Air-Stable Monolayer Cu 2 Se Exhibits a Purely Thermal Structural Phase Transition
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Chemistry↗
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Results for “Laser beams”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Faraday rotation study of plasma bubbles in GeV wakefield accelerators
We visualize plasma bubbles driven by 0.67 PW laser pulses in a plasma of density ne≈5×1017cm−3 by imaging Faraday rotation patterns imprinted on linearly polarized probe pulses of wavelength λpr=1.05 μm and duration τpr=2 or 1 ps that cross the bubble's path at right angles. When the bubble captures and accelerates tens to hundreds of pC of electron charges, we observe two parallel streaks of length cτpr straddling the drive pulse propagation axis, separated by ∼45 μm, in which probe polarization rotates by 0.3° to more than 5° in opposite directions. Accompanying simulations show that they result from Faraday rotation within portions of dense bubble side walls that are pervaded by the azimuthal magnetic field of accelerating electrons during the probe transit across the bubble. Analysis of the width of the streaks shows that quasi-monoenergetic high-energy electrons and trailing lower energy electrons inside the bubble contribute distinguishable portions of the observed signals, and relativistic flow of sheath electrons suppresses Faraday rotation from the rear of the bubble. The results demonstrate favorable scaling of Faraday rotation diagnostics to 40× lower plasma density than previously demonstrated.
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
What next: Further implosion space exploration on the path to NIF extended yield capability
We present quantitative motivations and assessments of various proposed and ongoing directions to further improving yields and target gain of igniting indirect-drive implosions at the National Ignition Facility (NIF). These include increasing compression and confinement time, improving hohlraum and ablator efficiency, and further increasing peak power and laser energy. 1D hydroscaled simulations, augmented by analytic 1D theory, have been used to project yield improvements for each of these implosion optimization tracks, normalized to the best current performing 4 MJ shot. At current NIF capabilities of 2.2 MJ, 450 TW, we project several paths could reach 15 MJ yield levels. We also expect several key implosion physics questions will be addressed in attempting to reach this yield level. These include demonstrating to what extent lower adiabat designs leading to higher compression will increase gain and efficiency, and whether we can reduce residual kinetic energy and ablator-fuel mix that is probably limiting the current burn-up fraction. For an envisaged NIF upgrade to EL = 3 MJ at fixed 450 TW peak power, scaling capsule size and fuel thicknesses faster than pure hydroscaling should allow for yields that could reach up to 60–80 MJ, depending on the efficiency gains realized in increasing deuterium-tritium fuel thickness, reducing hohlraum losses, and switching to lower Z ablators. The laser-plasma instability and beam transmission scaling in these larger hohlraums is shown to be favorable if the spot size is increased with hohlraum scale.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
A combined Phase Contrast Imaging and heterodyne interferometer for multiscale fluctuation measurements in tokamak plasmas
An upgrade to the Phase Contrast Imaging (PCI) diagnostic on the DIII-D tokamak has successfully combined PCI with density interferometry to provide electron density fluctuation measurements across an unprecedented range in wavenumber. The combined diagnostic uses a single laser and a single beam path through the tokamak, minimizing machine resources in anticipation of future reactor-scale devices where port access will be at a premium. The PCI multichannel detector provides low-noise, wavenumber-resolved detection of moderate-wavenumber turbulence, while the interferometer channel is sensitive to long-wavelength turbulence, including the peak of ion-scale turbulence and MHD. The overlap in wavenumber range between the two schemes allows for an in situ absolute calibration of the PCI.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Laser-assisted charge exchange as an atomic yardstick for proton beam energy measurement and phase probe calibration
Not Available
43 PARTICLE ACCELERATORS↗
Traveling-wave Thomson scattering for electron-beam spectroscopy
Not Available
43 PARTICLE ACCELERATORS↗
Structure-property relationships and mobility optimization in sputtered La-doped BaSn O 3 films: Toward 100cm 2 V -1 s -1
