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At least 757 records · Page 42

Characterization of rhenium compounds obtained by electrochemical synthesis after aging process

The proper identification of the molecular nature of the aged rhenium compound obtained by means of electrodeposition from an alkaline aqueous electrolyte was determined. Chemical, structural and vibrational experimental characterization of the aged Re compound showed agreement with quantum-computations, thereby allowing the unambiguous identification of the Re compound as H(ReO{sub 4})H{sub 2}O. - Graphical abstract: Rhenium oxides were electrodeposited on a copper surface and after environmental aging was formed the H(ReO{sub 4})H{sub 2}O compound. The characterization of the synthesized material was made through the comparison of experimental evidence with quantum mechanical computations carried out by means of density functional theory (DFT). - Highlights: • Aged rhenium compound obtained by means of electrodeposition was studied. • The study was made by combining experimental and DFT-computational information. • The aged electrodeposited material is consistent with the H(ReO{sub 4})H{sub 2}O compound.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effect of as-cast microstructure heterogeneity on aging behavior of a high-pressure die-cast A380 alloy

Highlights: • The surface layer hardened much faster than the central region during age. • More quantity of finer precipitates was found in the surface layer during age. • The surface layer had a lower activation energy of precipitation. • Si promoted the precipitation via inducing dislocations in matrix. - Abstract: Microstructure and hardness evolution of a vacuum-assistant die-cast A380 alloy during heat treatment were investigated. Both surface layer and central region of the casting component were analyzed in die-cast state, solutionized state and artificial age state. During the artificial age, the surface layer hardened more significantly than the central region due to faster precipitation and more refined hardening phases in the surface layer. Detailed analysis on the macro-segregation, microstructure morphology and grain size revealed that the different aging behaviors exhibiting in the surface and the central region were mainly attributed to a combining effect of the enrichment of Si and Cu at the surface layer, the fully-divorced morphology of eutectic in die-cast microstructure, and the presence of the externally solidified crystals at the central region. The presence of the Si particles, which exhibited quite different thermal expansion properties, changed the density and the distribution of the dislocations in the α-Al matrix, and consequently changed the precipitation of the hardening phases.

36 MATERIALS SCIENCE↗

High-energy synchrotron radiation X-ray diffraction measurements during in situ aging of a NiTi-15 at. % Hf high temperature shape memory alloy

NiTiHf high temperature shape memory alloys (HTSMAs) have begun to show considerable progress in their ability to be manufactured and are now on the cusp of becoming viable alloys for use in the aerospace industry, mainly as actuation devices. By aging the alloys at intermediate temperatures between 450 and up to 700 °C, Ni-rich NiTiHf HTSMAs form the H-phase, a Ni-rich nanoscale precipitate which can be used to strengthen the alloy and improve the shape memory response; however, precipitate phase evolution and growth has not yet been studied in-situ nor have the effects of previous thermo-mechanical processing on their formation. In this study, H-phase precipitate formation is observed experimentally in situ during aging of a Ni-rich NiTiHf alloy using high energy synchrotron radiation X-ray diffraction (SR-XRD) measurements. The effects of prior thermo-mechanical treatments, i.e. hot and cold rolling, on its formation rate and coarsening rate are compared. It is shown that growth of the H-phase can be observed in situ using SR-XRD and the H-phase formation rate seems to exhibit linear growth when aging at 550 °C, while increasing the temperature to 650 °C shows a logarithmic trend that plateaus after approximately 1 h of aging. Other properties such as incubation time, austenite lattice strains, texture evolution, and overall comparison between hot and cold rolling are discussed. New potential peak age conditions are suggested based on the diffraction data and evaluated using three-point bending and TEM imaging.

