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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Application of powder metallurgy technique to produce improved bearing elements for cryogenic aerospace engine turbopumps

Traditionally, vacuum melted 440C stainless steel is used for high performance bearings for aerospace cryogenic systems where corrosion due to condensation is a major concern. For the Space Shuttle Main Engine (SSME), however, 440C performance in the high-pressure turbopumps has been marginal. A basic assumption of this study was that powder metallurgy, rather than cast/wrought, processing would provide the finest, most homogeneous bearing alloy structure. Preliminary testing of P/M alloys (hardness, corrosion resistance, wear resistance, fatigue resistance, and fracture toughness) was used to 'de-select' alloys which did perform as well as baseline 440C. Five out of eleven candidate materials (14-4/6V, X-405, MRC-2001, T-440V, and D-5) based on preliminary screening were selected for the actual rolling-sliding five-ball testing. The results of this test were compared with high-performance vacuum-melted M50 bearing steel. The results of the testing indicated outstanding performance of two P/M alloys, X-405 and MRC-2001, which eventually will be further evaluated by full-scale bearing testing.

Moxson, V. S.↗
NASA NTRS1989

Making Jointless Dual-Diameter Tubes

Welds between sections having different diameters eliminated. Single tube made with integral tapered transition section between straight sections of different diameters and wall thicknesses. Made from single piece; contains no joints, welded or otherwise. Not prone to such weld defects as voids and need not be inspected for them. Tube fabricated by either of two methods: drawing or reduction. Both methods used to fabricate tubes of 316L corrosion-resistant stainless steel for use as heat-exchanger coil.

Kirkham, Kathleen E.↗
NASA NTRS1989

The effects of hydrogen embrittlement of titanium

Titanium alloys, by virtue of their attractive strength to density ratio, fatigue, fracture toughness and corrosion resistance are now commonly used in various aerospace and marine applications. The cost, once very expensive, has been reduced, making titanium even more of a competitive material today. Titanium and titanium alloys have a great affinity to several elements. Hydrogen, even in small amounts, can cause embrittlement, which in turn causes a reduction in strength and ductility. The reduction of strength and ductility is the subject of this investigation.

Taylor, Delbert J.↗
NASA NTRS1989

Mass spectrometric observations of metal oxychlorides produced by oxidation-chlorination reactions

It was recently reported that Cr2O3-forming alloys show less corrosion resistance than Al2O3-forming alloys in Cl2/O2 mixtures, which is attributed to the formation of porous Cr2O3 scales and stable CrO2Cl2 vapor species. This paper reports the results of direct mass spectrometric observations with a high-pressure sampling mass spectrometer of these metal oxychlorides forming on the surfaces of Hastelloy S and Alloy 600 superalloys. Samples were preoxidized for 2 hrs at 900 C before the exposure to a O2/Ar gas mixture containing 1 percent Cl2. Results of X-ray diffraction showed scales containing Cr2O3 and NiCr2O4 on both alloys. After exposure to Cl2, large quantities of Cr2O2Cl2 were demonstrated for both alloys, indicating that this is a route for the breakdown of Cr2O3 scales. The Mo present in the Hastelloy S leads to more rapid attack by Cl2, resulting in the formation of MoO2Cl2.

Jacobson, N. S.↗
NASA NTRS1989

Potential applications of MMC and aluminum-lithium alloys in cameras for CRAF spacecraft

In undertaking the design of a 2000-mm focal length camera for the Mariner Mark II series of spacecraft, JPL sought novel materials with the requisite dimensional and thermal stability, outgassing and corrosion resistance, low mass, high stiffness, and moderate cost. Metal-matrix composites and Al-Li alloys have, in addition to excellent mechanical properties and low density, a suitably low coefficient of thermal expansion, high specific stiffness, and good electrical conductivity. The greatest single obstacle to application of these materials to camera structure design is noted to have been the lack of information regarding long-term dimensional stability.

