Dependence of the kinetics of singlet-singlet energy transfer on spectral overlap.
Singlet-singlet energy transfer kinetics dependence on emission and absorption spectra overlap via dipole-dipole interaction
SEARCH · Engineering Papers
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Singlet-singlet energy transfer kinetics dependence on emission and absorption spectra overlap via dipole-dipole interaction
Galactic nucleus X ray source observations by Uhuru satellite, discussing emission and absorption spectra
Emission and absorption spectra of water vapor plasmas generated in a wall-stabilized arc at atmospheric pressure and 4 current, and at 0.03 atm and 15 to 50 A, were measured at high spatial and spectral resolution. The gas temperature was determined from the shape of Doppler-broadened rotational lines of OH. The observed nonequilibrium population distributions over the energy levels of atoms are interpreted in terms of a theoretical state model for diffusion-controlled arc plasmas. Excellent correlation is achieved between measured and predicted occupation of hydrogen energy levels. It is shown that the population distribution over the nonpredissociating rotational-vibrational levels of the A 2 Sigma state of OH is close to an equilibrium distribution at the gas temperature, although the total density of this state is much higher than its equilibrium density. The reduced intensities of the rotational lines originating in these levels yielded Boltzmann plots that were strictly linear.
A chemical analysis of the emission and absorption spectra in the combustion chamber of a nitrogen tetroxide/aerozine-50 rocket engine was conducted. Measurements were made under conditions of preignition, ignition, and post combustion operating periods. The cause of severe ignition overpressures sporadically observed during the vacuum startup of the Apollo reaction control system engine was investigated. The extent to which residual propellants or condensed intermediate reaction products remain after the engine has been operated in a pulse mode duty cycle was determined.
Survey of available information about the spectra of emission-line nuclei of planetary nebulae. The spectral features are classified into groups corresponding to WR, O VI, Of, and WR-Of types, and the observations are interpreted in terms of astrophysical processes occurring in these objects.
High resolution dynamic spectra of solar emissions in the range 80 to 20 MHz are discussed. The major features of observations described are (1) decametric storms, (2) type 3 bursts, and (3) time profile of type 3 bursts.
The bright visual-wavelength emission lines in spectra of filaments in the Crab Nebula cannot be used to derive unique values for the relative abundances of elements there, even under a simplifying assumption that heating is due entirely to photoionization by the Crab's nonthermal continuum. However, a range of possibilities may be estimated. By mass, helium is more abundant than hydrogen; but the mass fraction of heavier elements may be surprisingly small. Such conclusions are subject to modification if a noticeable fraction of the energy density involves fast particles around 1 MeV.
The observational techniques and results of IR measurements of the minor and trace molecular composition of the lower stratosphere are reviewed. Emphasis is given to those theoretical aspects of the formation of emission and absorption spectra which affect the quantitative interpretation of observational data in terms of the vertical distribution of observed molecular species. The principal experimental techniques currently being used are briefly reviewed, followed by a detailed summary of current knowledge of the abundances and spatial variability of the known minor constituents. The question of the determination of the minimum detectable concentration of a constituent molecule and its relationship to the instrumental parameters, the molecular transition intensities, and observation geometry is discussed; upper limit concentrations are given for some additional species of importance in current stratospheric studies.
A combined analytic and phenomenological approach, utilizing Maxwell's equations in the Born approximation with radiative transfer theory, is used to describe the propagation of microwave intensity in a scattering medium characterized by three-dimensional random fluctuations in refractive index, as well as nonrandom variations in permittivity, temperature, and loss. This approach yields microwave intensities as a function of polarization, direction, and position. Numerical techniques are presented to solve the transport equations, which include cases of spatially varying coefficients, and highly peaked phase functions. Some computed results illustrating the behavior of microwave intensity in various media are presented. Included are the angular and frequency spectra of thermal emission from semi-infinite media, and the diffuse transmission and reflection response of a scattering layer. The effects of scatterer geometry and scale sizes; correlation function; and gradients in temperature, loss, and scattering parameters are also demonstrated. This model should be particularly useful in interpreting active and passive remote sensing data.
Data for the stability of thin conductive indium tin oxide films on 0.003 inch thick Kapton substrates during exposure of the surface to electron beams are reported. The electron beam energy was 3 keV and the diameter was about 0.8 mm. Thermal effects and surface modifications are considered. For primary current greater than 0.6 microamperes, an obvious dark discoloration with diameter approximately that of the beam was produced. The structure of the discolored region was studied with the scanning electron microscope, and the findings are stated. Surface modifications were explored by AES, obtaining spectra and secondary emission coefficient as a function of time for different beam intensities. In all cases beam exposure results in a decrease of the secondary yield but because of thermal effects this change, as well as composition changes, cannot be directly interpreted in terms of electron beam dosage.