he wide band gap semiconducting perovskite BaSnO 3 is of high current interest due to outstanding room temperature mobility at high electron density, fueled by potential applications in oxide, transparent, and power electronics. Due in part to a lack of lattice-matched substrates, BaSnO 3 thin films suffer from high defect densities, however, limiting electron mobility. Additionally, the vast majority of BaSnO 3 thin film research has focused on pulsed laser deposition or molecular beam epitaxy. In this work, we present an exhaustive optimization of the mobility of Ba 0.98 La 0.02 SnO 3 films grown by a scalable, high-throughput method: high-pressure-oxygen sputter deposition. Considering target synthesis conditions, substrate selection, buffer layer structure, deposition temperature, deposition rate, thickness, and postdeposition annealing conditions, and by combining high-resolution x-ray diffraction, reciprocal space mapping, rocking curve analysis, scanning transmission electron microscopy, atomic force microscopy, and temperature-dependent electronic transport measurements, detailed understanding of synthesis-structure-property relationships is attained. Optimized room temperature mobility of 96 cm 2 V –1 s –1 is achieved in vacuum-annealed GdScO 3 (110)/BaSnO 3 (120 nm)/Ba 0.98 La 0.02 SnO 3 (200 nm) heterostructures, as well as 92 cm 2 V –1 s –1 on unbuffered substrates and 87 2 V –1 s –1 without postdeposition annealing. These results, including important trends in defect densities and a surprising dependence of mobility on lattice mismatch, substantially expand the understanding of the interplay between deposition conditions, microstructure, and transport in doped BaSnO 3 films, establishing competitive mobilities in films fabricated via a scalable, high-throughput, industry-standard technique.
36 MATERIALS SCIENCE↗
Ptychographic X-ray speckle tracking with multi-layer Laue lens systems
The ever-increasing brightness of synchrotron radiation sources demands improved X-ray optics to utilize their capability for imaging and probing biological cells, nano-devices and functional matter on the nanometre scale with chemical sensitivity. Hard X-rays are ideal for high-resolution imaging and spectroscopic applications owing to their short wavelength, high penetrating power and chemical sensitivity. The penetrating power that makes X-rays useful for imaging also makes focusing them technologically challenging. Recent developments in layer deposition techniques have enabled the fabrication of a series of highly focusing X-ray lenses, known as wedged multi-layer Laue lenses. Improvements to the lens design and fabrication technique demand an accurate, robust, in situ and at-wavelength characterization method. To this end, a modified form of the speckle tracking wavefront metrology method has been developed. The ptychographic X-ray speckle tracking method is capable of operating with highly divergent wavefields. A useful by-product of this method is that it also provides high-resolution and aberration-free projection images of extended specimens. Three separate experiments using this method are reported, where the ray path angles have been resolved to within 4 nrad with an imaging resolution of 45 nm (full period). This method does not require a high degree of coherence, making it suitable for laboratory-based X-ray sources. Likewise, it is robust to errors in the registered sample positions, making it suitable for X-ray free-electron laser facilities, where beam-pointing fluctuations can be problematic for wavefront metrology.
36 MATERIALS SCIENCE↗
Comparison of PID Shunting in Polycrystalline and Single-Crystal Silicon Modules via Multi-Scale, Multi-Technique Characterization
We used the methods we reported last year to investigate potential-induced degradation (PID). We have now applied these methods to single-crystalline silicon modules that have degraded during field deployment, as well as in minimodules stressed in the laboratory. We will compare these results to the polycrystalline results presented last year. Small cores have been removed from the modules and subjected to analysis. We use a combination of photoluminescence and dark lock-in thermography imaging, laser marking, electron-beam induced current measurements, and subsequent focused ion-beam marking to allow analysis of individual defects via time-of-flight secondary-ion mass spectrometry (TOF-SIMS) to investigate the root-cause mechanism for PID shunting. We see a direct correlation between recombination active shunts and sodium content. The sodium content in shunted areas peaks at the SiN/Si interface and is consistently observed at a concentration of 0.1%-1% in shunted areas. TOF-SIMS data taken on degraded and non-degraded single-crystalline sample areas show a similar trend as in the polycrystalline samples: more sodium is seen in the degraded areas.
