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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Modular Staged Pressurized Oxy-Combustion (SPOC) Power Plant for Coal and Biomass – Integration of Combustor Boiler and DCC

Utilities and grid operators worldwide are under significant pressure to incorporate intermittent renewable sources while strategizing on how to maintain the necessary stability and reliability of the grid. The development of a power plant which will be capable of flexible operation to meet the needs of the grid as more intermittent sources like wind and solar energy are incorporated is key to maintain the reliability of the grid. Through the use of innovative and cutting-edge technologies that improve efficiency and reduce carbon emissions, and being small compared to today's conventional utility-scale power plants, the modular Staged, Pressurized Oxy-Combustion (SPOC) process envisioned by and under development at Washington University in St. Louis (WUSTL) has the potential to achieve these goals. Specifically, the process offers: 1) a modular plant design that allows for better operational flexibility; 2) the utilization of fuel-staging and pressurized oxy-combustion, resulting in smaller plant size, improved plant efficiency, and reduced costs for pollutant and CO2 removal compared to traditional power plants with post-combustion capture technology; and 3) the use of small modular boilers and pollutant removal units that can be constructed off-site leading to reduced capital costs for the plant. WUSTL is advancing the development of the critical components for the SPOC power plant, including the integrated combustor-boiler system and the direct contact cooler. To demonstrate the boiler convective section and to obtain critical data for commercial-scale pressurized boiler design, a simulated convective heat transfer boiler test section was designed and integrated with the combustor (radiant section). A direct contact cooler (DCC) was integrated with the combustor-boiler to demonstrate the dynamic operation of the integrated system and the performance of the DCC, including the efficiency for simultaneous removal of NOx and SOx. This talk will present an update on the evaluation of the critical components for system integration, including heat transfer data from the simulated boiler, scrubbing efficiency for the DCC under different operating conditions, and CFD modeling and validation for burner and boiler development.

Magalhaes, Duarte↗
DOE OSTI2023

Development of the Modular Staged Pressurized Oxy-Combustion (SPOC) Power Plant for Coal and Biomass

Critical to the future of power generation is the development of a power plant that will be capable of flexible operation to meet the needs of the modern grid, providing resilient, low-emissions power to a grid that is increasingly seeing a large penetration of intermittent wind and solar. The modular Staged, Pressurized Oxy-Combustion (SPOC) process envisioned by and under development at Washington University in St. Louis (WUSTL) has the potential to achieve these goals. The process offers: 1) a modular plant design for improved operational flexibility; 2) fuel-staging combined with pressurized oxy-combustion, which leads to smaller plant size, higher plant efficiency, and lower cost for pollutant and greenhouse gases removal compared with traditional carbon-capture equipped coal power plants; and 3) small modular boilers and pollutant removal units that can be fabricated in shop and assembled on site, further reducing plant capital costs. Under DOE's support (DE-FE0031925), WUSTL is advancing the development of the critical components for the SPOC power plant, including the integrated combustion system and the direct contact cooler (DCC) from Technology Readiness Level (TRL) 4 to TRL-5, which would allow these technologies to be subsequently incorporated into a pilot plant. This talk will present an overview of the SPOC technology, CFD modeling and validation for burner and boiler development, and recent results to evaluate critical components needed to advance its TRL.

Magalhaes, Duarte↗
DOE OSTI2024

A Novel Dew Point Meter: Application to the Measurement of the Sulfuric Acid Dew Point for Combustion Flue Gas