36 MATERIALS SCIENCE↗

Aging mechanisms in RTV polysiloxane foams

The long-term use of polysiloxane foams requires a good understanding of the diverse factors that may influence their performance. The aim of the present work was to understand the interplay between in-service environments and reactive species that reside in the foams. Two foams (SX358 and S5370) were thermally aged under compressive strain to gauge the onset of compression set, an indicator of degradation. In this study, experiments were performed by either aging the foams in open air containers or in high humidity environments. Our results indicated that foams aged in open air environments exhibited less compression set than when aged in presence of moisture. These results were analyzed in terms of post-curing reactions, hydrolysis and rearrangement of the network, which are promoted by active residues that are left in the foam from the curing process. In particular, the residues from tin octoate, the catalyst used in the cure of the foams, were identified and their role in promoting aging was determined. Reactions were either catalyzed by tin(II) species or by a combination of trace amounts of water and octanoic acid, a product of the hydrolysis of tin octoate. More precisely, this work demonstrated that reactive residues promote chemical changes in the polymer, which resulted in compression set. On the other hand, the oxidized residues of the tin octoate show no catalytic activity towards promoting condensation reactions between silanol groups. In conclusion, our work established that, depending on service conditions, certain residues are more harmful to the foam's lifetime than others.

36 MATERIALS SCIENCE↗

Direct measurement of energy loss due to aging effects in the condensed phase explosive PBX 9404

The explosive performance of PBX 9404, a condensed phase explosive with HMX and nitrocellulose reactive ingredients, was evaluated using the detonation cylinder expansion test after it had been naturally aged for over 46 years. Nitrocellulose is known to chemically degrade with age, but the corresponding effect on explosive performance is currently unknown. Two new cylinder tests were fielded with the oldest known PBX 9404 explosive (>46 years) and the data was compared with prior PBX 9404 cylinder test data. A method for comparing wall motion data collected by streak camera and laser interferometry diagnostics was also introduced. Analysis of the cylinder motion indicated that the aged explosive exhibits decreased performance, which varied with cylinder expansion radius and product specific volume. This energy decrement was found to be 0.8% of the total initial explosive energy per decade of age at a product volume of 7.0 cc/g. In conclusion, the measured energy decrement in explosives older than 37 years exceeds the chemical energy content of nitrocellulose, indicating that nitrocellulose decomposition radicals are likely degrading the normally stable HMX molecules during the aging process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Zuotai and HgS differ from HgCl{sub 2} and methyl mercury in Hg accumulation and toxicity in weanling and aged rats

Mercury sulfides are used in Ayurvedic medicines, Tibetan medicines, and Chinese medicines for thousands of years and are still used today. Cinnabar (α-HgS) and metacinnabar (β-HgS) are different from mercury chloride (HgCl{sub 2}) and methylmercury (MeHg) in their disposition and toxicity. Whether such scenario applies to weanling and aged animals is not known. To address this question, weanling (21 d) and aged (450 d) rats were orally given Zuotai (54% β-HgS, 30 mg/kg), HgS (α-HgS, 30 mg/kg), HgCl{sub 2} (34.6 mg/kg), or MeHg (MeHgCl, 3.2 mg/kg) for 7 days. Accumulation of Hg in kidney and liver, and the toxicity-sensitive gene expressions were examined. Animal body weight gain was decreased by HgCl{sub 2} and to a lesser extent by MeHg, but unaltered after Zuotai and HgS. HgCl{sub 2} and MeHg produced dramatic tissue Hg accumulation, increased kidney (kim-1 and Ngal) and liver (Ho-1) injury-sensitive gene expressions, but such changes are absent or mild after Zuotai and HgS. Aged rats were more susceptible than weanling rats to Hg toxicity. To examine roles of transporters in Hg accumulation, transporter gene expressions were examined. The expression of renal uptake transporters Oat1, Oct2, and Oatp4c1 and hepatic Oatp2 was decreased, while the expression of renal efflux transporter Mrp2, Mrp4 and Mdr1b was increased following HgCl{sub 2} and MeHg, but unaffected by Zuotai and HgS. Thus, Zuotai and HgS differ from HgCl{sub 2} and MeHg in producing tissue Hg accumulation and toxicity, and aged rats are more susceptible than weanling rats. Transporter expression could be adaptive means to reduce tissue Hg burden. - Highlights: • Aged rats are more susceptible to HgCl{sub 2} and MeHg toxicity than weanling rats. • Zuotai and HgS differ from HgCl{sub 2} and MeHg in producing toxicity. • Zuotai and HgS differ from HgCl{sub 2} and MeHg in much less tissue Hg accumulation. • Renal transporters are altered by HgCl{sub 2} and MeHg, but unaffected by Zuotai and HgS • Liver transporters are less affected than kidney transporters by HgCl{sub 2} and MeHg.

