Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Mass density ratio”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Collimation of high-speed flow with thermal spread losses

The operation of the neutral beam collimator designed for the mass spectrometer inlet system of the Space Shuttle Induced Environment Contamination Monitor system is discussed. The collimator will allow selective views of a 10 deg half-angle conical volume of space so that backscattered molecules from within this volume can be measured and related to the column densities of outgassing species. Gas molecules which enter the collimator but do not have a view from the entrance orifice to the exit are directed to a gas getter and eliminated. The loss of properly directed molecules in the collimator due to their thermal distribution is calculated for the case of a directed flow, which would occur when the collimator is pointed in the direction of motion of the spacecraft. Inlet to outlet flux ratios are also computed as a function of angle of attack.

Taeusch, D. R.↗
DOE OSTI2021

Data from: "Warming of alpine tundra enhances belowground production and shifts community towards resource acquisition traits"

This archive contains data used to draw conclusions in “Warming of alpine tundra enhances belowground production and shifts community towards resource acquisition traits”, by Yang et al. 2020. Data were collected on Niwot Ridge, in an alpine meadow within the Alpine Treeline Warming Experiment (ATWE) field sites in Colorado, USA. Samples were also processed in the U.S. Geological Survey Forest and Rangeland Ecosystem Science Center, in Boise, Idaho. File formats in this archive include comma-separated values (.csv), portable document format (.pdf), Microsoft Excel (.xlsx), and two types of geospatial files: keyhole markup language (.kml), and ESRI shapefiles (.shp). Leaf scans are .jpg images, and root scans are .tiff/.tif images.The .csv files can be opened using R, Microsoft Excel, or any simple text-editing software such as TextEdit and Notepad. Microsoft Excel files can be opened using Microsoft Excel, and .pdf files can be opened with Adobe Acrobat Reader, Preview, or other compatible programs. Scanned images can be opened using any photo and/or picture viewing software.The .kml file can be opened using Google Earth and Google Maps, and the shapefiles can be opened by any programs compatible with shapefiles, such as the ArcGIS Desktop suite, and QGIS.------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------Measures of belowground net primary productivity (BNPP) are required to understand whether aboveground net primary production (ANPP) changes reflect changes in allocation or are indicative of a whole plant NPP response. Plant functional traits provide a key way to scale from the individual plant to the community level, and provide insight into drivers of NPP responses to environmental change. We used infrared heaters to warm an alpine plant community at Niwot Ridge, Colorado, and applied supplemental water to compensate for soil water loss induced by warming. We measured ANPP, BNPP, and leaf and root functional traits across treatments after 5 years of continuous warming. Community-level ANPP and total NPP (ANPP + BNPP) did not respond to heating or watering, but BNPP increased in response to heating. Heating decreased community-level leaf dry matter content and increased total root length, indicating a shift in strategy from resource conservation to acquisition in response to warming.

13C/12C isotope ratio↗
DOE OSTI2025

Convective shells in the interior of Cepheid variable stars: Overshooting models based on hydrodynamic simulations

