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At least 757 records · Page 42
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Do Piperonyl Butoxide Long-Lasting Insecticide Treated Nets Provide Additional Protection Against Malaria Infections Compared with Conventional Nets in an Operational Setting in Western Kenya?

Malaria control in sub-Saharan Africa has stagnated despite widespread adoption of control measures such as long-lasting insecticidal nets (LLINs). Progress has stalled, in part, because of pyrethroid insecticide resistance, driving the need for retooling to increase the effectiveness of bed nets. Consequently, LLINs have been treated with the chemical synergist piperonyl butoxide (PBO). Piperonyl butoxide LLINs have been shown to be efficacious in controlled settings; however, their effectiveness in real-world settings warrants investigation. In Bungoma County, Western Kenya, a cohort of 768 participants was followed from June 2017 to December 2023 via active and passive surveillance. Household visits were conducted monthly, during which LLIN use for nets distributed in 2017 and 2021 was recorded, and symptomatic malaria cases were identified using rapid diagnostic tests (RDTs). The comparative effectiveness of PBO versus conventional LLINs was assessed in terms of malaria infections. A multilevel logistic regression model was fit with monthly RDT results as the dependent variable. The study results indicate that PBO LLINs provide greater protection against malaria at the individual level than conventional LLINs (odds ratio: 0.70; 95% CI: 0.47–1.03), although the findings were not statistically significant. The added protection against malaria infections provided by PBO LLINs compared with conventional LLINs observed in the current study aligns with findings from most previous studies, although this finding was not statistically significant. In areas with documented pyrethroid resistance, the use of LLINs with an added synergist, such as PBO, can provide additional protection against malaria infections (compared with pyrethroid-only LLINs) and should be considered for scaled-up scenarios despite the additional cost.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2021

Impact of Materials Properties on Higher-Temperature Engine Operation

Here, we examine the effects on materials temperatures and engine efficiency via simulations of engines operating at temperatures which exceed the thermal limits of today’s materials. Potential focus areas include high-speed, high-load operation (in the fuel-enrichment zone) as well as conditions of selective cooling at lower speeds and loads. We focus on a light-duty DISI and a heavy-duty CI engine using GT-Power. Temperature distributions within the head, block, piston, and valves were obtained from 3D FEA simulations coupled with 1D GT-Power representations of the engine’s gas flow and combustion regions. We use experimentally measured thermal properties of current commercial alloys for specific engine components, as well as candidate developmental alloys with improved temperature tolerance, to gauge the effects of materials properties on engine performance, particularly focusing on operating areas where materials which can withstand higher temperatures can enable intensified combustion conditions and increased specific output. The outcome of this work is guidance on materials selection targets and benefits as OEMs meet engine-performance needs in the coming decades, to include Class 8 line-haul freight vehicles with reduced emissions, as well as design of future near net zero-carbon light-duty range extenders for more rapid electrification of medium- and heavy-duty vehicles.

36 MATERIALS SCIENCE↗
DOE OSTI2023

DME-Propane Ignition Delay Time Measurements at Mixing Controlled Compression Ignition Engine-Relevant Conditions

The blend of dimethyl ether (DME, CH 3 OCH 3 ) and propane (C 3 H 8 ) is a potentially renewable fuel mixture that has the potential to replace diesel in compression ignition engines. The combination can potentially reduce particulate and greenhouse gas emissions compared to a conventional diesel engine operating under similar conditions. However, detailed conceptual and simulation studies must be conducted before adopting a new fuel on a compression ignition engine. For these simulations, accurate chemical kinetic models are necessary. However, the validity of chemical kinetic mechanisms in the literature is unknown for mixing controlled compression ignition (MCCI) engine operating conditions. Hence, in this work, we studied the ignition of dimethyl ether (DME) and propane blends in a shock tube at MCCI engine conditions. Ignition delay time (IDT) data was collected behind the reflected shock for DME-propane mixtures for heavy-duty compression ignition (CI) engine parameters. Undiluted experiments spanning temperatures of 700 to 1100 K and pressures of 55 to 84 bar for various blends (100% CH 3 OCH 3 / 0% C 3 H 8, 100% C 3 H 8 / 0% CH 3 OCH 3 , 60% CH 3 OCH 3 / 40% C 3 H 8 ) of DME and propane were combusted in synthetic air (21% O 2 / 79% N 2 ). Some experiments were conducted at higher pressures (90-120 bar) to understand model performance at these conditions. Comparisons of IDT were made with the predictions of recent chemical kinetic mechanisms for DME-propane mixture, including the Aramco3.0, NUIG, and Dames et al. mechanisms. All mechanisms overpredicted IDT compared to experimental values. Sensitivity analysis was conducted with Dames et al. model, and critical reactions sensitive to IDT of DME-propane mixture near 100 bar are outlined.