60 APPLIED LIFE SCIENCES↗

Production of Secondary Organic Aerosol During Aging of Biomass Burning Smoke From Fresh Fuels and Its Relationship to VOC Precursors

After smoke from burning biomass is emitted into the atmosphere, chemical and physical processes change the composition and amount of organic aerosol present in the aged, diluted plume. During the fourth Fire Lab at Missoula Experiment, we performed smog-chamber experiments to investigate formation of secondary organic aerosol (SOA) and multiphase oxidation of primary organic aerosol (POA). We simulated atmospheric aging of diluted smoke from a variety of biomass fuels while measuring particle composition using high-resolution aerosol mass spectrometry. We quantified SOA formation using a tracer ion for low-volatility POA as a reference standard (akin to a naturally occurring internal standard). We report these smoke aging experiments revealed variable organic aerosol (OA) enhancements, even for smoke from similar fuels and aging mechanisms. This variable OA enhancement correlated well with measured differences in the amounts of emitted volatile organic compounds (VOCs) that could subsequently be oxidized to form SOA. For some aging experiments, we were able to predict the SOA production to within a factor of 2 using a fuel-specific VOC emission inventory that was scaled by burn-specific toluene measurements. For fires of coniferous fuels that were dominated by needle burning, volatile biogenic compounds were the dominant precursor class. For wiregrass fires, furans were the dominant SOA precursors. We used a POA tracer ion to calculate the amount of mass lost due to gas-phase oxidation and subsequent volatilization of semivolatile POA. Less than 5% of the POA mass was lost via multiphase oxidation-driven evaporation during up to 2 hr of equivalent atmospheric oxidation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Machine Learning Prediction of Tritium‐Helium Groundwater Ages in the Central Valley, California, USA

Abstract Groundwater ages provides insight into recharge rates, flow velocities, and vulnerability to contaminants. The ability to predict groundwater ages based on more accessible parameters via Machine Learning (ML) would advance our ability to guide sustainable management of groundwater resources. In this study, ML models were trained and tested on a large data set of tritium concentrations and tritium‐helium groundwater ages from the California Central Valley, a large groundwater basin with complex land use, irrigation, and water management practices. The ML models were trained on 63 features, including location, well construction information, landscape characteristics, and climate variables, water chemistry, and stable isotopes. The Bagging regressor method can accurately classify (F1‐score = 0.91) groundwater samples as either modern or pre‐modern whereas the accuracy of the ML prediction of continuous tritium‐helium groundwater ages is limited and explains only of the variability in this data set. In general, ML groundwater age prediction relies mostly on features related to (a) the source of groundwater recharge, (b) contaminant history, (c) aquifer materials, (d) well construction, and (e) geochemical reactions along flow paths.

54 ENVIRONMENTAL SCIENCES↗

The age distribution of global soil carbon inferred from radiocarbon measurements

Soils contain more carbon than the atmosphere and vegetation combined. An increased flow of carbon from the atmosphere into soil pools could help mitigate anthropogenic emissions of carbon dioxide and climate change. Yet we do not know how quickly soils might respond because the age distribution of soil carbon is uncertain. Here we used 789 radiocarbon (Δ 14 C) profiles, along with other geospatial information, to create globally gridded datasets of mineral soil Δ 14 C and mean age. We found that soil depth is a primary driver of Δ 14 C, whereas climate (for example, mean annual temperature) is a major control on the spatial pattern of Δ 14 C in surface soil. Integrated to a depth of 1m, global soil carbon has a mean age of 4,830 ± 1,730 yr, with older carbon in deeper layers and permafrost regions. In contrast, vertically resolved land models simulate Δ 14 C values that imply younger carbon ages and a more rapid carbon turnover. Overall, our data-derived estimates of older mean soil carbon age suggest that soils will accumulate less carbon than predicted by current Earth system models over the twenty-first century. Reconciling these models with the global distribution of soil radiocarbon will require a better representation of the mechanisms that control carbon persistence in soils.