Context. Because Cepheid variable stars have long been used as a cosmic benchmark for scaling distances in our Galaxy and beyond, the accuracy of stellar evolution models for Cepheids have wide-reaching effects. However, our understanding of the dynamics in the interiors of these physically complex stars is limited. Aims. Our goal is to provide a detailed multi-dimensional picture of hydrodynamic convection and convective boundary mixing in the interior of Cepheids. Methods. Using the Modules for Experiments in Stellar Astrophysics (MESA), we studied the structure of intermediate-mass stars that cross the instability strip. Then, we performed two-dimensional hydrodynamic simulations of six stars with the fully compressible Multidimensional Stellar Implicit Code (MUSIC). Our simulations did not model the radial pulsations but focused on the interior structure of this family of stars. We developed and applied a new statistical analysis to examine convection and convective boundary mixing in the interior of these stellar simulations. Results. Based on a grid of MESA models, we demonstrated that a common structure for intermediate mass Cepheids includes an interior convective shell as well as a thin outer convective envelope. Using the extreme value theory approach to analyze our MUSIC simulation data, we found that overshooting above the convective shell fills the space between these convectively unstable layers. We developed a new statistical analysis that provides a clearer picture of how overshooting fills this layer; it also allowed us to formulate a detailed comparison between overshooting above and below the convective shell. Our analysis effectively decomposes the overshooting layer into two layers: a weak overshooting layer and a strong overshooting layer. Statistically, this is accomplished by decomposing the strongly non-Gaussian probability density function into a mixture of gamma distributions. Using our mixture model, we showed that the ratio of overshooting lengths above and below the convective shell depends directly on the radial extent of the convective shell as well as its depth in the star. We proposed a new form for the diffusion coefficient that addresses the need for overlapping overshooting layers between convective shells. We introduced the idea of a “super-mixing layer” where overshooting from both the convective shell and the convective envelope results in efficient mixing and could be viewed as merging the two adjacent convective zones.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1994

Statistical association of QSO's with foreground galaxy clusters

We report a statistically significant overdensity of high redshift quasi-stellar objects (QSO's) in the directions of foreground galaxy clusters. QSO's are taken from the Large Bright QSO Survey (LBQS) between 1.4 less than or equal z less than or equal 2.2 with a limiting magnitude of m(sub B) = 18.5. Foreground clusters are regions within 6 Zwicky radii of small Zwicky clusters at a characteristic redshift of about z approximately = 0.2, covering about 40% of the total area surveyed (304 sq. deg). The overdensity, defined as the ratio of the number density of QSO's in the directions of clusters ('association QSO's) to that in the remainder of the fields ('background QSO's), is equal to 1.7, and formally differs from unity at 4.7 sigma significance. The observed overdensity probably is not due to statistical variation in QSO density, intrinsic QSO-QSO and/or cluster-cluster autocorrelations, or patchy Galactic obscuration. We thus interpret this observation as being due to statistical gravitational lensing of background QSO's by galaxy clusters. However, this amplitude of overdensity behind clusters cannot be accounted for in any cluster lensing model if the background QSO number-magnitude counts are similar to the intrinsic (unlensed) counts, and is implausible in any conventional model of cosmic mass distribution.

Rodrigues-Williams, Liliya L.↗
NASA NTRS2012

The Temperature and Distribution of Organic Molecules in the Inner Regions of T Tauri Disks

"High-resolution NIR spectroscopic observations of warm molecular gas emission from young circumstellar disks allow us to constrain the temperature and composition of material in the inner planet-forming region. By combining advanced data reduction algorithms with accurate modeling of the terrestrial atmospheric spectrum and a novel double-differencing data analysis technique, we have achieved very high-contrast measurements (S/N approx. 500-1000) of molecular emission at 3 microns. In disks around low-mass stars, we have achieved the first detections of emission from HCN and C2H2 at near-infrared wavelengths from several bright T Tauri stars using the CRIRES spectrograph on the Very Large Telescope and NIRSPEC spectrograph on the Keck Telescope. We spectrally resolve the line shape, showing that the emission has both a Keplerian and non-Keplerian component as observed previously for CO emission. We used a simplified single-temperature local thermal equilibrium (LTE) slab model with a Gaussian line profile to make line identifications and determine a best-fit temperature and initial abundance ratios, and we then compared these values with constraints derived from a detailed disk radiative transfer model assuming LTE excitation but utilizing a realistic temperature and density structure. Abundance ratios from both sets of models are consistent with each other and consistent with expected values from theoretical chemical models, and analysis of the line shapes suggests that the molecular emission originates from within a narrow region in the inner disk (R < 1 AU)."