Lane, Marc↗
NASA NTRS1990

Electrocatalysis for oxygen electrodes in fuel cells and water electrolyzers for space applications

The lead ruthenate pyrochlore Pb2Ru2O6.5, in both high- and low-area forms, has been characterized using thermogravimetric analysis, X-ray photoelectron spectroscopy, X-ray diffraction, cyclic voltammetry, and O2 reduction and generation kinetic-mechanistic studies. Mechanisms are proposed. Compounds in which part of the Ru is substituted with Ir have also been prepared. They exhibit somewhat better performance for O2 reduction in porous, gas-fed electrodes than the unsubstituted compound. The anodic corrosion resistance of pyrochlore-based porous electrodes was improved by using two different anionically conducting polymer overlayers, which slow down the diffusion of ruthenate and plumbate out of the electrode. The O2 generation performance was improved with both types of electrodes. With a hydrogel overlayer, the O2 reduction performance was also improved.

Prakash, Jai↗
NASA NTRS1991

Bonding Aramid Rope To Metal Fitting

Method for joining Kevlar (or equivalent) aramid rope to tubular corrosion-resistant steel end fitting increases strength of joint under tension to approximately three-fourths that of rope itself. End fitting contains internal thread, which provides good bonding surface. Small radial hole enables injection of adhesive into bore.

To, Dung T.↗
NASA NTRS1989

Evaluation of Composite Materials for Use on Launch Complexes

Commercially available composite structural shapes were evaluated for use. These composites, fiberglass-reinforced polyester and vinylester resin materials are being used extensively in the fabrication and construction of low maintenance, corrosion resistant structures. The evaluation found that in many applications these composite materials can be successfully used at the space center. These composite materials should not be used where they will be exposed to the hot exhaust plume/cloud of the launch vehicle during the liftoff, and caution should be taken in their use in areas where electrostatic discharge and hypergolic propellant compatibility are primary concerns.

Finchum, A.↗
NASA NTRS1990

A demonstration of chill block melt spinning of metal

One of the most exciting adventures in materials in recent times has been the discovery of amorphous metals and the pursuit of methods of manufacturing various alloys into various shapes which are amorphous. Some of these alloys possess electrical properties which are extremely beneficial, whereas others offer different benefits such as corrosion resistence and no solidification shrinkage anomalies. There are a number of techniques for producing such amorphous shapes, but one of the earliest systems used is referred to as chill block melt spinning. The object of this demonstration is to show the simplicity of the process. The equipment and procedures are described.

Pond, Robert B.↗
NASA NTRS1991

Dual ion beam processed diamondlike films for industrial applications

Single and dual beam ion source systems are used to generate amorphous diamondlike carbon (DLC) films, which were evaluated for a variety of applications including protective coatings on transmitting materials, power electronics as insulated gates and corrosion resistant barriers. A list of the desirable properties of DLC films along with potential applications are presented.

Mirtich, M. J.↗
NASA NTRS1990

Engineering, construction, and operations in space

The century-old Mond process for carbonyl extraction of metals from ore shows great promise as an efficient low energy scheme for producing high-purity Fe, Ni, Cr, Mn, and Co from lunar or asteroidal feedstocks. Scenarios for winning oxygen from the lunar regolith can be enhanced by carbonyl processing of the metallic alloy by-products of such operations. The native metal content of asteroidal regoliths is even more suitable to carbonyl processing. High-purity, corrosion resistant Fe and Ni can be extracted from asteroidial feedstocks along with a Co-rich residue containing 0.5 percent platinum-group metals. The resulting gaseous metal carbonyl can produce a variety of end products using efficient vapor forming techniques.

Johnson, Stewart W.↗
NASA NTRS1991

Effect of chromium and phosphorus on the physical properties of iron and titanium-based amorphous metallic alloy films

Amorphous iron and titanium-based alloys containing various amounts of chromium, phosphorus, and boron exhibit high corrosion resistance. Some physical properties of Fe and Ti-based metallic alloy films deposited on a glass substrate by a dc-magnetron sputtering technique are reported. The films were characterized using differential scanning calorimetry, stress analysis, SEM, XRD, SIMS, electron microprobe, and potentiodynamic polarization techniques.

Distefano, S.↗
NASA NTRS1992

Liquid/Gas Separator Handles Varying Loads

Liquid/gas separator includes two independent motors, one for pumping mixture and other for drawing off extracted gas. Two materials moved at speeds best suited for them. Liquid expelled radially outward from separator rotor. Entrained gas released, flows axially through rotor, and leaves through fan at downstream end. Unit developed to separate air from urine in spacecraft wastewater-treatment system, also functions in normal gravity. Made largely of titanium to resist corrosion.

