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Laboratory exercises, remote sensing of the environment

The exercises are designed to convey principles and theory of remote sensing, and methodologies of its application to civil engineering and environmental concerns, including agronomy, geography, geology, wildlife, forestry, hydrology, and other related fields. During the exercises the student is introduced to several types of remote sensing represented by imagery from conventional format: panchromatic, black-and-white infrared, color, and infrared, 35mm aerial photography, thermal infrared, radar, multispectral scanner, and LANDSAT. Upon completion of the exercises the student is expected to know: (1) the electromagnetic spectrum, its various wavelength sub-sections and their uses as sensors, (2) the limitations of each sensor, (3) the interpretation techniques used for extracting data from the various types of imagery, and (4) the cost effectiveness of remote sensing procedures for acquiring and evaluating data of the natural environment.

Mintzer, O.↗

Space Station gas-grain simulation facility - Microgravity particle research

The proposed Space Station gas-grain simulation facility (GGSF) and the possibilities for research in the facility are discussed. The physics of particles in microgravity is reviewed. The proposed design of the GGSF is illustrated and examined. Examples of experiments which have been suggested for the GGSF are presented, including the formation of organic haze particles in Titan's atmosphere, organic compound synthesis on surfaces of growing particles, fractal particles, planetary ring particle dynamics, aggregation of fine geological particulates in planetary atmospheres, and dipolar grain coagulation and orientation.

Carle, Glenn C.↗

Sapping Features of the Colorado Plateau: a Comparative Planetary Geology Field Guide

This book is an attempt to determine geomorphic criteria to be used to distinguish between channels formed predominantly by sapping and seepage erosion and those formed principally by surface runoff processes. The geologic nature of the Colorado Plateau has resulted in geomorphic features that show similarities to some areas on Mars, especially certain valley networks within thick sandstone formations. Where spring sapping is an effective process, the valleys that develop are unique in terms of their morphology and network pattern.

Howard, Alan D.↗

The violent side of mare volcanism

In the past 15 years it has become increasingly evident that lunar pyroclastic volcanism played an important role in the formation and resurfacing of portions of the Moon. Located on mare/highland boundaries, many of these deposits formed in association with mare volcanism. Based on recently acquired geologic and remote sensing data, two generally distinct types of pyroclastic mantling deposits have been identified: regional and localized. Both the regional dark mantling deposits (RDMD) and localized dark mantling deposits (LDMD) are widely distributed across the lunar nearside. The larger RDMD are typically located in lunar highland areas adjacent to many of the major lunar maria, while the smaller LDMD are found on the floors of pre-Imbrian and Inbrian craters. Both deposits are basaltic in composition and are presumed to have originated at great depth (approx. 300 km). The composition, geometry, and vent morphology of the pyroclastic deposits have been used to infer the eruption mechanisms and emplacement styles for both types of deposits.

Coombs, Cassandra R.↗

Early Mars: A regional assessment of denudation chronology

Within the oldest highland units on Mars, the record of crater degradation indicates that fluvial resurfacing was responsible for modifying the Noachian through middle-Hesperian crater population. Based on crater frequency in the Noachian cratered terrain, age/elevation relations suggest that the highest exposures of Noachian dissected and plateau units became stabilized first, followed by successively lower units. In addition, studies of drainage networks indicate that the frequency of Noachian channels is greatest at high elevations. Together, these observations provide strong evidence of atmospheric involvement in volatile recycling. The long time period of crater modification also suggests that dendritic highland drainage was not simply the result of sapping by release of juvenile water, because the varied geologic units as well as the elevation dependence of stability ages makes it unlikely that subsurface recycling could provide a continuous supply of water for channel formation by sapping. While such geomorphic constraints on volatile history have been established by crater counts and stratigraphic relations using the 1:2M photomosaic series, photogeologic age relationships at the detailed level are needed to establish a specific chronology of erosion and sedimentation. Age relations for discrete erosional slopes and depositional basins will help refine ages of fluvial degradation, assess effectiveness of aeolian processes, and provide a regional chronology of fluvial events.

Maxwell, T. A.↗

Wetting transition and fluid trapping in a microfluidic fracture

Immiscible fluid–fluid displacement in confined geometries is a fundamental process occurring in many natural phenomena and technological applications, from geological CO 2 sequestration to microfluidics. Due to the interactions between the fluids and the solid walls, fluid invasion undergoes a wetting transition from complete displacement at low displacement rates to leaving a film of the defending fluid on the confining surfaces at high displacement rates. While most real surfaces are rough, fundamental questions remain about the type of fluid–fluid displacement that can emerge in a confined, rough geometry. Here, we study immiscible displacement in a microfluidic device with a precisely controlled structured surface as an analogue for a rough fracture. We analyze the influence of the degree of surface roughness on the wetting transition and the formation of thin films of the defending liquid. We show experimentally, and rationalize theoretically, that roughness affects both the stability and dewetting dynamics of thin films, leading to distinct late-time morphologies of the undisplaced (trapped) fluid. Finally, we discuss the implications of our observations for geologic and technological applications.