Mandell, Avi↗
NASA NTRS1990

The formation phase of the solar nebula

Hydrodynamical calculations of the collapse of an axisymmetric, rotating protostellar cloud, with radiation transport and without magnetic fields, are presented. The collapse is assumed to start from a centrally condensed sphere of radius 5 x 10 to the 15th cm, a mean density of 4 x 10 to the -15th g/cu cm, a total mass of 1 solar mass, and a total angular momentum of 10 to the 53rd g sq cm per sec. The numerical grid is chosen to resolve the region of disk formation between 1 and 60 AU from the center. Frequency-dependent radiative transfer calculations show how the emergent spectrum of the structure depends upon viewing angle with respect to the rotation axis and how the observed isophotal contours should depend on wavelength and viewing angle. The central part of the protostar, interior to 1 AU, is not resolved numerically but is modeled approximately. At the end of the calculation, this region is found to have a mass of 0.6 solar mass and a ratio of rotational to gravitational energy of about 0.4, sufficiently large to be unstable to nonaxisymmetric perturbations. Although the disk is gravitationally stable according to the local Toomre criterion, the nonaxisymmetric structure in the center is likely to lead to angular momentum transport.

Bodenheimer, Peter↗
NASA NTRS1993

Density wave triggered star formation in grand design spirals

In normal spiral galaxies the arms are the main sites for star formation. This is the cause of their optical contrast compared with the rest of the disc. The spiral structure can be observed as a higher concentration of H2 regions, neutral gas (both atomic and molecular via CO), dust and stars than in the interarm disc. It seens generally accepted that, at least in grand design spirals, there are density waves in the discs. However, several questions are not clear yet and still under discussion. An important question could be termed the triggering dilemma (by analogy with the 'winding dilemma' raised in the forties): Is the enhanced star formation in the spiral arms triggered by the passage of a system of density waves or is it simply due to the presence of a higher column density of gas there? In the present work, we use triggering in the same sense as the moderate to strong triggering defined by Elmegreen (1992), that is to say that star formation in the arms occurs at a rate faster than that in the interarm zone, relative to the available placental gas. Our group has designed several tests to elucidate whether or not star formation is triggered in the arms with respect to the interarm region and we summarize one of them, that of the ratio of the star formation efficiency in the arms divided by that of the interarm zone at the same galactocentric distance which we may call the relative massive star formation efficiency, where the efficiency is defined using the ratio of the mass of stars (evaluated via the H alpha flux) to the mass of neutral gas, atomic plus molecular (which must be measured with the adequate angular resolution). If the relative efficiency is of order unity, the star formation is proportional to the mass of gas, if some kind of induced star formation is present, the relative efficiency should be considerably larger than unity.

Cepa, J.↗
NASA NTRS1992

Solar cycle variations in H(+) and D(+) densities in the Venus ionosphere - Implications for escape

The hydrogen ion concentrations recently observed on Venus, near solar minimum, by the Ion Mass Spectrometer on the Pioneer Venus Orbiter in the anti-solar sector of the ionosphere are more than an order of magnitude less than those previously observed at solar maximum. This strong solar cycle variation has a profound effect on the escape of hydrogen (and deuterium) from Venus; almost all escape occurs during solar maximum. After adjustment for solar cycle variation, a planet-averaged hydrogen escape flux of 0.6-1.4 x 10 exp 7/sq cm per sec is obtained along with a large deuterium fractionation factor of 0.1-0.14. These results suggest at least two plausible scenarios for the evolution of water on Venus: (1) water vapor on Venus may be approaching a steady state if the escape flux is balanced by endogenous sources of water or (2) the present day D/H ratio of 0.024 could be established by Rayleigh fractionation of an early low D/H water reservoir if the escape flux was sufficiently large in earlier times. An early water endowment at least 340 times today's abundance would be needed.