Mohammed, Zuhayr Pasha↗
DOE OSTI2024

Light Duty Engine Performance Characteristics with Dimethyl Ether and Propane

Here, this paper explores the performance characteristics of a compression ignition HYUNDAI 2.2L engine operating with Dimethyl Ether (DME). Test are carried out at three operating conditions that weigh heavily in the FTP75 certification cycle (1000rpm-12Nm, 1500rpm-50Nm, 2000rpm-100Nm). The engine features a high-pressure common rail fuel injection system designed to operate with liquified gases. The main component of the fuel system is a high-pressure pump that incorporates an electronic inlet metering valve commanded on a crank-angle base to control the rail pressure. The pump, which requires no pressure regulator, provides the flow needed to the injectors without flow returning to the inlet. This novel fueling system is leveraged in tests that are conducted to examine the impact of EGR, combustion phasing, injection pressure on efficiency and emissions. In addition, the impact of introducing 15% Propane by mass is examined. During the tests, the engine ECU is aided by an Engine Controller High Speed Oversight unit (ECHO) to provide combustion phasing control, improved cylinder-to-cylinder uniformity, and an effective optimization over the testing effort. The use of DME and Propane allowed for peak thermal efficiency of nearly 43%. These fuels enable significant carbon index (CI) reductions over the baseline Diesel fuel, with indications that 50% reduction in CO 2 over the Diesel engine are possible.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2024

The Dynamic Assimilation Technique measures photosynthetic CO2 response curves with similar fidelity as steady-state approaches in half the time

The net CO2 assimilation (A) response to intercellular CO2 concentration (Ci) is a fundamental measurement in photosynthesis and plant physiology research. The conventional A/Ci protocols rely on steady-state measurements and take 15-40 minute per measurement, limiting data resolution or biological replication. Additionally, there are several CO2 protocols employed across the literature, without clear consensus as to the optimal protocol or systematic biases in their estimations. We compared the non-steady state Dynamic Assimilation Technique (DAT) protocol and the three most used CO2 protocols in steady-state measurements, and tested whether different CO2 protocols lead to systematic differences in estimations of the biochemical limitations to photosynthesis.

A/Ci response↗
DOE OSTI2026

Machine-learning-based estimates of global natural vegetated wetland methane emissions (2000–2025)

