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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Single pilot IFR accident data analysis

The aircraft accident data recorded and maintained by the National Transportation Safety Board for 1964 to 1979 were analyzed to determine what problems exist in the general aviation single pilot instrument flight rules environment. A previous study conducted in 1978 for the years 1964 to 1975 provided a basis for comparison. The purpose was to determine what changes, if any, have occurred in trends and cause-effect relationships reported in the earlier study. The increasing numbers have been tied to measures of activity to produce accident rates which in turn were analyzed in terms of change. Where anomalies or unusually high accident rates were encountered, further analysis was conducted to isolate pertinent patterns of cause factors and/or experience levels of involved pilots. The bulk of the effort addresses accidents in the landing phase of operations. A detailed analysis was performed on controlled/uncontrolled collisions and their unique attributes delineated. Estimates of day vs. night general aviation activity and accident rates were obtained.

Harris, D. F.↗
DOE OSTI2015

Ion thermal and dispersion effects in Farley-Buneman instabilities

Farley-Buneman modes are an example of the collisional instability, which is thought to be the dominant mechanism for the irregularities in low ionosphere region. Despite high collisionality due to electron-neutral and ion-neutral collisions, the kinetic effects associated with finite temperature are important for determination of the mode frequencies and growth rate. This is especially important for ion component that is largely unmagnetized due to low ion cyclotron frequency. The ion thermal effects are strongly pronounced for shorter wavelengths and are crucial for the growth rate cut-off at high wavenumbers. We develop an extended fluid model for ion dynamics to incorporate the effects of ion thermal motion. The model is based on the extended MHD model that includes the evolution equations for higher order moments such as ion viscosity and ion heat flux. We also develop the generalized Chapman-Enskog closure model that provides exact linear closures based on the linearized kinetic equation. The results of these models are compared and tested against the linear kinetic model. The dispersion of Farley-Buneman modes and growth rate behavior are investigated in the short wavelength region.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1991

Association reactions at low pressure. IV - The HC3N(+)/HC3N system

Ion cyclotron mass spectrometry is used here to study the reactions between HC3N(+) and HC3N and between HC5N(+) and HC3N at pressures from 1 x 10 to the -7th to 0.001 Torr. The former reaction has both a bimolecular reaction path and a termolecular reaction path. The overall bimolecular reaction rate coefficient is 1.3 x 10 to the -19 cu cm/s. The primary product HC5N(+) represents 90 percent of the product ions, while HC6N2(+) and H2C6N2(+) each represent 5 percent. The termolecular association rate coefficient is 3.7 x 10 to the -24th cm exp 6/s, with He as the third body. The mean lifetime of the collision is 180 microsec. HC5N(+) reacts with HC3N to form the adduct ion H2C8N2(+) through both bimolecular and termolecular reactions. The bimolecular rate coefficient is 5.0 x 10 to the -10th cu cm/s and the termolecular one is 1.2 x 10 to the -22nd cm exp 6/s, with HC3N as the third body.

Sen, Atish D.↗
NASA NTRS2015

Numerical Simulations of the XR-5 Hall Thruster for Life Assessment at Different Operating Conditions

NASA's Jet Propulsion Laboratory has been investigating the applicability of Aerojet Rocketdyne's XR-5 thruster, a 4.5 kW class Hall thruster, for deep-space missions. Major considerations for qualifying the XR-5 for deep-space missions are demonstration of a wide throttling envelope and a usable life capability in excess of 10,000 h. Numerical simulations with the 2-D axisymmetric code Hall2De are employed to inform the qualification process by assessing erosion rates at the thruster surfaces in a wide range of throttling conditions without the need for conducting costly endurance testing. In previous work at JPL by Jorns et al., the anomalous collision frequency distribution for 11 different throttling conditions of the XR-5 spanning 0.3-4.5 kW were identified based on probe measurements of the electron temperature in the near plume region. In this paper, we provide estimates for the erosion rates at the channel walls and pole covers for the same 11 conditions. Uncertainties in the plasma measurements and in the anomalous collision frequency distribution are addressed by determining upper and lower bounds of the erosion rates. Results suggest that erosion of the walls only occurs in the last 5% of the acceleration channel and the rate of such erosion decreases as the geometry of the thruster changes in time due to magnetic shielding. A quasi-zero-erosion state is eventually achieved in all the examined throttling conditions. Examination of the results for pole surface erosion and estimated cathode life indicates that the XR-5 propellant throughput capability will exceed 700 kg, which provides 50% margin over the usable throughput capability of 466 kg as already demonstrated in wear testing.