42 ENGINEERING↗

Geologic Mapping of the Meridiani Region, Mars

The light toned bedrock that has been observed at the Mars Exploration Rover Opportunity landing site is an upper layer in a sequence >600 m thick in places. These outcrops contain mineral and textural signatures that require interaction of, and possibly formation from, water. Many distinct layers are visible in the remote sensing data (e.g. Figure 1) and no work has ever characterized the full set of these materials that cover an area >3 105 km2 spanning 20 of longitude. Thus, whatever water-related process( es?) altered, and possibly formed, the rocks at the Opportunity landing site extended over a vast region of Mars. Yet many questions remain to be answered, such as: (1) in what capacity did water form and alter the deposits?, (2) what are the temporal and spatial relations with other major events known from ancient Mars?, and (3) would this type of environment have been conducive to the development of life? To address these questions we are completing a detailed geologic, stratigraphic, and thermophysical properties study of this widespread terrain. Specifically, we are drafting a 1:2M-scale geological map covering the full extent of these water-related deposits. In tandem with the mapping, Hynek and Phillips [1] have conducted a preliminary stratigraphic analysis of the stack of materials. After mapping is complete, we will study the thermophysical properties of the varied layers to derive possible compositional information of the materials. These tasks serve several purposes including gaining an understanding of the complex nature of these materials, their potential source region(s), and their timing of emplacement. All of these efforts are necessary to place the observations by the Opportunity Rover in a broader context and prepare for potential future landed missions to the region. Understanding the large-scale paleohydrology of Mars is central to NASA s goals and vital for determining if life ever arose on the planet.

Hynek, B. M.↗

CarbonSAFE Phase II: Optimizing Alabama’s CO 2 Storage in Shelby County, Alabama (Project OASIS), Milestone M3 - Site Specific Drilling Report

The Phase II Storage Complex Feasibility project, entitled "Optimizing Alabama's CO 2 Storage in Shelby County, Alabama (Project OASIS)," is a part of the DOE/NETL's CarbonSAFE initiative. The Project is managed by the Southern States Energy Board (SSEB), and includes participation from Advanced Resources International, Inc. (ARI), Crescent Resource Innovation, Southern Company, Alabama A&M University, Auburn University, and Oklahoma State University. Project OASIS is working to establish the foundation for a commercial-scale geologic storage complex for CO 2 captured from Plant Gaston (home of the National Carbon Capture Center) and surrounding industrial sources of CO 2 located in Shelby County, Alabama. The Project objectives are: • Demonstrate that the subsurface saline formations at the storage complex can store commercial volumes of CO 2 safely and permanently. • Develop a comprehensive Community Benefits Plan. • Develop the infrastructure framework for a CO 2 storage hub. • Develop a rigorous risk registry and to conduct a comprehensive risk assessment. • Develop a monitoring plan. • Develop a comprehensive site characterization plan to support an Underground Injection Control Class VI Permit in a future Phase III program. • Evaluate the commercial viability of the project. Project OASIS is about 30 miles southeast of Birmingham, Alabama within a geologic province called the Valley and Ridge (Figure 1.1). The Valley and Ridge Province comprises a sequence of Paleozoic carbonate and clastic rocks that underwent structural deformation during the Alleghanian Orogeny. Storage prospects occur in relatively flat lying structural panels located between thrust faults. Available geologic studies related to hydrocarbon exploration suggest that Cambro-Ordovician carbonates and Cambrian clastic units offer multiple potential storage intervals, and that regional confining systems are present, such as the tectonically thickened Floyd-Parkwood Shale. The surface property is owned by a timber and land stewardship company, The Westervelt Company, Inc., who worked with the Project Team to select and prepare adequate sites for geologic assessment. The purpose of drilling the Westover Stratigraphic Test Well #2 was to collect geologic data to model the feasibility of commercial scale CO 2 injection and storage. This includes geological and geophysical evaluations, reservoir engineering analyses, and risk assessments.