Wetlands are the largest natural source of atmospheric methane (CH 4 ), yet comprehensive global budgets are typically delayed by years, preventing a timely understanding of CH 4 sources, sinks, and trends. To reduce this delay, we present a model emulator-driven framework and accompanying workflow that enable timely, continuous emission updates using a machine-learning emulator to reconstruct spatially explicit monthly emission fields at 1° × 1° resolution. We apply this framework to a global dataset of natural vegetated wetland CH 4 emissions to extend the most recent Global Methane Budget (GMB; Saunois et al., 2025) record that covers the 2000–2020 emissions through 2025. In the test data (∼ 30 % of the total dataset), the emulator achieved a global R 2 of 0.65 ± 0.003 (mean ± 95 % CI, hereafter) and an RMSE of 5.49 ± 0.12×10 -3 Tg CH 4 yr −1 . The emulator is trained on 35 GMB model estimates, including 22 process-based models and 13 atmospheric inversions, paired with 10 ensemble realizations of 11 gridded climate predictor variables from atmospheric reanalyses. Our results show that the global mean predicted wetland CH 4 emissions for 2021–2025 (157.8 ± 2.4 Tg CH 4 yr −1 ) are not significantly higher (∼ 0.05 Tg CH 4 yr −1 ) than the 2000–2020 baseline. However, this stability masks a significant hemispheric redistribution of emissions. We detect an increase in Northern Hemisphere (NH) emissions in 2021–2025, with mid- and high-latitudes increasing by 0.76 ± 0.07 and 0.35 ± 0.03 Tg CH 4 yr −1 , respectively, while the tropics and Southern Hemisphere (SH) extratropics show offsetting negative trends (−0.95 ± 0.19 and -0.11 ± 0.02 Tg CH 4 yr −1 , respectively). The predicted emissions are able to capture the low emissions in 2023 in South America linked to El Niño-related drought, as reported by recent studies (Ciais et al., 2026; Quinn et al., 2025). Furthermore, we identify a distinct seasonal amplification of global emission trends that peaks in late boreal summer. This new modeled dataset and operational framework bridge the gap between the latest updated budgets and low-latency monitoring, providing a scalable capacity to frequently update global emission estimates and critical early warnings of regional wetland feedback loops. The data are publicly available at https://doi.org/10.5281/zenodo.18870108 (Li et al., 2026).

Li, Mengze [National University of Singapore (Sing↗
DOE OSTI2024

A protocol for model intercomparison of impacts of marine cloud brightening climate intervention

A modeling protocol (defined by a series of climate model simulations with specified model output) is introduced. Studies using these simulations are designed to improve the understanding of climate impacts using a strategy for climate intervention (CI) known as marine cloud brightening (MCB) in specific regions; therefore, the protocol is called MCB-REG (where REG stands for region). The model simulations are not intended to assess consequences of a realistic MCB deployment intended to achieve specific climate targets but instead to expose responses to interventions in six regions with pervasive cloud systems that are often considered candidates for such a deployment. A calibration step involving simulations with fixed sea surface temperatures (SSTs) is first used to identify a common forcing, and then coupled simulations with forcing in individual regions and combinations of regions are used to examine climate impacts. Synthetic estimates constructed by superposing responses from simulations with forcing in individual regions are considered a means of approximating the climate impacts produced when MCB interventions are introduced in multiple regions. A few results comparing simulations from three modern climate models (CESM2, E3SMv2, and UKESM1) are used to illustrate the similarities and differences between model behavior and the utility of estimates of MCB climate responses that were synthesized by summing responses introduced in individual regions. Cloud responses to aerosol injections differ substantially between models (CESM2 clouds appear much more susceptible to aerosol emissions than the other models), but patterns in precipitation and surface temperature responses were similar when forcing is imposed with similar amplitudes in the same regions. A previously identified La Niña-like response to forcing introduced in the Southeast Pacific is evident in this study, but the amplitude of the response was shown to markedly differ across the three models. Other common response patterns were also found and are discussed. Forcing in the Southeast Atlantic consistently (across all three models) produces weaker global cooling than that in other regions, and the Southeast Pacific and South Pacific show the strongest cooling. This indicates that the efficiency of a given intervention depends on not only the susceptibility of the clouds to aerosol perturbations, but also the strength of the underlying radiative feedbacks and ocean responses operating within each region. These responses were generally robust across models, but more studies and an examination of responses with ensembles would be beneficial.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Attribution of the role of climate change in the forest fires in Sweden 2018

