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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42

Laminar or turbulent boundary-layer flows of perfect gases or reacting gas mixtures in chemical equilibrium

Turbulent boundary layer flows of non-reacting gases are predicted for both interal (nozzle) and external flows. Effects of favorable pressure gradients on two eddy viscosity models were studied in rocket and hypervelocity wind tunnel flows. Nozzle flows of equilibrium air with stagnation temperatures up to 10,000 K were computed. Predictions of equilibrium nitrogen flows through hypervelocity nozzles were compared with experimental data. A slender spherically blunted cone was studied at 70,000 ft altitude and 19,000 ft/sec. in the earth's atmosphere. Comparisons with available experimental data showed good agreement. A computer program was developed and fully documented during this investigation for use by interested individuals.

Anderson, E. C.↗

Preliminary performance of the Brayton 4.25 inch radial compressor operating in a helium xenon gas mixture

Compressor performance was mapped during the Brayton cycle power system testing. The range of testing included three shaft speeds: the design speed of 36,000 rpm, 10 percent overspeed (39,600 rpm), and 10 percent underspeed (32,400 rpm). A range of compressor inlet temperatures from 60 F to 120 F and discharge pressures from 20 to 45 psia were included. The effects of turbine inlet temperatures (from 1200 F to 1600 F) on the compressor were also studied. The data presented include plots of weight flow, compressor pressure ratio, efficiency, and temperature-rise ratio.

Asadourian, A. S.↗

Polynomial approximations of thermodynamic properties of arbitrary gas mixtures over wide pressure and density ranges

Computer programs for flow fields around planetary entry vehicles require real-gas equilibrium thermodynamic properties in a simple form which can be evaluated quickly. To fill this need, polynomial approximations were found for thermodynamic properties of air and model planetary atmospheres. A coefficient-averaging technique was used for curve fitting in lieu of the usual least-squares method. The polynomials consist of terms up to the ninth degree in each of two variables (essentially pressure and density) including all cross terms. Four of these polynomials can be joined to cover, for example, a range of about 1000 to 11000 K and 0.00001 to 1 atmosphere (1 atm = 1.0133 x 100,000 N/m sq) for a given thermodynamic property. Relative errors of less than 1 percent are found over most of the applicable range.

Allison, D. O.↗

Computation of pressure effects of inert-gas mixtures on atomic line shapes.

Recent line-shape experiments on the absorption series of cesium pressurized by various concentration ratios of argon and helium provide an opportunity to study the additivity of perturber interactions. Calculations which assume additivity and which assume additive adiabatic collisions agree well with the reported data. The results suggest that a systematic study of such experiments using accurate digitized data can furnish criteria for the valid applications of the additivity approximation.

Jacobson, H. C.↗

Determination of the temperature of gas mixtures by using laser Raman scattering

A theoretical model for the Raman rotational spectrum of air was formulated, yielding the spectral temperature dependence; and an error analysis of temperature measurement accuracies was performed. The theoretical spectra and the predicted temperature measurement error of + or - 20 K (7 percent) compared well with experimental data. These experimental data consisted of Raman spectra of air obtained for temperatures ranging from 243 to 313 K at a pressure of 1 atmosphere. The use of selected lines resulted in an experimental accuracy of + or - 13 K (-5 percent).

Coney, T. A.↗

Solutions of the chemical kinetic equations for initially inhomogeneous mixtures.

Following the recent discussions by O'Brien (1971) and Donaldson and Hilst (1972) of the effects of inhomogeneous mixing and turbulent diffusion on simple chemical reaction rates, the present report provides a more extensive analysis of when inhomogeneous mixing has a significant effect on chemical reaction rates. The analysis is then extended to the development of an approximate chemical sub-model which provides much improved predictions of chemical reaction rates over a wide range of inhomogeneities and pathological distributions of the concentrations of the reacting chemical species. In particular, the development of an approximate representation of the third-order correlations of the joint concentration fluctuations permits closure of the chemical sub-model at the level of the second-order moments of these fluctuations and the mean concentrations.

Hilst, G. R.↗

Phase equilibria in fluid mixtures at high pressures - The He-CH4 system.

An experimental study of phase equilibria in the He-CH4 system has been carried out over the temperature range 95 to 290 K and at pressures to 10,000 atm. The experimental results consist of equilibrium phase composition for twenty-eight isotherms in the region of coexistence of two fluid phases, together with the pressure-temperature trace of the three-phase boundary at which a CH4-rich solid phase is in equilibrium with the two fluid phases. The system exhibits a fluid-fluid phase separation which persists to temperatures and pressures beyond the range of this experiment. These findings are relevant to problems of deep atmosphere and interior structures in the outer planets.-

Streett, W. B.↗

Thermal conductivity of heterogeneous mixtures and lunar soils

The theoretical evaluation of the effective thermal conductivity of granular materials is discussed with emphasis upon the heat transport properties of lunar soil. The following types of models are compared: probabilistic, parallel isotherm, stochastic, lunar, and a model based on nonlinear heat flow system synthesis.

Vachon, R. I.↗

Vibrational deactivation of O3/101/ molecules in gas mixtures

The laser excited fluorescence method has been employed to determine rate constants for vibrational relaxation of O3(101) molecules by O3, O2, CO2, H2, D2, CH4, N2, He, and Ar collision partners at 298 K. Excitation of the O3(001) level by absorption of laser transitions on the CO2 9.5-micron band have permitted the first measurements of vibrational relaxation on O3.

Rosen, D. I.↗