Mann, John↗
NASA NTRS1992

Leak Stopper For Metal-To-Metal Tube Fittings

Plastic-coated steel device is conformal and strong. Washerlike seal stops leakage at Dynatube(TM) joints between metal tubes. Made to resist corrosion, seal aligns itself in joint for maximum effectiveness.

Trevathan, Joseph R.↗
NASA NTRS1991

Thermoviscoplastic response of Ti-15-3 under various loading conditions

Metal matrix composites (MMC's) are candidate materials for use in high temperature, high loading applications. In particular, an MMC consisting of a titanium alloy reinforced with silicon-carbide fibers is being considered for use on the National Aerospace Plane (NASP). Compared to other metals and metallic alloys, titanium alloys retain relatively high stiffness, strength, and corrosion resistance at elevated temperatures. However, above roughly 316 C titanium exhibits a significant thermoviscoplastic (creep) response. Since the temperatures encountered in many regions of the NASP are expected to exceed 316 C, the potential thermoviscoplastic behavior of titanium-based MMC's at elevated temperatures must be thoroughly investigated.

Tuttle, M. E.↗
NASA NTRS1992

Mach 6 electroformed nickel nozzle refurbishment: FNAS investigation of ultra-smooth surfaces

The task objective has been to apply a coating of nickel-phosphorous alloy to a laminar flow wind tunnel nozzle by catalytic deposition and then polish and inspect the inside surface using optical device processes. The surface of the nozzle was coated with a nickel-phosphorous alloy of sufficient hardness and corrosion resistance to improve the durability. Due to plating defects that were clearly process related and not inherent, the final polished part was less than the desired quality. Surface finishing processes and lapping media were identified which produced a submicron surface finish on the interior plated surface. Defects apparently manifested by the first plating attempt were repaired using a small brush plating process demonstrating that individual small defects can be repaired. Measurement and analysis by profilometry demonstrated that quantitative control of the surface can be achieved.

Rood, Robert↗
NASA NTRS1991

Oxynitride glass fibers

Research at the Army Materials Technology Laboratory (AMTL) and elsewhere has shown that many glass properties including elastic modulus, hardness, and corrosion resistance are improved markedly by the substitution of nitrogen for oxygen in the glass structure. Oxynitride glasses, therefore, offer exciting opportunities for making high modulus, high strength fibers. Processes for making oxynitride glasses and fibers of glass compositions similar to commercial oxide glasses, but with considerable enhanced properties, are discussed. We have made glasses with elastic moduli as high as 140 GPa and fibers with moduli of 120 GPa and tensile strengths up to 2900 MPa. AMTL holds a U.S. patent on oxynitride glass fibers, and this presentation discusses a unique process for drawing small diameter oxynitride glass fibers at high drawing rates. Fibers are drawn through a nozzle from molten glass in a molybdenum crucible at 1550 C. The crucible is situated in a furnace chamber in flowing nitrogen, and the fiber is wound in air outside of the chamber, making the process straightforward and commercially feasible. Strengths were considerably improved by improving glass quality to minimize internal defects. Though the fiber strengths were comparable with oxide fibers, work is currently in progress to further improve the elastic modulus and strength of fibers. The high elastic modulus of oxynitride glasses indicate their potential for making fibers with tensile strengths surpassing any oxide glass fibers, and we hope to realize that potential in the near future.

Patel, Parimal J.↗
NASA NTRS1992

Composite overwrapped nickel-hydrogen pressure vessels

The presentation is made in viewgraph format, the first of which states the purpose, which is to stimulate interest in composite overwrapped pressure vessel technology as applied to nickel hydrogen battery pressure vessels. The next viewgraph presents the history of nickel hydrogen pressure vessels over the last 15 years including materials, operating conditions, and market expansion to internationals. Basic materials properties are itemized such as thermal conductivity, corrosion resistance, and strength to weight ratio. The monolithic and composite overwrapped construction approaches are compared. A detailed description is presented of the advantages of composite overwrapped pressure vessels showing weight savings, manufacturing schedule reductions, and improved fatigue life. A discussion is also presented of B-1 application, the wide range of usable materials, and a sketch of a possible optimized design.

Reagan, John↗