Lopez Ortega, Alejandro↗
DOE OSTI2014

Comparison of Aleph and BOLSIG+ Results for Electron-Nitrogen Chemistry

The goal of this report is to document the current status of Aleph with regards to electron collisions under an electric field. Aleph and the community-accepted BOLSIG+ code are both used to compute reactions rates for a set of 25 electron-nitrogen interactions. A reasonable comparison is found (see below) providing evidence that Aleph is successfully simulating or implementing: (1) Particle-particle collision cross-sections via DSMC methodology, (2) Energy balance for simple particle interactions, and (3) Electron energy distribution function (EEDF) evolution

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2017

On the reaction of muon transfer from protium to neon at low collision energies

The reaction of direct muon transfer from protium to neon at thermal collision energies is considered. The question of whether it is possible to reconstruct the energy dependence of the reaction rate on the basis of available experimental data is discussed. A model based on the following two assumptions is proposed: (i) The reaction in question proceeds within an interaction sphere beyond which the entrance channel and the muon-transfer channel decouple. (ii) For s and p waves, the complex logarithmic derivatives of radial wave functions for the entrance channel at the surface of the interaction sphere are independent of energy at low collision energies. Two logarithmic-derivative values that comply with experimental data on the reaction rate at the temperatures of 20 and 300 К are found upon taking into account the s-wave contribution alone. In this temperature range, the reaction rates calculated at the resulting two values do not differ substantially. Sizable distinctions arise only at temperatures of a few kelvin units. The problem of choosing one specific value of the logarithmic derivative is solved by comparing the energy dependence of the S matrix with the results of an earlier calculation. Thereby, the proposed procedure can be viewed as a means for correcting calculations in the low-energy region.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Primordial black holes from bubble collisions during a first-order phase transition

We study the possibility of production of primordial black holes (PBHs) from bubble collisions during a first-order phase transition. While typical colliding bubbles are small and irrelevant for PBH production, we find that those that can produce PBHs must have a macroscopically thick fluid shell and have been born much before the typical nucleation time. Particularly large uncertainties arise from an exponential sensitivity of the nucleation rate on the required duration of bubble growth which depends on the details of the collisions and the evolution of the spacetime metric toward the end of the phase transition. We introduce a few parameters to be obtained from future numerical simulation to represent those unknowns, and estimate the PBH abundance in an Abelian Higgs benchmark model and show that it can be significant. We predict an approximately monochromatic PBH mass spectrum, and find regions in the parameter space where the PBHs can constitute entire dark matter or even overclose the Universe. Our result thus shows that models with a first-order phase transition can be constrained by overabundant PBHs or null results of other PBH searches. Published by the American Physical Society 2024

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1974

A model for accretion of the terrestrial planets

One possible origin of the terrestrial planets involves their formation by gravitational accretion of particles originally in Keplerian orbits about the sun. Some implications of this theory are considered. A formal expression for the rate of mass accretion by a planet is developed. The formal singularity of the gravitational collision cross section for low relative velocities is shown to be without physical significance when the accreting bodies are in heliocentric orbits. The distribution of particle velocities relative to an accreting planet is considered; the mean velocity increases with time. The internal temperature of an accreting planet is shown to depend simply on the accretion rate. A simple and physically reasonable approximate expression for a planetary accretion rate is proposed.

Weidenschilling, S. J.↗
DOE OSTI2014

Dynamics of gas phase Ne{sup *} + NH{sub 3} and Ne{sup *} + ND{sub 3} Penning ionisation at low temperatures