14 SOLAR ENERGY↗
Optimizing fused silica debris shield use in the National Ignition Facility
The National Ignition Facility (NIF) deliberately and routinely operates with its final optics exposed to fluences likely to induce and grow damage. This choice has enabled the NIF to operate at energies previously unachievable at the expense of limitations to delivered power and energy contingent on the ability to repair damage on the final optics. Prior to the introduction of the fused silica debris shield (FSDS), the grating debris shield (GDS) was the optic type on the NIF most prone to damage and hence a primary limiter to the delivered energy. The introduction of the FSDS has reduced the damage initiation rate on the GDS by about two orders of magnitude to date. Despite the FSDS being a disposable optic, it is important to understand how the FSDS damages and when its damage requires it to be exchanged to maximize the FSDS lifetime while still protecting the GDS from damage. We will define the FSDS exchange criteria and evaluate the damage initiation mechanisms of the FSDS. The surface damage morphologies provide insight into the impact of the various damage mechanisms that limit the FSDS lifetime. These results are utilized in our analysis to optimize the FSDS exchange criteria to further extend the GDS lifetime.
42 ENGINEERING↗
Structure and Dynamics of Domains in Ferroelectric Nanostructures – Phase-Field Modeling (Final Technical Report)
Domain pattern formation is one of the most common phenomena in nature and is a topic of immense interest in many fields ranging from materials science and physics to chemistry and biology. This DOE sponsored research project explored the basic science concerning the thermodynamic stability of mesoscale polarization domain patterns and their temporal evolution mechanisms during formation and subsequent switching in ferroelectric nanostructures and heterostructures. The project employed the computational phase-field method in combination of microelasticity and electrostatic theories. The research was carried out in close collaboration with a number of experimental groups who used High Resolution Transmission Electron Microscopy (HRTEM), in situ TEM with Scanning Probe Microscopy (SPM), or Piezoresponse Force Microscopy (PFM) to characterize the domain structures and dynamics of ferroelectric thin films and heterostructures and who grow high-quality ferroelectric and multiferroic thin films using advanced growth techniques such as Molecular Beam Epitaxy (MBE), Pulsed Laser Deposition (PLLD), and sputtering. The research efforts of the project help establish the phase-field method as the most powerful method for understanding and predicting domain structures in ferroelectric thin films and nanostructures. The findings of the project led to the basic understanding of stability and switching mechanisms of ferroelectric domains under different mechanical boundary conditions and under either homogeneous capacitor configurations or local fields using metallic probes as electrodes and the emergence of charged domain walls during domain switching. The project predicted the spatial length scales, temperature ranges, and electromechanical conditions for different polar states in heterostructures and guided the discovery of both transient and stable novel polarization states containing vortex lattices in oxide superlattices. The project resulted in 134 journal publications and 6 PhD theses with all the PhD graduates currently working in either academia or industry within the United States. The basic understanding on the stability of mesoscale polar states and pattern evolution achieved by the project improved our ability to control and engineer properties of ferroelectric thin films and heterostructures for potential applications in nanoscale electronic devices.
36 MATERIALS SCIENCE↗
Recycling and Reuse of Tungsten-Rhenium Refractory Alloy Powder for Additive Manufacturing (Quarterly Progress Report - 01 April 2023-30 June 2023)
Savannah River National Laboratory in partnership with 6K Inc is working on demonstrating laser and electron-beam powder bed additive manufacturing processes of W-24Re alloy and developing powder reconditioning (deoxidation) technology via plasma spheroidization and investigating the properties and performance of additively manufactured W-24Re components produced using both virgin and recycled powders.
36 MATERIALS SCIENCE↗
Rapid Design and Manufacturing of High-Performance Materials for Turbine Blades
This research demonstrated the concept of carbide precipitation-strengthened refractory high entropy alloys (RHEA). The advantage of a precipitation strengthened alloy is all phases are in thermodynamic equilibrium promoting microstructural stability, and consequently retention of properties at elevated temperatures. Additionally, as with any precipitation strengthened – or age hardened - alloy, components can be heat-treated after manufacturing to manipulate the microstructure and optimize properties for performance. This is an advantage of the precipitation strengthened alloys over composites and ceramics materials, where the microstructure and properties are essentially fixed upon the initial materials manufacturing stage. High throughput (HT), multi-scale computer modeling was used to identifying novel RHEA compositions with desired characteristics needed for precipitation strengthening. Designs were validated by producing small ingots via are melting. The results showed that carbides precipitated and consequently, the strength of the alloys (measured in compression) increased after heat-treatment, which is the desired effect. The project also demonstrated the feasibility of producing articles from RHEA by additive manufacturing (AM). Electron beam melting (EBM) and laser direct energy deposition (L-DED) additive manufacturing methods, were explored with various processing parameters were interrogated for both methods. Sound (crack-free and dense) precipitation strengthened RHEA samples were produced via EDM AM, demonstrating the feasibility of the concept.