Accurate knowledge of acid dew point is essential for industrial and applied combustion applications. Sulfur in the fuel or raw materials is converted to sulfur dioxide (SO2) during combustion, and a portion of the SO2 is oxidized to sulfur trioxide (SO3). The SO3 will react to form H2SO4 vapor when in the presence of water vapor. Even with just trace levels of H2SO4 vapor in the gas phase (1-10 ppm), the dew point can reach 100°C and higher. To avoid acid condensation and the resulting corrosion on heat recovery equipment, plant engineers must ensure that surface temperatures are above the acid dew point, but this decreases the efficiency of thermal energy recovery. Thus, there is a trade-off between minimizing equipment corrosion and maximizing thermal energy recovery, and the acid dew point is a key parameter for this optimization. Commercially available acid dew point meters use electric conductivity sensors. These sensors are known to greatly underestimate the dew point due to their low sensitivity. In addition, no validation testing has been reported for these units and they are often expensive. In this work, we analyze the theory of the sulfuric acid condensation and develop a novel dew point meter based on this analysis. The meter consists of a novel optical instrument that is designed to monitor the slightest appearance of condensation on a hydrophobic window surface as the surface temperature of the window is slowly decreased. In this way, an accurate measurement of the dew point is obtained under a wide range of concentrations. The basis of the instrument is that a collimated beam from a diode laser will generate forward scattered light when the beam encounters surface condensate, and a sophisticated array detector is used to sensitively monitor the onset of light scattering. The measurement procedures are established to rapidly find the acid dew point, while minimizing error. Further, to calibrate the dew point meter we developed a calibration system based on a liquid bubbler that can generate a stable gas flow with a known sulfuric acid dew point. Test results show that the dew point meter can accurately measure acid dew point over a wide range. For H2SO4 vapor concentrations as low as 6 ppm the acid dew point is measured with an error of only ~1°C. To demonstrate the versatility of this instrument, the dew point meter was adapted for use with a high-pressure flow cell to allow for measurements of the dew point of flue gas from pressurized oxy-fuel combustion in a 100 kWth pressurized reactor.

Cheng, Mao↗
DOE OSTI2025

Internally Catalyzed Hydrogen Atom Transfer (I-CHAT)—A New Class of Reactions in Combustion Chemistry

The current paradigm of low-T combustion and autoignition of hydrocarbons is based on the sequential two-step oxygenation of fuel radicals. The key chain-branching occurs when the second oxygenation adduct (OOQOOH) is isomerized releasing an OH radical and a key ketohydroperoxide (KHP) intermediate. The subsequent homolytic dissociation of relatively weak O–O bonds in KHP generates two more radicals in the oxidation chain leading to ignition. Based on the recently introduced intramolecular “catalytic hydrogen atom transfer” mechanism (J. Phys. Chem. 2024, 128, 2169), abbreviated here as I-CHAT, we have identified a novel unimolecular decomposition channel for KHPs to form their classical isomers—enol hydroperoxides (EHP). The uncertainty in the contribution of enols is typically due to the high computed barriers for conventional (“direct”) keto–enol tautomerization. Remarkably, the I-CHAT dramatically reduces such barriers. The novel mechanism can be regarded as an intramolecular version of the intermolecular relay transfer of H-atoms mediated by an external molecule following the general classification of such processes (Catal. Rev.-Sci. Eng. 2014, 56, 403). Here, we present a detailed mechanistic and kinetic analysis of the I-CHAT-facilitated pathways applied to n-hexane, n-heptane, and n-pentane models as prototype molecules for gasoline, diesel, and hybrid rocket fuels. We particularly examined the formation kinetics and subsequent dissociation of the γ-enol-hydroperoxide isomer of the most abundant pentane-derived isomer γ-C5-KHP observed experimentally. To gain molecular-level insight into the I-CHAT catalysis, we have also explored the role of the internal catalyst moieties using truncated models. All applied models demonstrated a significant reduction in the isomerization barriers, primarily due to the decreased ring strain in transition states. In addition, the longer-range and sequential H-migration processes were also identified and illustrated via a combined double keto–enol conversion of heptane-2,6-diketo-4-hydroperoxide as a potential chain-branching model. To assess the possible impact of the I-CHAT channels on global fuel combustion characteristics, we performed a detailed kinetic analysis of the isomerization and decomposition of γ-C5-KHP comparing I-CHAT with key alternative reactions—direct dissociation and Korcek channels. Calculated rate parameters were implemented into a modified version of the n-pentane kinetic model developed earlier using RMG automated model generation tools (ACS Omega, 2023, 8, 4908). Simulations of ignition delay times revealed the significant effect of the new pathways, suggesting an important role of the I-CHAT pathways in the low-T combustion of large alkanes.