Two isotopic chemical reactions, Ne{sup *} + NH{sub 3}, and Ne{sup *} + ND{sub 3}, have been studied at low collision energies by means of a merged beams technique. Partial cross sections have been recorded for the two reactive channels, namely, Ne{sup *} + NH{sub 3} → Ne + NH{sub 3}{sup +} + e{sup −}, and Ne{sup *} + NH{sub 3} → Ne + NH{sub 2}{sup +}+ H + e{sup −}, by detecting the NH{sub 3}{sup +} and NH{sub 2}{sup +} product ions, respectively. The cross sections for both reactions were found to increase with decreasing collision energy, E{sub coll}, in the range 8 μeV < E{sub coll} < 20 meV. The measured rate constant exhibits a curvature in a log(k)-log(E{sub coll}) plot from which it is concluded that the Langevin capture model does not properly describe the Ne{sup *} + NH{sub 3} reaction in the entire range of collision energies covered here. Calculations based on multichannel quantum defect theory were performed to reproduce and interpret the experimental results. Good agreement was obtained by including long range van der Waals interactions combined with a 6-12 Lennard-Jones potential. The branching ratio between the two reactive channels, Γ=([NH{sub 2}{sup +}])/([NH{sub 2}{sup +}]+[NH{sub 3}{sup +}]) , is relatively constant, Γ ≈ 0.3, in the entire collision energy range studied here. Possible reasons for this observation are discussed and rationalized in terms of relative time scales of the reactant approach and the molecular rotation. Isotopic differences between the Ne{sup *} + NH{sub 3} and Ne{sup *} + ND{sub 3} reactions are small, as suggested by nearly equal branching ratios and cross sections for the two reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2015

A Symmetric Time-Varying Cluster Rate of Descent Model

A model of the time-varying rate of descent of the Orion vehicle was developed based on the observed correlation between canopy projected area and drag coefficient. This initial version of the model assumes cluster symmetry and only varies the vertical component of velocity. The cluster fly-out angle is modeled as a series of sine waves based on flight test data. The projected area of each canopy is synchronized with the primary fly-out angle mode. The sudden loss of projected area during canopy collisions is modeled at minimum fly-out angles, leading to brief increases in rate of descent. The cluster geometry is converted to drag coefficient using empirically derived constants. A more complete model is under development, which computes the aerodynamic response of each canopy to its local incidence angle.

Ray, Eric S.↗
NASA NTRS2012

The Kinematic and Microphysical Control of Storm Integrated Lightning Flash Extent

The objective of this preliminary study is to investigate the kinematic and microphysical control of lightning properties, particularly those that may govern the production of nitrogen oxides (NOx) in thunderstorms, such as flash rate, type and extent. The mixed-phase region is where the noninductive charging (NIC) process is thought to generate most storm electrification during rebounding collisions between ice particles in the presence of supercooled water. As a result, prior radar-based studies have demonstrated that lightning flash rate is well correlated to kinematic and microphysical properties in the mixed-phase region of thunderstorms such as updraft volume, graupel mass, or ice mass flux. There is also some evidence that lightning type is associated with the convective state. Intracloud (IC) lightning tends to dominate during the updraft accumulation of precipitation ice mass while cloud-to-ground (CG) lightning is more numerous during the downdraft-driven descent of radar echo associated with graupel and hail. More study is required to generalize these relationships, especially regarding lightning type, in a wide variety of storm modes and meteorological conditions. Less is known about the co-evolving relationship between storm kinematics, microphysics, morphology and three-dimensional flash extent, despite its importance for lightning NOx production. To address this conceptual gap, the NASA MSFC Lightning Nitrogen Oxides Model (LNOM) is applied to North Alabama Lightning Mapping Array (NALMA) and Vaisala National Lightning Detection NetworkTM (NLDN) observations following ordinary convective cells through their lifecycle. LNOM provides estimates of flash type, channel length distributions, lightning segment altitude distributions (SADs) and lightning NOx production profiles. For this study, LNOM is applied in a Lagrangian sense to well isolated convective cells on 3 April 2007 (single cell and multi-cell hailstorm, non-severe multicell) and 6 July 2007 (non-severe multi-cell) over Northern Alabama. The LNOM lightning characteristics are compared to the evolution of updraft and precipitation properties inferred from dual-Doppler and polarimetric radar analyses applied to observations from a nearby Doppler radar network, including the UA Huntsville Advanced Radar for Meteorological and Operational Research (ARMOR, C-band, polarimetric). The LNOM estimated SAD and lightning NOx production profiles are placed in the context of radar derived profiles of vertical motion, precipitation types and amounts. Finally, these analyses are used to determine if storm integrated flash channel extent is as well correlated to volumetric updraft and precipitation ice characteristics in the mixed phase region as flash rate for these individual convective cells.