Donahue, Thomas M.↗
DOE OSTI2023

Weak Gravitational Lensing of Low Surface Brightness Galaxies in the Dark Energy Year 3 Catalog

We present galaxy-galaxy lensing measurements of a sample of low surface brightness galaxies (LSBGs) drawn from the Dark Energy Survey Year 3 (Y3) data. LSBGs are diffuse galaxies with a surface brightness dimmer than the ambient night sky. Given their faintness, the use of standard observational techniques proves challenging. Weak gravitational lensing probes both the baryonic and dark matter content of galaxies, rendering it a powerful technique to estimate LSBG masses. The LSBG lens sample consists of 23, 790 total extended galaxies separated into red and blue color types at \(g-i\ge 0.60\) and \(g-i\le 0.60\), respectively. We use the Y3 \sc{metacalibration} shape catalog as the source sample, with a number density of \(5.59 \mathrm{gal}/\mathrm{arcmin}^2\). We measure the tangential shear around the lens galaxies across angular scales of \(0.25-400\) arcmin and find a signal-to-noise of 6.67 for red galaxies, 2.17 for blue galaxies, and 5.30 for the total sample. We fit a model built from two NFW profiles corresponding to the LSBG dark matter subhalo and host halo to the red LSBG shear measurements with an MCMC. We estimate the host halo mass at \(7.3 ^{+2.0}_{-1.6}\times 10^{12} M_\mathrm{\odot}\). We place a 95\% upper bound on the subhalo mass at \(3\times 10^{11} M_\mathrm{\odot}\). We utilize the lens sample photometry to obtain an estimate of the red LSBG stellar mass distribution. We compare the ratio between the stellar mass and the subhalo mass to the parameterized, satellite-specific SHMR. This work represents the first example of an attempted constraint on the masses of LSBGs using weak gravitational lensing.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1995

Characteristics of coronal shock waves and solar type 2 radio bursts

In the solar corona shock waves generated by flares and/or coronal mass ejections can be observed by radio astronomical methods in terms of solar type 2 radio bursts. In dynamic radio spectra they appear as emission stripes slowly drifting from high to low frequencies. A sample of 25 solar type 2 radio bursts observed in the range of 40 - 170 MHz with a time resolution of 0.1 s by the new radiospectrograph of the Astrophvsikalisches Institut Potsdam in Tremsdorf is statistically investigated concerning their spectral features, i.e, drift rate, instantaneous bandwidth, and fundamental harmonic ratio. In-situ plasma wave measurements at interplanetary shocks provide the assumption that type 2 radio radiation is emitted in the vicinity of the transition region of shock waves. Thus, the instantaneous bandwidth of a solar type 2 radio burst would reflect the density jump across the associated shock wave. Comparing the inspection of the Rankine-Hugoniot relations of shock waves under coronal circumstances with those obtained from the observational study, solar type 2 radio bursts should be regarded to be generated by weak supercritical, quasi-parallel, fast magnetosonic shock waves in the corona.

Mann, G.↗
NASA NTRS2019

Performance Optimization of Plate Airfoils for Martian Rotor Applications Using a Genetic Algorithm

The Mars Helicopter Technology Demonstrator will be flying on the NASA Mars 2020 rover mission scheduled to launch in July of 2020. The goal is to demonstrate the viability and potential of heavier-than-air vehicles in the Martian atmosphere. Research is performed at the Jet Propulsion Laboratory and NASA Ames Research Center to extend these capabilities and develop the Mars Science Helicopter as the next possible step for Martian rotorcraft. The Mars Science Helicopter mass is scaled up to the 5 to 20 kg range, allowing a greater payload (approximately 0.5 to 2.0 kg), and greater range (approximately 3 km). Key to achieving these targets is careful aerodynamic rotor design. The Martian atmosphere’s low density and the small helicopter rotors result in very low chord-based Reynolds number flows, which reduces rotor performance. A continuous genetic algorithm is developed to optimize airfoil shapes at representative conditions for the Martian atmosphere. Previous research indicates that sharp leading edges and plate-like airfoils can out-perform conventional airfoil shapes. The present optimization allows for camber and thickness variation of curved and polygonal thin airfoils with sharp leading edges. The airfoil performance is evaluated at the highest attainable liftto- drag ratio near a moderate lift coefficient at compressible Mach numbers, as expected for Martian rotor application. Increases between 16% and 29% in airfoil lift-to-drag ratio at fixed lift coefficients are observed when compared with the Mars Helicopter Technology Demonstrator airfoils. Improvements in hover figure of merit are estimated to be between 4% and 10%, when applied to the Mars Helicopter Technology Demonstrator.