Biochemistry & Molecular Biology↗
DOE OSTI2020

Screening of Potential Biomass-Derived Streams as Fuel Blendstocks for Mixing Controlled Compression Ignition Combustion

Mixing controlled compression ignition or diesel engines are highly efficient and are likely to continue to be the primary means for movement of goods for many years to come. Low-carbon biofuels have the potential to significantly reduce the carbon footprint of diesel combustion and could potentially have advantageous properties for combustion such as high cetane number and reduced engine out particle emissions. In this study, we developed a list of potential biomass-derived diesel blendstocks. An online database of properties and characteristics of these bioblendstocks was populated with data. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the basic requirements for handling in the diesel distribution system and use as a blend with conventional diesel. Criteria included cetane number =40, flashpoint =52 degrees C, and boiling point or final boiling point <338 degrees C. Blendstocks needed to be soluble in diesel fuel, have a toxicity no worse than conventional diesel, and not be corrosive. Additionally, cloud point or freezing point below 0 degrees C was required. This screening produced a list of 27 potential bioblendstocks. Of these candidates, 13 were available commercially or could be synthesized by biofuels production researchers and included 11 nominally pure components and two mixtures. These 13 candidates were then subjected to further study based on how they impact fuel properties upon blending. Blend properties included cetane number, lubricity, conductivity, oxidation stability and viscosity. Results indicate that all thirteen candidates can meet the basic requirements for diesel fuel blending and are likely to reduce particle emissions from diesel combustion.

09 BIOMASS FUELS↗
DOE OSTI2023

Performance, Combustion and Emissions Evaluation of Liquid Phase Port-Injected LPG on a Single Cylinder Heavy-Duty Spark Ignited Engine

Liquefied petroleum gas (LPG), like many other alternative fuels, has witnessed increased adoption in the last decade, and its use is projected to rise as stricter emissions regulations continue to be applied. However, much of its use is limited to dual fuel applications, gaseous phase injection, light-duty passenger vehicle applications, or scenarios that require conversion from gasoline engines. Therefore, to address these limitations and discover the most efficient means of harnessing its full potential, more research is required in the development of optimized fuel injection equipment for liquid port and direct injection, along with the implementation of advanced combustion strategies that will improve its thermal efficiency to the levels of conventional fuels. This paper focuses on the development of a liquid phase port-injection system for LPG, the design of a reference piston, and the baseline evaluation of the performance, combustion, and emissions characteristics of a single cylinder research engine to establish a benchmark comparable to existing LPG engines. A sweep of start of injection (SOI) timing is performed by injecting liquid LPG at several closed and open intake valve timings, which demonstrates no significant variation in engine performance, but accounts for a 10% reduction in bsCO with the optimal SOI timing. Spark timing sweep demonstrates the 50% burn crank angle location related to maximum brake torque (MBT) point with a brake thermal efficiency (BTE) of ~34% for the tested load case. The effect of equivalence ratio is also presented with optimal SOI timing at MBT condition. The engine starts exhibiting knocking combustion at 140kPa intake manifold air pressure (IMAP) with a peak torque of 253Nm and a 5% reduction in brake specific fuel consumption compared to the naturally aspirated scenario.

Fosudo, Toluwalase↗
DOE OSTI2026

Methanol mixing controlled combustion process enabled by methanol dehydration to dimethyl ether

This work demonstrates an initial proof-of-concept approach for operating a compression ignition off-road and marine relevant engine using neat methanol. The approach utilizes mixing controlled compression ignition (MCCI) of methanol that is enabled by a homogeneous charge compression ignition (HCCI) pre-burn of premixed dimethyl ether (DME). Although two fuels are used, this work explores and evaluates the opportunity and performance to generate the premixed fuel via. methanol catalytic dehydration over an alumina catalyst at engine relevant temperatures, pressures, and space velocities. Conversion purity and species output results from catalytic dehydration bench flow reactor studies were coupled with single cylinder experiments of the characterized output species for pre-burn HCCI performance. Subsequent initial methanol MCCI performance is also evaluated and compared relative to conventional diesel combustion. The detailed flow reactor results show that the catalytic dehydration conversion efficiency of methanol to DME is a function of system pressure, temperature, and space velocity. The engine results demonstrate that a 100% conversion of methanol to DME is not required for successful pre-burn HCCI, and the water formed during the dehydration process does not need to be removed to achieve the desired HCCI event from this pre-burn mixture. Subsequent methanol MCCI combustion results show that the level of methanol slip in the dehydration process affects the pre-burn HCCI phasing, low temperature heat release process, and magnitude of energy released, all of which can dictate the available window for direct injection of methanol for MCCI combustion.