36 MATERIALS SCIENCE↗
Stable Beam Propagation for Efficient MeV Photon Dose Generation in Laser-Solid Interactions
Explore the source record for details and available documents.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
A Novel Dew Point Meter: Application to the Measurement of the Sulfuric Acid Dew Point for Combustion Flue Gas
Accurate knowledge of acid dew point is essential for industrial and applied combustion. Sulfur in the fuel or raw materials is converted to sulfur dioxide (SO2) during combustion, and a portion of the SO2 is oxidized to sulfur trioxide (SO3). The SO3 will react to form H2SO4 vapor when in the presence of water vapor. Even with just trace levels of H2SO4 vapor in the gas phase (1-10 ppm), the dew point can reach 100°C and higher. To avoid acid condensation and the resulting corrosion on heat recovery equipment, plant engineers must ensure that surface temperatures are above the acid dew point, but this decreases the efficiency of the thermal energy recovery. Thus, there is a trade-off between minimizing equipment corrosion and maximizing thermal energy recovery efficiency, and the acid dew point is a key parameter for this optimization. In this work, we analyze and discuss the theory of the sulfuric acid condensation process and develop a novel dew point meter based on this analysis. The meter consists of a novel optical instrument that is designed to monitor the slightest appearance of condensation on a hydrophobic window surface, and the surface temperature of the window is slowly decreased until condensation is first observed, yielding an accurate measurement of the dew point. The basis of the instrument is that a collimated beam from a diode laser generates scattered light when encountering surface condensate, and a sophisticated array detector is used to sensitively monitor the light scattering. The measurement procedures are established to rapidly find the acid dew point, while minimizing error. Further, we propose a calibration system based on a liquid bubbler, which can generate a stable gas flow with known sulfuric acid dew point, to test the dew point meter. Test results show that the dew point meter can accurately measure the acid dew point over a wide range.
Cheng, Mao↗
Compact absorptivity measurement system for additive manufacturing
The present disclosure relates to a powdered bed fusion additive manufacturing (PBFAM) apparatus. The apparatus uses a container for holding a quantity of powdered material. The container has a bottom wall for supporting the powdered material, wherein the bottom wall is made from the same material as the powdered material. A temperature sensing subsystem is coupled to a portion of the container for detecting a temperature of the container. A laser generates an optical beam directed at the powdered material held by the container for melting the powdered material. A controller receives temperature information from the temperature sensing subsystem and determines an absorptivity of the powdered material based on the temperature information.
36 MATERIALS SCIENCE↗
High power actively Q-switched downhole LIBS analysis systems
An actively Q-switched laser induced breakdown spectroscopy (LIBS) probe, utilizing an optical fiber, a pump beam transmitted through the optical fiber, a coupler, and a lens for collimating the pump beam. The actively Q-switched laser, coupled to a sensor which provides information to a computer that controls a high voltage pulser providing a pulse to a Pockels cell located within the laser which can selectively cause the laser to pulse, resulting in high energy pulses and a second lens for focusing the output pulse such that it creates a plasma or spark. The light from the spark is captured and directed back through an optical system to remote equipment for elemental and/or molecular analysis.
McIntyre, Dustin Langdon↗
LBNL-BELLA Center Monoenergetic Photon Source Experiments
This document outlines measurements made by Idaho National Laboratory (INL) staff at the Berkeley Lab Laser Accelerator (BELLA) Center. Measurements of a mono-energetic Thomson photon beam were made with various INL instruments. The photon beam was generated by a laser-plasma accelerator system. This project is referred to by the name Laser Wake. Key Lawrence Berkeley National Laboratory (LBNL) personnel involved include Liona Fan-Chiang, Cameron Geddes, Anthony Gonsalves, Robert Jacob, Tobias Ostermayr, and Hai-En Tsai.
46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