Koning, Witold J. F.↗
DOE OSTI2025

Design and Development of Novel Equiatomic Refractory Multi Principal elemental Alloys Based on MoNbTi System for Use in Irradiation Environments

Multi Principal Elemental Alloys (MPEA) have emerged as promising materials for next-generation nuclear reactors due to their exceptional irradiation resistance. Eight equiatomic MPEA based on the MoNbTi system, comprising of elements with low thermal neutron absorption cross-sections were explored using a combined approach employing empirical parameter estimations, and CALPHAD simulations by which the phases and elemental segregation observed in all the alloys in the as-cast state were predicted. Solution heat treatment at 1500°C transformed five alloys into single-phase matrix materials, enhancing homogeneity and reducing hardness. The densities of the alloys ranged between 6.47 to 7.68 g/cm3, hardness between 472 and 656 VHN, Young’s modulus between 142 GPa to 169 GPa, shear modulus between 54 GPa and 62 GPa, bulk modulus between 117 GPa to 194 GPa and Poisson’s ratio between 0.3 to 0.35. The in-situ high temperature Xray diffraction results, differential scanning calorimetry and dilatometry results up to 1000°C suggested the high temperature phase stability of the MPEA. Subsequent ageing heat treatment at 800 and 1000 oC for 96 hours revealed significant secondary phase precipitation in MoNbTiZr, MoNbTiZrV, and MoNbTiCrA. Oxidation studies at 800 oC for 24 hours in air revealed superior oxidation resistance and cubic rate law dependence in Cr containing MPEA especially in MoNbTiCrAl, while severe mass gain resulting in total disintegration and exfoliation in MoNbTiZr and MoNbTiZrV. This comprehensive study underscores the potential of novel MPEA as promising materials for advanced nuclear reactor applications, shedding light on their microstructural control, mechanical properties, thermal stability, and oxidation resistance.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2024

A Coordinated-Anion-Enriched Electrolyte for Lean-Electrolyte Li–S Batteries

The solid electrolyte interphase (SEI) on Li and cathode electrolyte interphase (CEI) at sulfurized polyacrylonitrile (SPAN) formed in the commonly used liquid electrolytes cannot accommodate the large volume change of both Li anode and SPAN cathode, resulting in severe electrolyte and Li consumption and fast capacity decay under high mass loading and lean electrolyte condition. Herein, a LiF-rich SEI and a LiF-Li x N y O z co-enriched CEI are simultaneously formed by adding ionic liquid (Py 13 TFSI) in the localized high-concentration electrolyte (LHCE), which forms a coordinated-anion-enriched solvation structure. In this study, the LiF-rich interphase results in less stress/strain during large volume changes of Li and SPAN and therefore achieving obviously improved stability even at a high areal capacity. Consequently, Li (50 μm)||SPAN (6 mg cm -2 ) pouch cells under the lean electrolyte condition (E/S ratio of 5 mL g SPAN -1 ) delivers a stable cycle life of 120 cycles with 79.2% capacity retention, demonstrating great promise for high-energy-density lithium-sulfur batteries.