58 GEOSCIENCES↗

The role of oxygen in automotive grade lithium-ion battery cathodes: an atomistic survey of ageing

The rising demand for high-performance lithium-ion batteries, pivotal to electric transportation, hinges on key materials like the Ni-rich layered oxide LiNi x Co y Al z O 2 (NCA) used in cathodes. The present study investigates the redox mechanisms, with particular focus on the role of oxygen in commercial NCA electrodes, both fresh and aged under various conditions (aged cells have performed >900 cycles until a cathode capacity retention of ~80%). Our findings reveal that oxygen participates in charge compensation during NCA delithiation, both through changes in transition metal (TM)–O bond hybridization and formation of partially reversible O 2 , the latter occurs already below 3.8 V vs. Li/Li + . Aged NCA material undergoes more significant changes in TM–O bond hybridization when cycling above 50% SoC, while reversible O 2 formation is maintained. Nickel is found to be redox active throughout the entire delithiation and shows a more classical oxidation state change during cycling with smaller changes in the Ni–O hybridization. By contrast, Co redox activity relies on a stronger change in Co–O hybridization, with only smaller Co oxidation state changes. The Ni–O bond displays an almost twice as large change in its bond length on cycling as the Co–O bond. The Ni–O 6 octahedra are similar in size to the Co–O 6 octahedra in the delithiated state, but are larger in the lithiated state, a size difference that increases with battery ageing. These contrasting redox activities are reflected directly in structural changes. The NCA material exhibits the formation of nanopores upon ageing, and a possible connection to oxygen redox activity is discussed. The difference in interaction of Ni and Co with oxygen provides a key understanding of the mechanism and the electrochemical instability of Ni-rich layered transition metal oxide electrodes. Our research specifically highlights the significance of the role of oxygen in the electrochemical performance of electric-vehicle-grade NCA electrodes, offering important insights for the creation of next-generation long-lived lithium-ion batteries.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mass–metallicity and star formation rate in galaxies: A complex relation tuned to stellar age

In this work we study the stellar mass–metallicity relation (MZR) of an extended sample of star-forming galaxies in the local Universe and its possible dependence on the star formation rate (SFR). We selected a sample of approximately 195 000 Sloan Digital Sky Survey (SDSS) star-forming galaxies up to z = 0.22 with the aim of analysing the behaviour of the MZR with respect to SFR whilst taking into account the age of their stellar populations. For the first time, with this sample, we obtained aperture corrected oxygen and nitrogen-to-oxygen abundances (O/H and N/O, respectively) and SFR using the empirical prescriptions from the Calar Alto Legacy Integral Field Area (CALIFA) survey. To perform this study we also make use of the stellar mass of the galaxies and the parameter Dn(4000) as a proxy for the age of the stellar population. We derive a robust MZR locus, which is found to be fully consistent with the ‘anchoring’ points of a selected set of well-studied nearby galaxies for which the chemical abundance has been derived using the direct method. We observe a complex relation between MZR and SFR across the whole range of galaxy mass and metallicity, where the slope changes seen in the O/H–SFR plane present a pattern that seems to be tuned to the stellar age of the galaxies, and therefore stellar age has to be taken into account in the stellar mass–metallicity–SFR relation. In order to provide an answer to the question of whether or not the MZR depends on the SFR, it is essential to take into account the age of the stellar populations of galaxies. A strong dependence of the MZR on SFR is observed mainly for star-forming galaxies with strong SFR values and low D n (4000). The youngest galaxies of our SDSS sample show the highest SFR measured for their stellar mass.

