Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “BURNING PROCESS”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 757 records · Page 42

Transient processes in combustion of single submillimeter metal droplets

A laser was used to ignite Al, Zr, Ti and Hf droplets in separate trials to study metal droplet combustion in air. The burning was recorded with high speed film at high magnification. Al was found to flash vaporize, melt, surface oxidize, revaporize, then combust. All species burned with a vapor diffusion flame surrounded by an oxide condensation front. The Zr, Ti and Hf droplets grew by condensation, coalesced, then convected toward the perimeter of the condensation zone. It is expected that the data will serve as bases for a theoretical vapor diffusion model. Finally, the introduction of a transverse acoustic field was observed to have no effect on either the luminosity or combustion zone geometry.

Pellett, G. L.↗

Development of beam lead RF integrated circuits

This paper describes the design and development of a set of multifunction VHF/UHF integrated circuits aimed at providing a major improvement in spacecraft radio reliability through low stress operation and the processing of these circuits in beam-lead form. The methods evolved for the high frequency characterization of the devices are discussed together with the design of suitable test fixtures. Typical test results and the distribution of test parameters are presented. A unique carrier for beam-lead devices is described, and the need for such a device is discussed. The application of the carrier to device screening, burn-in and drift measurements is discussed together with the incentives for providing these capabilities. An overview of the integration of the devices into the spacecraft radio is given and candidate assembly processes are discussed. The technology impact of this approach upon future spacecraft radio systems is qualitatively examined.

Kline, A. J.↗

The 20 Ne(d,p) 21 Ne Transfer Reaction in Relation to the s-Process Abundances

A study of the Ne-20(d,p)Ne-21 transfer reaction was performed using the Quadrupole Dipole Dipole Dipole (Q3D) magnetic spectrograph in Garching, Germany. The experiment probed excitation energies in Ne-21 ranging from 6.9 MeV to 8.5 MeV. The aim was to investigate the spectroscopic information of Ne-21 within the Gamow window of core helium burning in massive stars. Further information in this region will help reduce the uncertainties on the extrapolation down to Gamow window cross sections of the O-17(alpha,gamma)Ne-21 reaction. In low metallicity stars, this reaction has a direct impact on s-process abundances by determining the fate of O-16 as either a neutron poison or a neutron absorber. The experiment used a 22-MeV deuteron beam, with intensities varying from 0.5-1 mu A, and an implanted target of Ne-20 of 7 mu g/cm(2) in 40 mu g/cm(2) carbon foils. Sixteen Ne-21 peaks have been identified in the E-x = 6.9-8.5 MeV range, of which only thirteen peaks correspond to known states. Only the previously-known E-x = 7.960 MeV state was observed within the Gamow window.

Nsangu, C. T.↗

Plasma Surface Interactions: Bridging from the Surface to the Micron Frontier through Leadership Class Computing (Final Technical Progress Report)