25 ENERGY STORAGE↗
DOE OSTI2023

Weak Gravitational Lensing of Low Surface Brightness Galaxies in the DES Year 3 Catalog

We present galaxy-galaxy lensing measurements of a sample of low surface brightness galaxies (LSBGs) drawn from the Dark Energy Survey Year 3 (Y3) data. LSBGs are diffuse galaxies with a surface brightness dimmer than the ambient night sky. Given their faintness, the use of standard observational techniques proves challenging. Weak gravitational lensing probes both the baryonic and dark matter content of galaxies, rendering it a powerful technique to estimate LSBG masses. The LSBG lens sample consists of 23, 790 total extended galaxies separated into red and blue color types at \(g-i\ge 0.60\) and \(g-i\le 0.60\), respectively. We use the Y3 \metacal\ shape catalog as the source sample, with a number density of {\color{red}\(5.59 \mathrm{gal}/\mathrm{arcmin}^2\)}. We measure the tangential shear around the lens galaxies across angular scales of \(0.25-400\) arcmin and find a signal-to-noise of 6.67 for red galaxies, 2.17 for blue galaxies, and 5.30 for the total sample. W e fit a model built from two NFW profiles corresponding to the LSBG dark matter subhalo and host halo to the red LSBG shear measurements with an MCMC. We estimate the host halo mass at \(7.3 ^{+2.0}_{-1.6}\times 10^{12} M_\mathrm{\odot}\). We place a 95\% upper bound on the subhalo mass at \(2.8\times 10^{11} M_\mathrm{\odot}\). We utilize the lens sample photometry to obtain an estimate of the red LSBG stellar mass distribution. We compare the ratio between the stellar mass and the subhalo mass to the parameterized, satellite-specific SHMR \citep{Moster2010}. This work represents the first example of an attempted constraint on the masses of LSBGs using weak gravitational lensing.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Signature of hadron-quark crossover in binary-neutron-star mergers

Here, we study observational signatures of the hadron-quark crossover in binary-neutron-star mergers by numerical-relativity simulations with various mass configurations. We employ two equations of state (EoSs) for matter consistent with inference from the observational data. In the crossover scenario the EoS is softened in a density realized in binary-neutron-star mergers and is smoothly continued to quark matter. In the phase transition scenario without crossover, the EoS remains stiff and a first-order phase transition takes place in a density out of reach of mergers. A GW170817-like system forms a remnant massive neutron star in both scenarios, and it collapses into a black hole only in the crossover scenario due to the softening while gravitational-wave emission is strong. This difference is clearly reflected in the sudden shutdown of gravitational waves. For a given EoS, the lifetime of the merger remnant is determined primarily by the total mass of the system. Identifying these features in a variety of future events with the next generation of ground-based gravitational-wave detectors will enable us to clarify details of hadron-quark transition. The mass of the accretion disk surrounding the remnant black hole is affected not only by the lifetime of the remnant but also by the mass ratio of the system. Electromagnetic emission associated with the disk outflow will also be useful for detailed investigation of the hadron-quark transition.

QCD phase transitions↗
NASA NTRS2003

Modeling Variability of Plasma Conditions in the Io Torus

Telescopic observations an in situ measurements of the Io plasma torus show the density, temperature and composition to vary over time, sometimes up to a factor of 2. While previous models of the physical and chemical processes in the Io plasma torus have reasonably modeled the conditions of the Voyager 1 era, their authors have not addressed the observed variability nor explored the sensitivity of torus conditions to input parameters. In this paper we present a homogeneous torus model parameterized by five variables (transport timescale, neutral source strength, ratio of oxygen sulfur to atoms in the source, fraction of superthermal electrons, temperature of these hot electrons). The model incorporates the most recent data for ionization, recombination, charge exchange and radiative energy losses for the major torus species (S, S(sup +), S(sup ++), S(sup +++), O, O(sup +), O(sup ++). We solve equations of conservation of mass and energy to find equilibrium conditions for a set of input parameters. We compare model plasma conditions with those observed by Voyager 1 Voyager 2, and Cassini. Furthermore, we explore the sensitivity of torus conditions to each parameter. We find that (1) torus conditions are distinctly different for the Voyager 1, Voyager 2 and Cassini eras, (2) unique torus input parameters for any given era are poorly constrained given the wide range of solution space that is consistent with the range of observed torus conditions, (3) ion composition is highly sensitive to the specification of a non-thermal electron distribution, (4) neutral O/S source ratio is highly variable with model values ranging between 1.7 for Cassini to 4.0 for Voyager 1 conditions, (5) transport times range between 23 days for Voyager 2 to 50 days for Voyager 1 and Cassini, (6) neutral source strengths range between 7 to 30 x 10(sup -4) cm (sup -3) s(sup -1) which corresponds to a net production of 0.4 to 1.3 tons/s for a torus volume of 1.4 x 10(sup 31) cm(sup 3), or 38 R(sub j)(sup 3).