Carey, Lawrence↗
DOE OSTI2014

Depolarizing collisions with hydrogen: Neutral and singly ionized alkaline earths

Depolarizing collisions are elastic or quasielastic collisions that equalize the populations and destroy the coherence between the magnetic sublevels of atomic levels. In astrophysical plasmas, the main depolarizing collider is neutral hydrogen. We consider depolarizing rates on the lowest levels of neutral and singly ionized alkali earths Mg I, Sr I, Ba I, Mg II, Ca II, and Ba II, due to collisions with H°. We compute ab initio potential curves of the atom-H° system and solve the quantum mechanical dynamics. From the scattering amplitudes, we calculate the depolarizing rates for Maxwellian distributions of colliders at temperatures T ≤ 10,000 K. A comparative analysis of our results and previous calculations in the literature is completed. We discuss the effect of these rates on the formation of scattering polarization patterns of resonant lines of alkali earths in the solar atmosphere, and their effect on Hanle effect diagnostics of solar magnetic fields.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Reaction Pathways and Energy Consumption in NH 3 Decomposition for H 2 Production by Low Temperature, Atmospheric Pressure Plasma

Pathways for NH 3 decomposition to N 2 and N 2 H 4 by atmospheric pressure nonthermal plasma are analyzed using a combination of molecular beam mass spectrometry measurements and zero-dimensional kinetic modeling. Experimental measurements show that NH 3 conversion and selectivity towards N 2 formation scale monotonically with the specific energy input into the plasma with ~ 100% selectivity to N 2 formation achieved at specific energy inputs above 0.12 J cm −3 (3.1 eV (molecule NH 3 ) −1 ). The kinetic model recovers these trends, although it underpredicts N 2 selectivity at low specific energy input. These discrepancies can be explained by the underestimation of reaction rate coefficients for reactions that consume N 2 H x species in collisions with H radicals and/or radial nonuniformities in power deposition, gas temperature, and species concentrations that are not represented by the plug flow approximation used in the model. The kinetic model shows that N 2 formation proceeds through N 2 H x decomposition pathways rather than NH x decomposition pathways in low temperature, atmospheric pressure plasma. Higher selectivity toward N 2 production can be achieved by operating at higher NH 3 conversion and with a higher gas temperature. Furthermore, the high energy cost of NH 3 decomposition by atmospheric pressure nonthermal plasma found in this work (25–50 eV (molecule NH 3 converted) −1 ; 17–33 eV (molecule H 2 formed) −1 ) is a result of the energy requirement for electron-impact dissociation of NH 3 and the significant re-formation of NH 3 by three-body recombination reactions between NH 2 and H.

Nonthermal plasma↗
DOE OSTI2019

Multiscale modeling of fission gas behavior in U 3 Si 2 under LWR conditions

In this work, we present a model of fission gas behavior in U 3 Si 2 under light water reactor (LWR) conditions for application in engineering fuel performance codes. The model includes components for intra-granular and inter-granular behavior of fission gases. The intra-granular component is based on cluster dynamics and computes the evolution of intra-granular fission gas bubbles and swelling coupled to gas diffusion to grain boundaries. The inter-granular component describes the evolution of grain-boundary fission gas bubbles coupled to fission gas release. Given the lack of experimental data for U 3 Si 2 under LWR conditions, the model is informed with parameters calculated via atomistic simulations. In particular, we derive fission gas diffusivities through density functional theory calculations, and the re-solution rate of fission gas atoms from intra-granular bubbles through binary collision approximation calculations. Further, the developed model is applied to the simulation of an experiment for U 3 Si 2 irradiated under LWR conditions available from the literature. Results point out a credible representation of fission gas swelling and release in U 3 Si 2 . Finally, we perform a sensitivity analysis for the various model parameters. Based on the sensitivity analysis, indications are derived that can help in addressing future research on the characterization of the physical parameters relative to fission gas behavior in U 3 Si 2 . The developed model is intended to provide a suitable infrastructure for the engineering scale calculation of fission gas behavior in U 3 Si 2 that exploits a multiscale approach to fill the experimental data gap and can be progressively improved as new lower-length scale calculations and validation data become available.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2016

Sulfur Dioxide Accelerates the Heterogeneous Oxidation Rate of Organic Aerosol by Hydroxyl Radicals