In this study, we analyse the role of climate change in the forestfires that raged through large parts of Sweden in the summer of 2018 from ameteorological perspective. This is done by studying the Canadian FireWeather Index (FWI) based on sub-daily data, both in reanalysis data sets(ERA-Interim, ERA5, the Japanese 55 year Reanalysis, JRA-55, and Modern-Era Retrospective analysis for Research and Applications version 2, MERRA-2) and three large-ensemble climatemodels (EC-Earth, weather@home, W@H, and Community Earth System Model, CESM) simulations. The FWI, based on reanalysis, correlates well with the observed burnt area in summer (r=0.6 to 0.8). We find that the maximum FWI in July 2018 had return times of ~24 years (90 % CI, confidence interval, > 10 years) for southern and northern Sweden. Furthermore, we find a negative trend of the FWI for southern Sweden over the 1979 to 2017 time period in the reanalyses, yielding a non-significant reduced probability of such an event. However, the short observational record, large uncertainty between the reanalysis products and large natural variability of the FWI give a large confidence interval around this number that easily includes no change, so we cannot draw robust conclusions from reanalysis data. The three large-ensembles with climate models point to a roughly 1.1 (0.9 to 1.4) times increased probability (non-significant) for such events in the current climate relative to preindustrial climate. For a future climate (2 °C warming), we find a roughly 2 (1.5 to 3) times increased probability for such events relative to the preindustrial climate. The increased fire weather risk is mainly attributed to the increase intemperature. The other main factor, i.e. precipitation during summer months, isprojected to increase for northern Sweden and decrease for southern Sweden. We, however, do not find a clear change in prolonged dry periods in summer months that could explain the increased fire weather risk in the climate models. In summary, we find a (non-significant) reduced probability of such eventsbased on reanalyses, a small (non-significant) increased probability due to global warming up to now and a more robust (significant) increase in the risk for such events in the future based on the climate models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Validated CFD Model for Multimode Gasoline Compression Ignition Engine

A validated CFD model for the multimode combustion engine developed under the DOE funded project DE-EE0008478 (Co-optimized Mixed-Mode Engine and Fuel Demonstrator for Improved Fuel Economy while Meeting Emissions Requirements). It incorporates advanced physics-based fuel surrogate models for thermophysical properties and reaction kinetics. The combustion modes include spark ignition (SI), low temperature combustion (LTC), and compression ignition (CI). The real fuel model was validated for RON60, RON70, RON80, RON90, and two biofuel blends. The validation cases can be found in https://doi.org/10.2172/1887341.

02 PETROLEUM↗
DOE OSTI2024

Factors Predicting Apparent Ophidiomycosis in Wild Brown Watersnakes ( Nerodia Taxispilota )

Ophidiomycosis, also known as snake fungal disease, is caused by Ophidiomyces ophidiicola and is a threat to snake conservation worldwide. Ophidiomycosis has been reported throughout much of the eastern US, and outbreaks have been associated with local population declines of already strained populations. Previous studies report significant variability in ophidiomycosis among species sampled, with higher prevalence typically observed in Nerodia spp. Although ophidiomycosis can lead to morbidity and mortality in affected individuals, little is known about disease dynamics in free-ranging populations. Herein, we examine how individual-specific factors (e.g., life stage [immature, mature], contaminant status, sex, hemograms) may be associated with ophidiomycosis status in the brown watersnake (Nerodia taxispilota). During 2018–19, we sampled 97 N. taxispilota from five locations along the Savannah River in South Carolina and Georgia, US. Ophidiomyces ophidiicola DNA was detected in 66 snakes for a prevalence of 68% (95% confidence interval, 59–77). Mature snakes had a significantly higher risk of apparent ophidiomycosis (skin lesions present and quantitative PCR [qPCR], positive) relative to immature snakes. Snakes classified as having possible (skin lesions present, but qPCR negative) or apparent ophidiomycosis exhibited a relative azurophilia and heterophilia compared with individuals classified as negative (P≤0.037). Nerodia taxispilota in this region appear to have a high prevalence of apparent ophidiomycosis (22%; 95% CI, 14–31), similar to previous reports from the southeastern US. Furthermore, additional epidemiologic investigations are warranted to further elucidate other individual-specific and environmental factors that may dictate disease risk and outcomes in affected populations.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1968

Natural orbitals for H sub 2.

