the Advanced Light Source (ALS), we measured the photodissociation of molecular nitrogen (N 2 ) with vacuum UV photons where a single photon is sufficiently energetic to dissociate the strong bond. The nitrogen atoms produced are scavenged with H 2 to form ammonia, whose isotopic makeup is determined. Blending the experiments with dynamical computations that include the shielding of light, we examine the isotopic composition and electronic atomic states produced. The measured photodissociation of N 2 at a natural isotopic composition with a frequency broad light beam exceptionally strongly favors the formation of the heavier nitrogen isotope, 15 N. Computations concur and suggest that the maximum in the quantum yield reflects significant variations in the specific electronic quantum states of the product N atoms that have quite different reactivities. Our quantum computations show that at similar energies, photodissociation of 14 N 14 N and 15 N 14 N can lead to different product channels. The computed dynamics include extensive state-selective spin–orbit and nonadiabatic couplings affecting the light absorption and dissociation pathways that proceed via the triplet manifold of states. Our results are relevant for future exploration missions, both in situ and sample-return and for other molecules such as O 2 and CO.

Komarova, Ksenia [Hebrew Univ. of Jerusalem (Israe↗

Path-length distributions of photons diffusely reflected from a semi-infinite atmosphere.

Knowledge of the probability distribution of photon path lengths for diffuse reflection in the continuum from a planetary atmosphere greatly simplifies computation of the shape and strength of absorption lines formed under conditions of multiple scattering. Graphs of this probability distribution are presented for diffuse reflection from a semiinfinite conservative atmosphere for both isotropic and forward-directed scattering, and for several angles of incidence and reflection. Graphs showing distributions for the case of absorption in the continuum are also discussed. The distributions are obtained from an analytic expression for the path-length distribution for nth-order scattering and a tabulation of nth-order intensities. It is found that te shape of the probability distribution depends markedly on the degree of forward scattering due to the phase function. The results are compared with those obtained by a Monte Carlo computation of the sort which might be used if tabulated nth-order intensities were not available.

Appleby, J. F.↗

On the Importance of Laboratory Astrophysics and Astrochemistry and Interdisciplinary Research: Two Success Stories

Here we present two examples that demonstrate how cross-disciplinary research projects, where experimentalists, modelers and observers work together to answer science questions, allow expertise to be shared and misconceptions or missing key elements to be tackled by looking at the problem from different perspectives. They also show how, by working in unison, the group can accomplish more than the sum of its parts by combining results into a higher-level understanding of the chemical processes taking place. The first project is a collaborative study between experimentalists, modelers and observers to1) produce laboratory analogs of cosmic grains and planetary aerosols (Titan, Pluto...) from different gas mixtures in cold astrophysically relevant conditions (<200 K); and 2) characterize them with scanning electron microscopy and visible-to-far-infrared spectroscopy in order to assess the impact of the precursors on their growth structure and optical properties. We can then produce and study analogs that are representative of different formation stages or environments, and provide their complex refractive indices to the scientific community. We will show how, by using these experimental optical constants of more representative analogs in radiative transfer and reflectance spectra models, better interpretations of (exo)planetary atmosphere- and surface observations are possible. The second project is an interdisciplinary study of the formation of benzene clouds in the atmosphere of Saturn’s largest moon, Titan. We will show how combining Earth and Planetary Science laboratory expertise, modeling and observations has led to providing to the scientific community, for the first time, experimental vapor pressures for benzene at cold temperatures(<200K) relevant to Titan’s atmospheric conditions. These have been used in microphysical models instead of the higher temperature extrapolations used previously, allowing a better match to observations.

Ella Sciamma-o'Brien↗

Radio scintillations observed during atmospheric occultations of Voyager: Internal gravity waves at Titan and magnetic field orientations at Jupiter and Saturn

The refractive index of planetary atmospheres at microwave frequencies is discussed. Physical models proposed for the refractive irregularities in the ionosphere and neutral atmosphere serve to characterize the atmospheric scattering structures, and are used subsequently to compute theoretical scintillation spectra for comparison with the Voyager occultation measurements. A technique for systematically analyzing and interpreting the signal fluctuations observed during planetary occultations is presented and applied to process the dual-wavelength data from the Voyager radio occultations by Jupiter, Saturn, and Titan. Results concerning the plasma irregularities in the upper ionospheres of Jupiter and Saturn are reported. The measured orientation of the irregularities is used to infer the magnetic field direction at several locations in the ionospheres of these two planets; the occultation measurements conflict with the predictions of Jovian magnetic field models, but generally confirm current models of Saturn's field. Wave parameters, including the vertical fluxes of energy and momentum, are estimated, and the source of the internal gravity waves discovered in Titan's upper atmosphere is considered.

Hinson, D. P.↗

Application of high stability oscillators to radio science experiments using deep space probes

The microwave telecommunication links between the earth and deep space probes have long been used to conduct radio science experiments which take advantage of the phase coherency and stability of these links. These experiments measure changes in the phase delay of the signals to infer electrical, magnetic and gravitational properties of the solar system environment and beyond through which the spacecraft and radio signals pass. The precision oscillators, from which the phase of the microwave signals are derived, play a key role in the stability of these links and therefore the sensitivity of these measurements. These experiments have become a driving force behind recent and future improvements in the Deep Space Network and spacecraft oscillators and frequency and time distribution systems. Three such experiments which are key to these improvements are briefly discussed and relationship between their sensitivity and the signal phase stability is described. The first is the remote sensing of planetary atmospheres by occultation in which the radio signal passes through the atmosphere and is refracted causing the signal pathlength to change from which the pressure and the temperature of the atmosphere can be derived. The second experiment is determination of the opacity of planetary rings by passage of the radio signals through the rings. The third experiment is the research for very low frequency gravitational radiation. The fractional frequency variation of the signal is comparable to the spatial strain amplitude the system is capable of detecting. A summary of past results and future possibilities for these experiments are presented.

Kursinski, Emil R.↗

On the Causes of and Long Term Changes in Eurasian Heat Waves

The MERRA reanalysis, other observations, and the GEOS-S model have been used to diagnose the causes of Eurasian heat waves including the recent extreme events that occurred in Europe during 2003 and in Russia during 2010. The results show that such extreme events are an amplification of natural patterns of atmospheric variability (in this case a particular large-scale atmospheric planetary wave) that develop over the Eurasian continent as a result of internal atmospheric forcing. The amplification occurs when the wave occasionally becomes locked in place for several weeks to months resulting in extreme heat and drying with the location depending on the phase of the upper atmospheric wave. Model experiments suggest that forcing from both the ocean (SST) and land playa role phase-locking the waves. An ensemble of very long GEOS-S model simulations (spanning the 20th century) forced with observed SST and greenhouse gases show that the model is capable of generating very similar heat waves, and that they have become more extreme in the last thirty years as a result of the overall warming of the Asian continent.

Schubert, Siegfried↗