The performance demands on plasma-facing components (PFCs) in future fusion power plants are beyond the capability of current materials. In defining the plasma-surface interaction (PSI), it is evident that three coupled spatial regions influence PFC materials evolution and performance. These regions consist of (1) the edge and scrape-off layer region of the plasma, (2) the near-surface material response to extreme thermal and particle fluxes under the influence of, and feedback to, the plasma sheath, and (3) the structural material’s response to an intense, 14 MeV peaked neutron spectrum, which produces very high concentrations of transmuted elements through (n,p) and (n,α) reactions and structural material property degradation. The objective of this project is to develop and deploy validated, high-performance simulation tools capable of predicting the performance of tungsten-based plasma-facing components (PFCs) in a burning fusion plasma environment, which includes modeling surface morphology evolution in either erosion or re-deposition regimes, and the recycling of hydrogen species. This requires the development of a leadership-scale computational code to predict PFC behavior that is well integrated to a suite of multiscale modeling techniques to bridge the scales needed to address complex physical and computational issues at the plasma surface interface and the transition region below the surface where neutron damage processes in the bulk dominate material behavior. Successful completion of this project will provide PFC simulation tools to evaluate steady-state performance of tungsten-based PFC and divertor components in burning plasma environments. This will enable the identification of critical experiments to confirm whether practical PFC solutions exist for magnetic fusion energy beyond ITER. More specifically, the research activities within this project focus on two broadly defined research thrusts: 1) Developing a new simulation code, Xolotl-PSI to predict PFC operating lifetime and performance, that is specifically designed to take advantage of leadership class computing facilities; and 2) Integrating and applying discrete particle-based, as well as continuum-based, multiscale modeling techniques to provide scientific discovery of the mechanisms controlling PFC and bulk materials evolution under fusion plasma and 14-MeV neutron exposure; in this thrust, the challenge of scale-bridging between atomistic/microstructural modeling and the continuum-scale of PFC device performance is achieved through multiscale modeling techniques. Throughout the grant period, research at UMass Amherst focused on the atomic-scale analysis of the dynamics and kinetics (transport and reactions) of small mobile helium clusters near surfaces and grain boundaries in plasma-exposed tungsten, as well as the proper parameterization and incorporation of these processes into our SciDAC team’s continuum-level cluster dynamics code (Xolotl). Our work also included characterization of large-scale molecular-dynamics (MD) simulation results of helium implantation into tungsten based on the findings of our analysis and comparisons of Xolotl simulation predictions with the large-scale MD simulation results for Xolotl validation purposes; emphasis was placed on the impact of helium cluster dynamics/kinetics on tungsten surface morphology, near-surface tungsten structure, and helium retention. Furthermore, our work included initiation of a research program on evaluating the impact of structural defects in tungsten due to plasma exposure (such as helium nanobubbles) on tungsten’s thermophysical properties, focusing on lattice thermal conductivity. Our studies contributed to a fundamental understanding of the effects of plasma-surface interactions on the dynamical response of plasma-facing materials in nuclear fusion devices and the development of predictive hierarchical multiscale computational tools for the quantitative description of the material’s dynamical response to plasma exposure.

36 MATERIALS SCIENCE↗

Nitric oxide formation in gas turbine engines: A theoretical and experimental study

A modified Zeldovich kinetic scheme was used to predict nitric oxide formation in the burned gases. Nonuniformities in fuel-air ratio in the primary zone were accounted for by a distribution of fuel-air ratios. This was followed by one or more dilution zones in which a Monte Carlo calculation was employed to follow the mixing and dilution processes. Predictions of NOX emissions were compared with various available experimental data, and satisfactory agreement was achieved. In particular, the model is applied to the NASA swirl-can modular combustor. The operating characteristics of this combustor which can be inferred from the modeling predictions are described. Parametric studies are presented which examine the influence of the modeling parameters on the NOX emission level. A series of flow visualization experiments demonstrates the fuel droplet breakup and turbulent recirculation processes. A tracer experiment quantitatively follows the jets from the swirler as they move downstream and entrain surrounding gases. Techniques were developed for calculating both fuel-air ratio and degree of nonuniformity from measurements of CO2, CO, O2, and hydrocarbons. A burning experiment made use of these techniques to map out the flow field in terms of local equivalence ratio and mixture nonuniformity.

Mikus, T.↗

The use of carbohydrazide for plutonium concentration stripping in separator with inert packing

For the purpose of removing plutonium from uranium- plutonium extract it is proposed to employ concentration stripping process with the use of separator and a new reducing reagent: Carbohydrazide CO(N{sub 2}H{sub 3}){sub 2}. Using plutonium stripping from solution simulating the composition of extract of spent nuclear fuel from VVER-1000 reactor (without γ-emitting isotopes), with O: A ratio of = 28, a product solution was obtained containing 17.8 g/l of plutonium, 29.2 g/l of uranium and more than 1 g/l of technetium. The experiment on real spent fuel from VVER-1000 with burn-up of more than 50 GW*d/t of uranium after 17 year exposure, performed in the shielded box of FSUE 'MCP', confirmed the effectiveness and feasibility of the proposed process. Through concentration stripping (O:A = 20), a plutonium product solution was obtained with a part of uranium with the following composition: [U] = 150 g/l; [Pu] = 23,5 g/l; [Np] = 1,7 g/l, [Tc] = 1.5 g/l; gamma exposure rate - 0,022 mR/s*l. Direct extraction of plutonium in this operation was 95.3%, the rest of plutonium is refluxing to the preceding stage of the extraction cycle. A process flow diagram with organization of plutonium recycling is proposed, allowing for its complete removal into a single stream. Carbohydrazide is an effective reducing agent of plutonium (IV), ensuring the stability of uranium-plutonium separation process. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Design and qualification of an UHV system for operation on sounding rockets

