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At least 739 records · Page 41

Synthesis of Platinum Nanoparticles Supported on Fused Nanosized Carbon Spheres Derived from Sustainable Source for Application in a Hydrogen Generation Reaction

The dwindling supply of fossil fuels has prompted the search for an alternative energy source that could effectively replace them. Potential renewable energy sources such as solar, wind, tidal, and geothermal are all promising but each has its own drawbacks. Hydrogen gas on the other hand can be combusted to produce energy with only water as a byproduct and can be steadily generated via the aqueous media hydrolysis reaction of Sodium Borohydride (NaBH 4 ). This study successfully synthesized fused carbon spheres derived from sugar and decorated them with platinum nanoparticles to form a novel composite material (PtFCS) for catalyzing this reaction. The platinum nanoparticles were produced by reducing chloroplatinic acid in a solution with sodium borohydride and using sodium citrate as a capping agent for the nanoparticles. Transmission electron microscopy (TEM), Energy-dispersive X-ray spectroscopy (EDS), Fourier-transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) were used to characterize and determine the size and shape of the Pt nanoparticles (PtNPs) and fused carbon spheres. TEM was able to determine the average size of the fused carbon spheres to be 200 nm and the average size for the PtNPs to be 2–3 nm. The PtFCS composite was tested for its ability to catalyze the hydrolysis of NaBH 4 under various reaction conditions including various solution pH, various temperatures, and various dosages of sodium borohydride. The catalyst was found to perform the best under acidic solution conditions (pH 6), producing hydrogen at a rate of 0.0438 mL/mg cat ·min. The catalyst was determined to have an activation energy of 53.0 kJ/mol and could be used multiple times in succession with no loss in the volume of hydrogen produced. This sugar-derived composite catalyst shows promise and could be implemented as a sustainable catalyst for the generation of hydrogen fuel.

36 MATERIALS SCIENCE↗

Magnetic Field Strength Effects on Nucleosynthesis from Neutron Star Merger Outflows

Abstract Magnetohydrodynamic turbulence drives the central engine of post-merger remnants, potentially powering both a nucleosynthetically active disk wind and the relativistic jet behind a short gamma-ray burst. We explore the impact of the magnetic field on this engine by simulating three post-merger black hole accretion disks using general relativistic magnetohydrodynamics with Monte Carlo neutrino transport, in each case varying the initial magnetic field strength. We find increasing ejecta masses associated with increasing magnetic field strength. We find that a fairly robust main r -process pattern is produced in all three cases, scaled by the ejected mass. Changing the initial magnetic field strength has a considerable effect on the geometry of the outflow and hints at complex central engine dynamics influencing lanthanide outflows. We find that actinide production is especially sensitive to magnetic field strength, with the overall actinide mass fraction calculated at 1 Gyr post-merger increasing by more than a factor of 6 with a tenfold increase in magnetic field strength. This hints at a possible connection to the variability in actinide enhancements exhibited by metal-poor, r -process-enhanced stars.

79 ASTRONOMY AND ASTROPHYSICS↗

Enabling the Electrification of Offshore Activities – Co-Demonstration of Next-Generation Autonomous Offshore Power System and Resident, Uncrewed Mobile and Static Assets at PacWave Wave Energy Test Site

Oceans cover two-thirds of the earth's surface and form the world's biggest and best – yet largely untapped – battery. Ocean waves have more energy density than other renewables, including wind, solar, and biomass, and have the potential to supply 4x the world's annual energy consumption (Masterson, 2022; Zic, 2020). In addition to the impact wave energy can have on decarbonizing and diversifying the electric grid, it offers a significant value proposition in the emerging blue economy sector (LiVecchi et al, 2019). The blue economy consists of industries operating offshore, including shipping, oil and gas, defense and security, aquaculture, and research. These industries require bringing people and energy on site to perform daily work, but current energy costs in the blue economy are extremely high. Here, the prevailing processes are complex, including shore dependencies and fuel transportation logistics. Few alternatives for reliable power generation exist, with the most prominent being high cost and high carbon emissions diesel generation. Because of this lack of affordable, reliable power, the trends of electrification, digitization, and automation that have led to substantial innovation and improvements in the terrestrial economy over the last two decades are slow to come to the blue economy.

16 TIDAL AND WAVE POWER↗

Control-Oriented Model for Secondary Effects of Wake Steering

This paper presents a model to incorporate the secondary effects of wake steering in large arrays of turbines. Previous models have focused on the aerodynamic interaction of wake steering between two turbines. The model proposed in this paper builds on these models to include yaw-induced wake recovery and secondary steering seen in large arrays of turbines when wake steering is performed. Turbines operating in yaw-misaligned conditions generate counter-rotating vortices that entrain momentum and contribute to the deformation and deflection of the wake at downstream turbines. Rows of turbines can compound the effects of wake steering that benefit turbines far downstream. This model quantifies these effects and demonstrates that wake steering has greater potential to increase the performance of a wind farm due to these counter-rotating vortices especially for large rows of turbines. This is validated using numerous large-eddy simulations for three-turbine, five-turbine, and wind farm scenarios.