79 ASTRONOMY AND ASTROPHYSICS↗

Estimating Cohort Survival through Tributaries for Salmonid Populations with Variable Ages at Migration

Abstract Survival of juvenile anadromous Pacific salmonids from their earliest age of seaward movement (“out-migration”) through the tributaries that connect their rearing grounds to larger-order rivers (“cohort survival”) is an important yet often unmonitored factor in the complex life history of these species. Populations with variable age at out-migration (e.g., steelhead Oncorhynchus mykiss) or multiple juvenile rearing strategies (e.g., Chinook Salmon O. tshawytscha) raise particular challenges in survival monitoring. A multiple-state release–recapture model is presented to estimate cohort survival for salmonid species with variable age at out-migration and demonstrated in two case studies. Annual releases of fish tagged with passive integrated transponder (PIT) tags from the same brood year (cohort) and their detections by instream PIT-tag detection arrays in tributaries and at hydroelectric dams are used to estimate survival through tributaries and the age composition of juvenile migrants reaching downstream sites. The 2010 cohort of Chinook Salmon from the Chiwawa River in Washington State had estimated survival of 0.59 to the middle Wenatchee River array in Tumwater Dam Reservoir (river distance of 30 km) and 0.12 to McNary Dam (364 km) on the Columbia River. The age composition shifted from 60.1% subyearlings at the Wenatchee River array to 100% yearlings at McNary Dam, reflecting the use of the Wenatchee River as a nonnatal rearing area, whereas McNary Dam is in the migratory corridor. The 2010 cohort of steelhead from the Twisp River in Washington State had estimated survival from the yearling stage of 0.30 to Rocky Reach Dam (146 km from the Twisp River mouth) on the Columbia River and 0.17 to McNary Dam (439 km). The low survival to the Columbia River resulted from both mortality and adoption of a resident life history and reflects the diverse population structure in the Twisp River. Received February 4, 2015; accepted June 11, 2015

Buchanan, Rebecca A.↗

THE AGE OF THE LOCAL INTERSTELLAR BUBBLE

The Local Interstellar Bubble is an irregular region from 50 to 150 pc from the Sun in which the interstellar gas density is 10{sup -2}-10{sup -3} of that outside the bubble and the interstellar temperature is 10{sup 6} K. Evidently most of the gas was swept out by one or more supernovae. I explored the stellar contents and ages of the region from visual double stars, spectroscopic doubles, single stars, open clusters, emission regions, X-ray stars, planetary nebulae, and pulsars. The bubble has three sub-regions. The region toward the galactic center has stars as early as O9.5 V and with ages of 2-4 M yr. It also has a pulsar (PSRJ1856-3754) with a spin-down age of 3.76 Myr. That pulsar is likely to be the remnant of the supernova that drove away most of the gas. The central lobe has stars as early as B7 V and therefore an age of about 160 Myr or less. The Pleiades lobe has stars as early as B3 and therefore an age of about 50 Myr. There are no obvious pulsars that resulted from the supernovae that cleared out those areas. As found previously by Welsh and Lallement, the bubble has five B stars along its perimeter that show high-temperature ions of O VI and C II along their lines of sight, confirming its high interstellar temperature.

79 ASTRONOMY AND ASTROPHYSICS↗

AGE DETERMINATION FOR 346 NEARBY STARS IN THE HERSCHEL DEBRIS SURVEY

DEBRIS is a flux-limited survey of nearby stars (spectral types A-M) for evidence of debris disks with the Herschel Space Observatory. One goal of the survey is to determine disk incidence as a function of various stellar parameters. Understanding debris disk evolution depends on knowledge of the precise age of stars around which these debris disks are found. However, finding ages for field stars is notoriously difficult. Furthermore, in an unbiased sample like DEBRIS, one is working with stars across many spectral types. This requires a multi-method approach to age determination. In this paper, we outline several methods of age determination broken down by spectral type, including some strengths and limitations of each method. In total, we were able to calculate ages for 263 of 274 F-, G-, and K-type stars, and all 83 A-type stars in the DEBRIS sample.

79 ASTRONOMY AND ASTROPHYSICS↗

THE AGE-METALLICITY RELATIONSHIP OF THE LARGE MAGELLANIC CLOUD FIELD STAR POPULATION FROM WIDE-FIELD WASHINGTON PHOTOMETRY