The sounding rocket mission MAIUS-1 has the objective to create the first Bose–Einstein condensate in space; therefore, its scientific payload is a complete cold atom experiment built to be launched on a VSB-30 sounding rocket. An essential part of the setup is an ultrahigh vacuum system needed in order to sufficiently suppress interactions of the cooled atoms with the residual background gas. Contrary to vacuum systems on missions aboard satellites or the international space station, the required vacuum environment has to be reached within 47 s after motor burn-out. This paper contains a detailed description of the MAIUS-1 vacuum system, as well as a description of its qualification process for the operation under vibrational loads of up to 8.1 g{sub RMS} (where RMS is root mean square). Even though a pressure rise dependent on the level of vibration was observed, the design presented herein is capable of regaining a pressure of below 5 × 10{sup −10} mbar in less than 40 s when tested at 5.4 g{sub RMS}. To the authors' best knowledge, it is the first UHV system qualified for operation on a sounding rocket.

42 ENGINEERING↗

Electronic Production Control System News Note

The CMD subprogram develops and deploys multi-application weapon component manufacturing capabilities needed to replace sunset technologies, upgrade existing technologies, and introduce new technologies that support the nuclear weapons stockpile. Sandia National Laboratories (SNL) is currently developing an Electronic Production Control System (EPCS) for ASIC production in the back end of line (BEOL) flow. A pre-production version of EPCS has been released and is operating as intended. We are currently processing all ASIC products, including CVV validation ASICs. The BEOL flow includes wafer probe, packaging, quality inspection, initial electrical test, dynamic burn-in, final electrical test, quality inspection, final visual inspection, radiation testing, SNL acceptance, DOE SSO acceptance, and qualification testing steps. EPCS will execute this production workflow (initiate, control, and electronically track each product); it will implement defect prevention strategies; it will create an electronic inventory control system that is accountable for all ASIC material from inception to delivery; it will electronically collect and store any and all required quality evidence and most of the electronic BEOL data; and it will create a management reporting module with production statistics and timelines. The defect prevention strategies include the use of 2D marks on our ASICs with 2D scanners so that there will be no manual entry of part numbers (scanners), will not allow testing the wrong parts in Test and Burn-in. Other defect prevention strategies will negate the possibility of neither using the wrong test or burn-in program for any part nor the use of BEOL machines or boards that are out of calibration. In summary, EPCS is being implemented and it will greatly improve the product acceptance through full electronic data collection and quality control and defect prevention through bar codes, scanners, tracking training of personnel, and tracking tool availability.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Three-Dimensional Modeling of the Explicit Chemistry of Organic Aerosols: Formation, Removal, and Comparison with Observations

The major goals of the project were to further our understanding of the formation of secondary organic aerosols (SOA) from major anthropogenic and biogenic precursors, and to evaluate the GECKO-A chemistry model in the context of three DOE-led field campaigns (GoAmazon, BBOP, and HI-SCALE) with the long-term objective of improving the treatment of organic gases and particles in three-dimensional regional and global models. The three field campaigns were selected to evaluate and improve specific aspects of GECKO-A: (i) GoAmazon to help quantify interactions of biogenic and anthropogenic emissions; (ii) BBOP to predict the UV-visible absorption properties of biomass burning aerosols (brown carbon) from explicit molecular properties; and (iii) HI-SCALE to evaluate new model components that include aqueous (cloud) processing of organic gases and aerosols.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

UH cosmic rays: Possible origin in massive stars

The origin of the Z greater than 28, ultraheavy, cosmic rays in supernova explosions of massive stars is considered. For Z greater than 70, the UH data is dominated by an r-process source distribution, but for the elements just beyond iron, 29 or = Z less than 36, the data cannot be explained by any single process of nucleosynthesis. This problem is solved naturally in a massive star model by secondary neutron capture reactions occuring during core helium burning and during explosive carbon burning. Interstellar propagation calculations were performed with these episodes of synthesis as source distributions, and the results offer an explanation for the current UH cosmic-ray data. The heavy element synthesis during explosive carbon burning is reexamined using more realistic initial conditions given by the post-helium-burning configuration of the star. Effects of preferential acceleration are considered, and experimental tests are discussed.

