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LiTa2Os crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two LiTa2Os ribbons oriented in the (1, 0, 0) direction. Li is bonded in a linear geometry to two equivalent Ta atoms. Both Li–Ta bond lengths are 2.98 Å. Ta is bonded in a linear geometry to one Li and one Os atom. The Ta–Os bond length is 2.22 Å. Os is bonded in a linear geometry to two equivalent Ta atoms.
BeSc2Os crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two BeSc2Os ribbons oriented in the (1, 0, 0) direction. Be is bonded in a linear geometry to two equivalent Sc atoms. Both Be–Sc bond lengths are 2.80 Å. Sc is bonded in a linear geometry to one Be and one Os atom. The Sc–Os bond length is 2.24 Å. Os is bonded in a linear geometry to two equivalent Sc atoms.
Ho2OsGa is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ho is bonded in a body-centered cubic geometry to four equivalent Os and four equivalent Ga atoms. All Ho–Os bond lengths are 3.00 Å. All Ho–Ga bond lengths are 3.00 Å. Os is bonded in a body-centered cubic geometry to eight equivalent Ho atoms. Ga is bonded in a body-centered cubic geometry to eight equivalent Ho atoms.
Ta2OsRu is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ta is bonded in a body-centered cubic geometry to four equivalent Os and four equivalent Ru atoms. All Ta–Os bond lengths are 2.76 Å. All Ta–Ru bond lengths are 2.76 Å. Os is bonded in a body-centered cubic geometry to eight equivalent Ta atoms. Ru is bonded in a body-centered cubic geometry to eight equivalent Ta atoms.
La2OsAg crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two La2OsAg ribbons oriented in the (1, 0, 0) direction. La is bonded in a linear geometry to one Os and one Ag atom. The La–Os bond length is 2.40 Å. The La–Ag bond length is 3.07 Å. Os is bonded in a linear geometry to two equivalent La atoms. Ag is bonded in a linear geometry to two equivalent La atoms.
Nb2OsRu crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Nb2OsRu ribbons oriented in the (1, 0, 0) direction. Nb is bonded in a linear geometry to one Os and one Ru atom. The Nb–Os bond length is 2.26 Å. The Nb–Ru bond length is 2.22 Å. Os is bonded in a linear geometry to two equivalent Nb atoms. Ru is bonded in a linear geometry to two equivalent Nb atoms.
LiTi2Os crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two LiTi2Os ribbons oriented in the (1, 0, 0) direction. Li is bonded in a linear geometry to two equivalent Ti atoms. Both Li–Ti bond lengths are 3.08 Å. Ti is bonded in a linear geometry to one Li and one Os atom. The Ti–Os bond length is 2.17 Å. Os is bonded in a linear geometry to two equivalent Ti atoms.
OsPtAl2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two OsPtAl2 ribbons oriented in the (1, 0, 0) direction. Os is bonded in a linear geometry to two equivalent Al atoms. Both Os–Al bond lengths are 2.45 Å. Pt is bonded in a linear geometry to two equivalent Al atoms. Both Pt–Al bond lengths are 2.35 Å. Al is bonded in a linear geometry to one Os and one Pt atom.
OsOs2F is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of four osmium molecules and one Os2F framework. In the Os2F framework, Os+0.33+ is bonded to four equivalent F1- atoms to form a mixture of edge and corner-sharing OsF4 tetrahedra. All Os–F bond lengths are 2.60 Å. F1- is bonded in a body-centered cubic geometry to eight equivalent Os+0.33+ atoms.
OsOs2O is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of four osmium molecules and one Os2O framework. In the Os2O framework, Os+0.67+ is bonded to four equivalent O2- atoms to form a mixture of corner and edge-sharing OsO4 tetrahedra. All Os–O bond lengths are 2.58 Å. O2- is bonded in a body-centered cubic geometry to eight equivalent Os+0.67+ atoms.
Sc2OsRu crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Sc2OsRu ribbons oriented in the (1, 0, 0) direction. Sc is bonded in a linear geometry to one Os and one Ru atom. The Sc–Os bond length is 2.37 Å. The Sc–Ru bond length is 2.34 Å. Os is bonded in a linear geometry to two equivalent Sc atoms. Ru is bonded in a linear geometry to two equivalent Sc atoms.