Delamere, P. A.↗
DOE OSTI2024

Enzymatic depolymerization of polyester: Foaming as a pretreatment to increase specific surface area

Abstract Poly(ethylene terephthalate) (PET) is widely used for its high strength‐to‐weight ratio, gas barrier properties, and chemical resistance. The growing PET use highlights the demand for a better recycling system. Enzymatic recycling, alongside mechanical and chemical methods, is eco‐friendly and yields properties similar to virgin PET. Substrate properties ( T g , crystallinity, and specific surface area [SSA]) and enzyme stability significantly impact conversion efficiency. Higher SSA and lower crystallinity tend to yield improved depolymerization when employing leaf compost‐cutinase (LCC‐ICCG) enzymes. This study explored melt extrusion and foaming as pretreatment techniques to modify PET structural properties, using a low‐cost chemical foaming agent (CFA). The monomer conversion rate and efficiency during depolymerization were measured and related to the processing, extrudate micro‐ and meso‐structure, and polyester type. Pretreated PET substrates showed reduced T g , crystallinity, density, and enhanced SSA, resulting in a 90% mass loss for foamed RPET and VPET substrates within 2 days. In contrast, PET with ~30% of cyclohexanedimethanol comonomer exhibited a nearly 50% lower depolymerization rate, with zero BHET production. It indicates that the combination of low crystallinity, low T g , and high SSA leads to improved monomer conversion. These findings emphasize the significance of amorphization and foaming in enhancing PET enzymatic depolymerization.

42 ENGINEERING↗
NASA NTRS1990

Interacting nuclei in distant galaxies

The N-galaxy 3C 390.3 has been monitored spectroscopically since 1974 (Osterbrock, Koski and Phillips 1975; Oke 1988). From various archives and literature, it is found that the Balmer lines change their intensities and profiles in a dramatic manner. The H alpha profile is very broad and peculiar, and the relative intensities of its two humps changes consistently with time, possibly periodically. Before 1980, the blue hump was significantly stronger than the one in the red. From 1980 to 1983 the blue hump became stronger (see Oke 1988). After 1983 the H alpha profile has returned to its early shape and seems to have completed a full circle. Unlike the rapid (on the order of a month or even less) and aperiodic variation in the continuum and integrated line intensities, the change in broad profile seems slow and consistent. Taking the analogy of cataclysmic variables, the double-horn profiles have been observed in cases of interacting stars. For example, the emission lines, both in He II and hydrogen Balmer lines in GD 552 (Stover 1985) show double-horn profiles and periodical changes in their line profiles, including the change in ratios of two humps. It is understood that the D-wave components (Smak 1976) are the signature of an emitting disk and the S-wave component is from the emission at a hot spot which rotates and results in a moving component in the velocity space. The mass flow from the nearby interacting star provides the stream toward the core of a neutron star or white dwarf. Therefore, it is proposed that the variation of broad line profiles observed in 3C 390.3 may be the result of a pair of interacting massive cores. The rotational velocity dominates and produces a variable double-horn profile. However, the line widths observed in broad line radio galaxies are one order larger than that in interacting stars. The Balmer decrements imply a much smaller density (10(exp 10-12) cm(exp-3)) than that in the cataclysmic variables. The much larger velocity and much thinner density make it unlikely that the broad line emission is simply formed in an accretion disk. The authors postulate that a significant rotational motion is involved. If the observed squared profiles are indeed due to the rotational velocity field, one can naturally explain their rare occurrence.

Zheng, Wei↗