20 FOSSIL-FUELED POWER PLANTS↗

Geology of the lunar farside crater Necho

The ejecta morphology and distribution as well as the interior materials of the 30-km-diameter, Necho lunar crater is discussed and the effects of regional preimpact topography on the formation structure and modification of the crater are described. Three types of ejecta: hummocky, lineated, and smooth, that are concentrated in a band extending from the rim crest to a distance of less than one crater diameter are examined. The crater's interior, divided into floor units of textured, bubbled, and smooth material is analyzed and hypotheses of their origin are presented. The last area of study is the preimpact setting, characterized by a series of large, degraded, pre-Nectarian craters. Results showed that the Necho, in comparison with surrounding craters, was the freshest, insuring that the data from its excavation was preserved without a significant amount of degradation.

Gifford, A. W.↗

The geology, geochemistry, and geographic distribution of southern Idaho obsidian

The Snake River Plain Volcanic Province of Southern Idaho is host to an abundance of pyroclastic obsidian deposits that constitute the principal lithic raw material utilized by Native Americans of the region throughout the Precontact Period. Archaeologists have long looked to obsidian as a source of information on past patterns of raw material selection, landscape use, and mobility through geochemical analysis of obsidian artifacts and lithic raw materials. Formation of the Snake River Plain through cataclysmic “super-eruptions” of the Yellowstone hotspot, however, presents one of the most complex and poorly understood obsidian source-scapes of North America. To clarify the geographic distribution of Southern Idaho obsidian source groups, the INL CRMO has compiled a comprehensive reference library of geologic obsidian from 138 source locales distributed across the southern half of the state. In this report, we define 28 geochemically distinct obsidian source groups that occur at these deposits through X-ray Fluorescence spectrometry and contextualize the geographic distribution of each source group relative to the history of silicic magmatism on the Snake River Plain. This research facilitates ongoing investigations at the INL CRMO into patterns of obsidian procurement, conveyance, and exchange in Southern Idaho throughout the Precontact Period.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Uranyl oxalate species in high ionic strength environments: stability constants for aqueous and solid uranyl oxalate complexes

Uranyl ion, UO 2 2+ , and its aqueous complexes with organic and inorganic ligands can be the dominant species for uranium transport on the Earth surface or in a nuclear waste disposal system if an oxidizing condition is present. As an important biodegradation product, oxalate, C 2 O 4 2– , is ubiquitous in natural environments and is known for its ability to complex with the uranyl ion. Oxalate can also form solid phases with uranyl ion in certain environments thus limiting uranium migration. Therefore, the determination of stability constants for aqueous and solid uranyl oxalate complexes is important not only to the understanding of uranium mobility in natural environments, but also to the performance assessment of nuclear waste disposal. In this work, we developed a thermodynamic model for the UO 2 2+ –Na + –H + –Cl – –ClO 4 – –C 2 O 4 2– –NO 3 – –H 2 O system to ionic strength up to ~11 mol•kg –1 . We constrained the stability constants for UO 2 C 2 O 4 (aq) and UO 2 (C 2 O 4 ) 2 2– at infinite dilution based on our evaluation of the literature data over a wide range of ionic strengths up to ~11 mol•kg –1 . We also obtained the solubility constants at infinite dilution for solid uranyl oxalates, UO 2 C 2 O 4 •3H 2 O, based on the solubility data over a wide range of ionic strengths. The developed model will enable for the accurate stability assessment of oxalate complexes affecting uranium mobility under a wide range of conditions including those in deep geological repositories.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

FECM/NETL CO2 Saline Storage Cost Model CO2_S_COM 2024 (v4)

The U.S. Department of Energy's (DOE) Office of Fossil Energy and Carbon Management (FECM), in collaboration with the National Energy Technology Laboratory (NETL), has developed the FECM/NETL CO2 Saline Storage Cost Model (CO2_S_COM). This Excel-based tool provides a comprehensive framework for estimating the costs and breakeven prices associated with storing carbon dioxide (CO2) in deep saline formations. Designed from the perspective of a CO2 storage site owner, the CO2_S_COM incorporates four integrated modules—project management, financial analysis, activity cost estimation, and geological evaluation—to deliver fast, robust and actionable insights for screening project finances.

CO2 storage↗

Regional dust deposits on Mars - Physical properties, age, and history

This paper presents a description of the use of Viking infrared thermal mapper (IRTM), earth-based radar, and visual observations for the study of the existence of regional dust deposits. It is pointed out that these observations provide estimates of particle size, rock abundance, surface texture, thermal emissivity, and albedo. These estimates can be used to characterize surface deposits and to determine the degree of surface mantling. Attention is given to the regolith properties, atmospheric dust properties, and a model for formation of low-inertia regions. It is found that global dust storms deposit currently approximately 25 microns of material per year in the equatorial region. Over geologic time this value may vary from 0 to 250 microns due to variations in atmospheric conditions produced by orbital variations.