We analyze age and metallicity estimates for an unprecedented database of some 5.5 million stars distributed throughout the Large Magellanic Cloud (LMC) main body, obtained from CCD Washington CT{sub 1} photometry, reported on in Piatti et al. We produce a comprehensive field star age-metallicity relationship (AMR) from the earliest epoch until {approx}1 Gyr ago. This AMR reveals that the LMC has not evolved chemically as either a closed-box or bursting system, exclusively, but as a combination of both scenarios that have varied in relative strength over the lifetime of the galaxy, although the bursting model falls closer to the data in general. Furthermore, while old and metal-poor field stars have been preferentially formed in the outer disk, younger and more metal-rich stars have mostly been formed in the inner disk, confirming an outside-in formation. We provide evidence for the formation of stars between 5 and 12 Gyr, during the cluster age gap, although chemical enrichment during this period was minimal. We find no significant metallicity gradient in the LMC. We also find that the range in the metallicity of an LMC field has varied during the lifetime of the LMC. In particular, we find only a small range of the metal abundance in the outer disk fields, whereas an average range of {Delta}[Fe/H] = +0.3 {+-} 0.1 dex appears in the inner disk fields. Finally, the cluster and field AMRs show a satisfactory match only for the last 3 Gyr, while for the oldest ages (>11 Gyr), the cluster AMR is a remarkable lower envelope to the field AMR. Such a difference may be due to the very rapid early chemical evolution and lack of observed field stars in this regime, whereas the globular clusters are easily studied. This large difference is not easy to explain as coming from stripped ancient Small Magellanic Cloud (SMC) clusters, although the field SMC AMR is on average {approx}0.4 dex more metal-poor at all ages than that of the LMC but otherwise very similar.

79 ASTRONOMY AND ASTROPHYSICS↗

THE STELLAR AGES AND MASSES OF SHORT GAMMA-RAY BURST HOST GALAXIES: INVESTIGATING THE PROGENITOR DELAY TIME DISTRIBUTION AND THE ROLE OF MASS AND STAR FORMATION IN THE SHORT GAMMA-RAY BURST RATE

We present multi-band optical and near-infrared observations of 19 short {gamma}-ray burst (GRB) host galaxies, aimed at measuring their stellar masses and population ages. The goals of this study are to evaluate whether short GRBs track the stellar mass distribution of galaxies, to investigate the progenitor delay time distribution, and to explore any connection between long and short GRB progenitors. Using single stellar population models we infer masses of log(M{sub *}/M{sub sun}) {approx} 8.8-11.6, with a median of (log(M{sub *}/M{sub sun})) {approx} 10.1, and population ages of {tau}{sub *} {approx} 0.03-4.4 Gyr with a median of ({tau}{sub *}) {approx} 0.3 Gyr. We further infer maximal masses of log(M{sub *}/M{sub sun}) {approx} 9.7-11.9 by assuming stellar population ages equal to the age of the universe at each host's redshift. Comparing the distribution of stellar masses to the general galaxy mass function, we find that short GRBs track the cosmic stellar mass distribution only if the late-type hosts generally have maximal masses. However, there is an apparent dearth of early-type hosts compared to the equal contribution of early- and late-type galaxies to the cosmic stellar mass budget. Similarly, the short GRB rate per unit old stellar mass appears to be elevated in the late-type hosts. These results suggest that stellar mass may not be the sole parameter controlling the short GRB rate, and raise the possibility of a two-component model with both mass and star formation playing a role (reminiscent of the case for Type Ia supernovae). If short GRBs in late-type galaxies indeed track the star formation activity, the resulting typical delay time is {approx}0.2 Gyr, while those in early-type hosts have a typical delay of {approx}3 Gyr. Using the same stellar population models, we fit the broadband photometry for 22 long GRB host galaxies in a similar redshift range and find that they have significantly lower masses and younger population ages, with (log(M{sub *}/M{sub sun})) {approx} 9.1 and ({tau}{sub *}) {approx} 0.06 Gyr, respectively; their maximal masses are similarly lower, (log(M{sub *}/M{sub sun})) {approx} 9.6, and as expected do not track the galaxy mass function. Most importantly, the two GRB host populations remain distinct even if we consider only the star-forming hosts of short GRBs, supporting our previous findings (based on star formation rates and metallicities) that the progenitors of long and short GRBs in late-type galaxies are distinct. Given the much younger stellar populations of long GRB hosts (and hence of long GRB progenitors), and the substantial differences in host properties, we caution against the use of Type I and II designations for GRBs since this may erroneously imply that all GRBs which track star formation activity share the same massive star progenitors.