V4Os crystallizes in the orthorhombic Fmmm space group. The structure is three-dimensional. there are two inequivalent V sites. In the first V site, V is bonded in a 2-coordinate geometry to two equivalent V and two equivalent Os atoms. Both V–V bond lengths are 2.54 Å. Both V–Os bond lengths are 2.58 Å. In the second V site, V is bonded in a distorted body-centered cubic geometry to eight V atoms. There are two shorter (2.54 Å) and four longer (2.67 Å) V–V bond lengths. Os is bonded in a 4-coordinate geometry to four equivalent V atoms.
LaOs4As12 crystallizes in the cubic Im-3 space group. The structure is three-dimensional and consists of two lanthanum molecules and one OsAs3 framework. In the OsAs3 framework, Os+1.75- is bonded to six equivalent As+0.33+ atoms to form corner-sharing OsAs6 octahedra. The corner-sharing octahedral tilt angles are 58°. All Os–As bond lengths are 2.48 Å. As+0.33+ is bonded in a bent 120 degrees geometry to two equivalent Os+1.75- atoms.
Lu2OsCd is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Lu is bonded in a body-centered cubic geometry to four equivalent Os and four equivalent Cd atoms. All Lu–Os bond lengths are 3.01 Å. All Lu–Cd bond lengths are 3.01 Å. Os is bonded in a body-centered cubic geometry to eight equivalent Lu atoms. Cd is bonded in a distorted body-centered cubic geometry to eight equivalent Lu atoms.
Zr2OsFe crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Zr2OsFe ribbons oriented in the (1, 0, 0) direction. Zr is bonded in a linear geometry to one Os and one Fe atom. The Zr–Os bond length is 2.34 Å. The Zr–Fe bond length is 2.36 Å. Os is bonded in a linear geometry to two equivalent Zr atoms. Fe is bonded in a linear geometry to two equivalent Zr atoms.
Ta2ReOs is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ta is bonded in a body-centered cubic geometry to four equivalent Re and four equivalent Os atoms. All Ta–Re bond lengths are 2.77 Å. All Ta–Os bond lengths are 2.77 Å. Re is bonded in a body-centered cubic geometry to eight equivalent Ta atoms. Os is bonded in a body-centered cubic geometry to eight equivalent Ta atoms.
Y2OsZn crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Y2OsZn ribbons oriented in the (1, 0, 0) direction. Y is bonded in a linear geometry to one Os and one Zn atom. The Y–Os bond length is 2.39 Å. The Y–Zn bond length is 3.29 Å. Os is bonded in a linear geometry to two equivalent Y atoms. Zn is bonded in a linear geometry to two equivalent Y atoms.
U2OsB6 crystallizes in the orthorhombic Pbam space group. The structure is three-dimensional. there are two inequivalent U4+ sites. In the first U4+ site, U4+ is bonded in a 2-coordinate geometry to three equivalent Os2- and fourteen B1- atoms. There are a spread of U–Os bond distances ranging from 3.03–3.15 Å. There are a spread of U–B bond distances ranging from 2.61–2.76 Å. In the second U4+ site, U4+ is bonded in a 12-coordinate geometry to one U4+, two equivalent Os2-, and twelve B1- atoms. The U–U bond length is 2.51 Å. There are one shorter (3.01 Å) and one longer (3.04 Å) U–Os bond lengths. There are a spread of U–B bond distances ranging from 2.61–2.71 Å. Os2- is bonded in a 10-coordinate geometry to five U4+ and ten B1- atoms. There are a spread of Os–B bond distances ranging from 2.33–2.40 Å. There are six inequivalent B1- sites. In the first B1- site, B1- is bonded in a 3-coordinate geometry to four equivalent U4+, two equivalent Os2-, and three B1- atoms. There are a spread of B–B bond distances ranging from 1.77–1.84 Å. In the second B1- site, B1- is bonded in a 3-coordinate geometry to four U4+, two equivalent Os2-, and three B1- atoms. There is one shorter (1.69 Å) and one longer (1.82 Å) B–B bond length. In the third B1- site, B1- is bonded in a 3-coordinate geometry to four U4+, two equivalent Os2-, and three B1- atoms. There is one shorter (1.77 Å) and one longer (1.78 Å) B–B bond length. In the fourth B1- site, B1- is bonded in a 3-coordinate geometry to four U4+, two equivalent Os2-, and three B1- atoms. There is one shorter (1.69 Å) and one longer (1.83 Å) B–B bond length. In the fifth B1- site, B1- is bonded in a 9-coordinate geometry to four U4+, two equivalent Os2-, and three B1- atoms. In the sixth B1- site, B1- is bonded in a 8-coordinate geometry to six U4+ and two B1- atoms.