Jatana, Gurneesh [ORNL] (ORCID:0000000288903225)↗
NASA NTRS1968

Survey of the Relationship Between Theory and Experiment for Convective Heat Transfer From Rocket Combustion Gases

The problem of predicting the distribution of heat flux in a rocket engine is complicated by a flow field and thermodynamics so perturbed by as yet indescribable combustion effects that it continues to be necessary to utilize a simplified theoretical model against which to compare experimental results in order to gain insight. The most successful model applied to this problem is that of a compressible, turbulent, accelerating boundary layer flow with an arbitrary point of origin, and chemical reaction restricted to equilibrium recombination or diffusion-limited recombination on a catalytic wall. Analysis of this model was not possible without making several assumptions about the nature of the skin friction coefficient relationship and Reynold's analogy in an accelerating boundary layer flow. The paper summarizes the analysis of this model (together with detailed treatment of the special problems of variable properties, chemical reaction, and sources of transport properties), and describes several closed-form equations that have also been developed and applied to the problem. Described are results of several experiments with hot air flow made for the purpose of checking the validity of the assumptions in the boundary layer analysis. Most significant, however, are presentations of sample distributions of local heat flux measured in rocket engines operating with a wide range of conditions, propellants, injectors and sizes. When compared with predictions, these data show the significant range of deviation in heat flux that results from the combustion effects and which precludes a generally accurate prediction theory or correlation equation until the combustion process itself is correlated.

D R Bartz↗
NASA NTRS1971

The combustion process

The effect of thermodynamic, chemical, and physical properties on the combustion of materials is discussed. The mechanisms which produce and support combustion of various materials are examined. The effects of free radical reactions, convection and gravitational effects on combustion rates, and changes in flame propagation due to size and shape of surfaces are described.

Downs, W. R.↗
NASA NTRS1972

Some effects of swirl on turbulent mixing and combustion

A general formulation of some effects of swirl on turbulent mixing is given. The basis for the analysis is that momentum transport is enhanced by turbulence resulting from rotational instability of the fluid field. An appropriate form for the turbulent eddy viscosity is obtained by mixing length type arguments. The result takes the form of a corrective factor that is a function of the swirl and acts to increase the eddy viscosity. The factor is based upon the initial mixing conditions implying that the rotational turbulence decays in a manner similar to that of free shear turbulence. Existing experimental data for free jet combustion are adequately matched by using the modifying factor to relate the effects of swirl on eddy viscosity. The model is extended and applied to the supersonic combustion of a ring jet of hydrogen injected into a constant area annular air stream. The computations demonstrate that swirling the flow could: (1) reduce the burning length by one half, (2) result in more uniform burning across the annulus width, and (3) open the possibility of optimization of the combustion characteristics by locating the fuel jet between the inner wall and center of the annulus width.

Rubel, A.↗
NASA NTRS1971

The combustion of pure and composite propellants - The expansion and application of laminar flame theory to heterogeneous solid propellants.

Development of a combustion theory based on the laminarized solutions to the energy and flow conservation equations, which is more realistic in recognizing the nature of the heating-rate problem and in obtaining a practical solution to estimating its magnitude. A new experimental approach is used for studying the combustion behavior of pure monopropellants and composite propellants which uses a laser beam to supply additional heat feedback to a burning surface. New experimental data are presented for the laser-induced combustion rate and ignition delay of pure ammonium perchlorate. The pure monopropellant theory is generalized to include such nonadiabatic effects, and the new experimental data are in good agreement with the nonadiabatic theory.-

Hertzberg, M.↗
NASA NTRS1972

Flame spectra of solid propellants during unstable combustion.