17 WIND ENERGY↗

Geomagnetic Euler Potentials

Perturbation scheme deriving geomagnetic Euler potentials applied to magnetospheric model with solar wind effect

EULER EQUATION↗

Study on multi-satellite, multi-measurement of the structure of the earth's bow shock

The pulsation model of the earth's bow shock proposed a nonuniform shock having both perpendicular (abrupt, monotonic) and oblique (oscillatory, multigradient) properties simultaneously, depending on local orientation of the shock surface to the interplanetary field B sub sw in parallel planes defined by B sub sw and solar wind velocity. Multiple, concurrent, satellite observations of the shock and solar wind conditions were used. Twenty-six potentially useful intervals of concurrent Explorer 33 and 35 data acquisition were examined, of which six were selected for closer study. In addition, two years of OGO-5 and HEOS 1 magnetometer data were examined for possible conjunctions to these spacecraft having applicable data. One case of clear nonuniformity and several of field-dependent structure were documented. A computational aid, called pulsation index, was developed.

Source record↗

Results of the Low Speed Aeroelastic Buffet Test with a 0.046-scale Model (747-ax1322-d-3/orbiter 8-0) of the 747 Cam/orbiter in the University of Washington Wind Tunnel (CS 3)

A series of wind tunnel studies designed to assess the potential buffet problems resulting from orbiter wake characteristics with its tailcone removed are presented to provide design loads and acceleration environments, and to develop data on buffet sensitivity to various aerodynamic configurations and flight parameters. Data are intended to support subsequent analyses of structural fatigue life, crew efficiency, and equipment vibrations.

Gillins, R. L.↗

Computational wing optimization and comparisons with experiment for a semi-span wing model

A computational wing optimization procedure was developed and verified by an experimental investigation of a semi-span variable camber wing model in the NASA Ames Research Center 14 foot transonic wind tunnel. The Bailey-Ballhaus transonic potential flow analysis and Woodward-Carmichael linear theory codes were linked to Vanderplaats constrained minimization routine to optimize model configurations at several subsonic and transonic design points. The 35 deg swept wing is characterized by multi-segmented leading and trailing edge flaps whose hinge lines are swept relative to the leading and trailing edges of the wing. By varying deflection angles of the flap segments, camber and twist distribution can be optimized for different design conditions. Results indicate that numerical optimization can be both an effective and efficient design tool. The optimized configurations had as good or better lift to drag ratios at the design points as the best designs previously tested during an extensive parametric study.

Waggoner, E. G.↗

Advanced panel-type influence coefficient methods applied to unsteady three dimensional potential flows

A panel method for solving unsteady, subsonic wind-body-tail flow problems is formulated and partially verified. The method is applicable to general aircraft configurations consisting of arbitrary arrangements of wings, bodies, tails, and nacelles. The wake may be located arbitrarily and the unsteady, transverse component of vorticity in the wake may be assigned any covection velocity. The wake in the unsteady flow problem, therefore, can be given the location and convection velocity of the wake produced by a steady flow which is the mean flow of the unsteady flow problem. The panel method has been used as a basis for expanding the unsteady kernel function in a power series to obtain panel influence coefficients which can be integrated in closed form.

Dusto, A. R.↗

Analysis of the performance of the drive system and diffuser of the Langley unitary plan wind tunnel

A broad program was initiated at the Langley Research Center in 1973 to reduce the energy consumption of the laboratory. As a part of this program, the performance characteristics of the Unitary Plan Wind Tunnel were reexamined to determine if potential methods for incresing the operating efficiencies of the tunnel could be formulated. The results of that study are summarized. The performance characteristics of the drive system components and the variable-geometry diffuser system of the tunnel are documented and analyzed. Several potential methods for reducing the energy requirements of the facility are discussed.

Hasel, L. E.↗

Fluctuating pressures on fan blades of a turbofan engine: Static and wind-tunnel investigations

To investigate the fan noise generated from turbofan engines, miniature pressure transducers were used to measure the fluctuating pressure on the fan blades of a JT15D engine. Tests were conducted with the engine operating on an outdoor test stand and in a wind tunnel. It was found that a potential flow interaction between the fan blades and six, large support struts in the bypass duct is a dominant noise source in the JT15D engine. Effects of varying fan speed and the forward speed on the blade pressure are also presented.