Christensen, P. R.↗

Tectonic domains in the Eastern Hemisphere of Mars

The definition of boundaries of discrete structural provinces on the surface of Mars has previously been made by the assumptions of circular or radial symmetry (in the case of the Tharsis olateau), by artificial quadrangle boundaries for regional studies, or simply by regional geographical features. Much of the planetary structural mapping has been presented in a line or spot format in existing consortium data. Methods are being generated to convert the detailed maps of tectonic features to a format that can be used with standard image processing techniques. In this manner such data can be more readily compared to age and other attributes deduced from geological mapping, gravity results, and topography. The 24 photomosaics covering the Eastern Hemisphere of Mars have already been examined for four types of structural features: erosional remnants, ridges, graben, and scarps. When digitized, each feature was flagged according to feature type, azimuth and length. These values were stored as text files on a quad-by-quad basis for each quad studied.

Maxwell, Ted A.↗

The Hypothesis of Caves on Mars Revisited Through MGS Data; Their Potential as Targets for the Surveyor Program

In a previous publication, we proposed the formation of caves at mega and microscale on Mars and emphasized their potential for the exobiology exploration. The recent MOC images have shown promising indicators that caves are actually existing on Mars. In the first section, we develop the theoretical potential formation of martian caves. Then, we show how MOC is supporting this hypothesis of their formation and the new types of environments it suggests. The existence of caves on Mars from microscale to microscale structures can be predicted according to the Mars geological and climatic history. A first global approach is to consider caves as a result of underground water activity combined with tectonic movement. They can be formed by: (1) diversion of channel courses in underground conduits; (2) fractures of surface drainage patterns; chaotic terrain and collapsed areas in general; (4) seepage face in valley walls and/or headwaters; (5) inactive hydrothermal vents and lava tubes.

Grin, E. A.↗

Medusae Fossae-Elysium Region, Mars: Depression in the HEND/Odyssey Map of Mars Epithermal Neutrons

The first data from the Gamma Ray Spectrometer (GRS) onboard Mars Odyssey spacecraft showed that the low neutron fluxes characterize both subpolar regions of Mars. The low neutron fluxes mean the presence of hydrogen-rich soils and have been interpreted as an indication on abundant water ice in these areas. The equatorial region of Mars (equatorward of approx. 50 deg) is characterized by higher fluxes of both epithermal (0.4 eV-100 keV, come from depth 1-2 m) and fast (3.4-7.3 MeV, come from depth 0.2-0.3 m) neutrons meaning that this area is mostly dry. The pattern of distribution of the neutron fluxes is in a good agreement with the theoretical predictions on the stability of ground ice on present Mars. The actual distribution of the ice, however, depends on variations of thermal inertia of soils and albedo of the surface. The flux of the epithermal neutrons detected by the HEND instrument, which is part of GRS, has two noticeable depressions in the equatorial region, one in Arabia Terra and another in the Medusae Fossae-Elysium region (MFER). Here we present the initial results of analysis of characteristics of the neutron fluxes and regional geological setting of the epithermal neutron depression in this area. The main goal of our study was to put some constraints on the time of the anomaly formation and to assess possible form of hydrogen (ground ice vs. chemically bound water) there.

Ivanov, M. A.↗

Phyllosilicate Deposits in Shalbatana Vallis

Shalbatana Vallis is an ancient river valley on Mars, the westernmost of the southern Chryse outflow channels. The geologic history of this area has significant implications for understanding Mars' hydrologic and climate history. The highland flood basalts are cut by large collapse depressions, multiple outflow channels, and chaotic terrain. An intravalley paleolake with a depth of over 400 m, in the 125 km diameter Orson Welles crater (Fig. 1) and the adjacent section of Shalbatana Vallis, was deduced from Mars Orbiter Laser Altimeter (MOLA) topography, evidence of shorelines and the occurrence of fan-delta deposits, including Gilbert-style deltas [1]. A number of CRISM (Compact Reconnaissance Imaging Spectrometer for Mars) images with strong phyllosilicate signatures have been identified throughout the channel and nearby highlands (Fig. 1). A majority of the signatures are concentrated in areas exposed by impact cratering. Since such minerals can form by a variety of different geological processes, such as weathering, burial diagenesis, and hydrothermal alteration [2], the nature of the phyllosilicate deposits in the Shalbatana Vallis region may provide insights into the formation processes that took place and help to place constraints on the early aqueous activity in the region.

Wintzer, Anne E.↗