79 ASTRONOMY AND ASTROPHYSICS↗

INSIDE OUT AND UPSIDE DOWN: TRACING THE ASSEMBLY OF A SIMULATED DISK GALAXY USING MONO-AGE STELLAR POPULATIONS

We analyze the present day structure and assembly history of a high-resolution hydrodynamic simulation of the formation of a Milky-Way-(MW)-like disk galaxy, from the ''Eris'' simulation suite, dissecting it into cohorts of stars formed at different epochs of cosmic history. At z = 0, stars with t{sub form} < 2 Gyr mainly occupy the stellar spheroid, with the oldest (earliest forming) stars having more centrally concentrated profiles. The younger age cohorts populate disks of progressively longer radial scale lengths and shorter vertical scale heights. At a given radius, the vertical density profiles and velocity dispersions of stars vary smoothly as a function of age, and the superposition of old, vertically extended and young, vertically compact cohorts gives rise to a double-exponential profile like that observed in the MW. Turning to formation history, we find that the trends of spatial structure and kinematics with stellar age are largely imprinted at birth, or immediately thereafter. Stars that form during the active merger phase at z > 3 are quickly scattered into rounded, kinematically hot configurations. The oldest disk cohorts form in structures that are radially compact and relatively thick, while subsequent cohorts form in progressively larger, thinner, colder configurations from gas with increasing levels of rotational support. The disk thus forms ''inside out'' in a radial sense and ''upside down'' in a vertical sense. Secular heating and radial migration influence the final state of each age cohort, but the changes they produce are small compared to the trends established at formation. The predicted correlations of stellar age with spatial and kinematic structure are in good qualitative agreement with the correlations observed for mono-abundance stellar populations in the MW.

79 ASTRONOMY AND ASTROPHYSICS↗

THE INSIDIOUS BOOSTING OF THERMALLY PULSING ASYMPTOTIC GIANT BRANCH STARS IN INTERMEDIATE-AGE MAGELLANIC CLOUD CLUSTERS

In the recent controversy about the role of thermally pulsing asymptotic giant branch (TP-AGB) stars in evolutionary population synthesis (EPS) models of galaxies, one particular aspect is puzzling: TP-AGB models aimed at reproducing the lifetimes and integrated fluxes of the TP-AGB phase in Magellanic Cloud (MC) clusters, when incorporated into EPS models, are found to overestimate, to various extents, the TP-AGB contribution in resolved star counts and integrated spectra of galaxies. In this paper, we call attention to a particular evolutionary aspect, linked to the physics of stellar interiors, that in all probability is the main cause of this conundrum. As soon as stellar populations intercept the ages at which red giant branch stars first appear, a sudden and abrupt change in the lifetime of the core He-burning phase causes a temporary 'boost' in the production rate of subsequent evolutionary phases, including the TP-AGB. For a timespan of about 0.1 Gyr, triple TP-AGB branches develop at slightly different initial masses, causing their frequency and contribution to the integrated luminosity of the stellar population to increase by a factor of ∼2. The boost occurs for turn-off masses of ∼1.75 M{sub ☉}, just in the proximity of the expected peak in the TP-AGB lifetimes (for MC metallicities), and for ages of ∼1.6 Gyr. Coincidently, this relatively narrow age interval happens to contain the few very massive MC clusters that host most of the TP-AGB stars used to constrain stellar evolution and EPS models. This concomitance makes the AGB-boosting particularly insidious in the context of present EPS models. As we discuss in this paper, the identification of this evolutionary effect brings about three main consequences. First, we claim that present estimates of the TP-AGB contribution to the integrated light of galaxies derived from MC clusters are biased toward too large values. Second, the relative TP-AGB contribution of single-burst populations falling in this critical age range cannot be accurately derived by approximations such as the fuel consumption theorem, which ignore, by construction, the above evolutionary effect. Third, a careful revision of AGB star populations in intermediate-age MC clusters is urgently demanded, promisingly with the aid of detailed sets of stellar isochrones.

79 ASTRONOMY AND ASTROPHYSICS↗