Schoenster, J. A.↗

Experimental investigation of forebody and wing leading-edge vortex interactions at high angles of attack

An experimental investigation was conducted to assess the vortex flow-field interactions on an advanced, twin-jet fighter aircraft configuration at high angles of attack. Flow-field surveys were conducted on a small-scale model in the Northrop 0.41 - by 0.60-meter water tunnel and, where appropriate, the qualitative observations were correlated with low-speed wind tunnel data trends obtained on a large-scale model of the advanced fighter in the NASA Langley Research Center 30- by 60-foot (9.1- by 18.3-meter) facility. Emphasis was placed on understanding the interactions of the forebody and LEX-wing vortical flows, defining the effects on rolling moment variation with sideslip, and identifying modifications to control or regulate the vortex interactions at high angles of attack. The water tunnel flow visualization results and wind tunnel data trend analysis revealed the potential for strong interactions between the forebody and LEX vortices at high angles of attack. In particular, the forebody flow development near the nose could be controlled by means of carefully-positioned radome strakes. The resultant strake-induced flow-field changes were amplified downstream by the more powerful LEX vortical motions with subsequent large effects on wing flow separation characteristics.

Erickson, G. E.↗

Accuracy of vertical velocity determination

Typical wind spectra taken at Poker Flat, Alaska, using the vertically oriented antenna show velocities of 10's of cm to meters per second and spectral widths winds of 0.5 to 1 m/s. The potential errors in such measurements can be broken down into three categories: (1) those due to instrumental parameters and data processing, (2) those due to specular returns from non-horizontal surfaces, and (3) those due to other physical effects. Error analysis in vertical velocity measurement is further discussed.

Riddle, A. C.↗

Assessment of Plasma Transport and Convection at High Latitudes

The high-latitude ionosphere is strongly coupled to the thermosphere and magnetosphere. The magnetospheric coupling occurs via electric fields, field-aligned currents, and particle precipitation. Owing to the interaction of the shocked solar wind with the geomagnetic field, an electric potential difference is generated across the tail of the magnetosphere, with the resulting electric field pointing from dawn to dusk. Energetic particle precipitation from the magnetosphere in the auroral region leads to the creation of ionization and to electron, ion, and neutral gas heating. In order to assess the current understanding of plasma transport and convection at high latitudes, it is necessary to take account of the strong coupling between the ionosphere, thermosphere, and magnetosphere.

Source record↗

Implications of large flow velocity signatures in nearly isotropic ion distributions

ISEE-1 energetic ion distributions are compared with previously published lower-energy ISEE-1 H(+) and He(2+) distributions in the quiet-time plasma sheet at about 15 earth radii and within about 1 earth radius of the expected neutral sheet position. Although moment calculations performed over the nearly isotropic H(+) and He(2+) plasma distributions yield low bulk velocities of less than 14 km/s, the spectral shapes of these signatures are indicative of high flow speeds. It is suggested that H(+) and H(2+) ions of solar wind origin were accelerated through an electrostatic potential of about 2.4 kV prior to the ISEE-1 observations in the plasma sheet on a closed magnetospheric field line, and that a second plasma sheet population existed at this ISEE-1 position in the geomagnetic field.

Williams, D. J.↗

Evidence for diabatic cooling and poleward transport within and around the 1987 Antarctic ozone hole

Atmospheric dynamics at altitudes of 17.5-19 km were analyzed using measurements of N2O, total water, total odd-nitrogen species, and potential vorticity (derived from pressures, temperatures, and wind speeds) obtained aboard the ER-2 aircraft flown in the period between August 23 and September 22 during the Airborne Antarctic Ozone Experiment. Results indicated a consistent gradual poleward movement of air, extending from about 10 deg in latitude outside the boundary of the ozone hole to about 5 deg inside. Evidence is presented of ongoing diabatic cooling throughout this zone, both inside and outside the chemically perturbed region.

Profitt, M. H.↗

N2O as a dynamical tracer in the Arctic vortex

This paper reports N2O measurements obtained by the Airborne Tunable Laser Absorption Spectrometer from 14 flights of the NASA ER-2 aircraft during the 1989 Airborne Arctic Stratospheric Expedition field campaign. In the altitude range expected for ozone loss, N2O has a long photochemical lifetime, making it an excellent tracer of lower stratospheric air motions. As in the southern hemisphere, the zonal wind speed maximum and large gradients of potential vorticity and N2O identify the vortex edge. The N2O profiles inside the vortex indicate net descent relative to outside the vortex and to the summer polar lower stratosphere. The descent of the N2O profile during the Arctic night relative to the summer profile is comparable to the downward shift in the vertical profile observed in the 1987 Antarctic winter vortex. Winter profiles at the poles are very similar above the 435 K potential temperature surface, but divergent below.

Loewenstein, M.↗

Coherent Doppler lidars: Current US 9-11 micrometer systems

To gain a proper perspective of the potential of coherent Doppler lidars for global wind sensing sometime in the future, we need to examine where we are, how we got here, and the expectations for future lidar system development. First we give a brief review of lidar developments leading to our present technology. Next we survey present U.S. infrared systems with particular attention to the pulsed systems since they are the ones that will have sufficient range to operate from satellites. Finally we comment on trends and probable future developments. Only unclassified lidars are considered. The considerable DoD support for classified applications certainly enhances future developments in components and subsystems.

Hall, Freeman F., Jr.↗