Wefel, J. P.↗

Supermassive monopole stars

In this paper, the evolution of a superheavy monopole-dominated universe is reexamined; in particular, the evolution of rotation-stabilized monopole-burning 'stars', balancing effects of radiation and annihilation are examined. In contrast to earlier results, it is found that this can lead to complete burning of all poles present in such an object within finite time. If monopoles can be brought within acceptable limits by dynamical processes, an inflationary epoch of the early universe need not be associated with grand unification.

Fry, J. N.↗

Feasibility of using GPS measurements for OMV attitude update

This paper presents the results of a feasibility study to determine whether the measurements from GPS satellites can be used to estimate the OMV attitude to an accuracy comparable to the onboard sun sensors, i.e., better than 0.5 degree in each axis. The results documented in this paper demonstrate that OMV attitude can be estimated to an accuracy of 0.1 - 0.5 degree in each axis by processing GPS measurements in an onboard integrated, 17-state GPS/inertial navigation filter. The result is particularly significant for missions of short duration burns where accurate attitude information is needed to minimize guidance and control errors. It is shown that the GPS attitude technique described in this paper can be easily implemented in the current OMV navigation system design. Results reported in this paper are expected to support the goal of developing a fault-tolerant guidance, navigation, and control system offering an improved total navigation performance for the OMV.

Upadhyay, Triveni N.↗

Performance of an Integrated Gasification Direct-Fired Supercritical CO2 Power Cycle

This presentation discusses development and performance results of a coal gasification system integrated with a direct-fired supercritical CO2 (sCO2) power cycle. In this plant, coal is first gasified and cleaned in order to avoid introducing sulfur and particulate matter into the sCO2 cycle, with the sCO2 cycle’s oxy-combustor burning the cleaned syngas with oxygen in a recycled sCO2 stream. The plant is inherently amenable to carbon capture and storage (CCS) processes, as it produces a high pressure exhaust stream that is largely comprised of CO2. The baseline direct sCO2 cycle performance is discussed and compared to IGCC and oxy-coal AUSC reference plants with CCS. The sensitivity of the sCO2 cycle’s performance to various operating parameters is also discussed, as well as the effect of various heat integration options on thermal efficiency, operability, and cost.

Shelton, Walter↗

Computed potential energy surfaces for chemical reactions

The objective was to obtain accurate potential energy surfaces (PES's) for a number of reactions which are important in the H/N/O combustion process. The interest in this is centered around the design of the SCRAM jet engine for the National Aerospace Plane (NASP), which was envisioned as an air-breathing hydrogen-burning vehicle capable of reaching velocities as large as Mach 25. Preliminary studies indicated that the supersonic flow in the combustor region of the scram jet engine required accurate reaction rate data for reactions in the H/N/O system, some of which was not readily available from experiment. The most important class of combustion reactions from the standpoint of the NASP project are radical recombinaton reactions, since these reactions result in most of the heat release in the combustion process. Theoretical characterizations of the potential energy surfaces for these reactions are presented and discussed.

Walch, Stephen P.↗

Composition and Evolution of Southeast Asian Biomass Burning Trace Gas Emissions during a September 2019 Borneo Burning Event

Biomass burning in Southeast Asia is a major pollutant source contributing to poor air quality throughout the region. Thus, understanding these emissions is critical for predicting and mitigating their health impacts. While there have been many studies reporting ground-based and satellite measurements, regional scale measurements to tie the two together have not been common in this region. The 2019 Cloud, Aerosol and Monsoon Processes Philippines Experiment (CAMP2Ex) field campaign examined Southeast Asian regional sources and their effects on aerosol/cloud interactions using a combination of airborne, shipborne, and ground-based measurements. On 16 September, a major biomass burning event primarily located on Borneo was sampled via aircraft in the near-field over the Sulu Sea, while on 17 September, the aged plume from the event was sampled again east of the Philippines over the Philippine Sea. We discuss the emissions from this event, using tracer-tracer ratios (e.g. MCE, NOy/CO), HYSPLIT back trajectories, and HSRL-2 lidar retrievals to differentiate sources and provide insight into the composition and chemical evolution of the plume. This case study provides a valuable perspective into the accuracy of emission inventories as well as a rare opportunity for satellite validation.