There remains considerable uncertainty in how anthropogenic gas phase emissions alter the oxidative aging of organic aerosols in the troposphere. Here we observe a 10-20 fold acceleration in the effective heterogeneous OH oxidation rate of organic aerosol in the presence of SO 2 . This acceleration originates from the radical chain reactions propagated by alkoxy radicals, which are formed efficiently inside the particle by the reaction of peroxy radicals with SO 2 . As the OH approaches atmospheric concentrations, the radical chain length increases, transforming the aerosol at rates predicted to be up to 10 times the OH-aerosol collision frequency. Model predictions, constrained by experiments over orders of magnitude changes in [OH] and [SO 2 ], suggest that in polluted regions the heterogeneous processing of organic aerosols by OH ([SO 2 ] ≥ 40 ppb) occur on similar time scales as analogous gas-phase oxidation reactions. These results provide evidence for a previously unidentified mechanism by which organic aerosol oxidation is enhanced by anthropogenic gas phase emissions. (Chemical Equation Presented).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Direction-specific enhanced diffusion of CO 2 in chiral hexagonal boron nitride nanotubes

To meet performance requirements, the next generation of gas separation membranes will need both high gas permeability and selectivity, attainable if we could coax adsorbates to minimize random Brownian motion and produce direction-specific diffusion along a desired axis. In this atomistic modeling study, we detail how direction-specific diffusion of CO 2 can be achieved in chiral hexagonal boron nitride nanotubes (hBNNTs) by means of a non-Knudsen diffusion mechanism. Our findings detail how this mechanism of diffusion is driven by interactions with the tube walls and enables the CO 2 molecules to diffuse along the nanotube’s z-axis with minimized collisions and directional changes. hBNNTs with chiral indices exhibit CO 2 diffusion rates faster than non-chiral tubes of comparable and larger diameters. Of the hBNNTs studied, a (7,3) tube appears to be ideally sized (3.7 Å radius) exhibiting CO 2 diffusion that is 3.4 times faster than diatomic N 2 . Applying this mechanism of diffusion to hypothetical sheet membranes prepared with aligned chiral (7,3) hBNNTs results in membranes with a calculated CO 2 /N 2 permselectivity of 170 and a CO 2 permeability limit of nearly 1.35 ×10 7 Barrer, readily surpassing the Robeson upper bound for CO 2 /N 2 separations.

CO2↗
DOE OSTI2014

Extension of the quantum-kinetic model to lunar and Mars return physics

The ability to compute rarefied, ionized hypersonic flows is becoming more important as missions such as Earth reentry, landing high-mass payloads on Mars, and the exploration of the outer planets and their satellites are being considered. A recently introduced molecular-level chemistry model, the quantum-kinetic, or Q-K, model that predicts reaction rates for gases in thermal equilibrium and non-equilibrium using only kinetic theory and fundamental molecular properties, is extended in the current work to include electronic energy level transitions and reactions involving charged particles. Like the Q-K procedures for neutral species chemical reactions, these new models are phenomenological procedures that aim to reproduce the reaction/transition rates but do not necessarily capture the exact physics. These engineering models are necessarily efficient due to the requirement to compute billions of simulated collisions in direct simulation Monte Carlo (DSMC) simulations. The new models are shown to generally agree within the spread of reported transition and reaction rates from the literature for near equilibrium conditions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2014

Cosmic-ray induced gamma-ray emission from the starburst galaxy NGC 253

Cosmic rays in galaxies interact with the interstellar medium and give us a direct view of nuclear and particle interactions in the cosmos. For example, cosmic-ray proton interactions with interstellar hydrogen produce gamma rays via PcrPism→π{sup 0}→γγ. For a 'normal' star-forming galaxy like the Milky Way, most cosmic rays escape the Galaxy before such collisions, but in starburst galaxies with dense gas and huge star formation rate, most cosmic rays do suffer these interactions [1,2]. We construct a 'thick-target' model for starburst galaxies, in which cosmic rays are accelerated by supernovae, and escape is neglected. This model gives an upper limit to the gamma-ray emission. Only two free parameters are involved in the model: cosmic-ray proton acceleration energy rate from supernova and the proton injection spectral index. The pionic gamma-radiation is calculated from 10 MeV to 10 TeV for the starburst galaxy NGC 253, and compared to Fermi and HESS data. Our model fits NGC 253 well, suggesting that cosmic rays in this starburst are in the thick target limit, and that this galaxy is a gamma-ray calorimeter.

79 ASTRONOMY AND ASTROPHYSICS↗