The spectral and temporal details of the flames of a series of ammonium perchlorate-polyurethane propellants during both unstable and stable combustion were observed experimentally. A 400-scan per second optical spectrometer operating in the middle infrared region was used. During unstable combustion at low ratios of chamber free volume to nozzle throat area, three different frequencies were observed simultaneously. These were attributable to at least two mechanisms. During stable combustion periodic fluctuations in flame temperature and composition were also observed. Some aspects of theory of bulk mode instability were confirmed, but the assumptions of constant flame temperature and constant composition were found to be inaccurate.

Eisel, J. L.↗
NASA NTRS1972

Effects of rotating flows on combustion and jet noise.

Experimental investigations of combustion in rotating (swirling) flow have shown that the mixing and combustion processes were accelerated, flame length and noise levels significantly decreased, and flame stability increased relative to that obtained without rotation. Unsteady burning accompanied by a pulsating flame, violent fluctuating jet, and intense noise present in straight flow burning were not present in rotating flow burning. Correlations between theory and experiment show good agreement. Such effects due to rotating flows could lead to suppressing jet noise, improving combustion, reducing pollution, and decreasing aircraft engine size. Quantitative analysis of the aero-acoustic relationship and noise source characteristics are needed.-

Schwartz, I. R.↗
NASA NTRS1973

Experimental verification of computer spray-combustion models

Analytical model formulation, representing performance of spray-combustion device, is based on understanding of atomization, mixing, vaporization, and combustion which occurs in device. Report lists results of correlations of computed values with values obtained from experiments with rocket combustor. Technique offers excellent method for evaluating validity and ranges of applicability of combustion models.

Nurick, W. H.↗
NASA NTRS1973

Design handbook for gaseous fuel engine injectors and combustion chambers

Results of investigation of injection, mixing, and combustion processes using gaseous fuels and oxidizers have been summarized in handbook presenting succinct design procedures for injectors and methods for estimating combustion efficiency, chamber heat flux and stability characteristics. Handbook presents two approaches to injector and combustion chamber design: empirical and analytical.

Calhoon, D. F.↗
NASA NTRS1972

Some considerations in the combustion of AP/composite propellants

Theoretical studies are presented on the time-independent and oscillatory combustion of nonmetallized AP/composite propellants. Three hypotheses are introduced: (1) The extent of propellant degradation at the vaporization step has to be specified through a scientific criterion. (2) The condensed phase degradation reaction of ammonium perchlorate to a vaporizable state is the overall rate-limiting step. (3) Gas phase combustion rate is controlled by the mixing rate of fuel and oxidizer vapors. In the treatment of oscillatory combustion, the assumption of quasi-steady fluctuations in the gas phase is used to supplement these hypotheses. In comparison with experimental data, this study predicts several of the observations including a few that remain inconsistent with theoretical results.

Kumar, R. N.↗
NASA NTRS1973

Research on ignition and combustion in oxygen systems

The work on ignition and combustion research in oxygen systems under the sponsorship of NASA's Aerospace Safety Research and Data Institute is described. Preliminary results of ignition of nonmetallic materials by electric arc and mechanical impact are presented. Ignition by a resonant process involving repeated shock waves has been demonstrated and some of the results included. In addition, results of studies concerned with ignition due to the rapid rupture of metal films and diaphragms are reviewed. Burning rate studies of three nonmetallic materials in oxygen enriched environments were completed and the results presented. A brief description of these combustion studies under zero gravity is also included. These results are compared to combustion under one gravity.

Ordin, P. M.↗
NASA NTRS1973

Handbook of infrared radiation from combustion gases

The treatment of radiant emission and absorption by combustion gases are discussed. Typical applications include: (1) rocket combustion chambers and exhausts, (2) turbojet engines and exhausts, and (3) industrial furnaces. Some mention is made of radiant heat transfer problems in planetary atmospheres, in stellar atmospheres, and in reentry plasmas. Particular consideration is given to the temperature range from 500K to 3000K and the pressure range from 0.001 atmosphere to 30 atmospheres. Strong emphasis is given to the combustion products of hydrocarbon fuels with oxygen, specifically to carbon dioxide, water vapor, and carbon monoxide. In addition, species such as HF, HC1, CN, OH, and NO are treated.

Ludwig, C. B.↗