Ignition Delay Times and CO Composition during Ethanol Combustion in Miniature Shock Tube
Ignition delay times and composition of CO were measured simultaneously in a miniature high repetition rate shock tube (HRRST) using chemiluminescence and tunable diode laser absorption spectroscopy. Mixtures of 1% ethanol with oxygen and balance argon were tested with equivalence ratios 0.5, 1, and 1.2, over pressure range of 1.6 to 1.8 bar, and temperature range of 1180 to 1400K. Ignition delay times in this range were compared with those in larger shock tubes using several different techniques. One method included using the Livengood-Wu integral (and improved estimates from measured pressure trace). Another method involved direct modeling of conditions in the miniature shock tube using the measured pressure trace. CO composition was measured in parallel with the ignition delay time experiments. Comparison was made with mechanisms in the literature. Experiments were also performed doping CO into the Ar bath gas and conducting two-line CO measurements using TDLAS before ignition. With proper calibration, this measurement is sensitive to temperature.