Natural orbital expansion coefficients of LCAO-MO-SCF-CI wave functions for ground state of H molecule

Barker, W. H.↗
NASA NTRS1972

An integral test of the inelastic cross sections of Pb and Mo using measured neutron spectra

Comparison of measurements and calculations of fast neutron spectra from a radioactive neutron source inside spheres of Mo or Pb and from a cylindrical reactor containing a thick Pb or Mo reflector are used as a test of ENDF cross sections. The sphere leakage spectra were measured at a sphere-to-spectrometer distance of 2 meters using a 54 Ci spherical Am-Be neutron source. Reactor leakage spectrum measurements were made at the surface of the ZP-1 reactor when bare, with a Pb radial reflector 21 cm thick, and with a metallic Mo radial reflector 10 cm thick. In the case of the thin Mo sphere there is agreement between the calculation and measurement. The Pb calculation is much lower than the measurement except at the highest neutron energy. Two-dimensional calculations of reactor spectra result indicate that the reactor source is reasonably well known. Significant differences in leakage spectrum shape for both Mo and Pb reflectors suggest that there are large uncertainties in the inelastic cross sections for Pb and some for Mo.

Shook, D. F.↗
NASA NTRS1973

Excited electronic states of O2/-/.

Configuration interaction (CI) variational trial functions (which assure formally correct dissociation) and the single-configuration self-consistent-field approximation are applied to the calculation of the excited electronic states of the negatively charged oxygen molecule. The energy curves and wave functions of these states are analyzed. All the excited states are found to have equilibrium-internuclear separations at least 1 a.u. larger than the ground state. The two lowest energy states are characterized, respectively, as shape and valence Feshbach resonances.

Krauss, M.↗
NASA NTRS1973

Regression of altitude-produced cardiac hypertrophy.

The rate of regression of cardiac hypertrophy with time has been determined in adult male albino rats. The hypertrophy was induced by intermittent exposure to simulated high altitude. The percentage hypertrophy was much greater (46%) in the right ventricle than in the left (16%). The regression could be adequately fitted to a single exponential function with a half-time of 6.73 plus or minus 0.71 days (90% CI). There was no significant difference in the rates of regression for the two ventricles.

Sizemore, D. A.↗
NASA NTRS1973

Investigation of the responses of the general circulation at 700 mb to solar-geomagnetic disturbance

The Northern Hemisphere 700 mb contour heights from 20 N to 70 N for the period 1947-1970 are studied in conjunction with 272 key days, where the daily increase of the Ci index equals or exceeds 1.0. The superposed epoch method is applied from 33 days before to 66 days after the key day for a variety of zonal and meridional indices. It is shown that the 700 mb height difference between 20 N and 55 N increases significantly in winter 4 days following geomagnetic disturbance (in summer a less prominent but statistically significant increase is found 2 days earlier). The effect is most clear in winter in the quadrant 90-175 W and corresponds to a 7% increase in the mean geostrophic westerly flow. The statistical significance of the results is established by applying Student's t-test to the difference of each daily mean from the continuum.

Stolov, H. L.↗
NASA NTRS1974

Surface properties of the Orgueil meteorite - Implications for the early history of solar system volatiles

The Kr and H2O adsorption properties of Orgueil were studied. Dehydration by stepwise calcination produced a tenfold change in its B.E.T. surface area, which increased to 120 and then fell to 40 square meters per gram. Water exchangeability was measured by water regain from lab air between calcination cycles. Dehydration at room temperature showed that Orgueil contained 6 per cent by weight of water adsorbed on free surfaces. These results are consistent with an identification of Orgueil as montmorillonite, although chemical data conflict with this. High D/H ratios in CI carbonaceous chondrites may result from D enrichment in OH- groups during equilibration of dispersed phyllosilicate dust with preplanetary nebula gas at temperatures much less than 0 C.

Fanale, F. P.↗
NASA NTRS1974

Short-range interaction between hydrogen molecules

Recent calculations of the ground state energy of a system of four hydrogen atoms are reviewed with the aim of discerning the short-range repulsive part of the interaction potential between two hydrogen molecules. Extended-basis CI calculations which include a diffuse 2p orbital appear to be capable of determining the total interaction energy between to hydrogen molecules for any separation. Consistent results of such calculations suggest that the potential for intermolecular separations in the region from 1 to 2.5 A can now be specified to better than 10% with considerable confidence. Analytic fits to spherical averages of these results are presented.

Mcmahan, A. K.↗