The thermal synchrotron (TS) interpretation of gamma-ray burst continuum spectra requires an emission region which is hot, optically thin, and possessed of a super-Eddington flux of 10 to the 30 ergs/sq cm per sec for a 10-km neutron star. In order to maintain a pair population close to the Maxwellian, the collision excitation rate into higher Landau levels must exceed the cyclotron decay rates. Even if collective processes whose rates are close to the electron plasma frequency, or scattering by heavy ions, are invoked, a particle density of 10 to the 25th/cu cm is still needed. Both hypotheses point in the direction of a dense but thin emitting sheet, to whose structure attention is presently given together with the generation, propagation and coupling of the electromagnetic energy fluxes. A flare-like model can account for most of gamma ray bursts' general features.
The chemical composition, emission and line spectra, and structure of comet nuclei, cometary atmospheres, and comet tails are discussed. The role of ultraviolet and infrared astronomy in defining comets is examined.
Two X-ray emitting cataclysmic variables were discovered as a result of a program to identify faint X-ray sources located by the HEAO-A3 modulation collimator experiment. The objects, H0534-581 and 1H0542-407, have similar high excitation spectra with intense emission lines showing broad and narrow components. Photometry shows that H0534-581 and 1H0542-407 have average magnitudes of V=14.9 and 15.7 respectively, leading to Lx/Lopt ratios of 1.5 (typical of dwarf novae in quiescence). While pronounced variability of delta B or = 1.5 mag is observed from both systems, there is no clear evidence for repeatable orbital periods between 1 and 4 hr.
A field portable spectrometer suitable for collecting data relevant to remote sensing applications in the 8 to 12 micrometer atmospheric window has been built at the Jet Propulsion Laboratory. The instrument employs a single cooled HgCdTe detector and a continuously variable filter wheel analyzer. The spectral range covered is 5 to 14.5 micrometers and the resolution is approximately 1.5 percent of the wavelength. A description of the hardware is followed by a discussion of the analysis of the spectral data leading to finished emissivity and radiance spectra. A section is devoted to the evaluation of the instrument performance with respect to spectral resolution, radiometric precision, and accuracy. Several examples of spectra acquired in the field are included.
Interference filters centered at 0.365, 0.387, 0.406, 0.484, and 0.514 microns have been selected to represent UV continuum, CN emission, C3 emission, blue continuum, and C2 emission in cometary spectra, respectively. Adopted magnitudes and colors of this filter system are presented for 50 standard stars, ranging in bue magnitude from 4 to 12, in spectral type from O to K, and distributed primarily around equatorial regins of the sky. The tabulated uncertainties are generally of the order of 0.02 mag or smaller; the zero points of the photometric system are chosen so that blue continuum magnitudes are approximately equivalent to Johnson B, and so that color indices average zero for solar analog stars.
A search for white dwarf companions of MS-type stars was conducted, using IUE. The overendowments of these stars in typical S-process nuclides suggest that they, like the Ba II stars, may owe their peculiar compositions to earlier mass transfer. Short-wavelength IUE spectra show striking emission line variability in HD35155, HD61913, and 4 Ori; HD35155 and 4 Ori show evidence of white dwarf companions.
A field portable spectrometer has been built at the Jet Propulsion Laboratory which is suitable for collecting data relevant to remote sensing applications in the 4.7- to 5.6- and 8- to 12-micrometer atmospheric windows. The instrument employs a single cooled HgCdTe detector and a continuously variable filter wheel analyzer. The spectral range covered is 5- to 14.5-micrometers and the resolution is approximately 1.5 percent of the wavelength. A description of the hardware is followed by a discussion of the data processing steps leading to emissivity and radiance spectra. A section is devoted to the evaluation of the instrument performance with respect to spectral resolution, radiometric precision, and accuracy. Several examples of spectra acquired in the field are included.
The first phase-resolved IUE observations of the AM Herculis system E1405-451 is reported. The spectra show bright emission lines from N V, C IV, and He II, whose centroids vary drastically during the 101.5 minute period. The radial velocities measured from the line centroids show a sinusoidal variation with a semiamplitude of 300 km/s. An explanation for the observed emission line velocities is considered using a model for the system having inclination i = 60 deg and magnetic colatitude Delta = 20 deg.