Joshua P DiGangi↗

From BASE-ASIA Toward 7-SEAS: A Satellite-Surface Perspective of Boreal Spring Biomass-Burning Aerosols and Clouds in Southeast Asia

In this paper, we present recent field studies conducted by NASA's SMART-COMMIT (and ACHIEVE, to be operated in 2013) mobile laboratories, jointly with distributed ground-based networks (e.g., AERONET, http://aeronet.gsfc.nasa.gov/ and MPLNET, http://mplnet.gsfc.nasa.gov/) and other contributing instruments over northern Southeast Asia. These three mobile laboratories, collectively called SMARTLabs (cf. http://smartlabs.gsfc.nasa.gov/, Surface-based Mobile Atmospheric Research & Testbed Laboratories) comprise a suite of surface remote sensing and in-situ instruments that are pivotal in providing high spectral and temporal measurements, complementing the collocated spatial observations from various Earth Observing System (EOS) satellites. A satellite-surface perspective and scientific findings, drawn from the BASE-ASIA (2006) field deployment as well as a series of ongoing 7-SEAS (2010-13) field activities over northern Southeast Asia are summarized, concerning (i) regional properties of aerosols from satellite and in situ measurements, (ii) cloud properties from remote sensing and surface observations, (iii) vertical distribution of aerosols and clouds, and (iv) regional aerosol radiative effects and impact assessment. The aerosol burden over Southeast Asia in boreal spring, attributed to biomass burning, exhibits highly consistent spatial and temporal distribution patterns, with major variability arising from changes in the magnitude of the aerosol loading mediated by processes ranging from large-scale climate factors to diurnal meteorological events. Downwind from the source regions, the tightly coupled-aerosolecloud system provides a unique, natural laboratory for further exploring the micro- and macro-scale relationships of the complex interactions. The climatic significance is presented through large-scale anti-correlations between aerosol and precipitation anomalies, showing spatial and seasonal variability, but their precise cause-and-effect relationships remain an open-ended question. To facilitate an improved understanding of the regional aerosol radiative effects, which continue to be one of the largest uncertainties in climate forcing, a joint international effort is required and anticipated to commence in springtime 2013 in northern Southeast Asia.

biomass burning aerosols↗

Samarium electrodeposited acetate and oxide thin films on stainless steel substrate characterized by XPS

Characterization of a samarium thin film deposited on a stainless steel substrate using molecular electrodeposition was carried out using a Thermo Scientific K-Alpha X-ray photoelectron spectrometer. We studied two types of samarium electrodeposition samples, one as-deposited and one heated to 700 °C in an air flow. Survey scans include peaks coming from the stainless steel substrate, such as Fe and Cr. An X-ray photoelectron spectroscopy (XPS) survey spectrum, Sm 3d, C 1s, and O 1s narrow scans are shown. It was determined that the heating process decomposed the deposited Sm acetate to Sm 2 O 3 using XPS.

36 MATERIALS SCIENCE↗

Hierarchical Storage Management at the NASA Center for Computational Sciences: From UniTree to SAM-QFS

This paper presents the data management issues associated with a large center like the NCCS and how these issues are addressed. More specifically, the focus of this paper is on the recent transition from a legacy UniTree (Legato) system to a SAM-QFS (Sun) system. Therefore, this paper will describe the motivations, from both a hardware and software perspective, for migrating from one system to another. Coupled with the migration from UniTree into SAM-QFS, the complete mass storage environment was upgraded to provide high availability, redundancy, and enhanced performance. This paper will describe the resulting solution and lessons learned throughout the migration process.

Salmon, Ellen↗